This application claims the benefit of the filing dates of U.S. Provisional Application Ser. No. 60/068,347, filed Dec. 19, 1997 and U.S. Provisional Application Ser. No. 60/064,508, filed Nov. 5, 1997, and is a continuation-in-part of U.S. patent application Ser. No. 08/842,251, filed Apr. 24, 1997, which in turn claims the benefit of the filing dates of U.S. Provisional Application Ser. No. 60/016,554, filed Apr. 30, 1996, and U.S. Provisional Application Ser. No. 60/033,257, filed Dec. 6, 1996, all of which are incorporated herein by reference in their entirety.
Number | Name | Date | Kind |
---|---|---|---|
3117952 | Meriwether | Jan 1964 | |
3597403 | Ofstead | Aug 1971 | |
3798175 | Streck et al. | Mar 1974 | |
3855323 | Lyons | Dec 1974 | |
3857825 | Streck et al. | Dec 1974 | |
3957827 | Lyons | May 1976 | |
3962294 | Lyons | Jun 1976 | |
4323508 | Herrington et al. | Apr 1982 | |
5312940 | Grubbs et al. | May 1994 | |
5324616 | Sacripante et al. | Jun 1994 | |
5342909 | Grubbs et al. | Aug 1994 | |
5405924 | Kelsey | Apr 1995 | |
5491206 | Brown-Wensley et al. | Feb 1996 | |
5559262 | Beatty et al. | Sep 1996 | |
5599962 | Beatty et al. | Feb 1997 | |
5710298 | Grubbs et al. | Jan 1998 | |
5726334 | Beatty et al. | Mar 1998 | |
5728785 | Grubbs et al. | Mar 1998 | |
5728917 | Grubbs et al. | Mar 1998 | |
5750815 | Grubbs et al. | May 1998 | |
5831108 | Grubbs et al. | Nov 1998 | |
5849851 | Grubbs et al. | Dec 1998 | |
5880231 | Grubbs et al. | Mar 1999 | |
5900521 | Park et al. | May 1999 | |
5912376 | Van Der Schaaf et al. | Jun 1999 | |
5917071 | Grubbs et al. | Jun 1999 | |
5919962 | Sayo et al. | Jul 1999 | |
5929289 | Abatjoglou et al. | Jul 1999 | |
5939504 | Woodson, Jr. et al. | Aug 1999 | |
5977393 | Grubbs et al. | Nov 1999 | |
5981421 | Paez et al. | Nov 1999 | |
5998326 | Hafner et al. | Dec 1999 | |
6048993 | Grubbs et al. | Aug 1999 |
Number | Date | Country |
---|---|---|
0 366 390 | May 1990 | EPX |
0839821 | May 1998 | EPX |
WO 9102588 | Mar 1991 | WOX |
WO 9215400 | Sep 1992 | WOX |
WO 9616100 | May 1996 | WOX |
WO 9620235 | Jul 1996 | WOX |
9740934 | Nov 1997 | WOX |
9839346 | Sep 1998 | WOX |
Entry |
---|
C. Grunwald et al., Advance ACS Abstracts, vol. 4, No. 6, p. 140, Mar. 15, 1996. |
Gruenwald, C., et al., "Five-Coordinate 16-Electron Carbene-and Vinylideneruthenium (II) Complexes Prepared from [RuCI2(C8H12)]n or from the New Dihydridoruthenium (IV) Compound [RuH2CI2(PiPr3)2]", Organometallics (1996), 15: 1960-1962. |
Demonceau, A., et al., Novel Ruthenium-Based Catalyst Systems for the Ring-Opening Metathesis Polymerization of Low-Strain Cyclic Olefins, Macromolecules (1997), 30: 3127-3136. |
K.J. Ivin, "Summary of Catalyst Systems", Olefin Metathesis, Academic Press, New York, 1983, p. 34. |
Porri, L., et al., "Ring-Opening Polymerization of Cycloolefins with Catalysts Derived from Ruthenium and Iridiuim", Die Makromolekulare Chemie, 1974, 175: 3097-3115. |
Demonceau, A., et al., "Ruthenium-catalysed ring-opening metathesis polymerization of cycloolefins initiated by diazoesters", J. Mol. Catal, 1992, 76: 123-132. |
Stumpf, A.W., et al., "Ruthenium-based Catalysts for the Ring Opening Metathesis Polymerization of Low-strain Cyclic Olefins and of Functionalised Derivatives of Norbornene and Cyclooctene", J. Chem. Soc., Chem. Commun., 1995, pp. 1127-1128. |
Schwab, P., et al., A "Series of Well-Defined Metathesis Catalysts--Synthesis of [RuCI2(=CHR') (PR3)2] and Its Reactions", Angew. Chem. Int. Ed. Engl., 1995, 34: 2039-2041. |
Schwab, P., et al., "Synthesis and Applications of RuCI2(=CHR')(PR3)2: The Influence of the Alkylidene Moiety on Metathesis Activity", J. Am. Chem. Soc., 1996, 118: 100-110. |
Creary, X., "Tosylhydrazone Salt Pyrolyses: Phenyldiazomethanes", Org. Synth., Coll. vol. 7, 1990, pp. 438-443. |
Number | Date | Country | |
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Parent | 842251 | Apr 1997 |