Sealed Glass Ceramic Powered Anode Assemblage and Method For Impressed Current Cathodic Protection

Information

  • Patent Application
  • 20250171908
  • Publication Number
    20250171908
  • Date Filed
    November 28, 2023
    2 years ago
  • Date Published
    May 29, 2025
    9 months ago
  • Inventors
    • Stoltenburg; Timothy David (Vista, CA, US)
  • Original Assignees
    • (Vista, CA, US)
Abstract
A method of using an assemblage that is comprised in part by utilizing a ceramic material to form a glass-to-metal seal for the purpose of the impressed current cathodic protection (ICCP) of a structure. Until this invention, ICCP assemblages have utilized polymer seals which can often fail during use due to heat or thermal cycling. This new method is able to mitigate these detrimental environmental factors, thereby enhancing the reliability and longevity of the ICCP system.
Description
1. CROSS-REFERENCE TO RELATED APPLICATIONS

Provisional application Ser. No. 18/058,857 filed on Nov. 25, 2022.


2. PRIOR ART



  • U.S. Pat. No. 1,184,813 A, COMPRESSION-TYPE SEAL., 1916 May 30, WILFRED

  • U.S. Pat. No. 1,807,903 A, Preserving Underground Piping, 1931 Jun. 2, Dozier

  • US20110223475 A1, SEAL STRUCTURE AND ASSOCIATED METHOD, 2011 Sep. 15, Porob



At the time of writing this application, there are several “powered anode rod” manufacturers which sell assemblies that generally provide environmental sealing, though by different assembly elements and compositions than what is proposed in this invention, and with differing resulting reliability and useful life.


SUMMARY OF THE INVENTION

This invention pertains to a method for utilizing an assembly composed of heat-fused ceramic material that encapsulates an electrically conductive electrode within a rigid element. The purpose of this assembly is to facilitate the implementation of impressed current cathodic protection. Historically, glass-sealed assemblies have been utilized as environmental seals, particularly in applications requiring the conduction of electrical current in harsh environments, such as in spark plugs for combustion engines or in light bulbs. Notably, this specific type of seal has not yet been utilized in the context of impressed current cathodic protection. The adoption of such glass-sealed assemblies in this domain offers advantages, including enhanced reliability, increased longevity, and the potential for reduced cost of corrosion control.





BRIEF DESCRIPTION OF DRAWINGS


FIG. 1 is an isometric view of a simplified embodiment.



FIG. 2 is a front view of a preferred embodiment.



FIG. 3 is a section view of FIG. 2, of a preferred embodiment.



FIG. 4 is a front view of an embodiment using a ceramic fitting.



FIG. 5 is a section view of FIG. 4, an embodiment using a ceramic fitting.





DETAILED DESCRIPTION OF THE INVENTION
Technical Field

This invention relates to impressed current cathodic protection devices, often termed “powered anodes”, used for controlling corrosion of material in contact with an electrolyte, and to the field of ceramic materials such as glasses used in hermetic sealing, and to the field of glass-to-metal seals, and in particular to compression seals.


Definitions
Electrolyte:

For the purpose of this document, “electrolyte” is defined as a non-solid medium, typically a fluid, that facilitates the transfer of electrical potential. This term encompasses a broad range of substances, and examples include tap water and sea water, as well as various other fluids. An electrolyte, in the specified context, serves as a medium through which ions can move, enabling the flow of electric current.


Sacrificial Anode:

For the purpose of this document, a material which is in contact with an electrolyte and which is of a composition that more readily gives up its electrons than does the material which it is “sacrificing” itself for; in this manner, in operation, the sacrificial anode is dissolved or corroded instead of the element which it is protecting. Typically, in the field of protecting structures made of steel which are in contact with an electrolyte, the sacrificial anode will be comprised of magnesium or aluminum, both which are less noble than steel and therefore both give up the electrons that comprise their mass more easily than that of steel.


Ceramic:

For the purpose of this document, a material composition that is comprised in majority part of elemental oxides that can fuse to each other (or the composition to itself) due to sufficient heat; said fusion typically relying upon the formation of covalent or ionic bonds or both (and/or other forces of attraction) at the atomic level. Glass, ceramics, or glass-ceramic composite materials meet this definition, as many contain elements of silicon oxides, aluminum oxides, tin oxides, germanium oxides, etc, which are commonly utilized by those familiar with the art to create such material. Said ceramic material can be crystalline or amorphous or a mixture of both. It can be devitrifying or vitrifying. An example of a “ceramic composite” is a glass with additions of ceramic particles. Companies such as SCHOTT, NEG, Ferro, Corning, and others engage in the production of such materials, often categorizing it as “sealing glass” or “ceramic enamel” or “ceramic”, herein referred to as a ceramic material.


Environmental Seal:

For the purpose of this document, a seal which prevents no more than 0.025 milliliters of water per hour passage through itself, or the the surfaces in contact with it which are intended for sealing, at a pressure of 95 PSI on one isolated side of the seal and atmospheric pressure at sea level and a temperature of 105 degrees fahrenheit for the entirety of the seal. It is preferred that this amount of leakage be minimized beyond this, and that the most robust seal is one that does not allow any passage of any amount of water through its body nor through the surfaces which the seal contacts which are intended for sealing.


Rigid:

For the purpose of this document, a state or condition of matter that is sufficiently resistant to deformation when subjected to external forces so as to be used as intended under expected operating conditions.


Fitting:

For the purpose of this document, a generally rigid element which interfaces with a structure, oftentimes adding additional connectivity or features or enhancements to the structure. Particular to this document, a “fitting” is used to describe an element of an assembly which is fixtured to other elements thereby creating an assemblage. The fitting may most often resemble a pipe nipple but with added features and generally threads on only one end, as well as contains a through-hole passageway that has been sealed closed, and therefore the word “fitting” has been used here rather than “pipe nipple”.


Discovery and Like Names

For the purpose of aiding discovery of this invention, the inventor wishes to note that in common speech the invention may sometimes be described under the following terms: hermetically-sealed, glass-sealed, ceramic-sealed anode, powered anode, powered anode rod, impressed current cathodic protection device.


BACKGROUND

Impressed current cathodic protection (ICCP) has been known to the general public for nearly 200 years since the writings of Sir Humphry Davy made available to the Royal Society in London in 1824, and has since been used widely in the protection of corrodible metals, such as those found in ship hulls, steel reinforcement in concrete, steel pipelines (U.S. Pat. No. 1,807,903), steel oil tanks, water storage tanks, and more. In this process of ICCP, a direct current (DC) power source is electrically connected to the electrolyte that is in contact with the structure that is desired to have protection such that the anodic portion of the outside electrical current source is discharged into the electrolyte, and the structure intended for protection is electrically connected to the cathodic portion of the outside electrical current source, whereby a level of protection is achieved for those electrically conductive elements that are in a cathodic (negative or ground) state relative to an anodic electrolyte.


When ICCP is applied to hot water storage tanks typically found in commercial and residential buildings, often called “water heaters”, it is typically applied by use of a “powered anode” assembly that is inserted through a threaded female “anode port” on the tank and which replaces a factory-installed sacrificial anode. The powered anode assembly can be described as being comprised of three main functional elements, though possibly more real elements in application, but which fulfill three primary functions: (1) a rigid element that fixtures and generally seals the assembly to a structure or tank; (2) an electrically conductive element that is used to transfer an electric current from the exterior of the structure to the interior of the structure and which typically pierces through the center of the rigid element without conducting electrical current to it; (3) an electrically insulative element which prevents short circuit of the electrically conductive element to that of the rigid element of the assembly (if it is electrically conductive), and this same element which often serves to seal the environment of the inside of the tank from the environment outside the tank. Altogether, these aforementioned functional elements create what is often termed a “powered anode” or “powered anode rod” or “powered anode rod assembly”, that is: the assembly which is installed on the electrolyte-containing-structure and which is connected in the least to the anodic branch of electrical current from a power supply and which is typically comprised in part by an electrode which discharges the anodic current into an electrolyte within the structure.


In greater detail, generally the structures upon which these powered anode assemblies are installed upon are often called “hot water storage tanks” or “water heaters”, and contain a fluid, typically water, and are often under pressure (often measured in “pounds per square inch”, (PSI)) from city or well water supplies as is necessary for proper functioning of the hot water circuit for which it is used. This pressure is typically in the range of 40 PSI up to 125 PSI, but these tanks are often outfitted with pressure relief valves that do not open until about 150 PSI is reached, and so it can be stated with confidence that any powered anode assembly fitted to a tank should through its lifetime of use safely withstand pressure of 150 PSI or greater without leaking, and should typically include a margin of safety factor such that it is preferable that it should survive the same pressures as the tank, noting that tanks are often tested to survive a pressure of up to 300 PSI. It is preferable that these ICCP devices survive for a lifetime operation of typically no less than 2 years, and typically more than 5 years, and preferably longer than 10 years without leaking while under pressure and typically at an operation temperature of 115 to 180 degrees fahrenheit. Often, the first functional element to fail in an ICCP device is the dielectric (electrically-insulating material) or environmental sealing element which is most often a single element that is fulfilling both functions. Prior art and standard practice in ICCP assemblies is to seal the electrode with a polymer, typically polytetrafluoroethylene (PTFE) or similar, or an elastomer such as silicone or similar, or a thermosetting epoxy, or a combination of the above. Failure of this sealing element can occur in less than one year in assemblies that use epoxy, and can often be attributed to a mismatch of the coefficient of thermal expansion rates of the materials, which causes shear disbondment between the epoxy and the metal of the electrode or the metal of the exterior fixturing element and is most likely due to temperature fluctuations during operation which cause [differing rates of] expansion or contraction of the elements in the assembly after which there is a loss of adhesion which can cause a leak to occur. Failure of assemblies that use a compression seal of PTFE or another polymer can most likely be attributed to aging and relaxation or creep of the polymer, a well-known phenomenon, which then allows a small gap or a zone between elements of lower compressive force than that of the pressure within the structure, and thereby a leak can occur. Elastomeric seals can also fail due to degradation of the elastomer, which is most likely caused by a combination of heat aging and ion exchange through the material, the ion exchange being driven between the anodic centrally-located electrode and the cathodic fitting or tank. It is worth noting that in the year of this writing of 2023, and for many decades prior, that hot water storage tanks are coated on their interior for corrosion protection not by polymers such as epoxies and elastomers, but by ceramic materials, often called ceramic or glass or enamel. It has long been obvious and common practice in the field that materials such as copper, brass, stainless steel, and ceramic materials can survive the environment found in a hot water storage tank much longer than polymers can.


Therefore, the novelty found in this present invention is by the method of using ceramic material as the sealing element in an ICCP assembly rather than polymers so as to take advantage of this material's low-to-non-existent creep, extreme tolerance for heat, and slow hydrolysis; attributes, when used in an ICCP assembly, which can bestow advantages of increased reliability, longer lifetime, increased operation temperature, and lower lifetime costs to manufacturer and user.


DESCRIPTION OF RELATED ART

U.S. Pat. No. 1,184,813 describes a metal-to-glass compression seal which utilizes materials of substantially differing rates of thermal expansion to provide an assembly that can provide an environmental seal even while passing an electrical current. The assembly is made, as follows, described in order of outermost components to innermost: a metal (typically of highest CTE in the assembly) element is circumferentially located around a glass element which is then pieced through by another electrically conductive metal element; the preferred rates of thermal expansion being that the outermost element is of highest CTE, the CTE progressively becoming less, therefore resulting in an assembly that, if fashioned at a temperature substantively above its use-temperature that therefore upon reduction to said use-temperature results in an assembly of elements that are placed in generally radial compression (by the outermost metal element) to a central axis, providing a robust seal, furthermore enhanced if the assembly was made when the glass was at a temperature high enough so as to wet and adhere to the elements it contacts. It is generally this type of seal that is herein newly applied to ICCP assemblies.


U.S. Pat. No. 1,807,903 describes the use of electrical current to preserve steel in contact with an electrolyte, finding that placing the steel in a cathodic state relative to an anodic electrolyte prevents, with sufficient electrical current present, corrosion of the steel in the areas that are contacting the electrolyte. This method has become known as “impressed current cathodic protection” (ICCP), and it is in application of this method that this present invention proposes to utilize, in general terms, a glass-metal seal.


US20110223475 describes a glass and ceramic seal structure for use in energy storage devices, which includes the use of a sealing glass to join an electrically-insulating ceramic to an ion-conducting ceramic, and so claims coating compositions of the invention for resistance to the sodium or metal halides found in energy storage devices, which is not a claim of this present invention of applying a glass seal to ICCP.


DETAILED DESCRIPTION OF THE INVENTION

This invention is that of the method of utilizing an assembly comprising of a ceramic material to fixture an electrically conductive element inside a rigid element for application of said assemblage to structures in contact with an electrolyte for the purpose of utilizing an electrical current to protect said structure from corrosion under the method of “impressed current cathodic protection” (ICCP). Therefore, the goal of the invention is to provide corrosion protection by way of the method of ICCP by utilizing the novel step or method of using an assemblage which uses ceramic material to fixture an interior electrically conductive element inside a rigid element. Until the inventor's development of this, no such process existed, and the inventor and author of this present application, as of August of 2023, produces and sells such-made ICCP devices under his brand “STOLTCO”. It is most beneficial for the ceramic material to create a hermetic seal around the interior electrically conductive element to the walls of the exterior element, although there may be cases where this is not required and the ceramic material will only fixture the elements into an assemblage and that a different material will be used to seal against fluid or pressure transfer (or both).


In summary, this novel application of sealing is comprised of:

    • (1) Providing components for building a working assemblage as described in this application, which includes the use of a ceramic material generally to seal and fixture the elements of the assemblage;
    • (2) Producing the aforementioned assemblage;
    • (3) Utilizing the aforementioned assemblage (in sale or actual use, or both) as an ICCP device to control corrosion of structures in contact with an electrolyte.


Description of the Assembly

In the aforedescribed assembly of elements, it is desired (but not required) that the rate of thermal expansion of each element to be sequentially lesser from the outermost to the innermost; the reason for this is that if the innermost element is of the least thermal expansion rate, and if the assembly is made at a temperature that exceeds normal operation, then during normal operation all elements that are interior of the outermost element will be in a compressed state; preferably a radially-compressed state due to outer components exertion of force. In this orientation, so long as the outermost component is of sufficient tensile strength to bear the tensile strain placed upon it due to its shrinking upon the inner elements, the assembly as a whole, given the material characteristics of each element, becomes quite robust and resists injury caused by mechanical force, or fluid or gas pressures, or changes of temperature. In this assembly, if the innermost element is of a higher thermal expansion rate than that of the ceramic sealing material, it is then preferred that the element outside of, or otherwise generally encompassing, the ceramic material be of a higher thermal expansion rate than the ceramic material; furthermore, it is preferred then that the ceramic material be of as low of a fusing temperature as possible while remaining a solid at expected operation/use temperatures, and at its fusing temperature have good ability to “wet” any material it is generally encompassing. The low fusing/wetting temperature of the ceramic material generally allows for most of the shrinking of the innermost element to have occurred during a plastic or liquidus phase of the ceramic material, therefore aiding in a reduction of tensile stresses in the ceramic material as it cools and also aiding in forcing the ceramic material to have good contact with the electrically conductive element interior to it and subsequently stronger fixturing and greater probability of an environmental or hermetic seal. This seal, with an outside encompassing element generally in tension, and inner elements generally in compression is commonly known as a “compression seal”. Because this above-described seal is made of fused oxides, it is generally much more resistant to heat and aging than most methods of polymer seals.


Description of the Use of a Rigid Exterior Element in the Assembly

In the most simple embodiment, this rigid exterior element is a solid material band which is typically the outermost circumferentially located component to all other components and of sufficient tensile strength to withstand the stress of its shrinking upon the interior components, and of sufficient strength to withstand fixturing and pressure forces, as well as of a material that is not easily degraded by the environment it will encounter. This rigid exterior element of the assembly is typically either of a metal or of a ceramic material, and in either case it is generally rigid so as to aid in fastening and sealing to a structure for application of ICCP. In the case of a metal it should be of sufficient tensile strength, due to its composition and geometry, to withstand the tensile stresses induced by shrinking from the temperature required to fuse the interior-located ceramic material to that of a lower temperature typically encountered during assembly, shipping, and use. Generally, this metal will be a stainless steel alloy as these alloys well-provide the characteristics desired for this assembly and application such as: corrosion resistance for areas not in contact with electrolyte, tensile strength, and relatively high rate of thermal expansion in comparison to titanium and most ceramic materials. This exterior rigid element can be comprised of a ceramic material such as commonly molded ceramics of zirconia or alumina and others, and amorphous glasses and others. This rigid exterior element may be absent in some assemblies that are typically comprised of three elements of an assembly, and therefore present as one of two elements, whereby the other element is the electrically conductive element, and this rigid element is then comprised of electrically insulative ceramic material which may suffice to fasten directly to the structure intended for ICCP protection. It should be noted that although most embodiments will utilize a metal for a rigid exterior element, that other materials such as ceramics may suffice or in some cases be preferred, and that in these scenarios said rigid element may be low in tensile strength, and therefore when the assemblage is completed it may rely less upon a compression type seal, and more upon elements more closely matched in CTE and upon wetting and adhesion of the ceramic material to the contacting elements of the assemblage.


Description of the Use of a Ceramic Material in the Assembly

A type of ceramic material that can be used in this invention is commonly available in the electronics industry for hermetic sealing and is typically sold as “sealing glass”, although in practice the material used in this invention can be a glass or a ceramic, or a “glass-ceramic” combination of the two, and can be vitrifying or de-vitrifying, and can be amorphous or crystalline. The ceramic material need not be of a specific oxide makeup, as many various combinations of oxides will suffice for fusion and subsequent conglomeration into a ceramic monolithic seal, and these various combinations may have differing points of fusion and conglomeration, yet the ceramic material will preferably have a temperature of fusion sufficient to wet the surfaces of the materials it contacts, or in the least to become soft enough so as to fill voids created by the expansion of other elements of the assembly during the heating step of production of the assembly where, upon cooling and contraction, a compression seal sufficient for the goals of the assembly is achieved. In an assembly that relies upon a production method of fusing the ceramic material to itself, such as is the case of pieces of frit adhering to each other to become a monolithic element, then the temperature of the fusing is most likely limited at its high end by any detrimental changes it may induce in the other elements of the assembly which are heated with it; therefore, the phase-change points or melting points of the other materials are likely to be considered as the maximum temperature of production of the assembly. Generally, it is preferred that ceramic material fusion occurs at less than 1800-celsius as temperatures above this are energy intensive, and due to the high temperature most metals are precluded from use in the assembly. It is beneficial to have a low fusion temperature of the ceramic material, as energy use and time (and therefore cost) is saved, yet this minimum must not be so low as to be detrimental to the finished assembly, and so, due to likely applications to hot water storage tanks which may at times reach 100-degrees celsius, and desiring an allowance for a factor of safety, fusion of the ceramic material as is minimally suitable for the assemblage should occur at no less than 180-degrees celsius. Generally, it is preferable that the ceramic material fuse at a temperature below 850-degrees celsius to keep production costs low and to allow sealing to other elements of the assembly to comprise of commonly-available materials which may undergo detrimental phase-change above this temperature. It is also preferred that fusion be above 200-degrees celsius to provide an ample factor of safety during use.


Production of the assembly may be made at temperatures lower than the wetting temperature of the ceramic material if a pre-form of the ceramic material is made that has a close fit to the interfacing components, such that the assembly is heated to a deformation temperature of the ceramic material which is then forced by gravity, or by gas or mechanical pressure into greater and more intimate contact with the surrounding elements, afterwhich upon cooling the outermost element contracts more greatly upon the ceramic material element to form a compression seal.


The ceramic material may be wholly a sealing glass or ceramic or a combination of glass and ceramic such as ceramic particles mixed into a glass, any part of which may be vitrifying or devitrifying. In most embodiments, an important purpose that the ceramic material will perform is that of an electrical insulator between the assembly's interior-located electrically conductive element, and the assembly's exterior-located rigid element which is typically comprised of an electrically conductive metal, the ceramic material thereby preventing short circuit within the assembly and therefore the ceramic material typically used in this invention is generally preferred to be electrically insulative to the extent that it does not provide a short circuit path from the electrically conductive element it encompasses to other elements of the assembly or to the structure as this would impair or stop the functioning of the ICCP process. An alternative embodiment which can use a ceramic material that is electrically conductive (versus electrically insulative) is an assembly wherein the rigid outer member that is in contact with the electrically conductive structure during operation is itself electrically insulative (such made of a ceramic material), or when an ICCP assembly that uses an electrically conductive outer rigid member is to be installed on a structure or an area of the structure which is known to be electrically-insulated from the areas of the structure which are intended for corrosion protection; in this way, the path of electrical current from its source to the electrolyte is preserved from short circuiting directly upon the areas of the structure intended for its protection. In typical embodiments however, a generally electrically insulative ceramic material is most likely to be used to reduce risks of compromising the ICCP process. Another purpose of the ceramic material is typically that of environmental sealing. That is, when the ICCP assembly is properly installed upon a structure, the assembly, and specifically the ceramic material, seals the typical environment of the interior of the structure from the exterior; the environmental differences typically being that the structure contains a fluid, often under a pressure greater than normal atmosphere, and that outside of the structure exists typically a normal atmosphere at a normal atmospheric pressure. Therefore it is desired that the ceramic material is able to either sufficiently wet and adhere to the other elements of the assembly wherein sealing occurs, or it is placed enough in compression and its tolerances and surface topology so close-fitting, that sufficient sealing occurs, and thereby an environment seal is attained. An environmental seal is not a requirement of this element of the assembly, as it can later be filled with another element such as an elastomer to provide the environmental seal, but it is preferred. This ceramic material, generally in a solid state of matter during installation and use of the assemblage, will also typically serve the purpose of fixturing the elements of the assemblage to each other by one or both of “wetting” and adhesion, and/or by the compression of outer elements upon the inner, thereby making an assemblage that is generally installed and used as a singular item. It can be stated with confidence that no more than 0.025 milliliters of water should escape through the assembly at 95 PSI at a temperature of 140 degrees fahrenheit per hour; furthermore it is desirable that under those conditions that no water escapes through the seal.


Description of the Use of an “Electrically-Conductive Element” in the Assembly

The “electrically conductive element” of the assembly is a material which is generally electrically conductive to an extent that is sufficient for normal application of an ICCP device (which may depend on structure size, electrolyte type, and material composition of both). This material is typically a metal or metal alloy that is greater than 30% of any one of the following metals: titanium, platinum, iridium, iron, or nickel. This element is preferably a metal that has been coated, in whole or in part, with metal oxides or a metal which act to prolong its life when in contact with an electrolyte and/or while discharging an electrical current into the electrolyte, or which act to allow increased bond strength with the ceramic element during production (during fusion by heat). The material which comprises the electrically conductive element can potentially be comprised of an electrically-conducting glass or ceramic or metal-glass composite, such as common in the industry of creating “spark plugs” for use in internal combustion engines. It can also be comprised of carbon or graphite, or iron, or others, many of which have been utilized either as electrical conductors or for use in application of ICCP. Generally, in the scope of this invention, it is preferred that this element be of a composition that has a low rate of thermal expansion, good hydrolysis resistance, and of sufficient strength to function as an electrical connection. Most preferably, this element will be comprised of titanium, or of titanium that has been coated with mixed metal oxides, or of titanium with other metal coating which promote bonding to the oxide elements of the assembly during heat and fusion. The primary utility of this electrically conductive element of the assembly is to transfer electrical current from one side of the assemblage to the other, i.e., when the assemblage is installed on a structure such as a tank: to transfer electrical current from the outside of the structure to the inside, and, in conjunction with the other elements of the assembly, to do so without transfer of fluid, gas, or pressure between the interior and exterior of the structure to which it is fastened. This element may be used directly to connect to an external power source, or there may be additional electrically conductive components that are fastened to it to provide the electrical connection. This element may itself function not only as an environment-isolating electrical conduit, but also as the discharging electrode of the assembly, whereupon it discharges electrical current to the electrolyte directly. It is expected in many cases however, that a separate electrically conductive “electrode” will be attached to it, thereby this element mainly serves as a conduit for electrical current but not as the electrode which discharges electrical current to the electrolyte. This element can potentially be comprised of titanium, platinum, tungsten, or various nickel-cobalt or nickel-iron ferrous alloys such as Kovar, or Invar, depending on expected environment of use, noting that some of these materials must be coated or covered with an electrically insulative barrier if exposed to an electrolyte so as to reduce corrosion of the material when at a more greatly anodic potential than the electrolyte.


Embodiments

The following examples are submitted to illustrate but not to limit this invention.


A Simplified Embodiment (FIG. 1)

In this embodiment, shown in FIG. 1, an example is given by creating an assembly with only two elements. A titanium rod (FIG. 1, note 1.) that has been largely or entirely coated with mixed-metal oxides will serve the following purposes: as the electrically conductive element that pierces through the assembly, as the transferring element or “anode” or “electrode” that discharges into the electrolyte, and as a connection to outside power source. A sealing disc (FIG. 1, note 2) comprised of electrically insulative ceramic material of similar CTE as titanium surrounds the aforementioned titanium rod, and has been sealed to it due to the “wetting” action of the ceramic material at high temperature. This completed assembly can be installed onto a metal structure which is intended for ICCP, where the ceramic material disc 2 will provide an environmental seal to the titanium 1 as well as prevent unwanted electrical transfer directly between the titanium rod and the structure which it is installed upon, and thereby forces the electrical path to pass through an electrolyte within the structure. The disc 2 may be a variety of shapes and need not be a disc shape, though it is expected that a disc shape will suffer the least amount of detrimental stresses in any CTE mismatch, however slight. This assembly may preferably be bonded to the inside of a tank that is to be coated with ceramic material of similar CTE, whereby the structure is coated internally with a ceramic material and this ICCP assembly is positioned inside the structure concentrically over a hole in the structure (said hole being larger than the rod 1 and not in contact with it) so that one end of the titanium rod 1 exits the structure to the outside (generally the shorter end), and the end of the titanium rod intended for contact with the electrolyte (generally the longer end) is made internal to the structure; preferably the ICCP assemblage is located such that gravity is able to hold it in place that, during production, all the parts (structure and ICCP assemblage) are heated to a temperature sufficient to cause fusing of the enamel between the disc 2 of the ICCP assemblage and the tank and thereby adhere and seal and fixture the ICCP assembly to the the structure. Alternative to bonding by use of heat, the simple example ICCP assembly aforedescribed could be bonded internally to the tank using an elastomeric sealant and/or steel brackets or fasteners to aid in keeping it in place, whereby its internal location in the tank causes any pressure inside the tank to further drive the ICCP assembly upon the elastomer seal, and therefore creep or compression set of the seal is not as much of a concern as when such seal is located externally to the structure. This aforedescribed ICCP assembly (as shown in FIG. 1) can be made using glass-molding or casting techniques known by those who practice the art, such as through the use of graphite or ceramic molds into which is placed the titanium rod, and around which is placed a frit of ceramic material, afterwhich sufficient heating is provided causing the ceramic material to wet and bond to the titanium, afterwhich the assembly is cooled and then ready for installation, the assembly being that as shown in FIG. 1 of a metal electrical conductor generally of titanium 1, and a ceramic element 2 that circumferentially encapsulates the electrical conductor 1. Therefore, above-described are the materials and process for creating a simplified embodiment, but it should be known that the titanium rod 1 need not in all cases be coated with mixed-metal oxides, but can be coated with other metals to increase bonding to the ceramic material, or in some cases does not need to be coated and can remain bare titanium, as much depends upon the composition of the ceramic material. It should also be known that the ceramic element 2 need not in all cases provide inherent in its composition the quality of being electrically insulative, although this is typically desired. In some circumstances it could be that the ceramic element 2 is electrically conductive, either to a negligible amount, or to a large amount in which case it is potentially installed onto a part of the structure that is electrically isolated from the areas of the structure which are intended for the application of ICCP for the control of corrosion. In some cases this simplified embodiment can be made by first molding an alumina component 2 with a closely-matched through-hole for the electrically conductive element 1, with a small depression in the alumina around the area of the hole which is subsequently filled with a frit made of a low-temperature sealing glass, whereupon during heating the sealing glass melts and by wetting action creates an environmental seal between the outer alumina element and the innermost electrically conductive element; therefore, two or more types of ceramic material can be used to create this assemblage.


A Preferred Embodiment (FIG. 2 Front View, and FIG. 3 Section View)

The assembly of a preferred embodiment, first referencing FIG. 3, is generally comprised of 3 main elements: a metal electrical conductor 1, a metal fitting 2, and an element of ceramic material 3, the remaining notes in the figure being features of these elements.


In the paragraphs below, each of the elements that make up this example of a preferred embodiment are first discussed IN CAPITAL LETTERS AS HEADINGS as singular elements, and after this how they are assembled into an assemblage is discussed.


Referencing FIG. 3, a rigid exterior element of a METAL FITTING 2 is provided, typically of a steel or stainless steel, typically fashioned by investment casting and machining, or by machining extruded bars, or by metal injection molding, and which is preferably comprised of these features: pipe threads 4, which correspond to the structure intended for application, typically ¾-inch NPT; a generally hollow and generally radially-symmetrical interior passageway (shown in FIG. 3 filled by ceramic material 3), and typically a means of interfacing with a tool, such as square or hex shape on the end more distal to pipe threads for the purpose of fastening the finished assembly to a structure; in addition, there may be a step internal to the fitting (not shown nor evident in these drawings) which is not required but which may be present so as reduce the amount of ceramic material used to achieve the outcome desired as well as to provide additional strength to the fitting in the area of increased wall thickness, the step resulting in the fitting having more internal open volume in the area of the threads, and less internal open volume in the area which is to be filled with the ceramic material element, typically at the end of the fitting that is intended for interfacing with a tool used for tightening, typically most distal to the small end of any tapered pipe threads.


A METAL ELECTRICAL CONDUCTOR (FIG. 3, note 1) is generally fashioned from titanium rod stock that has been coated with Tantalum and Iridium oxides which are often known as mixed-metal-oxides (MMO), typically of a smooth cylindrical rod with a diameter of 0.2 mm up to 6.0 mm, although a variety of shapes or sizes may work, with a preferred shape of a cylinder and size of 2 mm for handling during assembly and for use as an electrical connector with a barrel plug. The titanium rod may be cut to size with a wire cutter or abrasive wheel, and preferably one end is rounded by using an abrasive wheel so that installation of an electrical connector called a barrel connector may be more easily performed. In this example embodiment of this element of the metal electrical conductor, this element serves as both an electrical conductor to receive current from a source, as well as to conduct it through the assemblage which it is used in, as well as to discharge the electrical current directly to an electrolyte, hence, it is preferred to be coated with a mixed-metal oxide such as tantalum and iridium oxides to extend its useful life. In this embodiment, the electrical discharge to the electrolyte would take place (after full assembly and installation) on the surface areas of the element shown at FIG. 3, note 5. It may be preferred in some cases to selectively coat the surface of this element 1, such as leaving the surface areas of the metal electrical conductor 1 that are within the fitting 2 raw and untreated, but to coat the areas more distal to the fitting 2 with mixed-metal oxides. The vise-versa of this may also be true, in that there may be cases where the areas of 1 should be coated within fitting 2, and left untreated elsewhere. The reasons for selective surface treatments of the metal electrical conductor 1 are that: (A) differing surface treatments offer differing bond forces with differing ceramic materials used for sealing, and it is generally preferable to maximize the bond force between the two elements; (B) differing surface treatments offer differing levels of electrical conduction to an electrolyte in contact with the surface treatment, and it is found in practice that it is beneficial to the ICCP process for the electrical discharge into the electrolyte to take place equidistant from the various parts of the structure which are to have corrosion controlled by the ICCP process, and to limit electrical transfer to any materials that are electrically bonded to the structure (cathodic) but that do not need corrosion control (such as stainless steel fittings, as may be used by this invention).


A CERAMIC MATERIAL (FIG. 3, note 3) typically utilized in frit form that is comprised of minerals which supply oxides, or of oxide powders or pellets directly (as opposed to oxides pre-combined in a ceramic frit form), and which typically fuses to itself and to the oxides it contacts on the assembly surfaces when heated to a temperature between 180-degrees celsius and 1800-degrees celsius, more preferably fusing at higher than 200-degrees celsius and less than 850-degrees celsius. In production of the assemblage, a frit is generally preferred to raw oxide use due to greater predictability of melting point and also a lower melting point than a mixture of raw oxides of the same composition. Typically this sealing material is lead-free so as to avoid hazards to human and animal and environmental health, although a leaded material may be useful in some circumstances. The ceramic material can be applied in the form of powder or granule frit, or a powder frit that has been mixed to form a liquid pourable solution, or it can be a molded shape “pre-form”; in this example it is applied as a granular frit which, when heated sufficiently, fuses to itself and to oxides it is in contact with (such as those oxides found on the surfaces of the other elements used in assembly) and conglomerates into a generally monolithic body. The composition of the oxides used for this assembly element may depend upon the electrolyte type that the completed assembly will be in contact with, and may depend on cost of the oxides, and may depend on the desired lifetime of use of the completed assembly. IT IS DESIRED THAT THIS SENTENCE BE STRICKEN FROM PUBLICATION OF THIS WRITING, but is hereby provided to assert knowledge of the subject that the composition of this element 3 is most preferably a sealing glass comprised in large part of bismuth, zinc, and boron oxides which impart a low temperature of fusion, as well as a CTE that is known to work well with an assembly that uses an exterior rigid element of stainless steel and an interior electrical conductor comprised 90% or greater by weight of titanium.


Not shown in the drawings presented: in some cases an element of the assemblage will be of AN ELECTRICALLY-INSULATIVE COVERING, typically a tube of electrically insulative material which can withstand the final-use environment (typically of a polymer) is (after the assembly has been heated and the ceramic material fused and then cooled) placed over the portion of the rod (FIG. 3, note 1) that is interior to the tank, typically covering a portion of surface 5 shown in FIG. 3 that is closest to the ceramic element 3, thereby blocking in large part electrical discharge from the surface 5 that is covered. This electrically insulative covering element is widely available in tube form and is cut to length with a shears, and can be held in position by adding an additional larger electrode element after it, or by bending a portion of the electrically conductive element (FIG. 3, note 1) that lies after it and most distal to the fitting 2. This potential assembly element of an “electrically insulative covering”, which is an electrically-insulating element, can be comprised of ceramic material which then affords the possibility of inclusion into the assembly prior to fusion of the ceramic material element of the assembly, and which also allows embedding of this element into the ceramic material element 3 which then fixtures this element to the assembly as well as eliminating a potential gap (which could be filled by electrolyte) between this element and that of the ceramic material element. The reason for the use of this element in the assembly (the reason for blocking electrical discharge in this area of the assembly) is so that excessive discharge will not occur in close proximity to the threads of the assembly, as exposed threads of the assembly or exposed threads of the structure may draw electrical current that might otherwise have been discharged more distal and to other areas of the structure that more readily succumb to corrosion that does the material the fitting is comprised of.


Assembly of the Aforedescribed Elements

Referencing FIG. 3, the of the assembly are typically assembled as follows: The pre-cut or pre-shaped components are laid out ready for use. The metal electrical conductor 1 is placed in a blind hole on a fixture plate. The metal fitting 2 is placed concentrically (sometimes with the aid of a washer) over and around the electrically conductive element 1 on the fixture plate with the threaded end pointing upwards. THIS SENTENCE IS REQUESTED NOT TO BE PUBLISHED: used as an assembly tool, a mineral or elemental oxide material such as alumina blasting media, generally of a particle form of less than 0.03-inches diameter with a self-fusion temperature that is substantially higher than that of the ceramic material 3 (such as aluminum oxide, silicon dioxide, or commercially available “kiln wash”) is poured in in a small amount in dry or wet form into the metal fitting 2 and around the metal electrical conductor 1 and on top of any fixturing elements to a thickness of typically 0.010-inches up to about 0.2-inches to form a barrier between the fixture plate and the ceramic material 3 which will be placed within the metal fitting 2. Ceramic material 3 in the form of frit, typically of a granular size between 0.0001-inches and 0.065-inches is poured in dry or wet form into the metal fitting 2 around the metal electrical conductor 1 and on top of any release compounds to a thickness of typically 0.060-inches up to 1.000-inches, with a preferred thickness that after fusion results in a fused monolithic element thickness of 0.1-inches up to 0.5-inches. The ceramic material can alternatively be installed into the assembly in the form of a monolithic “pre-form”, or installed in multiple pre-forms, these pre-forms being comprised of fused and monolithic ceramic material, or of power or frit ceramic material that has been conglomerated by adhesives or waxes that can be burned out. The pre-forms can all be of identical composition, or can be of different compositions such that during heating that different stages of melting occur whereby the last pre-form to melt imparts additional qualities to the mixture such as a higher-melting point typically associated with increased chemical and/or hydrolysis resistance; this assembly mode allows the lower-melting point pre-form to first flow around the surfaces of the assembly at a lower viscosity than could be achievable by a single pre-form of the higher melting point. The assembly is placed in a furnace and heated to a temperature point at which sufficient deformation of the ceramic material occurs to cause sealing and fixturing between the assembly elements, more preferably to the wetting point of said ceramic material, and allowed to “soak” at that temperature for the preferred time according to the composition of the material, and then allowed to cool at a rate appropriate for the material type. The assembly is then removed and tested under water or air pressure for leaks. If the application requires it, an electrically insulative tube is placed over the metal electrical conductor 1 at the end of the said conductor which is on the side of the metal fitting 2 that will be internal to a structure (typically a tank) during use (typically the side of the rod that is on the side of the metal fitting with the small part of any tapered threads, at FIG. 3, note 5), and an additional (typically mixed-metal-oxide-coated titanium) electrode is spot-welded to the metal electrical conductor 1, generally at the end near note 5. This finished assembly (either with, or without the dielectric covering and additional electrode material welded or fastened to it) can be treated at its threads 4 with a thread-sealant common to the art of plumbing such as PTFE tape, and then installed into a structure, typically a tank, which has the corresponding female threads. Tests were performed on assemblies made according to this embodiment, and it was found that the assembly when installed in a pressurized structure withstood without any signs of degradation, temperatures of 285 degrees fahrenheit, the contents of the structure being in one test liquid and in another test gaseous water solutions, both at pressures above 150 PSI, each test running for three days (after which the test was terminated). Longer tests at somewhat lower temperatures that utilized acidic aqueous solutions and also alkaline aqueous solutions further showed the robust nature of this type of seal utilizing a ceramic material, and therefore the attraction to use it in ICCP assemblies.


An Embodiment Using a Ceramic Fitting (FIG. 4 Front View, and FIG. 5 Section View)

First referencing FIG. 5, an embodiment using a fitting made of electrically insulative ceramic material is achievable by following the previously-described embodiment and process with the following changes: notably the allowance of direct contact of the rigid fitting element 2 (which in this case is an insulative ceramic material) with an electrically conductive element 1, contact shown at surface 6, which is typically not possible if the fitting 2 is electrically conductive as it would cause a short circuit, bypassing the electrolyte to the detriment of ICCP corrosion control. Referencing FIG. 5, the rigid fitting 2 is comprised of a generally electrically insulative ceramic material that is of a substantially higher softening point (softening due to application of heat) than that of the ceramic material 3 used to fixture and seal the electrically conductive element 1 within the rigid fitting 2. Many borosilicate-based glass compositions suffice for the use as rigid fitting 2, as do ceramic materials of zirconia and alumina and others. Referencing FIG. 5, the ceramic material 3 is chosen with a coefficient of thermal rate of expansion (CTE) that is similar to that of the fitting 2 so as to prevent disbondment and to aid in mitigating most ceramic material's general low tolerance of tensile strain. Generally the closer the match of CTE of the two materials the lesser the probability of disbondment or of fracture of a ceramic rigid fitting that would otherwise endure heightened tensile strain during or after cooling of a finished assembly. Preferably, though not required in all cases (depending on the composition of the sealing ceramic material 3 and material used for the fitting 2), the electrically conductive element 1 is of minimal diameter or size so as to reduce probability of disbondment of the ceramic material 3 to said electrically conductive element; this is because a smaller diameter will expand and contract at a lower real measurable unit of distance during thermal cycling than will an element of a larger diameter, as well as presents lower real surface area required for bonding or sealing. If this electrically conductive element is a metal, a preferred diameter is less than 2 mm, and more than 0.3 mm. An electrically conductive glass or ceramic or glass-metal composite used as assembly element 1 (instead of a metal) may have the quality of a CTE that more closely matches the fitting material 2, and so may have greater freedom of size of diameter than metal elements. In this embodiment, the interior surfaces (such as at FIG. 5, note 6) of the hole in the rigid fitting 2 can directly contact the electrically conductive element 1 because no substantive electrical short-circuit will occur due to the generally electrically insulative nature of the material used for fitting 2. Therefore, a rigid element 2 comprised of glass or ceramic can function during the assembly process to fixture the electrically conductive element 2 while the sealing ceramic material 3 are yet in a non-solid (and non-final) state, such as during assembly or during the molten state. As in other embodiments, the ceramic material 3 will be melted and flow around the electrically conductive element 1 and either fused or compressed (or both) to both elements 1 and 2, creating a seal and providing permanent fixturing of element 1 to element 3, and to element 2. In this assemblage, it is generally preferred that the through-hole piercing the fitting 2 through which the electrically conductive element 1 is placed is as tight-fitting to electrically conductive element 1 as possible, so that wetting of fitting 2 and electrically conductive element 1 may occur without excess leaking of the sealing ceramic material 3 through the gap between the bodies. Leakage of the sealing ceramic material 3 can also be mitigated by careful control of the temperature such that wetting occurs yet the ceramic material is of as high a viscosity as permissible. Additionally, the assembly can be made on a bed of high-melting-point ceramic material such as granules of aluminum oxide or silicon dioxide or others, with the electrically conductive element 1 piercing into the bed, and an end surface of the fitting 2 resting upon the surface of the bed, whereupon during heating any leaking of the sealing ceramic material 3 contacts the bed material and is stopped by it, either due to gap-filling (presence of material) and/or by the bed material “doping” the ceramic material 3 whereby viscosity of the sealing ceramic material is increased (and leaking subsequently decreased); such has been the experience had by the inventor by experimenting with these materials and this assemblage.


Use of the Assemblage During Installation 1

This possible use description is not intended to limit the extent of claims of this patent. The assemblage, including its discharging electrode element, will typically be inserted into a threaded fitting opening of a tank, with the electrode first being inserted, and the assembly fastened through the use of threads on the exterior portion of the assembly, typically turned by mechanical interference of a shape on the top portion of the assemblage such as a hex. It may be preferable to use a thread sealant on any threads prior to installation to aid in sealing any gasses and fluids in the structure from the environment outside of the structure. The assembly is then typically connected to the positive (anode) output of a DC power source via a connection terminal on the assembly that is exterior to the structure which then brings the current through the assembly to the interior of the structure. Most typically the electrical connections type will be of a flag or spade terminal, or a bolt and eyelet, or a barrel connector, or any number of cost-effective electrical connections available. The structure areas that are intended to have corrosion controlled by the impressed current are connected to the negative (cathode) portion of the electrical power supply.


Use of the Assemblage During Installation 2

An alternative to installing the assembly directly to the structure intended for ICCP protection is to make a miniaturized version of the assembly so as to reduce use of the quantity of ceramic material used in the assembly. This miniaturized assembly is then installed into a lower-cost mass-produced fitting which is then installed upon the structure intended for ICCP protection. In this way, the intent of this patent application is not obviated as the additional component serves only as an intermediary, and the intent of utilizing ceramic material to create an ICCP device is still apparent.


Use During Operation

This possible use of operation is not intended to limit the extent of claims of this patent. The installed assembly will allow conduction of an electrical current from one side of the assembly to the other side, the assembly being mounted upon a structure, while simultaneously preventing substantive transfer of one or more of the structure's environment-including fluids, pressure differential, or gasses; furthermore, the installed assembly will provide this same environment isolation regardless of connection to electrical power supply, or active or inactive flow of electrical current. Yet environment isolation is not a requirement of this proposed invention, but can be a result of it, and in most cases is a desired attribute. The structure may be a tank, a boat, or other type structure where an electrolyte exists in a partially or fully isolated condition in contact with the structure whilst an environment different from the electrolyte exists also in contact with the structure but such that it is desired that some aspect of the two environments be kept separate. An example of partial isolation might be a boat, wherein there is a structure that keeps water out of the boat so long as the boat is floating, but does allow pressure and atmosphere to exchange as it might given natural circumstances; in this same example, if a small boat were placed inside a tank, and the entire tank pressurized with water, the boat structure may no longer function to isolate environments as originally intended. An example of a tank as the structure indicates that the tank may hold a fluid under pressure and temperature within its structure, and thereby keep the fluid and pressure within it separate and isolated from the environment found on the exterior of the tank; so then in this example, the application of an ICCP assemblage to this tank would imply retaining this environment isolation while also conducting an electrical current to the fluid within the tank.

Claims
  • 1. A method of using a ceramic material element to fixture an electrically conductive metal element inside a stainless steel element for application to structures in contact with an electrolyte for the purpose of utilizing an electrical current to control the corrosion of said structure by the method of impressed current cathodic protection, the method including creation of an assemblage comprising: providing a stainless steel element with an internal passageway through its body;placing an electrically conductive metal element within the internal passageway of said stainless steel element such that contact is not made between the two elements;introducing a ceramic material element within the internal passageway of said stainless steel element;heating the aforementioned components to a temperature at which the ceramic material element undergoes sufficient softening to facilitate intimate contact between the stainless steel element and the electrically conductive metal element to form an environmental seal between said assembly elements and to environmentally seal the internal passageway of the stainless steel element;cooling the assembly to solidify the ceramic material element thereby fixing the elements of the assembly together, resulting in the formation of an assemblage.
  • 2. The assemblage of claim 1, wherein the electrically conductive metal element is electrically accessible on either end of the stainless steel element after having been formed into an assemblage.
  • 3. The assemblage of claim 1, wherein, in open air, 6 mA or less electrical current is transferred to the stainless steel element when the electrically conductive metal element is connected to 3-volts of direct-current electrical potential, thereby signifying a degree of electrical isolation of the stainless steel element from the electrically conductive metal element.
  • 4. The assemblage of claim 1, wherein the stainless steel element of the assembly has male threads for the purpose of installation into matching female threads.
  • 5. The assemblage of claim 1, wherein the temperature point of sufficient softening of the ceramic material element to fixture the elements of the assemblage to each other is greater than 200-degrees celsius and less than 1800-degrees celsius.
  • 6. An assemblage for application to structures in contact with an electrolyte for the purpose of utilizing an electrical current to control the corrosion of said structure by the method of impressed current cathodic protection, the assemblage comprising: a stainless steel element provided with an internal passageway that pierces as a through-hole the entirety its body;an electrically conductive element within the stainless steel element;a ceramic material placed internal to the stainless steel element which has sufficiently intimate contact with both the stainless steel element and the electrically conductive element such that all the elements are fixtured to each other and form an assemblage.
  • 7. The assemblage of claim 6, wherein one or more of the elements comprising the assembly is of sufficient electrically insulative quality so as to substantively prevent short circuit of electrical current from the assembly's internal electrically conductive element to an electrically conductive structure to which it is installed upon, except by a path found through an electrolyte.
  • 8. The assemblage of claim 6, wherein the electrically conductive element is comprised of one or more of the following materials: titanium, platinum, tungsten, iron, nickel, or an iron-nickel alloy.
  • 9. A method for producing an assemblage for the use of delivering an electrical current to an electrolyte for the purpose of controlling corrosion, the method comprising: providing a rigid element containing an internal passageway through its body;providing an electrically conductive element placed within the internal passageway of said rigid element;providing that a ceramic material is a part of the assemblage elements: as a third element of the assemblage which is present between the electrically conductive element and the rigid element, or providing said ceramic material as the composition of the aforementioned rigid element or providing said ceramic material as the composition of the aforementioned electrically conductive element, or providing said ceramic material as the composition of all or a combination of the elements of the assemblage;heating the aforementioned elements to a temperature at which the ceramic material has sufficient deformation to form intimate contact with a portion of the assembly elements;cooling the assembly to the solid material state of the ceramic material thereby fixturing the elements of the assembly to each other to form an assemblage.
  • 10. The assemblage of claim 9, wherein the rigid element composition is of sufficient electrically insulative quality so as to substantively prevent short circuit of electrical current from the assembly's internal electrically conductive element to the structure it is installed upon, excluding an electrical path found through electrolyte.
  • 11. The assemblage of claim 9, wherein the rigid element is made of a ceramic material or a metal.
  • 12. The assemblage of claim 9, wherein the rigid element is comprised of stainless steel.
  • 13. The assemblage of claim 9, wherein the ceramic material is able to fuse to itself solely due to heat and contact, at a temperature between 200-degrees celsius and 1800-degrees celsius.
  • 14. The assemblage of claim 9, wherein the ceramic element forms an environmental seal around the electrically conductive element and to the rigid element in the areas of a passageway in the rigid element that is used to house the electrically conductive element.
  • 15. The assemblage of claim 9, wherein the electrically conductive element is electrically accessible at both ends of the rigid element, allowing for connection to electric potential from either end.
  • 16. The assemblage of claim 9, wherein the electrically conductive element serves as both a path of electrical current through the passageway of the rigid element, and as an electrode for contact with an electrolyte.
  • 17. The assemblage of claim 9, wherein a portion of the electrically conductive element is connected to an electrode intended for contact with electrolyte.
  • 18. The assemblage of claim 9, wherein the electrically conductive element is comprised in whole or in part of titanium, platinum, tungsten, Iron, Nickel, or Iron-nickel alloy.
  • 19. The assemblage of claim 9, wherein the electrically conductive element is comprised of an electrically conductive ceramic material.
  • 20. The assemblage of claim 9, wherein the ceramic material is heated to a temperature at which point said ceramic material is able to wet elements it is in contact with.