The present disclosure relates to a screw extruder for extruding a kneaded material.
A process for manufacturing automobile tires uses an extrusion forming machine that is placed below a kneader to knead rubber as the raw material of the tires, The extrusion forming machine forms the rubber (kneaded material) fed from the kneader into a sheet shape while continuously extruding it.
Patent Literature 1 discloses a kneaded material transporter in which a gap is formed between a tapered screw and a casing disposed to surround a tip of the tapered screw A part of a raw material fed and transported through the casing toward the tip thereof by rotation of the tapered screw is released into the gap so that pressure applied on the raw material can be relieved to inhibit the pressure from increasing and heat from being generated from the raw material due to the pressure applied to the raw material. In addition, the fed raw material can flow (move) easily in a portion where the raw material is bitten by the screw. Thus, the load on the screw is reduced and the amount of the extruded raw material is increased so that the raw material can be fed to a compression portion smoothly.
In addition, Patent Literature 2 discloses a twin-screw extruder in which at least two screw blades are disposed in a position corresponding to a compression portion so that a lead angle of each screw blade in the position corresponding to the compression portion is set to be smaller than a lead angle of the screw blade in a position corresponding to a hopper portion. In the position corresponding to the hopper portion, the function of biting a massive material fed from a material supply port and feeding the material to the compression portion is exhibited. In the position corresponding to the compression portion, the function of compressing the material to generate pressure required for extruding the material from a material discharge port, and inhibiting the material from flowing reversely, thereby securing a throughput is exhibited.
Patent Literature 1: JP-A-2000-317291
Patent Literature 2: Japanese Patent No. 6202624
Recent diversification of materials causes a problem that some materials cannot be formed into sheets. One of the reason is considered to be a decrease of the quantity occupied by rubber in materials. The decrease in rubber quantity leads to a state in which there is no binding agent among pieces of the material. Thus, the material cannot be formed into a sheet easily. In order to form the material into a sheet under such a situation, it is necessary to enhance the function of the rubber serving as a binding agent. Specifically, it is necessary to improve the rubber density to increase the contact area among pieces of the rubber. In order to increase the contact area among pieces of the rubber, it is necessary to compress the rubber to enhance the density thereof. In order to form a sheet out of a material which is difficult to be formed into a sheet, it is therefore important to increase pressure in a hank portion where the kneaded material extruded by a screw accumulates.
According to Patent Literature 1, the extrusion amount increases to improve the kneading performance, but the capacity of increasing the pressure in the bank portion is reduced. According to Patent Literature 2, the material can be inhibited from flowing reversely, thereby enhancing the capacity of increasing the pressure in the bank portion, but the conveyance capacity is reduced so that there is a possibility that the effect of increasing the pressure cannot be obtained in some production capacity of the screw extruder.
An object of the present disclosure is to provide a screw extruder capable of improving capacity of increasing pressure in a bank portion.
The present disclosure is a screw extruder for extruding a kneaded material, the screw extruder including: a pair of screws; a casing that houses the pair of screws and includes a supply port for supplying a material, the supply port being provided on an upstream side of the casing; and a roller-die configured to extrude and form the material into a sheet shape, the roller-die being provided on a downstream side of the casing, in which: each of the screws includes a shaft portion, and a spiral flight portion provided in an outer peripheral surface of the shaft portion; the flight portion is formed into a shape in which a radial distance between the surface of the shaft portion and a tip of the flight portion decreases gradually toward a downstream end in an extrusion direction of a kneaded material; the casing has a tapered shape; and within a range between a downstream end of the supply port and a downstream end of the flight portion, a clearance between a top portion of the flight portion and an inner wall surface of the casing at the downstream end of the supply port is larger than a clearance at any other part.
In the present disclosure, within the range between the downstream end of the supply port and the downstream end of the flight portion, the clearance at the downstream end of the supply port is larger than the clearance at any other part. Accordingly, at the downstream end of the supply port, the rotational speed at the tip of the flight portion is reduced to reduce the strain rate in comparison with that in a configuration in which the clearance is constant between the downstream end of the supply port and the downstream end of the flight portion. As a result, at the downstream end of the supply port, the viscosity of the material is kept higher than that in the configuration in which the clearance is constant. Accordingly, leakage of the material toward the supply port is inhibited to improve the conveyance efficiency. Thus, it is possible to improve the capacity of increasing the pressure in the bank portion.
Preferred embodiments of the present disclosure will be described below with reference to the drawings.
A screw extruder according to a first embodiment of the present disclosure is to extrude a kneaded material. In the present embodiment, the screw extruder is a screw extruder with roller-die for extruding a kneaded material of a polymer such as rubber and forming the extruded material into a sheet shape.
A screw extruder 1 includes a pair of screws 2 and 3, and a casing 4 as illustrated in
Each of the screws 2 and 3 includes a shaft portion 6 and a flight portion 7. The shaft portion 6 is formed into a shape whose diameter decreases gradually toward its downstream end in the extrusion direction of the kneaded material. The flight portion 7 is provided on the outer peripheral surface of the shaft portion 6. The flight portion 7 has a spiral shape. In the flight portion 7 of each screw 2, 3, the distance in the radial direction between the surface of the shaft portion 6 thereof and the tip of the flight portion 7 is shorter as the flight portion 7 is closer to the downstream end in the extrusion direction of the kneaded material. That is, the flight portion 7 has a shape in which the distance in the radial direction between the surface of the shaft portion 6 and the tip of the flight portion 7 decreases gradually toward the downstream end in the extrusion direction. The screws 2 and 3 are designed to have the same shape and the same dimensions except that the torsion angles of the flight portions 7 are opposite to each other. In addition, the screws 2 and 3 are coupled to rotate in opposite directions to each other. The screws 2 and 3 are rotated at the same rotational speed by a not-illustrated single driving unit.
The casing 4 has a tapered shape and houses the pair of screws 2 and 3. In front of the casing 4 in the extrusion direction of the kneaded material, a pair of upper and lower rollers 8 and 9 are disposed. A part between the casing 4 and the rollers 8 and 9 is called a bank portion 10. The kneaded material extruded by the screws 2 and 3 accumulates in the bank portion 10.
The rollers 8 and 9 are coupled so as to rotate in directions opposite to each other. The rollers 8 and 9 are rotated at the same rotational speed by a not-illustrated single driving unit. The rollers 8 and 9 are called a roller-die, which is configured to roll the kneaded material and form it into a sheet shape (sheet 50).
A material (kneaded material) supply port 11 is provided on the upstream side of the casing 4 in the extrusion direction of the kneaded material. The casing 4 includes a casing upstream portion 13 in which the supply port 11 is provided at the top thereof, and a casing downstream portion 14 which is circumferentially surrounded by a wall surface. The kneaded material such as rubber supplied to the supply port 11 from above is extruded to the bank portion 10 by the screws 2 and 3 rotating in opposite directions to each other, and then passed between the rollers 8 and 9. Thus, the kneaded material is formed into a sheet shape.
Here, each of the screws 2 and 3 in the casing downstream portion 14 is divided into three regions 1 to 3 pitch by pitch for consideration. The screw 2, 3 has a tapered shape. Therefore, the conveyance capacity decreases in a more downstream region. Thus, the conveyance capacity in the region 1 is lower than that in the region 2. On the other hand, a part of the region 3 protrudes from the casing downstream portion 14 so that a sufficient amount of the kneaded material cannot be supplied to the region 3 only by the flight portion 7. Thus, the region 3 is not filled. As a result, the maximum conveyance capacity cannot be exerted. In addition, in some operating condition, the amount of the kneaded material supplied to the region 2 may be insufficient. Thus, the region 2 may not be filled, either.
Here,
Here, as shown in
Therefore, in the present embodiment, as shown in
In the screw extruder 1 according to the present embodiment, in the sectional view in the radial direction of the shaft portion 6, an imaginary line (broken line connecting top points of the flight portion 7 is a straight line and the inner wall surface (solid line) of the casing 4 is also a straight line all over the range between the downstream end 11a of the supply port 11 and the downstream end of the flight portion 7. Thus, the clearance increases gradually all over the range between the downstream end of the flight portion 7 and the downstream end 11a of the supply port 11. That is, the clearance D2 at the downstream end 11a of the supply port 11 is larger than the clearance DI at the downstream end of the flight portion 7.
Using the coordinates in
In addition, as shown in
As described above, in the screw extruder 1 according to the present embodiment, the clearance D2 at the downstream end 11a of the supply port 11 is larger than the clearance at any other part within the range between the downstream end 11a of the supply port 11 and the downstream end of the flight portion 7. Accordingly, at the downstream end 11a of the supply port 11, the rotational speed at the tip of the flight portion 7 decreases and the strain rate decreases in comparison with those in the configuration where the clearance is constant within the range between the downstream end 11a of the supply port 11 and the downstream end of the flight portion 7. As a result, at the downstream end 11a of the supply port 11, the viscosity of the material is kept higher than that in the configuration where the clearance is constant, such that leakage of the material toward the supply port 11 is inhibited to improve the conveyance efficiency. Thus, it is possible to improve the capacity of increasing the pressure in the bank portion 10.
In addition, the clearance increases gradually all over the range between the downstream end of the flight portion 7 and the downstream end 11a of the supply port 11. Thus, the capacity of increasing the pressure in the bank portion 10 can be further improved in comparison with the case where the clearance is discontinuous.
Next, a screw extruder according to a second embodiment will be described with reference to the drawings. Descriptions about a configuration common to that in the first embodiment and an effect attained by the configuration will be omitted, but different points from the first embodiment will be mainly described. The same members as those in the first embodiment are followed by the same references in the first embodiment.
In a screw extruder 101 according to the present embodiment, as shown in
In the screw extruder 101 according to the present embodiment, in the sectional view in the radial direction of the shaft portion 6, an imaginary line (broken line) connecting top points of the flight portion 7 is a curved line and the inner wall surface (solid line) of the casing 4 is a straight line ail over the range between the downstream end 11a of the supply port 11 and the downstream end of the flight portion 7. Thus, the clearance varies continuously all over the range between the downstream end 11a of the supply port 11 and the downstream end of the flight portion 7. In the present embodiment, the imaginary line connecting the top points of the flight portion 7 is a quadratic curve. However, the curved line is not limited thereto. In addition, the inner wall surface (solid line) of the casing 4 may be curved.
Using the coordinates in
As shown in
In addition, in the screw extruder 1 according to the first embodiment, as shown in
Therefore, in the present embodiment, as shown in
Here, in
The straight line (alternate long and short dash line) connecting the top point of the top portion at the downstream end of the flight portion 7 and the top point of the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to three rotations can be expressed as y=(Y3−Y0)/X3+Y0. The quadratic curve (dotted line) connecting the top point of the top portion at the downstream end of the flight portion 7 and the top point of the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to three rotations can be expressed as y=ax2+bx+c. The slope at the downstream end of the flight portion 7 in the quadratic curve is b, and the slope in the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to three rotations is 2aX3+b.
The slope of the quadratic curve is larger than the slope (Y3−Y0/X3 of the straight line at the downstream end of the flight portion 7, and smaller than the slope (Y3−Y0)/X3 of the straight line in the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to three rotations. Accordingly, the relationship of b>(Y3−Y0)/X3>2aX3+b is established.
In the background-art screw shape, a substantially proportional relationship is established between the slope of the flight height and the pressure ratio or the conveyance capacity ratio. A trade-off relationship is established between the pressure ratio and the conveyance capacity ratio. On the other hand, in the screw shape according to the present embodiment, the pressure ratio reaches about 7 times while the conveyance capacity is kept as large as in the background art. It is understood from the fact that the conveyance capacity can be improved as much as in the background art while the capacity of increasing the pressure in the bank portion 10 is improved.
As described above, in the screw extruder 101 according to the present embodiment, the clearance D3 in the intermediate portion between the downstream end 11a of the supply port 11 and the downstream end of the flight portion 7 is smaller than the clearance DI at the downstream end of the flight portion 7. Accordingly, the strain rate in the intermediate portion is smaller than that in the screw extruder 1 according to the first embodiment. As a result, in the intermediate portion, the viscosity coefficient of the material is kept higher than that in the screw extruder 1 according to the first embodiment, such that leakage of the material from the intermediate portion to the upstream side is inhibited to further improve the conveyance efficiency. Thus, it is possible to further improve the capacity of increasing the pressure in the bank portion.
In addition, the clearance varies continuously all over the range between the downstream end 11a of the supply port 11 and the downstream end of the flight portion 7. Thus, the capacity of increasing the pressure in the bank portion 10 can be further improved in comparison with the case where the clearance is discontinuous.
In addition, in the sectional view in the radial direction of the shaft portion 6, the imaginary line connecting the top points of the flight portion 7 is a curved line all over the range between the downstream end 11a. of the supply port 11 and the downstream end of the flight portion 7. In the screw extruder I according to the first embodiment, the volumes V1 to V3 in the respective pitches of each screw are smaller than those in the case Where the clearance is constant. Thus, the conveyance capacity is lowered. Therefore, in the sectional view in the radial direction of the shaft portion 6, the imaginary line connecting the top points of the flight portion 7 is formed into a curved line all over the range between the downstream end 11a of the supply port 11 and the downstream end of the flight portion 7. Accordingly, the height of the flight portion 7 in the intermediate portion is kept high. As a result, the volumes V1 to V3 in the respective pitches are larger than those in the screw extruder 1 according to the first embodiment. Thus, the conveyance capacity can be improved.
In addition, in the sectional view in the radial direction of the shaft portion 6, the inner wall surface of the casing 4 is a straight line all over the range between the downstream end 11a of the supply port 11 and the downstream end of the flight portion 7. Thus, the casing 4 can be produced easily.
In the screw extruder 101 according to the present embodiment, as shown in
As shown in
In
The straight line (dotted line) connecting the top point of the top portion at the downstream end of the flight portion 7 and the top point of the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to three rotations can be expressed as y=(Y3−Y0)/X3+Y0. The quadratic curve of the inner wall surface of the casing can be expressed as y=ax2+bx+YW. Here, YW designates an intersection between the quadratic curve and the y-axis. The slope at the downstream end of the flight portion 7 in the quadratic curve is b, and the slope in the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to three rotations is 2aX3+b.
The slope of the quadratic curve is smaller than the slope (Y3−Y0)/X3 of the straight line at the downstream end of the flight portion 7, and larger than the slope (Y3−Y0)/X3 of the straight line in the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to three rotations. Accordingly, the relationship of b<(Y3−Y0)/X3<2aX3+b is established.
As described above, according to the present modification, in the sectional view in the radial direction of the shaft portion 6, the inner wall surface of the casing 4 is a curved line all over the range between the downstream end 11a of the supply port 11 and the downstream end of the flight portion 7. When the imaginary line (broken line) connecting the top points of the flight portion 7 is a straight line, some interval between the shaft portions 6 of the screws 2 and 3 to be paired may cause the screws 2 and 3 to interfere with each other. However, when the inner wall surface (solid line) of the casing 4 is formed into a curved line, the interval between the shaft portions 6 can be made narrower than in the case where the imaginary line connecting the top points of the flight portion 7 is formed into a curved line.
In addition, in the sectional view in the radial direction of the shaft portion 6, the imaginary line connecting the top points of the flight portion 7 is a straight line all over the range between the downstream end 11a of the supply port 11 and the downstream end of the flight portion 7. Thus, the screws 2 and 3 can be produced easily.
Next, a screw extruder according to a third embodiment will be described with reference to the drawings. Description about a configuration common to that in the first embodiment and an effect attained by the configuration will be omitted, but different points from the first embodiment will be mainly described. The same members as those in the first embodiment are followed by the same references in the first embodiment.
In a screw extruder 201 according to the present embodiment, as shown in
In the screw extruder 101 according to the present embodiment, in the sectional view in the radial direction of the shaft portion 6, the inner wall surface (solid line) of the casing 4 is a straight line. In addition, an imaginary line (broken line) connecting top points of the flight portion 7 within a range starting in the top portion on the upstream side from the top portion at the downstream end in the flight portion 7 by the amount corresponding to one rotation, passing through the top portions thereof and reaching the downstream end 11a of the supply port 11 is a curved line. Further, an imaginary line (broken line) connecting top points of the flight portion 7 within a range between the aforementioned top portion on the upstream side by the amount corresponding to one rotation and the top portion at the downstream end is another curved line. Thus, the clearance varies continuously all over the range between the downstream end 13a of the supply port 11 and the downstream end of the flight portion 7. In the present embodiment, the two imaginary lines are quadratic curves respectively. However, the curved lines are not limited to quadratic curves. In addition, the inner wall surface (solid line) of the casing 4 may be a curved line.
In the case where the clearance DI at the downstream end of the flight portion 7 is smaller than the clearance D4 in the top portion on the upstream side from the top portion at the downstream end in the flight portion 7 by the amount corresponding to one rotation, the strain rate at the downstream end of the flight portion 7 is smaller than that in the screw extruder 101 according to the second embodiment. As a result, at the downstream end of the flight portion 7, the viscosity of the material is kept higher than that in the screw extruder 101 according to the second embodiment. Accordingly, leakage of the material from the bank portion 10 is inhibited to further improve the conveyance efficiency. Thus, it is possible to further improve the capacity of increasing the pressure in the bank portion 10.
In addition, as shown in
In addition, the production capacity of the screw extruder 201 mostly depends on the rotational speed of the rollers 8 and 9 (see
In
The straight line (alternate long and short dash line) connecting the intersection Y0 and the top point of the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to three rotations can be expressed as y=(Y3−Y0)/X3+Y0. The quadratic curve (dotted line) connecting the intersection Y0 and the top point of the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to three rotations can be expressed as y=ax2+bx+Y0. The slope at the downstream. end of the flight portion 7 in the quadratic curve is b, and the slope in the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to three rotations is 2aX3+b).
The slope of the quadratic curve is larger than the slope (Y3−Y0)/X3 of the straight line at the downstream end of the flight portion 7, and smaller than the slope (Y3−Y0)/X3 of the straight line in the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to three rotations. Accordingly, the relationship of b>(Y3−Y0)/X3>2aX3+b is established.
In addition, the straight line (dotted line) connecting the top point of the top portion at the downstream end of the flight portion 7 and the top point of the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to one rotation can be expressed as y=cx2dx+Y0′. The slope at the downstream end of the flight portion 7 in the quadratic curve is d, and the slope in the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to one rotation is 2cX1+d.
The slope of the quadratic curve is smaller than the slope (Y3−Y0)/X3 of the straight line at the downstream end of the flight portion 7, and equal to the slope 2aX1+b of the quadratic curve in the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to one rotation, Accordingly, the relationship of d<(Y3−Y0)/X3, and the relationship of 2aX1+b=2cX1+d are established.
As described above, in the screw extruder 201 according to the present embodiment, the clearance D1 at the downstream end of the flight portion 7 is equal to or smaller than the clearance D4 in the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to one rotation. Accordingly, the strain rate at the downstream end of the flight portion 7 is smaller than that in the screw extruder 101 according to the second embodiment. As a result, at the downstream end of the flight portion 7, the viscosity of the material is kept higher than that in the screw extruder 101 according to the second embodiment, such that leakage of the material from the bank portion 10 is inhibited to further improve the conveyance efficiency. Thus, it is possible to further improve the capacity of increasing the pressure in the bank portion 10.
In addition, the clearance varies continuously all over the range between the top portion on the upstream side by the amount corresponding to one rotation and the top portion at the downstream end. Thus, the capacity of increasing the pressure in the bank portion 10 can be further improved in comparison with the case where the clearance is discontinuous.
In addition, in the sectional view in the radial direction of the shaft portion 6, the imaginary line connecting the top points of the flight portion 7 is a curved line all over the range between the top portion on the upstream side by the amount corresponding to one rotation and the top portion at the downstream end. In the screw extruder 101 according to the second embodiment, the height of the top portion at the downstream end of the flight portion 7 is reduced so that the volume V1 on the downstream side of the flight portion 7 tends to be reduced. In view of the above, in the sectional view in the radial direction of the shaft portion 6, the imaginary line connecting the top points of the flight portion 7 is formed into a curved line all over the range between the top portion on the upstream side by the amount corresponding to one rotation and the top portion at the downstream end. Thus, the height of the top portion at the downstream end of the flight portion 7 can be increased in comparison with that in the screw extruder 101 according to the second embodiment, so that the conveyance amount (volume V1) on the downstream side of the flight portion 7 can be increased.
In addition, in the sectional view in the radial direction of the shaft portion 6, the inner wall surface of the casing 4 is a straight line all over the range between the top portion on the upstream side by the amount corresponding to one rotation and the top portion at the downstream end. Thus, the casing 4 can be produced easily.
In the screw extruder 201 according to the present embodiment, as shown in
Even in such a configuration, leakage of the material from the bank portion 10 is inhibited to further improve the conveyance efficiency. Thus, it is possible to further improve the capacity of increasing the pressure in the bank portion 10.
In
The straight line (dotted line) connecting the top point of the top portion at the downstream end of the flight portion 7 and the top point of the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to three rotations can be expressed as y=(Y3−Y0)/X3+Y0. In addition, the quadratic curve of the inner wall surface of the casing similar to that in
The slope of the quadratic curve is smaller than the slope (Y3−Y0)/X3 of the straight line at the downstream end of the flight portion 7, and larger than the slope (Y3−Y0)/X3 of the straight line in the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to three rotations. Accordingly, the relationship of b<(Y3−Y0)/X1<2aX3+b is established.
In addition, the quadratic curve (solid line) of the inner wall surface of the casing between the top portion at the downstream end of the flight portion 7 and the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to one rotation can be expressed as y=cx2+dx+Y0′. Here, Y0′ designates an intersection between the quadratic curve and the y-axis. The slope at the downstream end of the flight portion 7 in the quadratic curve is d, and the slope in the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to one rotation is 2cX1+d.
The slope of the quadratic curve is larger than the slope (Y3−Y0)X3 of the straight line at the downstream end of the flight portion 7, and equal to the slope 2aX1+b of the quadratic curve in the top portion on the upstream side from the top portion at the downstream end of the flight portion 7 by the amount corresponding to one rotation. Accordingly, the relationship of d>(Y3−Y0)/X3, and the relationship of 2aX1+b=2cX1+d are established.
As described above, according to the present modification example, in the sectional view in the radial direction of the shaft portion 6, the imaginary line connecting the top points of the flight portion 7 is a straight line all over the range between the top portion on the upstream side by the amount corresponding to one rotation and the top portion at the downstream end. Thus, the screws 2 and 3 can be produced easily.
The above description of the embodiments of the present disclosure are not to limit the present disclosure particularly, but they are merely exemplars. Specific configurations and so on can be designed and changed suitably. In addition, the operations and effects described in the embodiments of the disclosure are merely listed as most suitable operations and effects that can be obtained from the present disclosure. The operations and effects of the present disclosure are not limited to the operations and effects described in the embodiments of the present disclosure.
The present application is based on Japanese Patent Application No. 2018-119855 filed on Jun. 25, 2018, the content of which is incorporated herein by reference.
1, 101, 201 screw extruder
2,3 screw
4 casing
6 shaft portion
7 flight portion
8,9 roller
10 bank portion
11 supply port
11
a downstream end
13 casing upstream portion
14 casing downstream portion
50 sheet
Number | Date | Country | Kind |
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2018-119855 | Jun 2018 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2019/021875 | 5/31/2019 | WO | 00 |