Screw vacuum pump with a coolant circuit

Information

  • Patent Grant
  • 6758660
  • Patent Number
    6,758,660
  • Date Filed
    Monday, September 30, 2002
    22 years ago
  • Date Issued
    Tuesday, July 6, 2004
    20 years ago
Abstract
A screw vacuum pump (1) has shafts (7, 8) and rotors (3, 4) secured to the shafts. Each rotor has a central hollow chamber (31) which receives the shaft or contains in built-in components rotating along with the rotor to define a relatively thin annular slot segment (32) for cross-flow circulation of coolant. The annular slot segment is disposed between the built-in components and an inner wall of the rotor's hollow chamber and between a suction side and a delivery side of the rotor. Separate feed and discharge lines (41, 55, 63, 77, 78, 81, 89, 99, 101, 103) circulate the coolant through the annular slot segment in such a way that the coolant remains cavitation-free and bubble-free.
Description




BACKGROUND OF THE INVENTION




The present invention relates to a screw vacuum pump comprising two shafts and two rotors secured to the shafts, whereby each rotor has a central hollow chamber provided with devices for guiding a coolant flow.




Screw vacuum pumps of this kind are known from the German patent applications 197 45 616, 197 48 385 and 198 00 825. Since these are operated in a dry manner (without coolant or lubricant in the pump chamber), there exists the problem of dissipating the heat produced during operation caused chiefly by compressing the pumped gases.




In the instance of the screw vacuum pump known from DE-A-197 45 616 with a cantilevered rotor, both rotor and shaft are equipped with a pocket hole which is open towards the bearing side. A central coolant pipe affixed to the casing extends into the pocket hole, said coolant pipe being guided out of the bore on the side of the bearing and opening out on the rotor side just in front of the end of the pocket hole. With the aid of a coolant pump, the coolant is pumped through the central pipe into the bore. It flows back via the annular chamber between the stationary coolant pipe and the rotating inner wall of the pocket hole. The diameter of the bore in both the rotor and the shaft is relatively small so that the surfaces over which the coolant flows are also small. Moreover, shearing forces occur between the pipe fixed to the housing and the rotating wall of the hollow chamber, producing in the coolant unwanted friction and thus an increase in the temperature. The effectiveness of the desired cooling facility for the rotors is limited for these reasons.




In DE-A-197 48 385 two cooling methods are disclosed. In the instance of a first solution each of the rotors is equipped with a hollow chamber open on one side, into which the coolant is injected. Owing to the rotation, a film forms on the inside of the rotor said film flowing back to the opening of the hollow chamber. In the instance of a film cooling arrangement of this kind there exists the danger of the film breaking down so that the desired cooling effect is interrupted. In addition, it is proposed to equip the hollow chamber in the rotor with conical sections so as to be able to increase the dwell time of the coolant in the hollow chamber of the rotor and thus also influence the amount of heat dissipated. In the instance of such conical sections which support pumping of the flow, however, there all the more exists the danger of the coolant flow breaking down. Finally film cooling arrangements have the general disadvantage, that a stationary flow profile forms, in which that part of the film which is close to the wall flows much more slowly compared to the section of the film further away from the wall. The area close to the wall thus practically forms an isolating layer hampering heat dissipation. For the purpose of removing this disadvantage it has already been proposed to provide obstructions in the flow so that the stationary flow profile is interrupted by turbulence. Thus an exchange of heat can be attained between the film sections close to the wall and those further away from the wall. However, installing obstructions is involved and in all slows down the velocity of the coolant flow.




DE-A-198 20 523 discloses a cooling system similar to the one detailed above. Cooled oil is injected into a hollow section of the shaft. Due to centrifugal forces the oil is displaced outwards to the inner wall of the hollow chamber extending conically in the direction of the discharge side.




In a further embodiment disclosed in DE-A-197 48 385, the coolant flows through an annular slot between rotor shaft and a bearing base extending into the rotor's hollow chamber. As to cooling of the rotor itself, a coolant flow of this kind has very little effect.




DE 198 00 825 discloses a screw pump with entirely hollow rotors. Coolant/lubricant is continuously supplied to, respectively discharged from the hollow chambers. As to the bearings which are arranged on the side where the coolant is discharged, a kinematic reversal has been implemented, i.e., they have a stationary inner ring and a rotating outer ring. The hollow chambers may be designed to be cone-shaped (widening in the direction of the flow) or may have an inner pumping thread. In the instance of such a screw pump there forms a coolant film which requires high rotational or circumferential velocities. The already mentioned danger of the coolant film breaking down exists. Monitoring facilities for an even spread of the coolant quantity to both rotors is, for this reason, absolutely recommended. Also, the necessity detailed of producing turbulence in the film exists, in order to attain an effective cooling effect. Finally equipping a rotor with a conical hollow chamber has several disadvantages: the conical hollow chamber is difficult to manufacture. In the instance of a cantilevered rotor on the delivery side and feeding in the coolant on the suction side of the rotor, the mass of the rotor in the area distant from the bearing is large. Correspondingly, when employing a cantilevered rotor on the delivery side the design needs to be involved. Finally, the fact that the coolant needs to be discharged relatively far out on the delivery side (at a great radial distance), limits the design options available.




DE-A-198 00 825 discloses a further embodiment, in which the rotors are each cantilevered on a shaft stub which extends into a hollow chamber in the rotor, said chamber being only open on the bearing side. The disadvantages detailed above also apply to this embodiment.




In the instance of all cooling systems detailed, there exists in addition the disadvantage that cooling is not performed in a counterflow. The coolant is in each instance supplied to the suction side of the rotor and not to the delivery side which is exposed to a significantly greater extent to the heat produced within the pump.




It is the task of the present invention to equip a pump of the aforementioned kind with an effective cooling arrangement permitting the pump to be manufactured in a simple, compact and cost-effective manner.




SUMMARY OF THE INVENTION




This task is solved through the characterising features of the patent claims.




It has been found that the cooling arrangement in accordance with the present invention in which the coolant flows through a relatively narrow, preferably cylindrical slot in the rotating system at sufficient velocity, has an unexpectedly good cooling effect, particularly since the annular slot can be arranged far to the outside, i.e. in the immediate vicinity of the root circle of the rotor's profile. Since the coolant is not injected, any hollow cavities which might interrupt the cooling effect are not present. Finally there exists the advantage that the direction for the coolant flow may be selected freely so that there is no obstacle as to cooling by way of a counterflow. This results in an equalisation of the temperature spread so that on the delivery side and the suction side narrow rotor/casing slots can be maintained.




As to the selection for the thickness of the annular slot it is relatively narrow, 0.2 to 5 mm for example, preferably 0.5 to 2 mm, whereby the thickness of the slot also depends on the coolant employed, the oil commonly used in vacuum pumps, for example. Apparently it is important that the distance between the two boundary films close to the walls be relatively small so that they will mutually influence each other in a turbulent manner. A laminar flow not influenced by the boundary layers keeping these separated and impairing the transfer of heat is apparently not present or is of negligible thickness.




In order to effectively cool the rotors, the velocity of the coolant (again depending on the type of coolant employed) must be sufficiently high. Flow velocities in the order of 0.1 to 1 m/s, preferably 0.3 to 0.7 m/s have been found to be expedient in the instance of cooling oil. With the known oil supply pumps, be they centrifugal, gear or similar pumps, the required pressure differences can be generated.




Still further advantages of the present invention will become apparent to those of ordinary skill in the art upon reading and understanding the following detailed description of the preferred embodiments.











BRIEF DESCRIPTION OF THE DRAWINGS




The invention may take form in various components and arrangements of components, and in various steps and arrangements of steps. The drawings are only for purposes of illustrating a preferred embodiment and are not to be construed as limiting the invention.





FIG. 1

is a sectional view through a screw vacuum pump with cantilevered rotors;





FIG. 2

is a sectional view through a screw vacuum pump with rotors having bearings at both sides;





FIGS. 3

,


4


, and


5


are sectional views through each of two rotors of a screw vacuum pump in which the coolant is supplied to and discharged from the cooling slot by a central hollow chamber in the rotor shaft;





FIG. 6

is a sectional view of a rotor with a means for displacing the cooling slot to the outside;





FIGS. 7



a


,


7




b


and


8


illustrate an alternate embodiment in which a component is disposed in a hollow chamber of the rotor independent of shaft limits on the cooling slot;





FIG. 9

is an alternate embodiment with a two section rotor.











DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS




The screw vacuum pump


1


depicted in

FIG. 1

comprises pump chamber casing


2


with the rotors


3


and


4


. Inlet


5


and outlet


6


of the pump


1


are schematically marked by arrows. The rotors


3


and


4


are affixed on to the shafts


7


and


8


respectively, said shafts being each supported by a cantilevered manner by two bearings


11


,


12


and


13


,


14


respectively. One bearing pair


11


,


13


is located in a bearing plate


15


which separates the pump chamber being free of lubricant from a gear chamber


16


. Located in casing


17


of the gear chamber


16


are the synchronising toothed wheels


18


,


19


affixed to the shafts


7


and


8


, as well as a pair of toothed wheels


21


,


22


serving the purpose of driving the pump


1


, where one toothed wheel is coupled to the shaft of the drive motor


23


arranged vertically besides the pump


1


. Moreover, the gear chamber has the function of an oil sump


20


. The second pair of bearings


12


,


14


, of the shafts


7


,


8


is located in bores


24


,


25


said bores penetrating the bottom of the gear chamber housing


17


. The shafts


7


,


8


in turn penetrate through bores


24


,


25


and end in an oil containing chamber


26


being formed by casing


17


and a thereto affixed trough


27


.




From

FIG. 1

it is apparent that the rotors


3


and


4


each have a hollow chamber


31


in which the shaft


8


extends and in which the cooling slot


32


is located. Since only rotor


4


is depicted by way of a partial section, the present embodiment is explained only with reference to this rotor


4


. In the embodiment according to

FIG. 1

, the annular slot section


32


is located directly between shaft


8


(resp.


7


) and rotor


4


(resp.


3


). To this end the cylindrical inner wall of the rotor containing the hollow chamber


31


is equipped in its middle area with a section


33


turned off on a lathe, the depth of which corresponds to the thickness of the cooling slot


32


. On the suction side and the delivery side, the shaft


8


rests flush against the inner wall of the hollow chamber


31


. In addition, the shaft


8


is equipped in these areas with grooves


35


and


36


for sealing rings


37


and


38


which ensure a leak tight separation of the cooling slot


31


from the pump chamber.




The cooling slot


32


is supplied with the coolant through the shaft


8


. It is equipped with a first bore


41


extending from the bottom end of the shaft


8


to the end of the cooling slot


32


on the delivery side. Via a cross bore


42


the bore


41


is linked to the cooling slot


32


. The coolant is supplied to the cooling slot


32


through bores


41


and


42


. The coolant flows through the cooling slot


32


from the delivery side to the suction side of the rotor


4


. Since most of the heat which needs to be dissipated is generated on the delivery side of the rotor


4


, the rotor


4


is cooled in a counterflow.




The coolant is evacuated through the second bore


43


in the shaft


8


. Said bore extends from the suction side of the cooling slot


32


up to the level of the gear chamber


16


. The cross bores


41


,


45


provide in each instance the link between bore


43


with the cooling slot


32


respectively the gear chamber


16


.




Reliable cooling of the rotors


3


,


4


is attained when the coolant is capable of flowing through the relatively narrow cooling slots


32


relatively quickly and undisturbed (free of cavitation and contamination). For this reason it is expedient to ensure, besides cooling and filtering of the coolant, a sufficient pumping force. In the design example in accordance with

FIG. 1

, therefore, the gear chamber


16


, resp. the oil sump


20


is linked to the chamber


26


through a line


51


in which there is located besides a cooler


52


and a filter


53


, an oil pump


54


which may be designed by way of a gear pump, for example. The oil pump


54


ensures that the coolant enters at the necessary pressure and free of cavitation from chamber


26


into the bore


41


.




Moreover, there exists the possibility of arranging oil pumps (centrifugal pumps, gear pumps) in the area of the bottom ends of the shafts


7


,


8


. However, these need to be so designed that they are capable of meeting the requirements as to the desired pumping properties.




Depicted in

FIG. 2

is an embodiment in which the shafts


7


,


8


of the rotors


3


,


4


, are supported by bearings on both sides, specifically at bearing plate


15


(bearing


11


,


13


) and in the pump chamber housing


2


(bearing


12


,


14


). The lower ends of the shafts


7


,


8


end in gear chamber


16


.




Owing to the fact that the shafts


7


,


8


are supported by bearings at both sides, there exists the possibility of supplying the coolant on the suction side in a simple manner. To this end the shafts are equipped on the suction side with a preferably cylindrical pocket hole


55


which extends up to the end of the cooling slot


32


at the suction side.




Via a cross bore


56


the bore


55


is linked to the cooling slot


32


. On the delivery side the shafts


7


,


8


are equipped with a pocket hole


57


which extends up to the end of the slot


32


on the delivery side and which is linked to said slot via the cross bore


58


.




For the purpose of supplying the coolant to the pocket holes


55


, these are linked via line


51


, said line being connected to oil sump


20


whereby the line incorporates oil pump


54


, filter


53


and cooler


52


. In the instance detailed, the coolant flows through the cooling slot


32


from the suction side towards the delivery side.




In the design example according to

FIG. 3

in which only the rotor


4


and the shaft


8


are depicted, further means of supplying to, respectively evacuating the coolant from the cooling slot are detailed. The shaft


8


is equipped with a central pocket hole being open on the delivery side and extending over the end of the cooling slot


32


at the suction side. Said pocket hole forms a hollow chamber


61


in which a guide component


62


for the coolant is located. The guide component


62


extends from the bottom end of the shaft


8


up to and past the end of the cooling slot


32


on the delivery side. The coolant is supplied via the longitudinal bore


63


in the guide component


62


, said bore being linked via truly aligned cross bores


64


through the component


62


and the shaft


8


to the end of the cooling slot


32


on the delivery side. At the level of the cooling slot


32


on the suction side, the shaft


8


is equipped with one or several cross bores


66


which open out into the chamber formed by the pocket hole


61


and the face side of the guide component


62


. Said chamber is linked via the longitudinal bore


68


and the truly aligned cross bores


69


(in the guide component


62


and in the shaft


8


) to the gear chamber


16


(not depicted in FIG.


3


).




Depicted in

FIG. 4

is an embodiment in which the guide component


62


comprises three sections


71


,


72


,


73


which divide the hollow chamber


61


in the shaft


8


in to three partial chambers


74


,


75


,


76


which are each located at the level of the cross bores


69


,


64


and


66


respectively. Through suitable bores in the sections


71


to


73


as well as line sections


77


and


78


linking said bores, separate supply and evacuation of the coolant may be implemented. The guide component may be fitted easily, since bores which need to be truly aligned are not present. Cooling in a counterflow can be implemented in a simple manner.




In the embodiment in accordance with

FIG. 5

, the coolant is supplied in contrast to the embodiments in accordance with

FIGS. 3 and 4

, through a central bore


81


in the guide component


62


. The coolant passes into the hollow chamber


61


formed by the pocket hole as well as the guide component


62


and through the cross bore


66


into the cooling slot


32


. The evacuation bores


64


are linked to lateral longitudinal grooves or an annular chamber


82


turned off on a lathe said annular chamber being located in the guide component


62


. The longitudinal grooves or the annular chamber


82


extend up to the level of the gear chamber


16


where they are linked to the cross bores


69


.




The embodiment in accordance with

FIG. 6

differs from the embodiments detailed above in that a bore is provided fully penetrating the shaft


8


and the rotor


4


. For the formation of the hollow chamber


31


, a cover


85


is provided on the suction side, this cover being linked via a bolt


86


with the guide component


62


. The guide component


62


is firmly inserted from the suction side. Together with bolt


86


and the cover


85


it serves the purposes of axially affixing the rotor


4


. The shaft


8


is equipped with an outer sleeve


87


which together with the rotor


4


forms the cooling slot


32


. This slot extends substantially only at the level of the delivery side of the rotor


4


. Radially displacing the cooling slot


32


towards the outside improves the cooling effect. The coolant is only supplied through a relatively short section


88


turned off on a lathe said section being located in guide component


62


. Before it enters into the section


88


turned off on a lathe, it flows through bores


89


,


90


in the bearing plate


15


as well as the chamber


92


on the bearing side of an axial face seal


93


where it ensures the formation of the necessary barrier pressure. The coolant is returned through the central bore


81


in the guide component


62


, resp. in the shaft


8


.




In the embodiment of

FIGS. 7



a


and


7




b


, the shaft


8


does not extend into the rotor's hollow chamber


31


. Said shaft is linked to the rotor


4


at the level of the delivery side. The guide component


62


in the rotor's hollow chamber


31


has a section


94


with an increased diameter which together with the inner wall of the rotor


4


forms the cooling slot


32


. A second section


95


having, compared to the section


94


a smaller diameter, penetrates the bore


61


in the shaft


8


.




For thermal reasons of permitting on the one hand the supply of the coolant from the open side of the bore


61


through a central bore


81


in the guide component


62


and on the other hand to permit cooling of the rotor


4


in a counterflow, it is required that the guide component


62


provides a crossing for the coolant flows. This is implemented through cross bores and outer groove sections in the guide component


62


which are designed as detailed in the following (see

FIGS. 7



a


,


7




b


and


8


): Coolant supplied centrally through the pocket hole


81


enters through a cross bore


98


into two groove sections


99


facing each other and then the coolant enters into the hollow chamber


31


(delivery side). Thereafter the coolant flows through the cooling slot


32


and enters through cross bores


66


into a line section


101


located centrally in the guide component. Said line section extends to a second cross bore


102


placed on the suction side with respect to the first cross bore


98


. The two cross bores


98


and


102


are arranged approximately perpendicular to each other. The cross bore


102


opens out into groove sections


103


facing each other, which are offset by about


90


degrees with respect to groove sections


99


. Thus it is possible to guide the returning coolant through these groove sections


103


to the cross bores


69


in the area of the gear chamber


16


.




In the design example in accordance with

FIG. 9

, the rotor


4


comprises two sections


4


′ and


4


″ having differently designed threads as well as each with a hollow chamber


31


′ and


31


″ respectively. The shaft


8


extends into the hollow chamber


31


″ of the rotor section on the delivery side


4


″ and thus forms the cooling slot


32


″. The guide component


62


is similarly designed as in the embodiment in accordance with

FIGS. 7

,


8


. It has a section


94


with an increased diamter which is located in hollow chamber


31


′ of the rotor section


4


′ and which forms together with the inside wall of this rotor section


4


′ the cooling slot


32


′. A further section


95


of the guide component


62


having a smaller diameter penetrates the central bore


61


in shaft


8


. The guide component


62


is equipped with a central bore


81


extending to the suction side of the rotor


4


.




For simplicity and better overview, an embodiment is presented in which the coolant is supplied through the central bore


81


and where the coolant flows through lateral bores


64


′ in section


94


on the suction side into the cooling slot


32


′. Through a section


66


′,


105


turned off on a lathe (or also through longitudinal grooves) as well as cross bores


64


′ the end of the cooling slot


32


′ on the delivery side is linked to the end of the cooling slot


32


″ on the suction side so that the coolant passes sequentially through the two cooling slots


32


′,


32


″. Through a further section


106


turned off on a lathe, the evacuation opening


66


″ on the delivery side of the cooling slot


32


″ is linked to the evacuation opening


69


at the level fo the gear chamber


16


. Also in the instance of this solution there exists the possibility of also employing the guide component


62


as a tie rod, specifically for affixing the rotor section


4


′.




Of course there also exists the possibility in the instance of the embodiment in accordance with

FIG. 9

of designing the supply and evacuation lines for the coolant in such a manner that the cooling slots


32


′,


32


″ are supplied separately and/or in a counterflow.




The embodiments of

FIGS. 7

to


9


are of particular advantage when the rotors


3


,


4


are cantilevered, since then there exists the possibility of manufacturing the guide component


62


of light materials like plastic, for example. Thus the mass of the rotors far from the bearing can be kept small. The usage of plastic or similar materials also offers the general advantage that there are located between the in flowing and the outflowing coolant materials and do not conduct heat very well.




The invention has been described with reference to the preferred embodiment. Obviously, modifications and alterations will occur to others upon reading and understanding the preceding detailed description. It is intended that the invention be construed as including all such modifications and alterations insofar as they come within the scope of the appended claims or the equivalents thereof.



Claims
  • 1. A screw vacuum pump comprising:two interengaging rotors, each rotor defining a central hollow chamber; two shafts, each shaft being received in one of the rotor central hollow chambers with a narrow, annular cooling slot segment being defined between the shaft and the rotor and extending between a suction side and a discharge side, the shafts each defining a feed line which feeds coolant oil to the annular cooling slot and a discharge line which discharges the coolant oil from the annular cooling slot; the annular cooling slots each having a thickness which is sufficiently thin that the boundary/flow layer of the cooling coil flowing along a shaft side surface of the annular cooling slot influences a boundary flow layer of the coolant coil flowing along a rotor side surface of the annular cooling slot in a turbulent manner.
  • 2. The vacuum pump according to claim 1 wherein the thickness of the annular cooling slot is less than 5 mm.
  • 3. A screw vacuum pump comprising:two shafts; two rotors secured to the shafts, each rotor having a central hollow chamber; coolant guiding components mounted in the hollow chamber of the rotors and rotating along with the rotor, said components forming a relatively narrow, annular slot segment having a thickness of 0.2 to 5 mm through which the coolant flows, the annular slot segment extending between the components and an inner wall of the rotor hollow chamber and between a suction side and a delivery side of the rotors, the supply of the annular slot segment with coolant being performed via separate feed and discharge lines traversing the shaft; and a means for ensuring a cavitation-free and bubble-free flow through the annular slot segment.
  • 4. The pump according to claim 3, wherein the annular slot segment is cylindrical in shape.
  • 5. A The pump according to claim 3 further including:a means for pumping the coolant, the means being so designed that the coolant flows at a velocity of 0.1 to 1 m/s through the slot.
  • 6. The pump according to claim 3, wherein a direction of coolant flow is so selected that the coolant flows from the delivery side towards the suction side.
  • 7. The pump according to claim 3, wherein the rotors are supported by bearings at both sides and the feed line for feeding the coolant includes:a pocket hole open to the suction side of the shafts.
  • 8. The pump according to claim 3, wherein the discharge line for evacuating the coolant opens out into a gear chamber.
  • 9. The pump according to claim 3, wherein at least one of the feed and discharge lines are defined by axial bores in the shaft.
  • 10. The pump according to claim 3, wherein the feed and discharge lines are linked to the annular slot segment via radially oriented bores.
  • 11. The pump according to claim 3, wherein each annular slot segment is located directly between the shaft and an inner wall of the rotor hollow chamber.
  • 12. The pump according to claim 3, wherein each shaft has a sleeve whose outside limits the annular slot segment.
  • 13. The pump according to claim 3, wherein the annular slot segment is formed by a section tuned off on a lathe, said section limiting the annular slot segment.
  • 14. The pump according to claim 3, wherein the rotors are cantilevered and the feed line for feeding the coolant includes:a pocket hole open towards the delivery side of the shafts.
  • 15. The pump according to claim 14, further including:a coolant pump which pumps the coolant through the delivery side ends of the shafts.
  • 16. The pump according to claim 3, wherein the shaft has a hollow chamber and further including:a guide component for guiding the coolant disposed in the shaft hollow chamber.
  • 17. The pump according to claim 16, wherein the rotor are each equipped with a through hole and each guide component functions as a tie rod for affixing the rotor to the shaft.
  • 18. The pump according to claim 16, wherein at least one of the feed and discharge lines are defined by:central or non-central axial bores, lateral longitudinal groove sections, or annular slots turned off on a lathe, said annular slots being defined in the guide component.
  • 19. The pump according to claim 18, wherein the feed and discharge lines include axial and radial line sections arranged in the guide component to permit separate crossing guidance of fed-in coolant and of evacuated coolant.
  • 20. The pump according to claim 16, wherein an end of each shaft at the suction side is linked to an end of the rotor on the delivery side and the guide component extends into the rotor central hollow chamber, and the guide component limits the annular slot segment.
  • 21. The pump according to claim 20, wherein the guide component is made of a light material.
  • 22. The pump according to claim 3, wherein the rotors each have two sections, each section having an annular cooling slot segment.
  • 23. The pump according to claim 22, wherein each shaft penetrates one rotor section on the delivery side, the other section being linked to an end of the shaft on the delivery side,a guide component extends into the hollow chamber of the rotor section on the suction side and limits the annular slot segment.
Priority Claims (1)
Number Date Country Kind
199 63 172 Dec 1999 DE
PCT Information
Filing Document Filing Date Country Kind
PCT/EP00/12471 WO 00
Publishing Document Publishing Date Country Kind
WO01/48385 7/5/2001 WO A
US Referenced Citations (5)
Number Name Date Kind
2938664 Noller May 1960 A
4917583 Frings et al. Apr 1990 A
4983107 Steffens et al. Jan 1991 A
5924855 Dahmlos et al. Jul 1999 A
6045343 Liou Apr 2000 A
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Number Date Country
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19800825 Jul 1999 DE
19820523 Nov 1999 DE
0290663 Nov 1988 EP
1290239 Mar 1962 FR
464493 Apr 1937 GB
953268 Aug 1982 RU
WO 9919630 Apr 1999 WO
WO 9942729 Aug 1999 WO