RUI - 2D Magic-Angle Spinning NMR: A New Way to Probe the Local Structure of Quasicrystals

Information

  • NSF Award
  • 9804094
Owner
  • Award Id
    9804094
  • Award Effective Date
    7/1/1998 - 26 years ago
  • Award Expiration Date
    6/30/2002 - 22 years ago
  • Award Amount
    $ 150,800.00
  • Award Instrument
    Continuing grant

RUI - 2D Magic-Angle Spinning NMR: A New Way to Probe the Local Structure of Quasicrystals

9804094Adolphi This is a new proposal from an undergraduate institution prepared by two PIs who equally co-share a tenured assistant professor position in the Physics Department of Knox College, in Galesburg, Illinois. The research is focused on the study of the structure of quasi-crystals by means of magic-angle spinning (MAS) NMR. Diffraction studies of quasi-crystals show that the patterns are very sharp, which indicates some sort of long range order. These quasi-crystals possess five-fold symmetry, a symmetry which is predicted not to exist for a periodic structure according to classical group theoretical arguments. Discovered in 1984, these quasi-crystals pose new problems for the solid state physicist who now has to expand to notion of a periodic lattice structure to allow for a quasi-perodicity. The research described in this proposal focuses on the TiZrNi metal system which will be studied by 2D MAS NMR. The proposed work is outside the realm of investigations of well established problems. It is therefore high-risk research which has the potential of good scientific payoff. Besides the two co-PIs the work will involve the participation of undergraduate students. %%% This is a new proposal from an undergraduate institution prepared by two PIs who equally co-share a tenured assistant professor position in the Physics Department of Knox College, in Galesburg, Illinois. The research is focused on the study of the structure of quasi-crystals by means of magic-angle spinning (MAS) NMR. Diffraction studies of quasi-crystals show that the patterns are very sharp, which indicates some sort of long range order. These quasi-crystals possess five-fold symmetry, a symmetry which is predicted not to exist for a periodic structure according to classical group theoretical arguments. Discovered in 1984, these quasi-crystals pose new problems for the solid state phy sicist who now has to expand to notion of a periodic lattice structure to allow for a quasi-perodicity. The research described in this proposal focuses on the TiZrNi metal system which will be studied by 2D MAS NMR. The proposed work is outside the realm of investigations of well established problems. It is therefore high-risk research which has the potential of good scientific payoff. Besides the two co-PIs the work will involve the participation of undergraduate students. ***

  • Program Officer
    Wendy W. Fuller-Mora
  • Min Amd Letter Date
    6/18/1998 - 26 years ago
  • Max Amd Letter Date
    10/26/2000 - 24 years ago
  • ARRA Amount

Institutions

  • Name
    Knox College
  • City
    Galesburg
  • State
    IL
  • Country
    United States
  • Address
    2 E South St
  • Postal Code
    614014999
  • Phone Number
    3093417000

Investigators

  • First Name
    Andrew
  • Last Name
    McDowell
  • Email Address
    andrew.mcdowell@detect-ors.com
  • Start Date
    6/18/1998 12:00:00 AM
  • First Name
    Natalie
  • Last Name
    Adolphi
  • Email Address
    nadolphi@nmr.org
  • Start Date
    6/18/1998 12:00:00 AM