The disclosure of the following priority application is herein incorporated by reference: Japanese Patent Application No. 2010-017187, filed Jan. 28, 2010.
1. Field of the Invention
The present invention relates to a sealed battery cell in which an electrode group, in which a positive electrode, a negative electrode, and a separator are laminated together, is housed in a battery cell container.
2. Description of Related Art
With a prior art sealed battery cell in which an electrode group that includes electrodes wound around a core is housed within a battery cell container and is sealed therein, there is a fear as follows. If the battery cell is subjected to vibration, the electrode group may wobble there may be damage to the electrodes or failure of the battery cell, and a short circuit may occur between the positive and negative electrodes. In Japanese Laid-Open Patent Publication 2001-266947, a construction is proposed in which, in order to hold the electrode group, one end of the core in the axial direction is restricted and restrained and the other end of the core is elastically supported by an elastic member.
However, with the sealed battery cell disclosed in Japanese Laid-Open Patent Publication 2001-266947, an elastic member is required between the top cover portion and the bottom portion of the container for elastically supporting the core, and this increases the cost. Moreover, it is difficult to check the state of this elastic support after the battery cell has been sealed.
According to the 1st aspect of the present invention, a sealed battery cell comprises: a coiled electrode group comprising a positive electrode, a negative electrode, and a separator wound around a winding core; a cylindrical battery cell container having an open end and a bottom surface, that contains the coiled electrode group; and a sealed cover swaged in the open end of the battery cell container, which seals the open end; wherein the winding core is squeezed between the bottom surface of the battery cell container and the sealed cover, the bottom surface of the battery cell container being elastically deformed outwards in the axial direction.
According to the 2nd aspect of the present invention, a sealed battery cell according to the 1st aspect may further comprise: a positive current collection component installed at one end of the winding core, and connected to the positive electrode of the coiled electrode group; and a negative current collection component installed at the other end of the winding core, and connected to the negative electrode of the coiled electrode group; and wherein the sealed cover is disposed over the positive current collection component, while the negative current collection component is disposed over the bottom surface of the battery cell container.
According to the 3rd aspect of the present invention, the negative current collection component of a sealed battery cell according to the 2nd aspect may be welded to the bottom surface of the battery cell container via a negative lead, and the winding core fits into and is fixed into the negative current collection component.
According to the 4th aspect of the present invention, it is preferred that in a sealed battery cell according to the 1st aspect, a central portion of the bottom surface of the battery cell container being elastically deformed constitutes an end surface in the axial direction of the battery cell container.
According to the 5th aspect of the present invention, it is preferred that in a sealed battery cell according to the 1st aspect, a central portion of the bottom surface of the battery cell container being elastically deformed is positioned inwards in an axial direction from an end surface in the axial direction of the battery cell container.
According to the 6th aspect of the present invention, a sealed battery cell comprises: a flattened electrode group in which a positive electrode, a negative electrode, and a separator are laminated together; a battery cell container with a flattened shape including at least a pair of sides, that contains the flattened electrode group; a top cover that is fixed in an open end of the battery cell container and seals the open end; a pair of positive and negative electrode group support members that supports the flattened electrode group from the top cover, one ends of which are supported by the top cover respectively and the other ends of which are connected to positive and negative electrode connection portions of the flattened electrode group respectively; and a pair of support blocks, each of which is interposed between one of the pair of electrode group support members and each of the sides of the battery cell container, and deforms each of the sides of the battery cell container to the exterior so as to exert restraining force upon the electrode group support member, each of the sides of the battery cell container facing each of the pair of the electrode group support members respectively.
According to the 7th aspect of the present invention, it is preferred that in a sealed battery cell according to the 6th aspect, the battery cell container is formed as a rectangular parallelepiped having two wide rectangular sides, two long narrow rectangular sides, a long narrow aperture defined by those four sides, and a long narrow rectangular bottom surface opposite to the long narrow aperture, the flattened electrode group being inserted into the battery cell container via the long narrow aperture; and each of the support blocks is interposed between one of the two long narrow rectangular sides and each of the pair of electrode group support members respectively so as to deform the long narrow rectangular sides elastically to the exterior.
According to the present invention, it is possible to support the electrode group elastically in the container without using any separate dedicated member, and moreover it is possible to inspect the condition of this support visually from the outside.
Embodiments in which the sealed battery cell of the present invention is applied to a cylindrical lithium ion secondary battery cell will now be explained with reference to the drawings.
Overall Structure
As shown in
With this first embodiment of the secondary battery cell of the present invention, a winding core 7 of the coiled electrode group 8 is pressed against the bottom surface 1T of the cylindrical battery cell container 1, and the battery cell container 1 is sealed by the sealed cover 22. Due to this, the secondary battery cell 11 of this first embodiment is adapted so that the coiled electrode group 8 is restricted and restrained in the axial direction within the battery cell contained by the reaction force generated due to the fact that the bottom surface 1T is bulged outwards in the axial direction.
The Battery Cell Container
The battery cell container 1 before assembly is shown in
An outwardly bulged portion 1TE on the bottom surface of the battery cell container 1 will now be explained, although this feature will be described in greater detail hereinafter.
The Coiled Electrode Group
The coiled electrode group 8 will now be explained with reference to
A positive current collection component 5 and a negative current collection component 6 are fitted to the two ends of the winding core 7.
The Positive Current Collection Component
As shown in
The positive electrode tabs 12 are welded to the outer peripheral surface of the positive current collection component 5, for example by an ultrasound welding method. And one end portion of a positive lead 9 that is shaped as a rectangular ribbon is welded to the upper surface of the intermediate annular plate 53 of the positive current collection component 5. The other end 9a of this positive lead 9 is welded to a positive electrode connection plate 22c (refer to
The Negative Current Collection Component
As shown in
The Sealed Cover
As shown in
The cap 22a is formed in the shape of a hat, and has a convex portion that projects upwards from the battery cell container 1 at its central portion. This convex portion of the cap 22a constitutes a positive electrode terminal for the battery cell. The top cover case 22b is fixed to the peripheral part of the cap 22a by a swaging process. The cap 22a is make from nickel plated iron (SPCC), while the top cover case 22b and the positive electrode connection plate 22c are made from aluminum; and the top cover case 22b, the cap 22a, and the positive electrode connection plate 22c are electrically connected together.
As described above, the positive lead 9 is connected to the rear surface of the positive electrode connection plate 22c, so that the cap 22a is electrically connected to the positive electrode 14 via the top cover case 22b, the positive electrode connection plate 22c, the positive lead 9, and the positive current collection component 5.
The peripheral part of the sealed cover 22 is fixed to the battery cell container 1 by a swaging process, via the insulation gasket 2. Due to this, the external diameter of the peripheral part of the top cover case 22b that is swaged to the peripheral part of the cap 22a is almost equal to the internal diameter of the inner circumferential surface of the battery cell container 1.
The sealed cover 22 constitutes an anti-explosion mechanism. When, due to generation of gas in the interior of the battery cell container 1, its internal pressure rises to an abnormally high level, then the top cover case 22b suffers cracking at its cleavage grooves. And then the internal gas is vented via these cracks that have appeared in the top cover case 22b and is discharged from the exhaust aperture 22h of the cap 22a, so that the pressure interior to the battery cell container 1 is reduced. Furthermore, the electrical connection to the positive electrode connection plate 22c is broken due to the top cover case (i.e. diaphragm) 22b bulging outwards from the battery cell container 1 due to the internal pressure therein, so that the flow of excessive electrical current is prevented.
The Procedure for Assembly of the Battery Cell
The procedure for assembly of the various structural elements described above will now be explained.
As shown in
The other end 9a of the positive lead 9 that is welded to the intermediate annular plate 53 of the positive current collection component 5 is welded to the rear surface of the positive electrode connection plate 22c of the sealed cover 22. Electrolyte is injected into the battery cell container 1, and the battery cell container 1 is mounted upon the jig JG. Then the sealed cover 22 is mounted upon the positive current collection component 5 by being moved in the direction of the arrow in the drawing, and a predetermined load F1 in the axial direction is imposed from the sealed cover 22 by a pressurization jig not shown in the figures. The annular axially projecting portion 51 at the center of the lower surface of the positive current collection component 5 is thus fitted into the winding core 7, and the load F1 operates via the winding core 7 upon the bottom surface 1T of the battery cell container 1. As a result, the bottom surface 1T is bulged outward, as shown by the outwardly bulged portion 1TE in
With this predetermined load F1 in the axial direction being maintained without release, in the state with the insulation gasket 2 disposed in the opening portion 20, the sealed cover 22 is pushed into the opening portion 20 and is fitted tightly thereinto, and thereby the opening portion 20 is blocked. Due to this type of swaging process, the sealed cover 22 is fixed to the battery cell container 1 via the insulation gasket 2. The insulation gasket 2 seals the periphery of the sealed cover 22 against ingress of water, along with providing electrical insulation between the sealed cover 22 and the battery cell container 1.
It should be understood that the insulation gasket 2 may be made from perfluoroalkoxy-fluoroplastic resin (PFA).
The cylindrical secondary battery cell according to the first embodiment of the present invention described above includes the coiled electrode group 8 in which the positive electrode 8E, the negative electrode 8D, and the separators 8E are wound upon the winding core 7, the cylindrical battery cell container 1 that contains this coiled electrode group 8, and the sealed cover 22 that is swaged in the open end 20 of the battery cell container 1 and seals this open end, with the winding core 7 being squeezed between the bottom surface 1TE of the battery cell container 1 and the sealed cover 22, and with the bottom surface 1TE of the battery cell container 1 being elastically deformed outwards in the axial direction.
When as described above the sealed cover 22 is fixed to the battery cell container 1 by swaging, the winding core 7, the positive current collection component 5, and the negative current collection component 6 are sandwiched and squeezed in the axial direction between the sealed cover 22 and the bottom surface 1TE by the reaction force of the bottom surface 1TE, so that the coiled electrode group 8 is held and restrained within the battery cell container 1. Due to this elastic support, when this cylindrical lithium ion secondary battery cell 1 is subjected to shock or vibration, the coiled electrode group 8 is stably supported and fixed and does not wobble, so that it is possible to prevent damage to and failure of the electrodes and other structural components, and also short circuiting.
Furthermore, since it is possible to check the state of elastic deformation of the battery cell container bottom surface 1TE from the exterior, it is possible to ascertain the effectiveness by which the coiled electrode group 8 is being held and supported, even after the battery cell container 1 has been sealed.
A plurality of cylindrical lithium ion secondary battery cells 11 constructed as described above may, for example, be enclosed within a casing and may be used as a power supply device.
It would also be acceptable to use a battery cell container 51 made as shown in
With the battery cell container 51 of this first variant embodiment, when the sealed cover 22 is fixed by swaging to the battery cell container 51, even though the circular portion 51T bulges outwards in the axial direction by 0.1 to 0.3 mm, still the circular portion 51TDE does not project from the end surface of the battery cell container 51 in the axial direction after deformation, so that the bottom surface of the container 51 remains approximately flat.
It would also be acceptable to use a battery cell container 61 made as shown in
With the battery cell container 61 of this second variant embodiment, when the sealed cover 22 is fixed by swaging to the battery cell container 61, even though the circular portion 61T bulges outwards in the axial direction by 0.1 to 0.3 mm, still the circular portion 61TDE does not project from its position well within the axial end surface of the battery cell container 61.
A second embodiment in which the secondary battery cell according to the present invention is embodied as a square type flattened secondary battery cell will now be explained with reference to
As shown in
As shown in
The positive plate 81E included in the coiled electrode group 81 is made from aluminum foil that constitutes a positive current collection foil, and, on both sides of this aluminum foil, a positive electrode active material mixture that includes lithium-containing transition metal oxide such as manganese lithium oxide or the like as a positive electrode active material is spread and adhered approximately equally and uniformly. Apart from this positive electrode active material, an electrically conductive material such as a carbonaceous material or the like and a binder (i.e. a bonding substance) such as polyvinylidene fluoride (hereinafter abbreviated as PVDF) or the like are combined into the positive electrode active material mixture. During the coating of the positive electrode active material mixture onto the aluminum foil, the viscosity may be adjusted with a dispersal solvent such as N-methyl-pyrrolidone (hereinafter abbreviated as NMP) or the like.
At this time, the uncoated portion 81A is formed by one of the long edges of the aluminum foil not being coated with the positive electrode active material mixture. In other words, the aluminum foil is exposed over this uncoated portion 81A. Then the density of this positive plate 81E is adjusted by rolling pressing, after it has been dried.
On the other hand, the negative plate 81D included in the coiled electrode group 81 is made from copper foil that constitutes a negative current collection foil. And on both sides of this copper foil, a negative electrode active material mixture that includes a carbonaceous material such as graphite or the like that can reversibly either occlude or emit lithium ions is spread and adhered as a negative electrode active material, approximately equally and uniformly. Apart from this negative electrode active material, an electrically conductive material such as acetylene black or the like and a binder such as PVDF or the like are combined into this negative electrode active material mixture. During the coating of the negative electrode active material mixture onto the copper foil, the viscosity may be adjusted with a dispersal solvent such as NMP or the like. At this time, the uncoated portion 81B is formed by one of the long edges of the copper foil not being coated with the negative electrode active material mixture.
In other words, the copper foil is exposed over this uncoated portion 81B. Then the density of this negative plate 81D is adjusted by rolling pressing, after it has been dried. It should be understood that the length of the negative plate 81D is set to be longer than the length of the positive plate 81E, so that, when the positive plate 81E and the negative plate 81D are rolled up, the positive plate 81E does not experience disturbance from the negative plate 81D in the winding direction at the innermost turn and the outermost layer.
The uncoated portions 81A and 81B are arranged to face the elongated rectangular side surfaces 71S1 and 71S2 of the battery cell container 71. An electrically conductive electrode group support member 82 is connected to each of these uncoated portions 81A and 81B, and these electrode group support members are supported by the top cover 72. In other words, the uncoated portions 81A and 81B constitute respective positive and negative electrode connection portions.
Connecting terminals 74 and 75 shaped as bolts are fitted to the top cover 72 from the interior, and these connection terminals 74 and 75 function as external positive and negative electrodes, respectively. The connection terminals 74 and 75 are passed through the electrode group support members 82 and the top cover 72 and are held on by external nuts 76, and thereby the connection terminals 74 and 75 and the electrode group support members 82 are solidly fixed to the top cover 72.
Gaskets 83 that are made from an insulating material are inserted between the nuts 76 and the electrode group support members 82, and the top cover 72, so that sealing structures are provided around the connection terminals 74 and 75 against the escape of electrolyte from the interior of the battery cell container 71. The top cover 72 is fixed to the battery cell container 71 by welding.
A support block 84 that projects sideways is fixed to each of the electrode group support members 82. Since the sides 71S1 and 71S2 are pressed outwards by these support blocks 84, accordingly the sides 71S1 and 71S2 are elastically deformed. The support blocks 84 are made using a resin material or the like, and accordingly the uncoated portions 81A and 81B are insulated from the battery cell container 71.
The electrode group support members 82 are elastically supported by the resilient force due to elastic deformation of the sides 71S1 and 71S2, and, due to this, the coiled electrode group 81 is supported and fixed within the battery cell container 71. The sides 71S1 and 71S2 are shaped as elongated rectangles, and their rigidity is high as compared with the larger sides 71S3 and 71S4, so that they are capable of generating a high elastic support force. The coiled electrode group 81 has a comparatively fragile construction due to the positive electrode 81E, the negative electrode 81D, and the separators 81C being wound together into a roll, so that it is not desirable for much load to be applied directly to it. Due to this fact, the electrode group support members 82 are made to have high strength and rigidity, so that the coiled electrode group 81 is protected.
As described above, the flattened type secondary battery cell according to the second embodiment of the present invention includes: the flattened electrode group 81 in which the positive electrode 81E, the negative electrode 81D, and the separators 81C are laminated together; the battery cell container 71 having a flattened shape, that contains the flattened electrode group 81; the top cover 72 that is fixed in the open end 71A of the battery cell container 71 and seals the open end 71A; the pair of positive and negative electrode group support members 82, the one ends of which are supported by the top cover 72, and the other ends of which are connected to the positive and negative electrode connection portions 81A and 81B of the flattened electrode group 81 and support the flattened electrode group 81 from the top cover 72; and the pair of support blocks 84, each of which is interposed between one of the pair of electrode group support members 82 and a side 71S1 or 71S2 of the battery cell container 71 that faces it, and deforms that side 71S1 or 71S2 of the battery cell container 71 to the exterior so as to exert restraining force upon the electrode group support member 82.
According to the structure described above, the coiled electrode group 81 is supported by the electrode group support members 82, and also is pressed by the battery cell container 71 via the support blocks 84. Due to this, if the sealed battery cell 111 is subjected to vibration, the coiled electrode group 81 does not wobble very much, so that it is possible to prevent damage to the electrodes, and short circuiting thereof.
It should be understood that, instead of the support blocks 84 being fixed to the electrode group support members 82, they could also be fixed to the interiors of the sides 71S1 and 71S2 of the battery cell container 71.
According to this flattened type secondary battery cell of the second embodiment, in a similar fashion to the beneficial effect obtained with the first embodiment, the beneficial effect is obtained that it is possible to hold the electrode group in a stable manner.
Instead of the structure for the electrode group 81 shown in
With the laminated type electrode group 91 of this variant embodiment, the positive electrode side electrode support member 82 is connected to the uncoated portions 91A, while the negative electrode side electrode support member 82 is connected to the uncoated portions 91B, and these two electrode support members 82 are fixed to the top cover 72. The support blocks 84 are interposed between the pair of electrode support members 82 and the elongated rectangular sides 71S1 and 71S2 and the sides 71S1 and 71S2 are elastically deformed outwards by the pressure exerted by the blocks 84, and thereby the electrode support members 82, and the electrode group 91 as well, are stably supported within the battery cell container.
The above described embodiments are examples, and various modifications can be made without departing from the scope of the invention.
Number | Date | Country | Kind |
---|---|---|---|
2010-017187 | Jan 2010 | JP | national |