The invention relates to a sampler for sampling a mixture of a medium and particles of a solid.
When a combustible substance is burned, the quality of burning may be measured by sampling a combustion gas in the combustion chamber, the combustion gas being a heterogeneous mixture of a continuous gas phase and solid particles, and by measuring the amount of one or more substances in the sample, for instance, as a concentration. The gas phase generally comprises various gases produced in the combustion and gases entered into the combustion chamber from the environment.
Loom The sampler may comprise, for instance, a probe locating in the combustion chamber and a pipe between the probe and a measuring part. A sample may be sucked by vacuum into the probe in the combustion chamber, wherefrom the pipe conveys the sample into the measuring part. Because the gas phase, especially, indicates the quality of combustion, the probe includes a filter that prevents access of at least major particles into the measurement. In addition, the filter prevents particles from blocking the pipe and the measuring part.
Sampling involves problems, however. Particles adhere to the filter in the probe all the time, whereby filtering capacity of the filter changes. This may change the measurement result constantly, and consequently it is difficult to obtain reliable information on the action of the combustion process. In addition, the filter may be blocked quickly, and it does not allow a gas sample to pass through at all, or only to an excessively small extent, and therefore the filter has to be replaced frequently. Replacing may be cumbersome, however, and it may require that the combustion process be extinguished. Even though the combustion process would not have to be extinguished, the filter replacement interrupts sampling and measuring, and thus prevents continuous sampling and measuring of the combustion process.
The replacement interval of the filters may be prolonged by cleaning the filters. Even though it may not be necessary to displace the filter for cleaning it, but the filter may be cleaned, for instance, by pressurized gas against the sampling, yet the cleaning operation interrupts the sampling and the measurement frequently.
On account of the above, there is a need for improved sampling of a heterogeneous mixture containing a gas phase and particles of a solid.
It is an object of the invention to provide an improved sampler. This is achieved by a sampler of claim 1.
The invention relates to a method for sampling in accordance with claim 9.
Preferred embodiments of the invention are disclosed in the dependent claims.
The sampler of the invention provides several advantages. No separate filter is needed for filtering a mixture sample to be introduced into an ejector, which enables continuous sampling. Thus, there is no need for cleaning and/or replacing the filters either.
The invention will now be described in greater detail by means of preferred embodiments, with reference to the accompanying drawings, in which:
As regards
The ejector 100 acting as the probe in the sampler and the sample channel 112 extending thereto may be placed in a heterogeneous mixture 102 of a gas phase and particles of a solid. The ejector 100 may also be placed in a heterogeneous mixture 102 of a liquid phase and particles of a solid. The mixture 102 may contain e.g. smoke, dust, ash, sand, air or the like. The sampler may sample smoke, for instance, in such a manner that the ejector 100 and the sample channel 112 extending thereto are in the combustion chamber where the combustion reaction takes place. In a combustion reaction, a combustible substance reacts with oxygen, which releases thermal energy. Therefore, it may be very hot in the combustion chamber, e.g. over 100° C. or even over 1000° C. Despite the heat, separation of the solid particles and the medium and sampling may be carried out in the combustion temperature.
The sampler may also be used in dusty processes, other than combustion chambers, for taking measuring samples. In addition, apart from gas, a liquid is also a possible medium for particles of a solid. The mixture sample 110 may be, for instance, sludge wherefrom the amount of solid particles may be reduced, or the size distribution of solid particles may be altered in the ejector 100 on the basis of flow and inertia.
In the following, embodiments are described using a mixture of solid particles and a gas as an example.
The sample channel 112 of the sampler, which may also be a pipe connected to the outer pipe 106 of the ejector 100, takes a measuring sample 122 of the mixture sample 110 locating inside the outer pipe 106. The measuring sample 122 may be taken, for instance, by means of partial vacuum that draws the measuring sample 122 from the mixture sample 110 into the sample channel 112. The vacuum in the sample channel 112 exceeds the vacuum produced by the ejector 100, which means that the pressure in the sample channel 112 is lower than in the ejector 100.
The sample channel 112 is employed to take a desired measuring sample 122 of the mixture sample 110 flowing inside the ejector 100 into the sample channel 112. The desired measuring sample 122 may refer, for instance, to the fact that the particle size of the solid in the measuring sample 122 is smaller than a predetermined limit size. The desired measuring sample may also refer, for instance, to the fact that the particle density of the solid in the measuring sample 122 is lower than a predetermined limit density. The desired measuring sample may also refer, for instance, to the fact that the mass of the particles of the solid in the measuring sample 122 is lower than a predetermined limit mass. The desired measuring sample 122 is obtained by separating the particles of the solid and the medium from one another in the ejector 100 on the basis of the flow and inertia of the mixture sample 110. It is possible to affect the characteristics in the solid particles of the measuring sample 122 by how the sample channel 112 is placed in the ejector 100 and by the direction in which the measuring sample 122 is taken in relation to the flow of the mixture sample 110 in the ejector 100.
The sample channel 112 may be placed in the end 120 of the ejector 100 that is opposite to the outlet 116 of the ejector 100. The inner pipe 104 of the ejector 100 extends further than the sample channel 112 inside the outer pipe 106 of the ejector 100. The end 124 of the inner pipe 104 may be fairly close to the outlet 116 inside the outer pipe 106, but the end 128 of the sample channel 112 is not located in the immediate vicinity of the outlet 116. In general, the end 124 of the inner pipe 104 may be located at the point which is between the midway of the outer pipe 106 and the outlet 116. Whereas, in general, the end 128 of the sample channel 112 may be located in an area between the midway of the outer pipe 106 and the end 120.
The space 126 in the outer pipe 106 remaining between the end 124 of the inner pipe 104 and the end 120 contains the mixture sample 110, of which the measuring sample 122 is taken with the sample channel 112, because the sample channel 112 extends to this space 126. Because there is a separating distance 130 between the end 124 of the inner pipe 104 and the end 128 of the sample channel 112, the fluid generating vacuum and discharging from the inner pipe 104 does not mix unintentionally with the measuring sample 122. Thus is obtained a clean measuring sample 122, which is advantageous to accurate measurement.
In the space 126 of the outer pipe 106 between the end 124 of the inner pipe 104 and the end 120 the principal flow direction of the mixture sample 110 is towards the outlet 116 as indicated by the arrows. The flow may be laminar and/or turbulent. The gas in the mixture sample 110 is able, however, to spread in the space 126. The sample channel 112 may suck a measuring sample 122 out of the mixture sample 110 in a direction deviating from the flow direction of the mixture sample 110. In
When the flow direction of the mixture sample 110 and the sampling direction of the measuring sample 122 differ from one another, due to solid particle inertia the particles of the solid tend to continue in their direction of motion towards the outlet 116, but the gas in the mixture sample 110 may more readily change its direction and enter the sample channel 112. The larger the angle between the flow direction of the mixture sample 110 and the flow direction of the measuring sample 122 in the sample channel 112, the more difficult for the solid particle to change its direction of motion and the more unlikely said particle ends up in the sample channel 112. In addition, the larger the mass of the solid particle, the more unlikely said particle will be transferred into the sample channel 112. The likelihood for the solid particle to be included in the measuring sample in the sample channel 112 also reduces as the flow rate of the mixture sample 110 increases. Inertia thus separates the solid particles and the gas from one another and inertia may be utilized in taking the measuring sample 122 into the sample channel 112 in such a manner that solid particles in the measuring sample 122 will be sufficiently or completely avoided. Tiny particles, if there are any in the mixture sample 110, may access the sample channel 112 along with the measuring sample 122.
Because the flow rates of the mixture sample 110 and the measuring sample 122 and/or the angles of flow direction may be set as desired, it is possible to affect the size and/or weight distribution of the solid particles entering the sample channel 112, To put it simply, the place, the flow rate and/or the difference in flow directions may define the threshold mass or threshold size under which particles are allowed in the sample channel 112. It is often desired that the measurement includes tiny solid particles in addition to gas.
When the mixture sample 110 flows without any particular turbulence from the inlet 108 towards the outlet 116 and when the measuring sample 122 is taken of the mixture sample 110, the principle of sampling is similar to that of a virtual impactor, with the exception that in the present solution the sampling is performed on the gas, not on the particles. In addition to the measuring sample, however, it is also possible to take a sample of particles. When mainly a gas sample is measured, blocking and fouling of the measuring devices are avoided. In addition, in the measurement it is possible to eliminate measurement of substances bound to the particles. Further, the concentration of gas to be measured may be determined.
To provide turbulent motion at least one inlet 108 may be a pipe on the outer periphery of the ejector 100, the central axis of the pipe being directed tangentially to the inner surface of the outer pipe 106 of the ejector 100. To place the inlet 108 in the ejector 100 in this manner brings the mixture sample 110 to the turbulent motion in the ejector 100 following the inner surface of the outer pipe 106 of the ejector 100. The mixture sample 110 sampled in the mixture 102 with vacuum by the ejector 100 is thus in turbulent motion about the longitudinal axis of the ejector 100 parallel with the flow-through.
The sampler also comprises a sample channel 112 whereby a measuring sample 122 may be taken, in the direction of the longitudinal axis, in the centre of the ejector 100 where the particles of the mixture sample 110 are smallest. Thus, when the end 128 of the sample channel 122 is placed in the ejector 100 to a location where the turbulent flow of the mixture sample 110 renders the distribution of solid particles different from that elsewhere in the mixture sample 110, the mixture sample 110 may be sampled for a desired measuring sample 122. The desired measuring sample 122 contains solid particles of a desired size. To put it simply, the place, the flow rate and/or the difference in flow directions may define the threshold mass or threshold size under which particles are allowed to drift along with the gas into the sample channel 112.
The sample channel 112 may also be a pipe whose cross section may be the same as that of the inner and outer pipes 104, 106 of the ejector 100. The sample channel 112 may surround the inner pipe 104, i.e. the sample channel 112 and the inner pipe 104 may be nested as shown in
In an embodiment the measuring sample 122 is not necessarily diluted with any fluid prior to measurement. Undilutedness enables elimination of errors resulting from dilution in the measurement. In fact, it will be sufficient for the measurement that the temperature of the measuring sample 122 can be lowered to an appropriate measuring temperature during the sample transfer. An appropriate measuring temperature may be, for instance, a water boiling temperature or a temperature below that. In particular, an undiluted measuring sample 122 can be measured for moisture in the measuring sample 122, for instance. Yet, it is also possible to measure a diluted measuring sample 122 for moisture.
In
In the case of other
In an embodiment the combustion chamber 400 is a steam turbine boiler.
In an embodiment the combustion chamber 400 is a boiler which burns cooking liquor used in pulp making. The cooking liquor to be burnt may be e.g. black lye or the like.
In an embodiment the combustion chamber 400 may be a boiler of a heat distribution centre.
In an embodiment the combustion chamber 400 is a lime sludge reburning kiln.
The measurement may be carried out in such a manner that a measuring sample 122 is transferred along the sample channel 112 to a measuring part, for instance, where optical, chemical and/or other measurements may be performed to find out the properties of the mixture. The direction of transfer in the sample channel may be opposite to the feed direction of the fluid 118 generating vacuum.
The ejector 100 need not have a mechanical filter at the inlet 108 for filtering large particles from sampling, because apart from the measuring sample 122 both the gas and all the solid particles sucked into the ejector 100 are also blown out of the ejector 100. The measuring sample 122 will not contain much solid particles, or they are below a predetermined limit in size, because the flow of the mixture sample 110 takes the solid particles of highest density and largest size with it and only the measuring sample 122 will enter the sample channel 112.
In the cyclone solution, it is highly likely that solid particles escape from the centre of the ejector 100, because the density of solid particles is higher than that of the gas. In fact, the speed of the turbulent motion determines at least partly how effectively the solid particles disappear from the centre of the ejector, and consequently also how clean the measuring sample 122 to be taken will be. As the speed of the turbulent motion increases, the size of the solid particles appearing in the centre of the ejector 100 is smaller and smaller.
In this manner the filtering is performed dynamically in both impactor-type and cyclone-type sampling without a mechanical filter whose meshes define the largest diameter of solid particles allowed through the filter.
Because there is no need for a filter to prevent solid particles from accessing the measurement, or the filter used has so large meshes that it does not get fouled or blocked and it does not directly define the size of solid particles found in the measuring sample 122, the sampling need not be interrupted to replace or clean the filter. Thus, the sampling may be continuous without interruptions. In addition, several advantages are achieved, because the ejector 100, which takes the mixture sample 110 from the mixture 102 of solid particles and a medium, dynamically filters the mixture sample 110 for a measuring sample 122 into the sample channel 112 and returns the remaining mixture sample 110 into the mixture 102 after sampling the measuring sample 122, is placed in the mixture 102 of solid particles and a medium.
If the mixture sample 110 was not processed on the sampling site, but it would be transferred somewhere outside the mixture 102, the measuring sample 122 might change chemically and structurally. A change may occur as a function of time and/or through an environmental effect. The environmental effect may be a change in temperature, for instance. A change in the mixture sample 110 due to transfer also complicates the processing of the mixture sample 110. For instance, it may become more difficult or impossible to provide a desired measuring sample 122 from the mixture sample 110 for reasons resulting from the transfer. This applies to a measuring sample 122 taken in the combustion chamber 400, for instance.
Whereas, if the mixture sample 110 were not returned back into the mixture 102, a problem would arise where to place the residual mixture sample. Now that it is returned back to where it comes from, no new problem will arise.
Even though the invention is described above with reference to the examples of the attached drawings, it is clear that the invention is not restricted to them, but may be modified in a variety of ways within the scope of the accompanying claims.
Number | Date | Country | Kind |
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20115703 | Jul 2011 | FI | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/FI2012/050679 | 6/28/2012 | WO | 00 | 12/24/2013 |