Scrubber for HVAC system

Information

  • Patent Grant
  • 10792608
  • Patent Number
    10,792,608
  • Date Filed
    Wednesday, August 24, 2016
    8 years ago
  • Date Issued
    Tuesday, October 6, 2020
    4 years ago
Abstract
In some embodiments, there is provided a scrubber system for cleaning return air in an HVAC unit, where the scrubber system attaches directly to an inlet of the return-air side of the HVAC unit, for example, by the mating of a flange on the system with a matching flange on the HVAC unit. The bolt-on scrubber system may comprise one or more sorbent materials, a fan for circulating return air through the sorbent, a damper-controlled inlet and a damper-controlled outlet to the attached return air side of the HVAC unit. Further, an additional air flow channel and a damper may be included in the system to control the flow of outside air into the HVAC unit. In some embodiments, the sorbents may be contained in removable inserts.
Description
FIELD OF THE DISCLOSURE

The present application generally relates to HVAC systems and particularly to indoor air treatment and contaminant removal therefrom.


BACKGROUND

Removal of contaminants from indoor air may be used as a means to achieving improved indoor air quality and improved economics of heating, ventilation and air conditioning (HVAC). Energy savings may be achieved as an indirect result of the contaminant removal, which enables reduced rate of air replacement. Scrubbers are a general category of air cleaning devices. Certain scrubbers utilize sorbent materials which effectuate air cleaning by selectively adsorbing certain gas species from air that comes into contact with the sorbent material. The use of regenerable sorbents in a scrubber incorporated into an air management system allows for long term operation, as a relative small amount of sorbent can be used repeatedly through a two-phase cycle of adsorption and regeneration.


SUMMARY OF SOME OF THE EMBODIMENTS

Some embodiments of the current disclosure include a scrubber assembly for scrubbing air from an enclosed environment, comprising: a housing; an interface arranged on an exterior of the housing and including a return air inlet (RAI) and a treated air outlet (TAO), and an adsorbent material configured to treat air received from the RAI. In some embodiments, the first interface is configured to mate with or otherwise couple to an external air inlet (EAI) of a heating, ventilation and air conditioning (HVAC) system; the EAI opens to a chamber of the HVAC system, through which air returned from an interior space (return air) traverses; the RAI is configured to receive at least a portion of the return air flowing via an EAI; the adsorbent material is configured to treat the at least a portion of the return air received via the RAI by adsorbing at least one contaminant contained therein, and the treated air is expelled from the scrubber assembly back to the HVAC system via the EAI.


In some embodiments, the adsorbent is regenerable, and may be configured to be regenerated in-situ. In some embodiments, the adsorbent material may be contained within a removable insert or cartridge. The assembly may further comprise one or more outside air inlets configured to receive outside air, wherein the one or more outside air inlets are further configured to receive at least a portion of the return air for use as a purging air for regenerating the regenerable adsorbent material. In some embodiments, the HVAC system includes one or more of an air handling unit (AHU) and a rooftop unit (RTU).


In some embodiments, the assembly further comprises one or more air outlets for expelling air from the scrubber assembly, wherein the one or more air outlets comprise one or more purging air outlets configured to expel air used to regenerate the absorbent material. In some embodiments, the return air from the chamber can flow directly into the scrubber assembly via the RAI without use of a conduit, and further the treated airflow may flow directly into the chamber via the TAO without us of a conduit. In some embodiments, the coupling of the interface to the EAI is facilitated via a mating of a flange of the scrubber assembly with a matching flange of the HVAC unit.


In some embodiments, the coupling of the interface to the EAI covers the EAI entirely, and wherein the scrubber assembly further comprises a pathway configured to allow flow of outside air into the chamber of the HVAC unit. In some embodiments, wherein the coupling of the interface to the EAI covers the EAI partially, the system may further comprise a separate channel configured to allow a flow of outside air into the chamber via an unobstructed portion of the EAI. In some embodiments, the coupling of the interface to the EAI may be configured to minimize a re-entrance of expelled, treated air into the scrubber assembly. In some embodiments, the coupling of the interface to the EAI can support at least a substantial portion of a weight of the assembly.


In some embodiments, the scrubber assembly can be configured as a portable unit configured for removable attachment to the HVAC system. It may further comprise a fan for circulating the return air through the adsorbent material. In some embodiments, the flow of the return air through the RAI, and/or the flow of the treated air through the TAO may be controlled by a damper. In some embodiments, the assembly may further comprise a heat source for heating at least one of a purging gas and the adsorbent material, the heat source selected from the group consisting of: a heat pump, a furnace, solar heat, an electrical coil and hot water. In addition, the assembly may contain a bypass damper configured to facilitate circulation of the heated air in the assembly through and/or over the adsorbent.


In some embodiments, the scrubber assembly may comprise one or more sensors configured to measure an amount of a contaminant in the at least a portion of the return air received via the RAI and/or the treated air expelled via the EAI. In some embodiments, the measurements can be used to control an activation and/or deactivation of the assembly.


Some embodiments of the current disclosure further include a system for cleaning air from an enclosed environment, comprising: an air handling unit (AHU) including an external air inlet (EAI), and a mixing chamber for allowing a mixing of air returned from an interior space (return air) of the enclosed environment with air entering via the EAI; and a fastened-on scrubber (BOS) assembly, the BOS assembly comprising a housing; an interface arranged on an exterior of the housing and including a return air inlet (RAI) and a treated air outlet (TAO), and an adsorbent material configured to treat air received from the RAI. In some embodiments, the interface is configured to mate with or otherwise couple to the EAI; the RAI is configured to receive the return air via the EAI, the return air having traversed through the mixing chamber; the adsorbent material is configured to treat the return air received via the RAI by adsorbing at least one contaminant contained therein, and the treated air is expelled from the scrubber assembly back to the AHU via the EAI.


In some embodiments, the coupling of the interface to the EAI may facilitate a direct flow of the mixed air into the BOS assembly. Further, the coupling of the interface to the EAI may also facilitate a direct flow of the treated into the mixing chamber of the AHU. In addition, the coupling of the interface to the EAI can support at least a portion of a weight of the BOS assembly.


It should be appreciated that all combinations of the foregoing concepts and additional concepts discussed in greater detail below (provided such concepts are not mutually inconsistent) are contemplated as being part of the inventive subject matter disclosed herein. In particular, all combinations of claimed subject matter appearing at the end of this disclosure are contemplated as being part of the inventive subject matter disclosed herein. It should also be appreciated that terminology explicitly employed herein that also may appear in any disclosure incorporated by reference should be accorded a meaning most consistent with the particular concepts disclosed herein.





BRIEF DESCRIPTION OF THE DRAWINGS

The skilled artisan will understand that the drawings primarily are for illustrative purposes and are not intended to limit the scope of the inventive subject matter described herein. The drawings are not necessarily to scale; in some instances, various aspects of the inventive subject matter disclosed herein may be shown exaggerated or enlarged in the drawings to facilitate an understanding of different features. In the drawings, like reference characters generally refer to like features (e.g., functionally similar and/or structurally similar elements).



FIG. 1 shows a schematic illustration of a rooftop unit (RTU) with a bolt-on scrubber (BOS) attached to the RTU's external air inlet (EAI), according to some embodiments.





DETAILED DESCRIPTION OF SOME OF THE EMBODIMENTS

In some embodiments, heating, ventilation and air conditioning (HVAC) systems may be used to treat and/or condition indoor air of an enclosed environment such as a building. For example, a HVAC system may comprise a roof-top unit (RTU), also known as a unitary system or a packaged unit. Such systems or units are usually placed outside a building, such as but not limited to the roof and the sides of the building. An RTU can refer to a complete “packaged unit” including an air handling unit (AHU) and a chiller, and/or an air handling unit receiving cold or hot fluid from a separate chiller or boiler. Throughout this disclosure, the terms “HVAC” and “RTU” may be used interchangeably to refer to a system for treating and/or conditioning air (including an AHU).


In buildings with HVAC systems in general and RTUs in particular, a scrubber may be added to the air circulation system. In some embodiments, the location of the scrubber and its interface with the indoor air circulation system can be an important determinant of the cost and performance of the added scrubber. Scrubbers may be integrated into a HVAC system, or they may be separate from but operationally coupled to the HVAC system. In buildings where the HVAC systems include outdoor RTUs, the physical installation and mechanical support of an outdoor scrubber to accompany the RTUs may be mechanically and structurally challenging, besides being cost-ineffective. For example, ducts may have to be used to connect scrubbers to RTU systems. Further, the installation and maintenance of the HVAC systems including the scrubbers may affect the structural integrity of the roof on which the HVAC system is located.


The present disclosure introduces a counter-intuitive and yet convenient and practical way to incorporate scrubbers into buildings with RTUs, by operationally coupling the scrubber (e.g., physically attaching the scrubber) to an external inlet (EAI) of the RTU. In some embodiments, the EAI may be a pre-existing outside air inlet. In some embodiments, the EAI may be an inlet of the RTU (or in general HVAC system) configured to specifically couple to the disclosed scrubber. That is, the EAI may be configured to couple to a scrubber so that the EAI provides the scrubber access to a mixing chamber of the HVAC or RTU where entering outside air and air returning from an enclosed environment mix. In such embodiments, the EAI may be the inlet that allows the outside air to enter into the mixing chamber. For example, a flange on the scrubber can be designed to mate with a flange around the EAI, and the connection may serve to support the weight and stability of the scrubber on the roof or the ground, as well as sealing the air flow pathways between the scrubber and the rooftop unit. Such a scrubber may be referred to as a bolt-on scrubber (BOS). Attaching a scrubber directly to an EI is counterintuitive because scrubbers are mainly used to treat or scrub return air (RA) returning from an enclosed environment such as a building. For example, the RA may be indoor air from a building and may contain unwanted substance that may have originated from occupants of the enclosed space, building materials, food, consumer products (e.g., cleaning products, etc.), and/or the like. Examples of such air contaminants include inorganic compounds, organic vapors, micro-organisms such as but not limited to bacteria, viruses, mold, fungi, airborne particles, etc., gases such as but not limited to carbon dioxide, carbon monoxide, sulfur oxide, nitrous oxide, radon, etc., and/or the like. Outside air (OA), which usually has less or no concentration of such contaminants, is usually not the subject of scrubbing systems. The inventors of the present disclosure have discovered that operationally coupling a BOS to an OA of a RTU provides a practical and effective system to scrub indoor air containing contaminants with little or no effect on the structural integrity of a roof.


In some embodiments, an RTU may include a mixing chamber operationally coupled to a return air inlet and an EAI of the RTU, which are configured to allow into the mixing chamber return air and outside air, respectively. In the mixing chamber, the RA may mix with the OA, in some cases diluting the concentration of the contaminants in the RA. In some embodiments, the RA inlet and/or the EAI may include dampers, valves, shutters, etc., to control the amount of OA to be mixed with the RA. The EAI may be protected by a louver or a rain cover.


In some embodiments, the coupling of the BOS to the RTU, or in general to a HVAC unit, may be in the form of a direct attachment between the BOS and the HVAC. For example, the BOS may include an interface that is configured to align with the EAI of the HVAC. In some embodiments, the BOS may include a housing and an interface arranged on an exterior surface of the housing. The interface may include a return air inlet (RAI) and a treated air outlet (TAO), and the interface may be configured to mate with or otherwise couple to an external air inlet (EAI) of the HVAC. In some embodiments, the EAI may be arranged adjacent a chamber of the HVAC system through which air returned from an interior space (return air) traverses. Further, the RAI may be configured to receive return air via the EOA, and once the return air is treated by the BOS (e.g., by an adsorbent material of the BOS, as will be discussed below), the treated air may be expelled from the TAO back to the HVAC system via the EAI.


In some embodiments, the BOS may be coupled to the EAI of the RTU such that a channel separate from the BOS may form and serve as an inlet for outside air. For example, the BOS may cover some fraction of the surface area of the RTU's EAI such that OA enters the RTU through the unobstructed portion of the RTU's EAI. The fraction may range from about 10% to almost about 100%, including values and subranges there between. In some embodiments, the BOS may cover the entire EAI of the RTU. With the addition of the bolt-on scrubber to the RTU, in some embodiments, a pathway may be used to allow OA into the mixing chamber. The OA may be utilized to maintain positive pressure in the enclosed environment that is being air-conditioned, for example, to compensate for intentional or unintentional air escaping from the building, including exhaust from bathrooms, etc. Furthermore, when outdoor temperature and humidity conditions are favorable, it may be energetically preferable to increase the amount of outside air so as to reduce the conditioning (cooling, heating, etc.) of the air to be supplied to the enclosed environment. In such embodiments, the BOS may include a pathway or channel that facilitates the introduction of OA into the RTU (via the BOS, for example). There may also be an additional separate channel (in addition to the pathway through the BOS) that facilitates the flow of OA into the RTU. The bolt on scrubber may entirely cover the EAI, and it can address the changing need for OA by having a controlled pathway for outdoor air to flow directly into the mixing chamber. The flow of OA through the unobstructed portion and/or the BOS pathway may be controlled via any suitable means such as but not limited to dampers, shutters, fans, blowers, and/or the like. For example, the amount of OA flowing through the noted pathway can be controlled by one or more dampers, and may be further assisted by a booster fan, although in general the RTU inlet has a lower pressure that the outside air.


In some embodiments, the coupling of the BOS to the EAI may be configured to facilitate the streaming of air into the BOS from the RTU. For example, the BOS may be positioned on the EAI in such a manner as to allow the BOS to receive a stream of air from the mixing chamber of the RTU. For example, the BOS may be directly attached to the EAI (e.g., an interface of the BOS including the RAI and the TAO may be directly attached or “mated” with the EAI of the HVAC or RTU). The air from the mixing chamber may be mixed air containing both OA and RA. In some embodiments, the BOS and/or the BOS's coupling to the RTU may be configured such that the mixed air that flows into the BOS contains a desired proportion of RA to OA. For example, the BOS may be coupled to the RTU such that a RA inlet of the BOS may be positioned so as to intercept a desired amount (at least approximately) of RA entering the mixing chamber. In some embodiments, the amount of RA flowing into the BOS may comprise between about 75% to about 100%, between about 85% to about 100%, between about 90% to about 100%, about 95%, etc., including values and subranges there between, of the total amount of mixed air entering the BOS. In some embodiments, ducts may be used to couple the inlets/outlets of the BOS to those of the RTU. For example, the BOS RA inlet and TAO may be coupled to the EAI of the RTU via ducts. In some embodiments, however, the couplings may be direct connections without the aid of ducts or similar equipment. For example, the BOS RA inlet and treated air outlet may be directly attached to the RTU's EAI. As will be discussed below, such coupling or mechanical attachment may also facilitate the secure placement of the BOS to that of the RTU.


In some embodiments, the BOS may also be equipped with air flow aids such as a fan, blower, etc., to urge air to flow from the mixing chamber to the BOS. The RTU may also contain a flow aid to assist in the flow of mixed air from the mixing chamber of the RTU into the BOS. In some embodiments, the RTU and/or the BOS may also be equipped with a diverter that directs the incoming (into the mixing chamber) RA to flow towards the BOS such that the mixed air entering the BOS contains a higher amount of RA (e.g., compared to OA).


In some embodiments, the coupling or mechanical attachment of the BOS to the EAI of the RTU is configured to securely place the BOS relative to the RTU and prevent its movement without separately securing it to the roof or the ground. Such a configuration is in particular useful to securely incorporate the BOS to the RTU with little or no adverse effect to the structural integrity of the roof. For example, the attachment may support some or all of the BOS's weight, thereby reducing or even eliminating the need to provide separate structural support between the BOS and the roof or ground. Further, the coupling of the BOS to the RTU's EAI can provide a direct connection to the RA stream, from which one may draw RA (which may flow into the BOS as part of a mixed RA and OA stream) to treat (e.g., filter, scrub, etc.) and reinject the treated air back into circulation. The secure coupling or mechanical/physical attachment of the BOS to the RTU allows for the formation of a single module that may be convenient for universal installation procedures of field retrofits, and less dependent on building specifics. Such modules make the retrofitting or installation procedures easier to accomplish, and also to easier teach to and train installation technicians.


In some embodiments, the BOS may comprise a BOS inlet to receive mixed RA and OA from the mixing chamber of the RTU, and a BOS treated air outlet to release air treated by the RTU back into the mixing chamber. The BOS may also include an additional purge gas inlet for receiving purge gas for use in the regeneration of the sorbent of the BOS, and an exhaust outlet for releasing exhaust purge gas containing some or all of the contaminants desorbed from the sorbent of the scrubber during regeneration. In some embodiments, the purge gas may be outside air, and/or RA diverted away from the mixing chamber. For example, there may be certain situations where one may not wish to use outside air as a purge air (e.g., when OA itself contains a high level of pollution). In such cases, some or all of the RA may be diverted towards the BOS (e.g., through the purge gas inlet) to regenerate a sorbent that may have been saturated with contaminants. In some embodiments, a combination of OA and RA may be used as purge air to regenerate the adsorbent, and the OA inlet and/or the RA inlet of the BOS can be used as an inlet to receive the purge air into the BOS.


In some embodiments, the BOS may include a heat source to heat the purge gas (OA and/or RA, for example) so as to enhance the desorption of the sorbent during the regeneration phase. In some cases, the purge air may be at the requisite temperature (e.g., when the purge air is an outside air in the summer when temperatures are elevated), and the purge air may be used to regenerate with sorbent of the scrubber without further heating. The heat source may also be used to directly heat the adsorbents. Examples of a heat source that can be used to heat the purge gas and/or the adsorbent directly include an electrical coil, a radiator, a heat pump, a solar heater, a furnace, hot water, gas or other fuel, and/or the like.


In some embodiments, as mentioned above, a source of heat for heating a purging gas and/or adsorbent materials of the BOS may be a heat pump. The heat pump may use fluids and compressors in a closed chiller loop of condensation and evaporation, also referred to as a “condenser-evaporator loop”, so as to move heat opposite its usual direction, namely removing heat from a lower temperature evaporator region and adding heat to a higher temperature condenser region. In this way, a heat pump can act to continuously cool the ambient environment in a cold region (i.e. the evaporator side or cold side) while heating the ambient in a warmer region (the condenser side or warm side). Viewed as a refrigerator or chiller, it facilitates the cooling of air below its surrounding temperature; viewed as a heater, it delivers heat where needed. In some embodiments, the heat pump may be configured to remove heat from RA and concurrently heat the purge gas (e.g., OA).


In some embodiments, the BOS may also comprise filters configured to capture contaminants contained in air entering the BOS. For example, one or more filters may be used to remove unwanted substances from the mixed air coming in from the mixing chamber and/or the purge air (outside air and/or returning air). In some cases, the filter may not remove all the unwanted substances in the air being filtered (e.g., very small sized particles). The scrubbing of the mixed air may be accomplished via a sorbent configured to remove some or all of the contaminants or unwanted substances contained in the mixed air. For example, the sorbent may include an adsorbent material or a scrubber configured to capture and adsorb the contaminants in the incoming mixed air. The sorbent material may be distributed in the path of the air flowing through the scrubber, or it may be held in one or more locations in replaceable and/or removable inserts or cartridges, to facilitate sorbent replacement when needed. As discussed above the mixed air flowing through the scrubber may at least partially be cleaned by the process of filtration by the one or more filters. Further, the air may be scrubbed of some or all of its remaining contaminants via the adsorption of the contaminants onto the sorbent materials. The cleaned air may then flow back into the mixing chamber via the BOS outlet, from where it can be returned back into the building as a supply air (SA) after being air conditioned through the cooling (or heating) coils of the RTU. In some embodiments, some of this clean air may be returned back into the BOS as part of the mixed air flowing into the BOS. In most embodiments, this portion of cleaned air that returns back into the BOS from the mixing chamber may constitute a small proportion of the total mixed air entering into the BOS. For example, the portion may be less than about 10%, less than about 8%, less than about 5%, less than about 3%, less than about 1%, of the total mixed air, including values and subranges there between. In some embodiments, the portion of cleaned air that may be immediately returned back into the BOS from the mixing chamber may be minimized by judicious use of fans, valves, blowers, etc., and favorable placements of the BOS inlet and outlet (e.g., so as to direct the cleaned air away from the BOS inlet and towards the air-conditioning units of the RTU).


In some embodiments, the scrubber may comprise a regenerable adsorbent material that is configured to adsorb at least one gaseous contaminant contained in the mixed airflow of OA and RA during the adsorption mode of the operation of the scrubber. During the regeneration mode, the regenerable adsorbent material is configured to release contaminants adsorbed onto the adsorbent. Regeneration may be achieved under appropriate conditions where the contaminants that have been captured by the adsorbent material are released and purged, allowing the adsorbent material to regain some or all of its adsorptive properties. For example, regeneration may take place during a temperature-swing cycle where the adsorbent material is heated directly by a heat source (e.g., heater) and/or by a heated purging gas, followed by the purging of the contaminants by the purging gas to be exhausted through an exhaust outlet of the scrubber. The combination of the effects of the heat and the purging air may remove some or all of the contaminants via temperature swing regeneration of the sorbents. Examples of adsorbent materials that can be used as scrubber in the BOS include clays, molecular sieves, zeolites, various forms of silica and alumina, porous silica, porous alumina, various forms of carbon, activated carbon, carbon fibers, carbon particles, titanium oxide, porous polymers, polymer fibers and metal organic frameworks, and/or the like. One or more of these adsorbent materials may be used to scrub contaminants from the mixed air, the contaminants including but not limited to carbon dioxide, volatile organic compounds, sulfur oxides, radon, nitrous oxides and carbon monoxide, and/or the like.


In some embodiments, the BOS may have the capability to perform automatic regeneration of the sorbent material from time to time. In other words, the BOS may be designed to switch automatically between the adsorption mode where contaminants are captured by the adsorbent to the regeneration mode where the adsorbent is regenerated (e.g., via temperature swing regeneration). The determination to switch between the modes may be made based on measurements of the concentration of contaminants in the air being treated (mixed RA and OA, for example) and/or the concentration of adsorbed contaminants on the adsorbents. For example, the BOS may comprise one or more sensors and a controller where the one or more sensors are configured to generate a signal corresponding to the concentration of the at least one gaseous contaminant and/or the presence of the at least one gaseous contaminant, and transmit the signal to the controller system. Upon processing the data from the signal, in some embodiments, the controller (e.g., an electromechanical control system) may instruct the regeneration accessories to initiate the regeneration process. For instance, the controller system may instruct the dampers of the BOS's RAI to not let in any more mixed air into the BOS, while allowing the damper of the BOS's OA inlet to receive outside air that can serve as a purging air. The switching between adsorption and regeneration may take place automatically as well as repeatedly.


In some embodiments, regeneration can be accomplished by heating the sorbent and subsequently purging the sorbent with a stream of air that is exhausted externally. For example, the BOS may be equipped with an exhaust outlet, as well as with a damper that can open and close the outlet, i.e., control flow of the exhaust through the outlet. In some embodiments, one may wish to recycle the purging gas before exhausting the gas out the exhaust outlet. In such embodiments, the BOS may include a closed loop return path that may return used purge gas back to flow through and/or over the adsorbent in the BOS so as to regenerate it repeatedly. In some embodiments, whether to recycle a purging gas or not may be determined by the controller based on purging gas airflow contaminant level measurements obtained from the one or more sensors of the BOS. For example, if the gaseous contaminant level in the exhausted purging gas is below some threshold level, then the exhausted purging gas may be recycled and reused as purging gas airflow by returning it to the adsorbent via the closed loop return path. In some embodiments, the recycled purging gas may also be combined with fresh purging gas (e.g., fresh OA and/or RA). In some embodiments, the closed loop return path may be provided with dampers to control the flow of the exhausted purge gas airflow into and out of the closed loop. For example, one or more dampers within the BOS may be opened so as to facilitate the circulation of a purging gas within the BOS while other dampers (such as those located at BOS inlets and outlets) are closed off to prevent entry and/or escape of the purging gas before the regeneration is complete.


In some embodiments, the BOS can be operably coupled to a heat exchanger that is configured to facilitate thermal communication between the exhaust purge gas and gas coming into the BOS to be used as a fresh purge gas. For example, the heat exchanger may facilitate thermal communication between an exhaust purge gas and OA, RA, and/or a combination thereof. The thermal communication may elevate the temperature of the incoming fresh purge gas, aiding in the regeneration of the adsorbents with little or no heating of the purge gas with additional heating source (hence conserving energy, for example). In some embodiments, the heat exchanger may facilitate thermal communication between the exhaust purge gas and the mixed air in the mixing chamber (for example, the mixed air drawn into the BOS for treatment).


Thermal communication may include any type of heat transfer, such as by contact, convention or conduction, etc. For example, the heat exchanger may comprise a shell and tube configuration, an air coil configuration, a plate configuration, a fin configuration or a counter-flow configuration. In some embodiments, the heat exchange may be facilitated by having conduits carrying the incoming air (e.g., OA, RA, combination thereof, etc.) and the exhaust purge air to run in parallel and in close thermal communication over an extended length of these conduits. Thermal communication can be assisted by increasing a shared surface area of the parallel conduits. In some embodiments, the two conduits may be arranged so that the incoming gas and the exhaust purge gas flow in opposite directions, substantially increasing the heat exchange rate. In some embodiments, the purge gas may be recycled until the efficiency of thermal communication falls below a desired threshold (e.g., the temperature of the exhaust purge gas becomes too low to heat the incoming purge gas in any substantial manner).



FIG. 1 is a schematic illustration of a rooftop unit (RTU) 200 with a bolt-on scrubber (BOS) 100 attached to the RTU's EAI 210. The RTU may comprise a mixing chamber 220 into which return air (RA) returning from the enclosed environment and outside air (OA) entering from outside the enclosed environment may flow. OA may enter the RTU via a pathway through the BOS (for example, if the BOS covers the entire EAI 210 of the RTU) or the OA may enter into the mixing chamber through a separate channel 300. Without the disclosed BOS, a mixture of the RA and the OA may proceed to and be filtered by filter 240 before being conditioned (e.g., heated and/or cooled) by an air conditioning unit 250 (e.g., cooling/heating coils). The treated air may then be supplied back into the enclosed environment as a supply air (SA).


In the presence of the BOS, the RA, the OA or a mixture thereof may flow into the BOS return air inlet (RAI) 110 for scrubbing by the sorbents 160. The flow of the air into the BOS 100 may be facilitated by a suitable means such as a fan 150 that draws the air into the BOS 100 via the BOS RA inlet 110. The air is then scrubbed of some or all of its contaminants by a scrubber containing inserts or cartridges of sorbents 160 before being released back into the mixing chamber via the BOS treated air outlet 120. The BOS may include such sorbent inserts and cartridges along the flow path of the air to be treated (e.g., OA and RA mixture) between the RA inlet 110 and treated air outlet 120 of the BOS. In some embodiments, the air may also be filtered by a filter 190 in the BOS. In some embodiments, the BOS RAI 110 and the TAO 120 face the mixing chamber 220 of the RTU, and are securely attached or otherwise coupled to the RTU EAI 210. In some embodiments, the BOS 100 may not cover the entire RTU EAI 210, leaving a portion of the inlet to be used as a separate channel 300 for allowing in outside air. In some embodiments, there may be a separate channel 300 in addition to an OA pathway through the BOS 100 configured to allow OA flow into the RTU 200. Dampers 310 may be used to control flow of OA into the mixing chamber 220.


In some embodiments, the adsorbent 160 may be regenerated so as to desorb and remove the contaminants captured by the adsorbent 160. The adsorbent may be in the form of inserts or cartridges, and in some cases it may be removable (i.e., replaceable). During regeneration, the adsorbent 160 may be heated directly or indirectly by a heating source 180. In some embodiments, air circulates inside the scrubber in a closed loop, by opening a bypass damper 170, carrying heat from the heating source 180 to the sorbent 160. Accordingly, the adsorbent 160 may be heated so as to facilitate the removal of the contaminants adsorbed onto the adsorbent 160. Upon the heating of the adsorbent 160, in some embodiments, a purge air in the form of OA incoming through the OA inlet 130 may flow through/over the adsorbent 160 and purge or remove the contaminants. In some embodiments, the purge gas may be recycled by opening the bypass damper 170 and closing most or all other dampers in the BOS. In some embodiments, the purge air itself, containing OA and/or RA, may be heated by the heating source 180, and the heated purge air may then heat the adsorbent so as to facilitate the removal of the adsorbed contaminants, i.e., the heated purge air may heat the adsorbent and concurrently purge away the contaminants. Examples of a heating source include an electrical coil, a radiator, a heat pump (using fluids and compressors in a closed chiller loop of condensation and evaporation, for example), a solar heater, a furnace, hot water, gas or other fuel, and/or the like.


The switch between the adsorption mode, where mixed air of OA and RA flows through the adsorbent 160 so that the adsorbent 160 captures contaminants contained within the mixed air, and the regeneration mode, where some or all of the adsorbed contaminants are removed from the adsorbents 160, may be determined based on the measurements of one or more sensors 115 located in the BOS 100 and/or the RTU 200. The sensors may measure, for example, the concentration of contaminants adsorbed onto the adsorbent 160 and/or the amount of contaminants in the mixed air, and transmit (wirelessly or wired, for example) the measurements to controller (not shown) (e.g., microprocessor). The controller may then make a determination and initiate the appropriate mode for the BOS 100. For example, if the contaminant concentration of the RA or mixed air exceeds a certain threshold amount, the controller may activate the dampers of inlets and outlets of the BOS and the RTU to allow the air flow into the BOS 100 and be scrubbed. Similarly, damper 310 may be activated to allow OA into the mixing chamber 220. The controller may accomplish such tasks by transmitting signals wirelessly, for example. Once the adsorbents are regenerated, the exhaust purge gas may be discarded into the outside environment via a BOS exhaust outlet 140. In some embodiments, the exhaust purge gas may be reused for more cycles based on the amount of contaminant concentration contained within (for example, as measured by a sensor) or based on the temperature of the exhaust purge gas (if the temperature of the exhaust purge gas is still high enough to heat up the adsorbent, for example). The recycling of the purge gas may be accomplished via a closed loop return path. An example of such a closed loop return path occurs when dampers located at 110, 120, 130 and 140 are closed and damper 170 is open, facilitating the formation of a closed loop path where purging gas circulates in the BOS using the closed path via the opening through damper 170 and the passageway proximate to exhaust outlet 140. In this manner, a purging gas may be recycled and used again to regenerate the adsorbent in the BOS.


While various inventive embodiments have been described and illustrated herein, those of ordinary skill in the art will readily envision a variety of other means and/or structures for performing the function and/or obtaining the results and/or one or more of the advantages described herein, and each of such variations and/or modifications is deemed to be within the scope of the inventive embodiments described herein. More generally, those skilled in the art will readily appreciate that all parameters, dimensions, materials, and configurations described herein are meant to be an example and that the actual parameters, dimensions, materials, and/or configurations will depend upon the specific application or applications for which the inventive teachings is/are used. Those skilled in the art will recognize, or be able to ascertain using no more than routine experimentation, many equivalents to the specific inventive embodiments described herein. It is, therefore, to be understood that the foregoing embodiments are presented by way of example only and that, within the scope of the appended claims and equivalents thereto, inventive embodiments may be practiced otherwise than as specifically described and claimed. Inventive embodiments of the present disclosure are directed to each individual feature, system, article, material, kit, and/or method described herein. In addition, any combination of two or more such features, systems, articles, materials, kits, and/or methods, if such features, systems, articles, materials, kits, and/or methods are not mutually inconsistent, is included within the inventive scope of the present disclosure. Some embodiments may be distinguishable from the prior art for specifically lacking one or more features/elements/functionality (i.e., claims directed to such embodiments may include negative limitations).


Also, various inventive concepts may be embodied as one or more methods, of which an example has been provided. The acts performed as part of the method may be ordered in any suitable way. Accordingly, embodiments may be constructed in which acts are performed in an order different than illustrated, which may include performing some acts simultaneously, even though shown as sequential acts in illustrative embodiments.


Any and all references to publications or other documents, including but not limited to, patents, patent applications, articles, webpages, books, etc., presented anywhere in the present application, are herein incorporated by reference in their entirety. Moreover, all definitions, as defined and used herein, should be understood to control over dictionary definitions, definitions in documents incorporated by reference, and/or ordinary meanings of the defined terms.


The indefinite articles “a” and “an,” as used herein in the specification and in the claims, unless clearly indicated to the contrary, should be understood to mean “at least one.”


The phrase “and/or,” as used herein in the specification and in the claims, should be understood to mean “either or both” of the elements so conjoined, i.e., elements that are conjunctively present in some cases and disjunctively present in other cases. Multiple elements listed with “and/or” should be construed in the same fashion, i.e., “one or more” of the elements so conjoined. Other elements may optionally be present other than the elements specifically identified by the “and/or” clause, whether related or unrelated to those elements specifically identified. Thus, as a non-limiting example, a reference to “A and/or B”, when used in conjunction with open-ended language such as “comprising” can refer, in one embodiment, to A only (optionally including elements other than B); in another embodiment, to B only (optionally including elements other than A); in yet another embodiment, to both A and B (optionally including other elements); etc.


As used herein in the specification and in the claims, “or” should be understood to have the same meaning as “and/or” as defined above. For example, when separating items in a list, “or” or “and/or” shall be interpreted as being inclusive, i.e., the inclusion of at least one, but also including more than one, of a number or list of elements, and, optionally, additional unlisted items. Only terms clearly indicated to the contrary, such as “only one of” or “exactly one of” or, when used in the claims, “consisting of,” will refer to the inclusion of exactly one element of a number or list of elements. In general, the term “or” as used herein shall only be interpreted as indicating exclusive alternatives (i.e. “one or the other but not both”) when preceded by terms of exclusivity, such as “either,” “one of” “only one of” or “exactly one of” “Consisting essentially of,” when used in the claims, shall have its ordinary meaning as used in the field of patent law.


As used herein in the specification and in the claims, the phrase “at least one,” in reference to a list of one or more elements, should be understood to mean at least one element selected from any one or more of the elements in the list of elements, but not necessarily including at least one of each and every element specifically listed within the list of elements and not excluding any combinations of elements in the list of elements. This definition also allows that elements may optionally be present other than the elements specifically identified within the list of elements to which the phrase “at least one” refers, whether related or unrelated to those elements specifically identified. Thus, as a non-limiting example, “at least one of A and B” (or, equivalently, “at least one of A or B,” or, equivalently “at least one of A and/or B”) can refer, in one embodiment, to at least one, optionally including more than one, A, with no B present (and optionally including elements other than B); in another embodiment, to at least one, optionally including more than one, B, with no A present (and optionally including elements other than A); in yet another embodiment, to at least one, optionally including more than one, A, and at least one, optionally including more than one, B (and optionally including other elements); etc.


In the claims, as well as in the specification above, all transitional phrases such as “comprising,” “including,” “carrying,” “having,” “containing,” “involving,” “holding,” “composed of,” and the like are to be understood to be open-ended, i.e., to mean including but not limited to. Only the transitional phrases “consisting of” and “consisting essentially of” shall be closed or semi-closed transitional phrases, respectively, as set forth in the United States Patent Office Manual of Patent Examining Procedures, Section 2111.03.

Claims
  • 1. A system for cleaning air from an enclosed environment, comprising: an air handling unit (AHU) including: an external air inlet (EAI), anda mixing chamber for allowing a mixing of air returned from an interior space (return air) of the enclosed environment with air entering via the EAI; anda fastened-on scrubber (BOS) assembly, the BOS assembly comprising: a housing;an interface arranged on an exterior of the housing and including a return air inlet (RAI) and a treated air outlet (TAO), andan adsorbent material configured to treat air received from the RAI,wherein: the interface is configured to mate with or otherwise couple to the EAI,the RAI is configured to receive the return air via the EAI, the return air having traversed through the mixing chamber,the adsorbent material is configured to treat the return air received via the RAI by adsorbing at least one contaminant contained therein, andthe treated air is expelled from the scrubber assembly back to the AHU via the EAI.
  • 2. The system of claim 1, wherein the coupling of the interface to the EAI facilitates a direct flow of the mixed air into the BOS assembly.
  • 3. The system of claim 1, wherein the coupling of the interface to the EAI facilitates a direct flow of the treated air into the mixing chamber of the AHU.
  • 4. The system of claim 1, wherein the coupling of the interface to the EAI supports at least a portion of a weight of the BOS assembly.
  • 5. The assembly of claim 1, where the adsorbent is regenerable.
  • 6. The assembly of claim 1, where the adsorbent is configured to be regenerated in-situ.
  • 7. The assembly of claim 1, wherein the RAI is further configured to receive at least a portion of the return air for use as a purging air for regenerating the regenerable adsorbent material.
  • 8. The assembly of claim 1, further comprising one or more air outlets configured to expel air used to regenerate the absorbent material.
  • 9. The assembly of claim 1, wherein the coupling of the interface to the EAI is facilitated via a mating of respective flanges of the interface and the EAI.
  • 10. The assembly of claim 1, wherein the coupling of the interface to the EAI covers the EAI entirely, and wherein the BOS assembly further comprises a pathway configured to allow flow of outside air into the chamber of the HVAC unit.
  • 11. The assembly of claim 1, wherein the coupling of the interface to the EAI covers the EAI partially, and wherein the system further comprises a separate channel configured to allow a flow of outside air into the chamber via an unobstructed portion of the EAI.
  • 12. The assembly of claim 1, wherein the coupling of the interface to the EAI is configured to minimize a re-entrance of expelled, treated air into the BOS assembly.
  • 13. The assembly of claim 1, wherein the coupling of the interface to the EAI supports at least a substantial portion of a weight of the assembly.
  • 14. The assembly of claim 1, wherein the BOS assembly is configured as a portable unit configured for removable attachment.
  • 15. The assembly of claim 1, further comprising a fan for circulating the return air through the adsorbent material.
  • 16. The assembly of claim 1, wherein the flow of the return air through the RAI, and/or the flow of the treated air through the TAO is/are controlled by a damper.
  • 17. The assembly of claim 1, further comprising a heat source for heating at least one of a purging gas and the adsorbent material, the heat source selected from the group consisting of: a heat pump, a furnace, solar heat, an electrical coil and hot water.
  • 18. The assembly of claim 1, further comprising one or more sensors configured to measure an amount of a contaminant in the at least a portion of the return air received via the RAI and/or the treated air expelled via the EAI.
  • 19. The assembly of claim 18, wherein the measurements obtained from the sensors are used to control an activation and/or deactivation of the BOS assembly.
  • 20. The assembly of claim 1, wherein the adsorbent material is contained within a removable insert or cartridge.
CROSS REFERENCE TO RELATED APPLICATIONS

This application is a 35 U.S.C. § 371 national stage entry of PCT/US2016/048439, filed Aug. 24, 2016, entitled “Scrubber for HVAC System,” which claims priority to U.S. Provisional Patent Application No. 62/208,822, filed Aug. 24, 2015, entitled “Bolt-On HVAC Scrubber.” The disclosures of each of the above applications are which is incorporated by reference herein in their entireties.

PCT Information
Filing Document Filing Date Country Kind
PCT/US2016/048439 8/24/2016 WO 00
Publishing Document Publishing Date Country Kind
WO2017/035254 3/2/2017 WO A
US Referenced Citations (242)
Number Name Date Kind
1522480 Allen Jan 1925 A
1836301 Bechthold Dec 1931 A
2633928 Chamberlain Apr 1953 A
3042497 Johnson et al. Jul 1962 A
3107641 Haynes Oct 1963 A
3344050 Mayland et al. Sep 1967 A
3511595 Fuchs May 1970 A
3594983 Yearout Jul 1971 A
3619130 Ventriglio et al. Nov 1971 A
3702049 Morris, Jr. Nov 1972 A
3751848 Ahlstrand Aug 1973 A
3751878 Collins Aug 1973 A
3795090 Barnebey Mar 1974 A
3808773 Reyhing et al. May 1974 A
3885927 Sherman et al. May 1975 A
3885928 Wu May 1975 A
4182743 Rainer et al. Jan 1980 A
4228197 Means Oct 1980 A
4249915 Sirkar et al. Feb 1981 A
4292059 Kovach Sep 1981 A
4322394 Mezey et al. Mar 1982 A
4325921 Aiken et al. Apr 1982 A
4409006 Mattia Oct 1983 A
4433981 Slaugh et al. Feb 1984 A
4451435 Hölter et al. May 1984 A
4472178 Kumar et al. Sep 1984 A
4530817 Hölter et al. Jul 1985 A
4551304 Holter et al. Nov 1985 A
4559066 Hunter et al. Dec 1985 A
4711645 Kumar et al. Dec 1987 A
4810266 Zinnen et al. Mar 1989 A
4816043 Harrison Mar 1989 A
4863494 Hayes Sep 1989 A
4892719 Gesser Jan 1990 A
4917862 Kraw et al. Apr 1990 A
4976749 Adamski Dec 1990 A
4987952 Beal et al. Jan 1991 A
5046319 Jones Sep 1991 A
5087597 Leal et al. Feb 1992 A
5109916 Thompson May 1992 A
5137548 Grenier et al. Aug 1992 A
5149343 Sowinski Sep 1992 A
5186903 Cornwell Feb 1993 A
5194158 Matson Mar 1993 A
5221520 Cornwell Jun 1993 A
5231063 Fukumoto et al. Jul 1993 A
5281254 Birbara et al. Jan 1994 A
5290345 Osendorf et al. Mar 1994 A
5292280 Janu et al. Mar 1994 A
5322473 Hofstra et al. Jun 1994 A
5352274 Blakley Oct 1994 A
5376614 Birbara et al. Dec 1994 A
5389120 Sewell et al. Feb 1995 A
5407465 Schaub et al. Apr 1995 A
5443625 Schaffhausen Aug 1995 A
5464369 Federspiel Nov 1995 A
5471852 Meckler Dec 1995 A
5492683 Birbara et al. Feb 1996 A
5584916 Yamashita et al. Dec 1996 A
5614000 Kalbassi et al. Mar 1997 A
5646304 Acharya et al. Jul 1997 A
5672196 Acharya et al. Sep 1997 A
5675979 Shah Oct 1997 A
5702505 Izumi et al. Dec 1997 A
5707005 Kettler et al. Jan 1998 A
5827355 Wilson Oct 1998 A
5869323 Horn Feb 1999 A
5876488 Birbara et al. Mar 1999 A
5904896 High May 1999 A
5948355 Fujishima et al. Sep 1999 A
5964927 Graham et al. Oct 1999 A
5984198 Bennett et al. Nov 1999 A
6024781 Bülow et al. Feb 2000 A
6027550 Vickery Feb 2000 A
6102793 Hansen Aug 2000 A
6113674 Graham et al. Sep 2000 A
6120581 Markovs et al. Sep 2000 A
6123617 Johnson Sep 2000 A
6187596 Dallas et al. Feb 2001 B1
6254763 Izumi et al. Jul 2001 B1
6280691 Homeyer et al. Aug 2001 B1
6364938 Birbara et al. Apr 2002 B1
6375722 Henderson et al. Apr 2002 B1
6402809 Monereau et al. Jun 2002 B1
6428608 Shah et al. Aug 2002 B1
6432367 Munk Aug 2002 B1
6432376 Choudhary et al. Aug 2002 B1
6533847 Seguin et al. Mar 2003 B2
6547854 Gray et al. Apr 2003 B1
6605132 Fielding Aug 2003 B2
6623550 Dipak et al. Sep 2003 B2
6711470 Hartenstein et al. Mar 2004 B1
6726558 Meirav Apr 2004 B1
6773477 Lindsay Aug 2004 B2
6796896 Laiti Sep 2004 B2
6797246 Hopkins Sep 2004 B2
6866701 Meirav Mar 2005 B2
6908497 Sirwardane Jun 2005 B1
6916239 Siddaramanna et al. Jul 2005 B2
6916360 Seguin et al. Jul 2005 B2
6930193 Yaghi et al. Aug 2005 B2
6964692 Gittleman et al. Nov 2005 B2
6974496 Wegeng et al. Dec 2005 B2
7288136 Gray et al. Oct 2007 B1
7407533 Steins Aug 2008 B2
7407633 Potember et al. Aug 2008 B2
7449053 Hallam Nov 2008 B2
7472554 Vosburgh Jan 2009 B2
7645323 Massenbauer-Strafe et al. Jan 2010 B2
7662746 Yaghi et al. Feb 2010 B2
7666077 Thelen Feb 2010 B1
7802443 Wetzel Sep 2010 B2
7846237 Wright et al. Dec 2010 B2
7891573 Finkam et al. Feb 2011 B2
8157892 Meirav Apr 2012 B2
8210914 McMahan et al. Jul 2012 B2
8317890 Raether et al. Nov 2012 B2
8398753 Sergi et al. Mar 2013 B2
8491710 Meirav Jul 2013 B2
8690999 Meirav et al. Apr 2014 B2
8734571 Golden et al. May 2014 B2
9316410 Meirav et al. Apr 2016 B2
9328936 Meirav et al. May 2016 B2
9399187 Meirav et al. Jul 2016 B2
9566545 Meirav et al. Feb 2017 B2
9802148 Meirav et al. Oct 2017 B2
9919257 Meirav et al. Mar 2018 B2
9939163 Meirav et al. Apr 2018 B2
9950290 Meirav et al. Apr 2018 B2
9976760 Meirav et al. May 2018 B2
9987584 Meirav et al. Jun 2018 B2
10046266 Meirav et al. Aug 2018 B2
10086324 Meirav Oct 2018 B2
10281168 Meirav et al. May 2019 B2
10525401 Meirav et al. Jan 2020 B2
20010021363 Poles et al. Sep 2001 A1
20010054415 Hanai et al. Dec 2001 A1
20020056373 Fielding May 2002 A1
20020078828 Kishkovich et al. Jun 2002 A1
20020083833 Nalette et al. Jul 2002 A1
20020147109 Branover et al. Oct 2002 A1
20020183201 Barnwell et al. Dec 2002 A1
20020193064 Michalakos et al. Dec 2002 A1
20030037672 Sircar Feb 2003 A1
20030041733 Sequin et al. Mar 2003 A1
20030097086 Gura May 2003 A1
20030188745 Deas et al. Oct 2003 A1
20040005252 Siess Jan 2004 A1
20040020361 Pellegrin Feb 2004 A1
20040069144 Wegeng et al. Apr 2004 A1
20040118287 Jaffe et al. Jun 2004 A1
20050133196 Gagnon et al. Jun 2005 A1
20050147530 Kang et al. Jul 2005 A1
20050191219 Uslenghi et al. Sep 2005 A1
20050262869 Tongu et al. Dec 2005 A1
20050284291 Alizadeh-Khiavi et al. Dec 2005 A1
20050288512 Butters et al. Dec 2005 A1
20060032241 Gontcharov et al. Feb 2006 A1
20060054023 Raetz et al. Mar 2006 A1
20060079172 Fleming et al. Apr 2006 A1
20060112708 Reaves Jun 2006 A1
20060148642 Ryu et al. Jul 2006 A1
20060225569 Schmidt et al. Oct 2006 A1
20060236867 Neary Oct 2006 A1
20060249019 Roychoudhury et al. Nov 2006 A1
20080119356 Ryu et al. Mar 2008 A1
20080078289 Sergi et al. Apr 2008 A1
20080127821 Noack et al. Jun 2008 A1
20080135060 Kuo et al. Jun 2008 A1
20080173035 Thayer et al. Jul 2008 A1
20080182506 Jackson et al. Jul 2008 A1
20080210768 You Sep 2008 A1
20080216653 Paton-Ash et al. Sep 2008 A1
20080293976 Olah et al. Nov 2008 A1
20090000621 Haggblom et al. Jan 2009 A1
20090044704 Shen Feb 2009 A1
20090071062 Hedman Mar 2009 A1
20090120288 Lackner et al. May 2009 A1
20090188985 Scharing et al. Jul 2009 A1
20090220388 Monzyk et al. Sep 2009 A1
20090260372 Skinner et al. Oct 2009 A1
20100076605 Harrod et al. Mar 2010 A1
20100154636 Liu et al. Jun 2010 A1
20100224565 Dunne et al. Sep 2010 A1
20100254868 Obee et al. Oct 2010 A1
20100262298 Johnson et al. Oct 2010 A1
20100275775 Griffiths et al. Nov 2010 A1
20100278711 Find Nov 2010 A1
20110064607 Hedman Mar 2011 A1
20110079143 Marotta et al. Apr 2011 A1
20110085933 Mazyek et al. Apr 2011 A1
20110146494 Desai et al. Jun 2011 A1
20110179948 Choi et al. Jul 2011 A1
20110189075 Wright et al. Aug 2011 A1
20110192172 Delacruz Aug 2011 A1
20110206572 McKenna et al. Aug 2011 A1
20110250121 Schmidt Oct 2011 A1
20110262327 Dillon et al. Oct 2011 A1
20110269919 Min et al. Nov 2011 A1
20110277490 Meirav Nov 2011 A1
20110296872 Eisenberger Dec 2011 A1
20120004092 Raatschen et al. Jan 2012 A1
20120012005 Burke Jan 2012 A1
20120052786 Clawsey Mar 2012 A1
20120076711 Gebald et al. Mar 2012 A1
20120129267 Daly May 2012 A1
20120137876 Miller Jun 2012 A1
20120148858 Wu Jun 2012 A1
20120152116 Barclay et al. Jun 2012 A1
20120168113 Karamanos Jul 2012 A1
20120216676 Addiego et al. Aug 2012 A1
20120222500 Riess et al. Sep 2012 A1
20120271460 Rognili Oct 2012 A1
20120272966 Ando et al. Nov 2012 A1
20120311926 Mittelmark Dec 2012 A1
20120321511 Lorcheim Dec 2012 A1
20130052113 Molins et al. Feb 2013 A1
20130291732 Meirav Nov 2013 A1
20130331021 Rodell Dec 2013 A1
20140013956 Ericson Jan 2014 A1
20140020559 Meirav Jan 2014 A1
20140242708 Lundgren Aug 2014 A1
20140298996 Meirav et al. Oct 2014 A1
20140326428 Meirav et al. Nov 2014 A1
20150078964 Meirav et al. Mar 2015 A1
20150297771 Law et al. Oct 2015 A1
20160271556 Okano Sep 2016 A1
20160363333 Meirav et al. Dec 2016 A1
20170227241 Claesson Aug 2017 A1
20180147526 Meirav et al. May 2018 A1
20180187907 Meirav et al. Jul 2018 A1
20180207574 Meirav et al. Jul 2018 A1
20180264396 Meirav et al. Sep 2018 A1
20180339261 Meirav et al. Nov 2018 A1
20180339262 Perl-Olshvang et al. Nov 2018 A1
20190143258 Meirav et al. May 2019 A1
20190186762 Meirav et al. Jun 2019 A1
20190247782 Meirav et al. Aug 2019 A1
20190262761 Meirav Aug 2019 A1
20190299154 Meirav et al. Oct 2019 A1
20190344211 Meirav et al. Nov 2019 A1
20190346161 Meirav et al. Nov 2019 A1
Foreign Referenced Citations (71)
Number Date Country
2 640 152 Apr 2010 CA
2141873 Sep 1993 CN
2612444 Apr 2004 CN
2729562 Sep 2005 CN
1872388 Dec 2006 CN
101001767 Jul 2007 CN
101072620 Nov 2007 CN
200993448 Dec 2007 CN
101199913 Jun 2008 CN
101444693 Jun 2009 CN
101500704 Aug 2009 CN
101564634 Oct 2009 CN
201363833 Dec 2009 CN
201618493 Nov 2010 CN
102233217 Nov 2011 CN
202032686 Nov 2011 CN
202270445 Jun 2012 CN
103119376 May 2013 CN
102006048716 Feb 2008 DE
0 475 493 Mar 1992 EP
2 465 596 Jun 2012 EP
2 387 791 Oct 2012 ES
56-158126 Dec 1981 JP
59-225232 Dec 1984 JP
60-194243 Oct 1985 JP
02-092373 Apr 1990 JP
03-207936 Sep 1991 JP
05-161843 Jun 1993 JP
06-031132 Feb 1994 JP
08-114335 May 1996 JP
09-085043 Mar 1997 JP
2000-291978 Oct 2000 JP
2001-170435 Jun 2001 JP
2001-232127 Aug 2001 JP
3207936 Sep 2001 JP
2004-150778 May 2004 JP
2005-090941 Apr 2005 JP
2006-275487 Oct 2006 JP
2009-150623 Jul 2009 JP
2009-202137 Sep 2009 JP
2010-149086 Jul 2010 JP
2015-148227 Aug 2015 JP
WO 8805693 Aug 1988 WO
WO 0208160 Jan 2002 WO
WO 0212796 Feb 2002 WO
WO 2006016345 Feb 2006 WO
WO 2007128584 Nov 2007 WO
WO 2008155543 Dec 2008 WO
WO 2009126607 Oct 2009 WO
WO 2010091831 Aug 2010 WO
WO 2010124388 Nov 2010 WO
WO 2011114168 Sep 2011 WO
WO 2011146478 Nov 2011 WO
WO 2012071475 May 2012 WO
WO 2012100149 Jul 2012 WO
WO 2012120173 Sep 2012 WO
WO 2012134415 Oct 2012 WO
WO 2012145303 Oct 2012 WO
WO 2012152930 Nov 2012 WO
WO 2012158911 Nov 2012 WO
WO 2013012622 Jan 2013 WO
WO 2013074973 May 2013 WO
WO 2013106573 Jul 2013 WO
WO 2014015138 Jan 2014 WO
WO 2014047632 Mar 2014 WO
WO 2014078708 May 2014 WO
WO 2014153333 Sep 2014 WO
WO 2014176319 Oct 2014 WO
WO 2015042150 Mar 2015 WO
WO 2015123454 Aug 2015 WO
WO 2017019628 Feb 2017 WO
Non-Patent Literature Citations (21)
Entry
International Search Report and Written Opinion for International Application No. PCT/US2016/048439, dated Nov. 16, 2016.
ASHRAE. ANSI/ASHRAE Standard 62.1-2013 Ventilation for Acceptable Indoor Air Quality. American Society of Heating, Refrigerating and Air-Conditioning Engineers, Inc., Atlanta, GA; 2013, 58 pages.
Bennett, D. et al. (Oct. 2011) Indoor Environmental Quality and Heating, Ventilating, and Air Conditioning Survey of Small and Medium Size Commercial Buildings: Field Study. California Energy Commission. CEC-500-2011-043, 233 pages.
Gesser, H.D., “The Reduction of Indoor Formaldehyde Gas and that Emanating from Urea Formaldehyde Foam Insulation,” Environmental International, 10:305-308 (1984).
Goeppert, A. et al., “Carbon Dioxide Capture from the Air Using a Polyamine Based Regenerable Solid Adsorbent,” J. Am. Chem. Soc., 133:20164-20167 (2011).
Gray, M.L. et al., “Performance of immobilized tertiary amine solid sorbents for the capture of carbon dioxide,” International Journal of Greenhouse Gas Control, 2:3-8 (2008).
Hodgson, A.T. and Levin, H. (Apr. 21, 2003) Volatile Organic Compounds in Indoor Air: A Review of Concentrations Measured in North America Since 1990. Report LBNL-51715. Berkeley, California: Environmental Energy Technologies Division, E.O. Lawrence Berkeley National Laboratory; 31 pages.
Hotchi, T. et al. (Jan. 2006) “Indoor Air Quality Impacts of a Peak Load Shedding Strategy for a Large Retail Building” Report LBNL-59293. Berkeley, California: Environmental Energy Technologies Division, E.O. Lawrence Berkeley National Laboratory; 17 pages.
Jones, C.W., “CO2 Capture from Dilute Gases as a Component of Modern Global Carbon Management,” Annu. Rev. Chem. Biomol. Eng., 2:31-52 (2011).
Kang, D-H. et al. (Jun. 14, 2007) “Measurements of VOCs emission rate from building materials during bakeout with passive sampling methods” Clima 2007 WellBeing Indoors, REHVA World Congress, Jun. 10-14, 2007, Helsinki, Finland. O. Seppänen and J. Säteri (Eds.) FINVAC [online]. Retrieved from: http://www.inive.org/members_area/medias/pdf/Inive%5Cclima2007%5CA12%5CA12C1334.pdf, 6 pages.
Ma, C. et al., “Removal of low-concentration formaldehyde in air by adsorption on activated carbon modified by hexamethylene diamine,” Carbon, 49:2873-2875 (2011).
Nuckols, M. L. et al., Technical Manual: Design Guidelines for Carbon Dioxide Scrubbers. Naval Coastal Systems Center, NCSC Tech Man 4110, Revision A, Jul. 1985, 10 pages.
Offerman, F.J. et al. (1991) “A Pilot Study to Measure Indoor Concentrations and Emmission Rates of Polycyclic Aromatic Hydrocarbons” Indoor Air, 4:497-512.
Serna-Guerrero, R. et al., “Triamine-grafted pore-expanded mesoporous silica for CO2 capture: Effect of moisture and adsorbent regeneration strategies,” Adsorption, 16:567-575 (2010).
Sidheswaran, M.A. et al., “Energy efficient indoor VOC air cleaning with activated carbon filter (ACF) filters,” Building and Environment, 47:357-367 (2012).
United States Environmental Protection Agency, “Carbon Adsorption for Control of VOC Emissions: Theory and Full Scale System Performance”, EPA-450/3-88-012, Jun. 1988, 84 pages.
United States Environmental Protection Agency, “EPA Ventilation and Air Quality in Offices, Fact Sheet” Air and Radiation (6609J), 402-F-94-003, Revised Jul. 1990, 4 pages.
Wu, X. et al. (2011) “Volatile Organic Compounds in Small- and Medium-Sized Commercial Buildings in California. Suporting Information” Environ Sci Technol, 45(20):S1-S29 [online]. Retrieved from: https://pubs.acs.org/doi/suppl/10.1021/es202132u/suppl_file/es202132u_si_001.pdf.
ZORFLEX® ACC, 100% Activated Woven Carbon Cloth. Calgon Carbon Corporation, 2008, www.calgoncarbon.com, 2 pages.
ZORFLEX® ACC, 100% Activated Woven Carbon Cloth, Calgon Carbon Corporation, 2011, www.calgoncarbon.com, 2 pages.
International Preliminary Examination Report on Patentability for International Application No. PCT/US2016/048439, dated Feb. 27, 2018, 10 pages.
Related Publications (1)
Number Date Country
20180236396 A1 Aug 2018 US
Provisional Applications (1)
Number Date Country
62208822 Aug 2015 US