Claims
- 1. A rubber-modified rigid silicone resin comprising a copolymerized reaction product of:
- (A) an organosilicon composition selected from the group consisting of:
- (I) an organosilicone resin consisting essentially of silsesquioxane units and of the empirical formula
- R.sup.1.sub.a R.sup.2.sub.b R.sup.3.sub.c SiO.sub.(4-a-b-c)/2
- wherein: a is a positive numerical value, b and c are zero or positive numerical values with the proviso that 0.8.ltoreq.(a+b+c).ltoreq.1.6, R.sup.1, R.sup.2 and R.sup.3 are monovalent radicals independently selected from the group consisting of hydrogen, hydroxyl, alkyl, alkenyl, alkoxy, oximo, alkyloximo, aryloximo, aryl, alkylepoxide, arylepoxide, alkylcarboxyl, arylcarboxyl, alkylether, arylether, alkylamide, arylamide, alkyl amino and arylamino radicals; and
- (II) hydrolyzable precursors of (I); and
- (III) an hydrolyzate formed from (II);
- (B1) a first silicone rubber of the empirical formula:
- (R.sup.4.sub.(3-p) R.sup.5.sub.p SiO.sub.1/2)(R.sup.4.sub.2 SiO.sub.2/2).sub.x -
- {(R.sup.4.sub.(2-q) R.sup.5.sub.q SiO.sub.2/2)(R.sup.4.sub.2 SiO.sub.2/2).sub.x }.sub.y (R.sup.4.sub.(3-p) R.sup.5.sub.p SiO.sub.1/2)
- wherein each R.sup.4 is a monovalent radical independently selected from the group consisting of alkyl and aryl radicals, each R.sup.5 is a monovalent radical independently selected from the group consisting of hydrogen, hydroxyl, alkenyl, alkoxy, oximo, alkyloximo, aryloximo, alkylepoxide, arylepoxide, alkylcarboxyl, arylcarboxyl, alkylamide, arylamide, aklyl amino and arylamino radicals, p is 1, 2 or 3, q is 1 or 2, x ranges from 6 to 100, and y ranges from zero to 10; and
- (B2) a second silicone rubber of the empirical formula
- (R.sup.4.sub.(3-p) R.sup.5.sub.p SiO.sub.1/2)(R.sup.4.sub.2 SiO.sub.2/2).sub.w (R.sup.4.sub.(3-p) R.sup.5.sub.p SiO.sub.1/2)
- wherein R4, R5 and p are as defined above and w ranges from about 200 to about 1,000;
- said organosilicon composition (A) and said first and second silicone rubbers (B1) and (B2) being present in relative quantities such that said rubber-modified silicone resin has a Young's modulus of at least 6.9.times.10.sup.8 Pa.
- 2. A rubber-modified silicone resin in accordance with claim 1 wherein said copolymerized reaction product is obtained by a condensation reaction.
- 3. A rubber-modified silicone resin in accordance with claim 2 wherein said condensation reaction is carried out in the presence of a condensation catalyst.
- 4. A composition in accordance with claim 3 wherein said condensation catalyst is selected from the group consisting of choline octoate and metal esters and alkoxides of tin, titanium and zinc.
- 5. A rubber-modified silicone resin in accordance with claim 1 wherein said copolymerized reaction product is obtained by an addition reaction.
- 6. A rubber-modified silicone resin in accordance with claim 5 wherein said addition reaction is carried out in the presence of (D) an addition catalyst.
- 7. A rubber modified silicone resin in accordance with claim 6 wherein said addition catalyst is selected from the group consisting of platinum compounds and platinum complexes.
- 8. A rubber-modified silicone resin in accordance with claim 1 wherein said copolymerization reaction product further comprises a silicon-based crosslinker.
- 9. A rubber-modified silicone resin in accordance with claim 1 wherein said copolymerized reaction product is obtained by free-radical polymerization.
- 10. A rubber-modified silicone resin in accordance with claim 1 wherein said first silicone rubber (B1) is present in an amount up to 30 weight percent of said composition and said second silicone rubber is present in an amount up to 20 weight percent of said composition, with the proviso that the aggregate quantity of (B1) and (B2) does not exceed about 35 weight percent of the composition of the invention.
- 11. A composition in accordance with claim 10 wherein said first silicone rubber (B1) is present in an amount of about 10 weight percent and said second silicone rubber is present in an amount from 2.5 and 5 weight percent of said composition.
- 12. A composition in accordance with claim 1 wherein said second silicone rubber (B2) segregates from the remaining components and is present in said resin in a shape that approximates spheres.
- 13. A composition in accordance with claim 12 wherein said spheres have a diameter of 2 micrometers or less.
- 14. A composition in accordance with claim 13 wherein said spheres have a diameter of about 1 micron or less.
- 15. A composition in accordance with claim 14 wherein said spheres have a diameter ranging from 60 to 100 nanometers.
CROSS-REFERENCE TO RELATED APPLICATIONS
The present application for patent is a continuation-in-part of U.S. patent application Ser. Nos. 08/775,557 and 08/775,661, each of which was filed on Dec. 31, 1996, and now U.S. Pat. Nos. 5,830,950 and 5,747,608, respectively.
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Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
775557 |
Dec 1996 |
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