The invention relates to a screen printing screen which has a screen printing stencil carrier and a screen printing stencil.
During screen printing, a screen printing screen is arranged on a printing material or substrate. The screen printing screen has a screen printing stencil and a screen printing stencil carrier, the screen printing stencil being connected to the screen printing stencil carrier which is configured as a screen. The screen is formed by polyester or stainless steel threads which are woven with one another. In order for it to be possible to handle the screen printing screen, it is tensioned tautly in a screen printing frame.
The screen printing screen has free regions which can receive a printing medium such as an ink or a paste. If a doctor is guided over the screen printing screen, the printing medium passes through the free regions of the screen printing screen onto the substrate which is arranged under it. In order to produce fine printed tracks, screen printing stencils can be used which are produced photomechanically.
A screen having a small mesh width and thin mesh wires is required for a high resolution of the printed image and a high print quality. The smaller the wire spacings and the thinner the wires, the more complicated and the more expensive is the production of a screen of this type, however. In the case of thin mesh wires having a diameter of, for example, 5 micrometers, a high tensile stress can no longer be applied, with the result that a screen which is produced from said wires is relatively sensitive mechanically.
If a doctor were guided over a screen of this type, firstly the wires can be damaged quickly, and secondly the screen could have an abrasive effect on the doctor edge which comes into contact with the screen. The consequence would be a very low service life of the screen. In order to prevent this, a coating which is joined to the screen wires with a strong bond and increases the stability can be applied on the upper side and underside of the screen. A construction of this type has the disadvantage that it is complicated. Furthermore, the printed image and the resolution which can be achieved are influenced negatively by the additional coatings which possibly have to be applied multiple times in method steps which follow one another. If the surface to be printed has a relatively great roughness, the fine-meshed screen can be damaged rapidly, with the result that only a short service life is achieved.
It is therefore an object of the invention to provide a screen printing screen for technical screen printing, by way of which screen printing screen a high resolution can be achieved which has a high service life even in the case of rough surfaces to be printed, can be produced inexpensively in the process and does not have an abrasive effect on an associated doctor. Furthermore, printed tracks having thicknesses in the range from 0.5 micrometer to 100 micrometers are to be achieved by way of the screen printing screen.
The object is achieved by the subject matter of the independent patent claim. Advantageous developments of the invention are the subject matter of the subclaims.
The screen printing screen according to the invention has:
In the screen printing screen according to the invention, sensitive mesh wires which form a screen are therefore not used, but rather a film having recesses. A film is understood here to mean a flat flexible structure which is homogeneous per se and is self-supporting. For example, the film can be rolled, cast, calendered or extruded, and can be formed homogeneously from one layer or as a multiple layer composite. The use of a film in a screen printing screen is advantageous in many regards. Firstly, a film can be produced with low expenditure in such a way that it has a low surface roughness of, for example, Rz<10 micrometers (according to DIN 4768). Reference is made to the fact that the roughness Rz is equivalent to the thread strength in the case of woven screens. This property is already achieved without the application of an additional coating, with the result that, in contrast to a screen which is woven from wires, no more complicated coating measures are required, in order to smooth surface roughnesses. If a printing doctor is guided along on the upper side of a screen printing stencil carrier which is configured as a film, virtually no more abrasive loading acts on the printing doctor even without a single additional coating.
Since, in the case of the film, in contrast to woven screens, coatings are no longer required on the upper side to smooth surface unevennesses, no exposure reflections are produced on a coating either. A higher resolution and quality can therefore be achieved in the printed image. Ragged printed edges, as can occur in the case of coated screens with woven screen printing carriers, are avoided by way of this.
Furthermore, the low surface roughness of a film can be achieved on its entire surface equally. The considerable surface elevations at the crossing points of a woven screen do not occur in the case of a film. High compressive loads at crossing points can therefore also be avoided reliably with negative effects on uniform thickness and geometry of a coating and an increasing loss of elasticity and shape of the screen. A screen printing stencil carrier with a long service life can therefore be achieved by use of a film.
In addition, recesses which lie close to one another can be made in a film with low expenditure, with the result that a high resolution can be achieved during printing. In addition, in comparison with a fine-meshed screen made from wires, a film with recesses is considerably more stable mechanically. Moreover, recesses with any desired geometry can be formed in the case of a film, whereas only substantially square free spaces for passing the printing medium through are possible in the case of a screen made from mesh wires.
The use of a nonmetallic masking layer can achieve a situation where there is a low hardness of the layer which can be adapted satisfactorily to a rough surface of a substrate with a jagged topography. It is therefore also possible to print rough surfaces with a high edge sharpness.
It is advantageous if the underside of the film has a roughness Rz of less than 30 micrometers, preferably of less than 2 micrometers. Even at a layer thickness of 0.5 micrometer, the nonmetallic masking layer on the underside of the film achieves satisfactory flatness, since no topography of a screen fabric has to be compensated for. The low layer thickness brings about a situation where reflections widthwise are reduced in the case of an exposure. A low roughness of the film underside therefore makes a printed image with an even higher resolution possible. This is achieved even when the thickness of the coating on the underside, that is to say the thickness of the screen printing stencil, is relatively great. A roughness Rz of less than 30 micrometers, preferably of less than 2 micrometers, on the upper side of the film ensures that no coating is required on the upper side for flattening a rough topography, with the result that the doctor can be guided directly on the film upper side and is worn away only unsubstantially. Therefore, not only the screen printing screen but also the doctor achieves a high service life.
According to one development of the invention, the nonmetallic masking layer is formed on the basis of an emulsion. An emulsion of this type can be applied in liquid form to the film and does not require a developer. Excess material can be washed off with water after an exposure, with the result that the handling is simple. In addition, an emulsion layer can be produced with a low hardness, with the result that it can be adapted flexibly even to a rough surface topography of a substrate, such as a solar cell. Satisfactory results can be achieved with a masking layer which has a hardness in a range from 30 to 60 Sh(A).
The masking layer on the underside of the film preferably has a thickness in a range from 0.5 micrometer to 60 micrometers, with the result that a printed image having a height of from 0.5 to 60 micrometers can be built up on the substrate by way of a single printing operation, disregarding a mechanical compression of the masking layer. Greater thicknesses of the masking layer are possible without restriction, this being limited only by the desired resolution. A particularly suitable masking layer is formed on the basis of polyvinyl alcohol. A masking layer of this type can be connected particularly satisfactorily to the surface of the screen printing stencil carrier, a satisfactory connection also being achieved on the side walls of small recesses.
In another embodiment, the masking layer comprises a dry film or solid resist or what is known as a capillary film. Said dry film is laminated onto the underside of the screen printing stencil carrier. For this purpose, the dry film can comprise different layers, it being possible for an upper layer to be etched readily, in order to facilitate the connection to the screen printing carrier. The dry film is laminated only onto one side of the screen printing stencil carrier and does not penetrate completely through the holes. The dry film is exposed and developed with the negative printed image, with the result that the screen printing stencil is produced.
The masking layer can be contained at least partially in the recesses of the film. If the film has a regular pattern of recesses, a printed image which has a different arrangement than the recesses of the film can be produced by a masking layer which is applied partially in the recesses of the film.
According to one development of the invention, the masking layer is provided in the recesses of the film from the underside of the film in the direction of the upper side of the film, but does not project beyond the upper side of the film. The doctor can therefore be guided along over the smooth upper side of the film and does not have its movement impeded by projecting material of the masking layer. Here, the masking layer can be provided in such a way that it extends flatly and in one plane with the upper side of the film. However, it is equally possible that the masking layer does not reach the upper side of the film, with the result that there is a small height difference between the masking layer and the upper side of the film. If the masking layer is exposed in this last way, there is even greater certainty that no masking layer material projects beyond the upper side of the film and therefore the doctor is not impeded during a movement along the upper side.
If, in the case of the screen printing screen according to the invention with a film as screen printing stencil carrier, a masking layer is provided exclusively on the underside and possibly also in the recesses, an emulsion layer on the basis of polyvinyl alcohol is particularly advantageous, since reliable adhesion can be achieved only on these sides. In contrast to woven screen printing stencil carriers, an additional coating on the upper side is not required.
The recesses of the film can be circular, rectangular or hexagonal. A film of this type can be produced simply and forms a very homogeneous carrier. The film preferably has a thickness of from 10 to 100 micrometers and the spacing between the recesses has a width of from 1 micrometer to 50 micrometers. Here, the spacing between the recesses can vary. If, for example, recesses of circular cross section are provided, the spacing between two adjacent circles can be 1 micrometer at the narrowest point, the narrowest point resulting on an imaginary connecting line between the two center points of the circles. If a movement is carried out perpendicularly with respect to this connecting line, the spacing between the circular lines is increased correspondingly. A film having recesses of this type therefore has no bars as carrying structural elements, as are present in a mesh having wires, but rather the inverted image to a hole pattern.
If the recesses are produced, for example, by etching, very small spacings can be achieved between the recesses, by an etchant acting on a film for a sufficiently long time. As the duration of action increases, a recess is enlarged and the spacing between the recesses decreases. In the case of processing of a film using the reel to reel process, this is possible with low technical expenditure and therefore with low costs. It is likewise possible to combine recesses of different types with one another on one film and to arrange them according to the desired printed image. In the case of a film, in contrast to a woven screen, very small openings can likewise be produced simply by a short etching duration.
It is advantageous to achieve an increase in the surface roughness of the film, for example by contact with etching media such as phosphoric acid or alkaline media such as NaOH or KOH. The adhesion of the masking layer to the film can be improved in this way. It is advantageous if, in the case of the screen printing screen according to the invention, the roughness is increased selectively only on the surfaces which are to carry a masking layer. These surfaces are the underside of the film (printing side) and the surfaces within the recesses. In the case of the upper side which comes into contact with the doctor, it is advantageous if an increase of this type in the surface roughness is not carried out, since the doctor can therefore be moved more smoothly and achieves a longer service life.
The film can be a metal film which has stainless steel, copper, nickel or another metal in pure form or as an alloy. However, it is equally possible to use a plastic film, the latter preferably being reinforced with glass fibers or carbon fibers.
In contrast to a galvanically produced film, a rolled metal film can be produced with a very small flatness tolerance. For the screen printing screen according to the invention, a rolled film is preferably used with a flatness tolerance of less than 5%, preferably of less than 2.5% of the film thickness. In addition, the film should have a low roughness. In the case of a film having a thickness of 50 micrometers, a roughness Rz of <10 micrometers, in particular Rz of <1 micrometer, can be achieved inexpensively using the reel to reel process. If a metal film having a surface roughness and a flatness tolerance of this type is used for the screen printing stencil carrier, a very accurate screen printing stencil and a very accurate printed image can be produced. Depending on the requirement of resolution and quality, the recesses can be produced using the processes which are customary in the prior art, for example by laser drilling, wet etching, ultrasonic etching, erosion or punching.
In a further embodiment, the film has, on the surface, a layer for modifying the wettability and/or passivation with respect to etching media. A modification to the wettability of the screen printing stencil can be brought about, for example, by hydrophilization or hydrophobicization. Hydrophilization brings about a situation where the printing medium can pass in an improved manner through the partly very small recesses. A hydrophobicization achieves a situation where the printing medium is released more readily from the screen printing stencil, without getting caught partly in the recesses. In general, an effect of this type, in the case of which a printing medium which is introduced into the recesses remains in the recesses only to a small proportion when the screen printing screen is removed from the substrate, can be achieved by a layer which has a contact angle with water in a range of greater than 90° to 150°. A contact angle denotes the angle which a liquid drop forms on the surface of a solid with respect to said surface. In the case of the stated contact angle range, a small interaction of the printing medium with the surface of the coating can be achieved. The result can then be a printed track, in the case of which the ratio of height to width is in the region of 1:1 or greater. For applications, in the case of which a low application of printing medium is required, the coating can have a contact angle with water in a range of greater than 0° to 90° and can have a high interaction of the printing medium with the surface of the coating.
In a development of the screen printing screen, both the screen printing carrier film and the screen printing stencil are provided with a coating.
A modification to the wettability can also be achieved by a described selective treatment with alkaline media, a stainless steel surface becoming more hydrophilic after treatment with an alkaline medium.
In order to manufacture a screen printing screen as shown above, a method can be used which has the following steps:
removal of the unexposed regions of the masking material on the upper side, underside and in the recesses of the film, with the result that a masking layer is formed.
In this way, a film can be manufactured which has a smooth upper side without masking layer, there being a masking layer on the underside and in the recesses.
An exposure dosage for the masking material in the recesses of the film can be selected in such a way that the masking material which is present on the underside and in the recesses of the film is exposed down to a depth which reaches at most the upper side of the film. The doctor which is guided along on the upper side therefore does not experience an obstacle as a result of the exposed masking material and can achieve a maximum service life.
An increase in the surface roughness of the film can be limited to the regions, in which an exposed masking material is to adhere to the film, with the result that improved adhesion can be achieved.
A substance which etches the surface of the film can be used to increase the surface roughness, it being possible for NaOH, KOH or phosphoric acid to be used. Here, alkaline media are particularly suitable for simultaneous degreasing. The substance can be applied by way of a doctor. The unexposed regions of the masking material can be removed by being washed out.
According to a further embodiment, the screen printing stencil carrier and/or the screen printing stencil are/is configured in such a way that a projection protrudes into the region of at least one of the first or second recesses and reduces its passage surface area for a printing medium. A projection in a recess leads to the recess not being reduced in its cross section over its entire length, but rather only in a small region. The recess can be of broad configuration outside this region, it being possible, however, for a cross-sectional reduction of the recess to be achieved by the projection for a printing medium which is to be conveyed through said recess. This makes it possible to produce fine printing tracks, although the recess can have a generous cross section apart from the projection.
The high expenditure for the accurate positioning of a screen printing stencil carrier in relation to the screen printing stencil, in order to bring a first recess with a relatively small cross section at least partially into congruence with a second recess with a likewise small cross section, therefore does not arise. Rather, work can be carried out with customary manufacturing accuracy. Moreover, the force for introducing the printing medium into a relatively broad recess with a projection which protrudes into the recess is lower than in the case of a recess which has a continuously small cross section. This is joined by the fact that a projection in a screen printing stencil or a screen printing stencil carrier increases its flexural stiffness and tensile strength. When a doctor is moved along on the surface of the screen printing stencil carrier, the screen printing screen is therefore stretched to a less pronounced extent, with the result that its geometry is retained with higher reliability. A screen printing screen of this type therefore achieves a relatively high service life.
This embodiment can advantageously be produced by electrodeposition.
The method for producing the screen printing screen which has a projection has the following steps:
As a result of the electrodeposition, it is possible to achieve the growth of the projection and a reduction in the cross-sectional surface area in one step without further structuring. Etching of the metal is not required. Furthermore, the electrodeposition makes it possible to form a projection which results in a passage surface area for a recess, which passage surface area is virtually as small as desired. In the extreme case, the projection can even close a recess completely.
According to a further embodiment of a screen printing screen, at least one of the first recesses has a printing medium inlet opening on the respective upper side and a printing medium outlet opening on the respective underside, the surface area of the printing medium inlet opening of the at least one recess lying, in the case of a projection perpendicularly with respect to said surface area, at most partly above the surface area of the printing medium outlet opening of the one recess.
In the case of a construction of this type of a screen printing stencil carrier, the printing medium no longer has to be introduced into a recess normally or perpendicularly with respect to the upper side of the screen printing stencil carrier, but can also be conveyed in a direction which deviates from the normal. This facilitates the transport of the printing medium in the direction of the substrate, with the result that the printing medium can be transported through a recess with less force application by a doctor. A longer service life of the screen printing stencil carrier can be achieved in this way.
According to a further embodiment of the screen printing screen, a spacer element is provided on the screen printing stencil carrier and/or the screen printing stencil on their/its underside, which spacer element is suitable for arranging the screen printing stencil carrier and/or the screen printing stencil at a spacing from a plane, on which the substrate to be printed is placed.
According to a development of the invention, the screen printing screen has a frame with a clamping fabric for clamping the screen printing stencil carrier which is configured as a film. In an edge region, the film can have a surface structure which is suitable to receive a joining material such as adhesive in such a way that joining of the edge region with the clamping fabric can be achieved. The structure can be formed in such a way that it is made from the film or results as an inverted region comprising elements which are attached on the film. The manufacture is particularly inexpensive if the surface structures are configured with a circular, rectangular or hexagonal cross section and are manufactured at the same time as the recesses. Continuous holes in the edge region of the film are particularly advantageous, in order that a join of an adhesive or joining material can be formed in a similar manner to a pin.
The clamping fabric and the screen printing stencil carrier are preferably joined to one another by means of melted plastic, the plastic having penetrated into depressions or holes of the screen printing stencil carrier and mesh of the clamping fabric. Production can take place in such a way that the screen printing stencil carrier which is provided with through holes in the edge region is arranged above the clamping fabric. A plastic film which is melted by heat input is then placed between the screen printing stencil carrier and the clamping fabric. The molten material penetrates into the through holes of the screen printing stencil carrier and into mesh of the clamping fabric, and permanently joins the screen printing stencil carrier to the clamping fabric after cooling. This join is very strong and can be achieved with low technical complexity without adhesives and, as a result, is very suitable for inexpensive mass production.
In the following text, exemplary embodiments of the invention will be explained with reference to the drawings, in which:
The masking layer 5 is also situated partially in the recesses 7 of the film 2, see reference sign 9. To this end, the exposure for producing the masking layer 5 takes place in such a way that, starting from the underside 4, a masking material 51 (see
As can be seen from
The production of the screen printing screen 1 according to the invention can be carried out by way of the following method steps:
If the metal layer 77 and the varnishing form 76 are subsequently separated from the substrate 75 and the varnishing form 76 is removed, recesses 72 are formed with projections 74, as is shown in
The screen printing stencil carrier 80 is configured in such a way that, in the case of a projection along the projection direction 89 perpendicularly with respect to this surface area 86, the surface area 86 of the inlet opening 85 lies at most partially one above the other with the surface area 88 of the outlet opening 87. This means that there is either no congruence at all of the two surface areas 86 or 88 or only a partial congruence of the two surface areas 86 or 88. The region, in which the surface areas 86 and 88 overlap partially, is denoted as overlapping surface area 90 in the following text. This overlapping surface area 90 is always smaller than the surface area 86 or 88. According to one embodiment of the invention, the overlapping surface area 90 has a size which is not more than 30% of the surface area 86 or surface area 88. The two surface areas 86 and 88 preferably do not overlap, with the result that there is also no overlapping surface area 90.
In the embodiment of a screen printing stencil carrier shown in
In the situation which is shown in
If a printing medium 116 is pressed through the screen printing screen 120 by means of a doctor 115, a vertically downwardly directed force acts on the screen printing screen 120. The spacer elements 114 ensure that the screen printing stencil carrier 110 is not pressed down as far as the substrate support 113 in the region of the outer edges of the substrate 112, but rather is held in a position which, in the region of the substrate 112, makes a horizontal support of the screen printing stencil 111 possible on the upper side of the substrate 112. As a result, a uniform and correct printed image can be achieved even into the edge regions of the substrate 112. Furthermore, the screen printing stencil 111 and the screen printing carrier 110 are mechanically protected in the edge regions of the substrate 112 by the spacer elements 114 if the doctor 115 is pulled along on the surface of the screen printing stencil carrier 110.
If a relatively soft substrate support 113 is used, it can occur that, while the doctor 115 is being pulled along over the screen printing stencil carrier 110 in the region of the spacer elements 114, said spacer elements 114 are pressed into the substrate support 113, with the result that the screen printing stencil carrier 110 and the screen printing stencil 111 do not rest flatly on the substrate 112 in the edge regions of the substrate 112. In this case, according to one development of the invention, the spacer elements 114 can have such a height that, in an unloaded state, that is to say without application of a vertical force by the doctor 115, in the case of contact of the spacer elements 114 with the substrate support 113, the screen printing stencil carrier 110 and the screen printing stencil 111 are situated at a spacing from the upper side of the substrate 112.
The spacer element 114 can be attached retrospectively to the screen printing stencil carrier 110 and/or to the screen printing stencil 111. It can be a flat material or a film made from plastic or metal which is configured in one piece. Furthermore, it is possible that a plurality of spacer elements 114 are arranged around the edge region of the substrate 112 at a predefined spacing from one another.
The spacer element 114 can also be machined from the screen printing stencil carrier 110 or the screen printing stencil 111. In this case, assembly and precise assignment between spacer element 114 and screen printing stencil carrier 110 or screen printing stencil 111 are no longer required, with the result that assembly complexity is omitted completely. In the case of a machined spacer element 114, no requirements are to be met with regard to fit, flatness and parallelism of surfaces which are to be joined to one another.
A spacer element 114 is particularly advantageous which is configured in one piece in the form of a frame around the edge region of the substrate 112, with the result that the screen printing stencil carrier 110 and/or the screen printing stencil 111, during prepositioning in relation to the position with respect to the substrate 112, are/is centered with respect to the substrate 112 at the same time, with the result that precision positioning and orientation of the screen printing stencil carrier 110 and/or the screen printing stencil 111 in relation to the substrate 112 are no longer required.
Number | Date | Country | Kind |
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20 2008 012 829.3 | Sep 2008 | DE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/DE09/01330 | 9/25/2009 | WO | 00 | 3/25/2011 |