Patent Grant
8808264
This invention relates to absorbent articles such as catamenial devices and light incontinence products. In particular, this invention relates to catamenial devices such as sanitary napkins having improved comfort and body fit.
Sanitary napkins and related disposable absorbent articles that provide for the collection of menses and other bodily discharges are well known in the art. It has long been an object of those designing sanitary napkins to make them such that they readily intercept menses upon discharge from the wearer. Such sanitary napkins have long had a means, typically pressure sensitive adhesive, for affixing the sanitary napkin to the undergarment of the wearer and maintaining the sanitary napkin in the proper position to intercept the discharged menses.
However, the undergarment may not, in fact, move in concert with the body of the wearer. Specifically, the crotch of the undergarment of the wearer may not remain in constant registration with and position relative to the vaginal opening. Also, as the wearer walks, runs, sits, etc., the sanitary napkin may not flex and twist with the undergarment, thereby stressing the means for affixing the sanitary napkin to the undergarment of the wearer. In fact, the sanitary napkin may be detached from the undergarment.
Several attempts have been made to provide a sanitary napkin which may be attached to the undergarment of the wearer and also maintain the constant position with respect to the body of the wearer. For example, U.S. Pat. No. 4,425,130 issued Jan. 10, 1984 to DesMarais discloses a sanitary napkin having decoupled components joined to one another at the transverse or end edges.
Other attempts have been made in the art to provide a sanitary napkin which maintains contact of the topsheet with the body of the wearer. For example, U.S. Pat. No. 4,804,380, issued Feb. 4, 1989 to Lassen et al. discloses a three dimensionally shaped sanitary protecting device that claims to readily fit and align itself with the wearer's anatomy. However, the structure of Lassen does not provide the aforementioned independence of movement between the body of the wearer and the undergarment.
U.S. Pat. No. 5,007,906 issued Apr. 16, 1991 to Osborn, III et al. discloses a sanitary napkin having a topsheet and an absorbent core. The topsheet and core are decoupled from the backsheet of the sanitary napkin allowing the topsheet and backsheet to be separated from one another in the Z-direction. However, the decoupled topsheet and core of Osborn does not provide the desired body conformance.
Accordingly, there is a need for a disposable absorbent article having improved body fit that can be simply and economically manufactured.
Additionally, there is a need for a sanitary napkin capable of reliably achieving an improved body-fitting profile.
An absorbent article providing improved body fit is disclosed. The absorbent article has a longitudinal axis and a periphery. The absorbent article includes an extensible fluid permeable facing layer and a first absorbent layer joined to the facing layer. The first absorbent layer includes zones of extensibility. Each zone of extensibility is a region of the first absorbent layer of relatively higher extensibility than regions of first absorbent layer adjacent to the zone of extensibility. A liquid impermeable backsheet is joined to the facing layer at the periphery. The liquid impermeable backsheet has a garment facing surface. A fastening means is disposed on at least a portion of the garment facing surface of the liquid impermeable backsheet. The fastening means defines attachment zones. At least a portion of the first absorbent layer is decoupled from the attachment zones of the fluid impermeable backsheet.
While the benefits of the present invention can be enjoyed in virtually all feminine hygiene products designed to be worn in the panties of the wearer, such as sanitary napkins, pantiliners, and light incontinence products, the invention will be disclosed with respect to the Figures as a preferred embodiment of a sanitary napkin.
The term “extensible,” as used herein refers to webs or articles that, upon application of a force, can increase in at least one of their dimensions (e.g., in the MD-CD plane when in a substantially flat condition) sufficiently to permit three-dimensional deformation of the facing layer 21 and the first absorbent layer 24 for body fit and comfort, as discussed below. During use extensibility is preferably due to the naturally occurring forces imposed by the wearer's body and panties when the wearer uses the article of the present invention. The term extensible includes articles that are stretchable and elastically stretchable (defined below). Extensible materials or portions of materials, including in zones of extensibility referred to herein, preferably are extensible at least 5% under forces of less than or equal to about 800 grams, preferably less than or equal to about 400 grams, and most preferably less than or equal to about 300 grams.
The term “stretchable”, as used herein, refers to articles that are extensible when stretching forces are applied to the article and offer some resistance to stretching.
As used herein the term “joined” refers to the condition where a first member is attached, or connected, to a second member either directly; or indirectly, where the first member is attached, or connected, to an intermediate member which in turn is attached, or connected, to the second member.
As used herein the term “decoupled” refers to the independence of movement of two components of the sanitary napkin 20 and requires separability of such components, at least within the range of movement experienced by the components during use.
As used herein, the term “nonwoven web” refers to a web having a structure of individual fibers or threads which are interlaid, but not in a regular, repeating manner as in a woven or knitted fabric. Nonwoven webs or fabrics have been formed from many processes, such as, for example, meltblowing processes, spunbonding processes, hydroentangling processes, and bonded carded web processes. The basis weight of nonwoven fabrics is usually expressed in grams per square meter (gsm) and the fiber diameters are usually expressed in microns. Fiber size can also be expressed in denier. The basis weight of nonwoven webs useful as components of the present invention, such as the facing layer 21 (which can be a single layer or a composite of more than one layer), can range from 10 gsm to 200 gsm.
The constituent fibers of nonwoven webs can be polymer fibers, and can be monocomponent, bicomponent, and/or biconstituent, capillary channel fibers, and can have major cross-sectional dimensions (e.g., diameter for round fibers) ranging from 5-200 microns. The constituent fibers can range from about 0.1 denier to about 100 denier.
As used herein, “spunbond fibers” refers to small diameter fibers that are formed by extruding molten thermoplastic material as filaments from a plurality of fine, usually circular capillaries of a spinneret with the diameter of the extruded filaments then being rapidly reduced. Spunbond fibers are generally not tacky when they are deposited on a collecting surface. Spunbond fibers are generally continuous and have average diameters (from a sample of at least 10) larger than 7 microns, and more particularly, between about 10 and 40 microns.
As used herein, the term “meltblowing” refers to a process in which fibers are formed by extruding a molten thermoplastic material through a plurality of fine, usually circular, die capillaries as molten threads or filaments into converging high velocity, usually heated, gas (for example air) streams which attenuate the filaments of molten thermoplastic material to reduce their diameter, which may be to microfiber diameter. Thereafter, the meltblown fibers are carried by the high velocity gas stream and are deposited on a collecting surface, often while still tacky, to form a web of randomly dispersed meltblown fibers. Meltblown fibers are microfibers which may be continuous or discontinuous and are generally smaller than 10 microns in average diameter.
As used herein, the term “polymer” generally includes, but is not limited to, homopolymers, copolymers, such as for example, block, graft, random and alternating copolymers, terpolymers, etc., and blends and modifications thereof. In addition, unless otherwise specifically limited, the term “polymer” includes all possible geometric configurations of the material. The configurations include, but are not limited to, isotactic, atactic, syndiotactic, and random symmetries.
As used herein, the term “monocomponent” fiber refers to a fiber formed from one or more extruders using only one polymer. This is not meant to exclude fibers formed from one polymer to which small amounts of additives have been added for coloration, antistatic properties, lubrication, hydrophilicity, etc. These additives, for example titanium dioxide for coloration, are generally present in an amount less than about 5 weight percent and more typically about 2 weight percent.
As used herein, the term “bicomponent fibers” refers to fibers that have been formed from at least two different polymers extruded from separate extruders but spun together to form one fiber. Bicomponent fibers are also sometimes referred to as conjugate fibers or multicomponent fibers. The polymers are arranged in substantially constantly positioned distinct zones across the cross-section of the bicomponent fibers and extend continuously along the length of the bicomponent fibers. The configuration of such a bicomponent fiber may be, for example, a sheath/core arrangement wherein one polymer is surrounded by another, or may be a side-by-side arrangement, a pie arrangement, or an “islands-in-the-sea” arrangement.
As used herein, the term “biconstituent fibers” refers to fibers that have been formed from at least two polymers extruded from the same extruder as a blend. The term “blend” is defined below. Biconstituent fibers do not have the various polymer components arranged in relatively constantly positioned distinct zones across the cross-sectional area of the fiber and the various polymers are usually not continuous along the entire length of the fiber, instead usually forming fibrils which start and end at random. Biconstituent fibers are sometimes also referred to as multiconstituent fibers.
As used herein, the term “capillary channel fibers” refers to fibers having capillary channels capable of facilitating fluid movement via capillarity. Such fibers can be hollow fibers, for example, but are preferably fibers having capillary channels on their outer surfaces. The capillary channels can be of various cross-sectional shapes such as “U-shaped,” “H-shaped,” “C-shaped,” and “V-shaped.”
The sanitary napkin 20, as well as each layer or component thereof can be described as having a “body facing” surface and a “garment facing” surface. As can be readily understood by considering the ultimate use for sanitary napkins, the body facing surfaces are the surfaces of the layers or components that are oriented closer to the body when in use, and the garment facing surfaces are the surfaces that are oriented closer to the undergarment of the user when in use. Therefore, for example, facing layer 21 has a body facing surface 30 (that can actually be a body contacting surface), and a garment facing surface 31 that is the surface that can be adhered to the underlying first absorbent layer 24. The garment facing surface 32 of the fluid impermeable backsheet 22 of a sanitary napkin, for example, is oriented closest to, and may contact, the wearer's panties in use (via adhesive attachment means, if used).
Sanitary napkin 20 has a longitudinal axis L, a transverse axis T and a vertical axis H. Longitudinal axis L and transverse axis T define a two-dimensional plane of the sanitary napkin prior to use, which, in the embodiment shown is associated with the machine direction (MD) and cross machine direction (CD) as is commonly known in the art of making sanitary napkins in high-speed commercial production lines. The sanitary napkin 20 has a length, which is the longest dimension measured parallel to the longitudinal axis L. The sanitary napkin has a width, which is the dimension measured in the CD, e.g., parallel to the transverse axis. The width can vary or be substantially constant along the length of the sanitary napkin. In general, the width can be measured between lateral edges 29 parallel to the transverse axis T. Without being bound by theory, it is believed that the width should be sufficient to be effective in facilitating portions of the sanitary napkin to be deformed “out-of-plane,” i.e., buckled, or deflected upwardly by the lateral, i.e., inward, compression forces of the wearer's thighs when the sanitary napkin is used. In general, by “out-of-plane” is meant extending in the “Z”-direction, as indicated by
Sanitary napkin 20 can have side extensions 28, commonly referred to as “wings,” designed to wrap the sides of the crotch region of the panties of the user of sanitary napkin 20. Sanitary napkin 20 and/or wings 28 can have fastening means including attachment components, such as pressure sensitive adhesive, or mechanical fasteners such as hook and loop fasteners. The sanitary napkin 20 shown in
In general, the presence of fastening means defines an attachment zone that is coextensive with the fastening means. The attachment zone is the portion of the sanitary napkin, typically the backsheet thereof, that is fixed with respect to the wearer's panties. Thus, the attachment zone(s) must move in a one-to-one correspondence with the panty when the wearer moves. As discussed more fully below, one benefit of the present invention is a decoupling of the body-contacting portions of the sanitary napkin from the attachment zones. This decoupling improves body fit and comfort to the wearer of the sanitary napkin.
The sanitary napkin 20 can be made by hand or on commercial high-speed production lines as is known in the art.
To conform to the wearer's body, both statically and dynamically, the sanitary napkin must bend multi-axially, and the bending required is different at different locations along the longitudinal axis thereof. Moreover, to provide for increased body fit and comfort over longer periods of time, the sanitary napkin must be capable of adapting to the widely varying pudendal anatomies of different women, as well as the dynamically changing shape with their body movements during use. Body fit and comfort, both statically and dynamically, are provide for by the structure of the sanitary napkin of the present invention.
The sanitary napkin 20 of the present invention achieves improved static and dynamic body fit by providing zones of extensibility in the first absorbent layer wherein the zones of extensibility are decoupled from the attachment zones. As shown in
It is recognized that the forces applied to the sanitary napkin 20 of the present invention can be relatively low, such as the forces applied by the wearer's labia while walking Therefore, while it is recognized that all materials typically used in a sanitary napkin have some extensibility, the portions rendered extensible in the zones of extensibility 33 readily extend under the relatively low forces exerted by portions of the wearer's body for dynamic body fit and comfort. Another way of describing this property, therefore, is that the zones of extensibility 33 have a relatively lower elastic modulus, i.e., Young's modulus, than the adjacent non-rendered portions.
Extensibility can be rendered in the zones of extensibility 33 by means known in the art, such as by the method commonly referred to as “ring rolling” in which the portion to be rendered extensible is processed through the nip of counter-rotating, grooved rollers to locally incrementally stretch the rendered portion. Such methods are disclosed, for example, in U.S. Pat. Nos. 5,916,661 and 5,628,097. Likewise, extensibility can be rendered by similar means in which one of the counter-rotating rollers comprises teeth to form regions of extensibility comprising a plurality of spaced-apart rib-like elements, as disclosed in U.S. Pat. No. 5,518,801.
In a preferred embodiment, as shown in
Such slits can permit multi-axis bending, such as simultaneous bending about the longitudinal axis L to form an inverted V-shape that can itself be bent about an axis parallel to transverse axis T as shown in
As shown in
As shown in
The sanitary napkin, therefore, can be described as an absorbent article for absorption of human exudate comprising a liquid impermeable backsheet, an extensible fluid permeable facing layer and an absorbent layer therebetween, and comprising a front portion adapted to form a flattened or concave portion for positioning exterior of the clitoris and pubic mons and a rearward portion adapted to yield a raised peak having a length and forming the pad into an inverted V shape for positioning in alignment with the creases of the perineum and buttocks, and wherein the liquid impermeable backsheet, the extensible fluid permeable facing layer and the absorbent layer are adapted to permit the raised peak to multi-axially articulate.
The specific extensibility and modulus can be adjusted by adjusting the size and spacing of zones of extensibility 33, and the optimum design based on the size and configuration of sanitary napkin 20 can readily be determined by those skilled in the art. For typical materials used in sanitary napkins, zones of extensibility covering a total of from about 10% to about 50% of first absorbent layer 24 can be used and the zones of extensibility can be sized and spaced so as to have generally equally-sized non-extensible zones adjacent zones of extensibility. In one embodiment, in a sanitary napkin similar to that shown in
Because zones of extensibility 33 can be formed by methods such as slitting that can be performed relatively easily at the high speeds necessary for commercial production, sanitary napkins 20 of the present invention provide improved body fit that can be simply and economically manufactured. By providing such an easily manufactured structure, the first absorbent layer 24 can be made flat, and yet be adaptable to conform to the body of the wearer by folding. Further, the folds or ridges formed by folding can also articulate about any of axes L, T, or H during wearing and movement by the user, so that an improved fitting sanitary napkin is achieved. Thus, in one embodiment, the invention can be described as a sanitary napkin having a generally flattened pre-use configuration that can be described as being in a plane defined by the L and T axes, in which, upon use, portions of the sanitary napkin dynamically conform to the wearer's body. By dynamically conform is meant that, upon being worn next to the body in a panty of the wearer, the sanitary napkin is adapted to form a longitudinally-aligned fold, e.g., an inverted V shaped fold 40 about longitudinal axis L, and, unlike prior art sanitary napkins, the longitudinally-aligned fold can itself articulate about axes parallel to either the transverse axis T or axis H.
Facing layer 21 can comprise nonwoven materials or apertured polymer films as are known in the art for topsheets on disposable absorbent articles, and the facing layer can be extensible or have at least portions being extensible. For example, facing layer 21 can comprise an apertured polymer film sold under the trade name DRI-WEAVE® by The Procter & Gamble Co., Cincinnati, Ohio, or an apertured formed film as disclosed in U.S. Pat. No. 4,629,643, obtained from Tredegar Film Products, Terre Haute, Ind. under the designation X27121. If additional extensibility of facing layer 21 is desired, facing layer 21 or portions thereof can be rendered extensible. Portions to be zones of enhanced extensibility can be rendered extensible by the same methods described above with respect to rendering zones of extensibility in first absorbent layer 24. In general, since facing layer 21 and first absorbent layer 24 are bonded sufficiently to be, in effect, a laminate material, in a preferred embodiment facing layer 21 is sufficiently extensible, or rendered sufficiently extensible in zones of enhanced extensibility 43, as shown in
First absorbent layer 24 (and second absorbent layer 25, if used), and backsheet 22 can comprise absorbent materials, and liquid impermeable film materials, respectively, as is well known in the art. Extensions 28, e.g., wings, if used, can be integral extensions of the facing layer or the backsheet or both, and they can be symmetric about the longitudinal axis L, transverse axis T, or both.
Nonwoven webs used in the present invention can be any known nonwoven webs or composites of two or more nonwoven webs. Nonwoven webs used in the present invention can comprise fibers that can be monocomponent, bicomponent, biconstituent, capillary channel fibers or combinations thereof. For use as the facing layer 21, nonwoven webs used in the present invention should be extensible.
Sanitary napkins of the present invention provide for improved body fit, as well as improved comfort, while absorbing all or most of any fluid discharges experienced by the wearer. These advantageous properties are a result of the shape the sanitary napkin takes on during use. Although provided in a generally flat configuration, upon use portions of a sanitary napkin of the present invention deform upwardly, i.e., toward the wearer's body, such that the body-facing surface of the napkin is in close proximity, or even in contact with, the wearer's body at the point of fluid discharge, thereby enhancing both the comfort of the wearer and the performance of the sanitary napkin. Moreover, an important improvement provided by the sanitary napkin 20 of the present invention is that the upwardly-deformed portion, e.g., ridge 40 can articulate about multiple axes under relatively low forces exerted by the wearer's body in the pudendal region, thereby permitting the sanitary napkin to dynamically conforming during use.
Joining of the facing layer 21 and the first absorbent layer 24 can be by any means known in the art, such as by adhesive bonding, thermal bonding, ultrasonic bonding, and the like. While complete bonding at interface is not necessary, or even desirable, it is believed that the bonding should be sufficient to facilitate the components act, as a unit, e.g., bending out-of-plane together. The facing layer 21 and first absorbent layer 24 can be joined, at least in portions intermediate zones of extensibility 33 by Findley HX1500-1 meltblown adhesive applied at a loading of approximately 6.4 gsm. Alternatively, the facing layer 21 and first absorbent layer 24 can be joined in selected regions by thermal bonding, for example, by thermal spot bonding.
First and/or second absorbent layer can be Foley Fluff pulp available from Buckeye Technologies Inc., Memphis, Tenn. that is disintegrated and formed into a core having a density of about 0.07 grams per cubic centimeter (g/cm3) and a caliper of about 10 mm.
The extensibility and/or elastic modulus of portions of the components of sanitary napkin 20, including zones of extensibility 33 and zones of enhanced extensibility 43 is/are a property of materials that can be determined by any of many well-known means known in the art. In general, persons skilled in the art will recognize that any tensile test as are known and used in conjunction with testing equipment made by Instron, MTS, Thwing-Albert, and the like, can be used to measure stress/strain and to report extension and/or elastic modulus. It is implied herein that any of such tensile forces are measured at relatively low strains from about 0.1% to about 10%, and at appropriate rates of strain representative of in use conditions. By way of example, an appropriate rate of strain is defined as anything from 100% strain in about 2 seconds to 100% strain in about 3 minutes. For a given strain of between about 0.1% to about 10%, the ratio of the elastic modulus of the zones of extensibility 33 to the elastic modulus of the regions between (or intermediate to, or adjacent to; each term being synonymous in this context) the zones of extensibility 33 of first absorbent layer 24 can be from about 1 to 1.5 to about 1 to 1000, and is preferably from about 1 to 100 to about 1 to 300.
Joining of the facing layer 21 and the first absorbent layer 24 can be by any means known in the art, such as by adhesive bonding, thermal bonding, ultrasonic bonding, and the like. While complete bonding at interface is not necessary, it is believed that the bonding should be sufficient to facilitate the components act, as a unit, e.g., bending out-of-plane together upon sufficient lateral force, as described more fully below. In a preferred embodiment, the facing layer 21 is adhered to the body-facing side of the first absorbent layer 24 at substantially the entire surface interface between the two components, e.g., by the use of meltblown thermoplastic adhesive. Adhesion can be by application of a substantially uniform layer of adhesive applied by means known in the art, such as by spraying or slot coating. The adhesive, if uniformly coated should not block fluid flow into the first absorbent layer. Therefore, in a preferred embodiment, the adhesive is a fluid permeable adhesive, such as the aforementioned Findley HX1500-1 adhesive.
All documents cited in the Detailed Description of the Invention are, in relevant part, incorporated herein by reference; the citation of any document is not to be construed as an admission that it is prior art with respect to the present invention.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
| Number | Name | Date | Kind |
|---|---|---|---|
| 4182234 | Reed | Jan 1980 | A |
| 4804380 | Lassen | Feb 1989 | A |
| 5007906 | Osborn | Apr 1991 | A |
| 5324278 | Visscher | Jun 1994 | A |
| 5454802 | Lindquist | Oct 1995 | A |
| 5484430 | Osborn | Jan 1996 | A |
| 5514104 | Cole | May 1996 | A |
| 5558656 | Bergman | Sep 1996 | A |
| 5611790 | Sugahara et al. | Mar 1997 | A |
| 5624421 | Dabi | Apr 1997 | A |
| 5674214 | Visscher | Oct 1997 | A |
| 5702382 | Osborn | Dec 1997 | A |
| 5713883 | Hsieh | Feb 1998 | A |
| 5713884 | Osborn | Feb 1998 | A |
| 5824004 | Osborn | Oct 1998 | A |
| 5951536 | Osborn | Sep 1999 | A |
| 6059764 | Osborn | May 2000 | A |
| 6096017 | Osborn | Aug 2000 | A |
| 6221062 | Osborn | Apr 2001 | B1 |
| 6264641 | Van Gompel | Jul 2001 | B1 |
| 6287288 | Osborn | Sep 2001 | B1 |
| 6296628 | Mizutani | Oct 2001 | B1 |
| 6312416 | Brisebois | Nov 2001 | B1 |
| 6409883 | Makolin | Jun 2002 | B1 |
| 6423045 | Wise | Jul 2002 | B1 |
| 6447494 | Kashiwagi | Sep 2002 | B1 |
| 6448466 | Carvalho | Sep 2002 | B1 |
| 6450999 | Kitabjian | Sep 2002 | B1 |
| 6458113 | Kashiwagi | Oct 2002 | B2 |
| 6475199 | Gann | Nov 2002 | B1 |
| 6503233 | Chen | Jan 2003 | B1 |
| 6503234 | Canuel | Jan 2003 | B1 |
| 6562192 | Hamilton | May 2003 | B1 |
| 6585712 | Yoshimasa | Jul 2003 | B2 |
| 6695827 | Chen | Feb 2004 | B2 |
| 20020055726 | Costa | May 2002 | A1 |
| 20030097105 | Chen | May 2003 | A1 |
| 20040147892 | Mizutani | Jul 2004 | A1 |
| 20040147893 | Mizutani | Jul 2004 | A1 |
| 20040147894 | Mizutani et al. | Jul 2004 | A1 |
| 20040147895 | Mizutani et al. | Jul 2004 | A1 |
| 20040147896 | Mizutani et al. | Jul 2004 | A1 |
| 20040147897 | Mizutani et al. | Jul 2004 | A1 |
| 20040147898 | Mizutani et al. | Jul 2004 | A1 |
| 20040149613 | Mizutani et al. | Aug 2004 | A1 |
| 20040153042 | Mizutani et al. | Aug 2004 | A1 |
| 20040158219 | Mizutani et al. | Aug 2004 | A1 |
| 20040158220 | Mizutani et al. | Aug 2004 | A1 |
| 20040158221 | Mizutani et al. | Aug 2004 | A1 |
| 20040158222 | Mizutani et al. | Aug 2004 | A1 |
| 20040158223 | Mizutani et al. | Aug 2004 | A1 |
| 20040162539 | Mizutani et al. | Aug 2004 | A1 |
| 20040167491 | Mizutani | Aug 2004 | A1 |
| 20040167492 | Mizutani et al. | Aug 2004 | A1 |
| 20040178104 | Mizutani et al. | Sep 2004 | A1 |
| 20040181201 | Mizutani et al. | Sep 2004 | A1 |
| 20050143597 | Mizushima et al. | Jun 2005 | A1 |
| Number | Date | Country |
|---|---|---|
| 0 888 765 | Jan 1999 | EP |
| WO 9210984 | Jul 1992 | WO |
| WO 9517150 | Jun 1995 | WO |
| WO 9520931 | Aug 1995 | WO |
| WO 9701996 | Jan 1997 | WO |
| WO 9827910 | Jul 1998 | WO |
| WO 9827915 | Jul 1998 | WO |
| WO 9855065 | Oct 1998 | WO |
| WO 9901097 | Jan 1999 | WO |
| WO 0236057 | May 2002 | WO |
| Entry |
|---|
| PCT International Search Report dated Nov. 22, 2004. |
| U.S. Appl. No. 10/613,296 (aka 9322), filed Jul. 3, 2003, Office Actions and Responses from Jul. 3, 2003 to Aug. 1, 2012. |
| Number | Date | Country | |
|---|---|---|---|
| 20120302984 A1 | Nov 2012 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 10613296 | Jul 2003 | US |
| Child | 13566671 | US |
