Patent Grant
7294426
1. Field of the Invention
The present invention relates to a proton exchange membrane fuel cell, particularly to a sealing structure for sealing single fuel cell and stacked fuel cell module.
2. Description of the Prior Art
In the field of fuel cell technology, fuel cell is classified based on the electrolyte thereof. There are approximately five kinds of fuel cells which have been developed, namely, proton exchange membrane fuel cell or polymer electrolyte membrane fuel cell, abbreviated as PEMFC, alkaline fuel cell (AFC), phosphoric acid fuel cell (PAFC), molten carbonate fuel cell (MCFC) and solid oxide fuel cell (SOFC). Each kind of fuel cell has its own advantages, disadvantages and extent of applications. Among these known fuel cells, the PEMFC would be the most competitive power supply and has high practical value.
Principally, a fuel cell is combines hydrogen and oxygen in an electrochemical reactions to produce water and release electrical energy, which can be basically considered a device that is the reverse of water electrolysis.
The performance of fuel cell mainly depends on the extent of the electrochemical reaction, which is affected by the materials forming the layers of the fuel cell and the sealing between the plates. Hence, the selections of the materials and prevention of leakage between the layers will be the important factors of the performance of the fuel cell operations.
However, although much effort has been put to settle the aforesaid problems, the result is not satisfied. Generally speaking, there are two reasons adversely affecting the precise control: one is a failure to efficiently perform the leak and pollution proof functions between the anode and cathode bipolar plates, and the other is a failure to properly control the conductive compression pressure between each layer under an optimal status.
Please refer to
The inner surface of the anode plate 101 facing the MEA is formed with a plurality of anode gas channels 101a, and the inner surface of the cathode plate 102 facing the MEA is formed with a plurality of cathode gas channels 102a. The anode plate 101 and cathode plate 102 are separately provided with gaskets 106, 107 along edge portions thereof. Then, the MEA is disposed on a central portion of the anode plate 101 and cathode plate 102, forming a gastight single cell.
Practically, a plurality of such single cells are stacked to configure a fuel cell stack as shown in
However, this construction for the fuel cell will result in the following problems:
Accordingly, to provide a highly efficient, mass-producible and cost-saving modulized single cell and cell module to solve the above-mentioned problems and further supply breakthrough ideas in manufacturing the PEMFC is a common desire of people skilled in this field.
The primary objective of this invention is to provide a single cell of a fuel cell, particularly a single cell of a PEMFC or a module thereof assembled by the single cells, by means of modulizing and unitizing the cell and module, to simplify the manufacturing process of a PEMFC. Because it is possible to test the performance of each single cell or module in advance according to this invention, the quality of the whole fuel cell is significantly improved and the manufacturing cost thereof is reduced to a mass production scale, thereby practically replacing the existing energy.
Another objective of this invention is to provide a sealing structure for a fuel cell assembled by a plurality of modulized single cells or modules. By means of dispensing a desired amount of silicone rubber between the circumferential portions of the anode plate and cathode plate, the two plates and the MEA sandwiched therebetween can be well positioned in a cushioned manner and can be controlled under a predetermined compression pressure in advance before the silicon rubber is cured, thereby ensuring that a high quality single cell and module is obtained.
Yet a further object of this invention is to provide a single cell of a fuel cell or a module comprising the single cells with excellent gastight effect. By means of dispensing silicone rubber between plates, the leakage of the gases and liquid guided through the channels on the plates can therefore be avoided.
To achieve the above objects, in accordance with the present invention, there is provided a sealing structure for sealing a proton exchange membrane fuel cell. The fuel cell includes a membrane electrode assembly, an anode plate, and a cathode plate. Both of the plates are formed with a peripheral groove and an extended groove at a circumferential portion thereof, and silicone rubber is applied to the peripheral groove and the extended groove. Before the silicone rubber is cured, the anode plate, the membrane electrode assembly and the cathode plate are stacked and compressed with a predetermined compression pressure, such that the silicone rubber at the peripheral groove of the anode plate binds correspondingly to the silicone rubber at the peripheral groove of the cathode plate to form a tight sealing at the circumferential portions between the anode plate and the cathode plate, and the membrane electrode assembly is tightly sandwiched between the silicone rubber at the extended groove of the anode plate and the silicone rubber at the extended groove of the cathode plate to form a tight sealing around the ports between the anode plate and cathode plate.
The detailed technology and preferred embodiments implemented for the subject invention are described in the following paragraphs accompanying the appended drawings for people skilled in this field to well appreciate the features of the claimed invention.
Please refer to the drawings and in particular to
Of course, the technical concept is not restricted to a PEMFC. The modulization technology of the subject invention is applicable to any type of fuel cell having similar construction.
The modulized single cell 10 includes an anode plate 1 and a cathode plate 2, serving as separator plates for the fuel cell. The anode plate 1 has a first surface 11, a second surface 12, a central portion 13 and a circumferential portion 14. The central portion 13 on the first surface 11 is formed with a plurality of anode gas channels 15 having predetermined layout for hydrogen flowing therethrough. The circumferential portion 14 of the anode plate 1 is formed with a hydrogen inlet port 16a, a hydrogen outlet port 16b, an air inlet port 16c, an air outlet port 16d, a coolant inlet port 16e and a coolant outlet port 16f. In the embodiment, the second surface 12 of the anode plate 1 is generally flat in structure.
Similarly, the cathode plate 2 has a first surface 21, a second surface 22, a central portion 23 and a circumferential portion 24. The central portion 23 on the second surface 22 is formed with a plurality of cathode gas channels 25 having predetermined layout for air flowing therethrough. The circumferential portion 24 of the cathode plate 2 is formed with a hydrogen inlet port 26a, a hydrogen outlet port 26b, an air inlet port 26c, an air outlet port 26d, a coolant inlet port 26e, and a coolant outlet port 26f.
When the cathode plate 2 is superimposed on the anode plate 1, the hydrogen inlet port 26a, the hydrogen outlet port 26b, the air inlet port 26c, the air outlet port 26d, the coolant inlet port 26e, and the coolant outlet port 26f at the circumferential portion 24 of the cathode plate 2 are located oppositely and communicated respectively with the hydrogen inlet port 16a, the hydrogen outlet port 16b, the air inlet port 16c, the air outlet port 16d, the coolant inlet port 16e and the coolant outlet port 16f at the circumferential portion 14 of the anode plate 1, forming passages for flowing of hydrogen, air, and coolant respectively.
A membrane electrode assembly (MEA) 3 is mounted between the anode plate 1 and cathode plate 2. The MEA 3 has an anode gas diffusion layer (GDL) 32, a proton exchange membrane (PEM) 31 and a cathode gas diffusion layer (GDL) 33, that are sequentially stacked and located between the central portion 13 of the anode plate 1 and the central portion 23 of the cathode plate 2. An anode catalytic layer (not shown) is coated between the anode GDL 32 and the PEM 31, and a cathode catalytic layer (not shown) is coated between the PEM 31 and the cathode GDL 33, such that the hydrogen introduced through the channels 15 of the anode plate 1 and the oxygen introduced through the channels 25 of the cathode plate 2 are adapted to proceed with the reverse reaction of the electrolytic dissociation of water.
The first surface 11 of the circumferential portion 14 of the anode plate 1 is formed with a peripheral groove 17. Also, an extended groove 17a is formed in the vicinity of the ports 16a, 16b, 16c, 16d, 16e, 16f and communicated with the peripheral groove 17.
Similarly, the second surface 22 of the circumferential portion 24 of the cathode plate 2 facing the anode plate 1 is formed with a peripheral groove 27. An extended groove 27a is formed in the vicinity the ports 26a, 26b, 26c, 26d, 26e, 26f and communicated with the peripheral groove 27.
In this embodiment, the first surface 21 of the central portion 23 of the cathode plate 2 is also formed with a plurality of coolant channels 28 having predetermined layout for coolant flowing therethrough. The first surface 21 at the circumferential portion 24 of the cathode plate 2 is formed with a peripheral groove 29. An extended groove 29a is formed in the vicinity of the ports 26a, 26b, 26c, 26d, 26e, 26f and communicated with the peripheral groove 29.
In the assembly of the single cell 10, appropriate amounts of silicone rubbers 4, 4a are applied to the peripheral groove 29 and the extended groove 29a at the first surface 21 of the cathode plate 2 and cured, as shown in
Then, appropriate amounts of silicone rubbers 5, 5a are applied to the peripheral groove 17 and the extended groove 17a at the first surface 11 of the circumferential portion 14 of the anode plate 1. As shown in
Moreover, the PEM 31 of the MEA 3 is adhered by the silicone rubber 5a at the extended groove 17a of the anode plate 1 and the silicone rubber 6a at the extended groove 27a of the cathode plate 2. Thereby, the PEM 31 is stably located in position between the anode plate 1 and the cathode plate 2, and tight sealing are formed around the ports between the anode plate 1 and cathode plate 2 after the silicone rubbers are cured. Thereby, each of the ports 16a, 16b, 16c, 16d, 16e, 16f at the anode plate 1 is only in communication respectively with the corresponding ports 26a, 26b, 26c, 26d, 26e, 26f at the cathode plate 2. Accordingly, a modulized unitary single cell 10 is formed.
By means of the described technology, the single cell 10 is tightly sealed at the circumferential portion. Moreover, the anode plate, MEA and cathode plate are stably positioned and fastened to each other. Sealing is provided between the ports of the anode plate and cathode plate, forming a plurality of separate passages. Thereby, hydrogen gas, oxygen gas and coolant are separately transported and sealed from leakage.
In the embodiment, silicone rubber is used as the adhesive material for binding the separator plates of the single cell 10. Preferably, the silicone rubber is selected from material which has non-corrosive electronic grade and can be cured under moisture or heat.
According to experimental and practical experiences, in the event that the silicone rubber made of heat-cured material is utilized for the manufacture of the single cell, the silicone rubber generally has a heat-cured temperature of 100-140° C. Because the curing temperature of the silicone rubber is higher than the working temperature (lower than 100° C.) of PEMFC, the silicone rubber is stable and can perform an optimal after-cured effect thereof. Preferably, to provide an optimal sealing and positioning effect, the viscosity of the silicone rubber utilized is greater than 150,000 centi-poise. Furthermore, the silicone rubber having a dielectric strength ranging from 15-20 V/mil would sufficiently perform a considerable electricity resistance. Nevertheless, the above-mentioned values are proposed for people skilled in this field to implement the present invention under a preferred situation. It dos not mean that any values going beyond the proposed ranges cannot perform well the expected functions as set forth therein.
In practical application, one can assemble a plurality of single cells as mentioned above and superimpose them onto one another to form a cell module for performing high power output.
a shows a cross-sectional view of a second embodiment of the present invention, in which two single cells are superimposed to form a fuel cell module. Two modulized single cells 10, 10a are formed in accordance with the technology as mentioned. Please refer to
In this embodiment, the cell module 10b comprises an anode plate 1, a bipolar plate 7 and a first MEA 3a. The anode plate 1 has a first surface 11, a second surface 12, a central portion 13, a circumferential portion 14, a plurality of anode gas channels 15, a peripheral groove 17, an extended groove 17a, and a plurality of ports. The bipolar plate 7 comprises a first surface 71, a second surface 72, a central portion 73, a peripheral portion 74, a plurality of cathode gas channels 75, a peripheral groove 77, an extended groove 77a, a peripheral groove 79, an extended groove 79a, and a plurality of ports. Furthermore, the first surface 71 of the central portion 73 is formed with a plurality of anode gas channels 78 for anode gas flowing therethrough. The first MEA 3a comprises a proton exchange membrane 31a, an anode gas diffusion layer 32a and a cathode gas diffusion layer 33a.
A second MEA 3b is stacked on the first surface 71 of the bipolar plate 7. The second MEA 3b comprises a proton exchange membrane 31b, an anode gas diffusion layer 32b and a cathode gas diffusion layer 33b, in which the anode gas diffusion layer 32b of the second MEA 3b is superimposed on the central portion 73 at the first surface 71 of the bipolar plate 7. A cathode plate 8 is then stacked on the top of the cathode gas diffusion layer 33b of the second MEA 3b.
The cathode plate 8 includes a first surface 81, a second surface 82, a central portion 83, a circumferential portion 84, a plurality of cathode gas channels 85, a peripheral groove 87 and an extended groove 87a formed at the second surface 82, a peripheral groove 89 and an extended groove 89a formed at the first surface 81 and a plurality of ports. Also, a plurality of coolant channels 88 are formed at the first surface 81 of the central portion 83 of the cathode plate 8 for coolant flowing therethrough.
In the manufacture of the cell module 10b, the peripheral groove 89 and extended groove 89a at the first surface 81 of the circumferential portion 84 are dispensed with silicone rubbers 91, 91a, as shown in
Then, the peripheral groove 17 and extended groove 17a of the anode plate 1 are applied with silicone rubbers 92, 92a. Similarly, the peripheral grooves 77, 79 and extended grooves 77a, 79a of the bipolar plate 7 and the peripheral groove 87 and extended groove 87a of the cathode plate 8 are respectively applied with silicone rubbers 93, 94, 93a, 94a, 95, 95a. Before the silicone rubbers are cured, the anode plate 1, first MEA 3a, bipolar plate 7, second MEA 3b, and cathode plate 8 are precisely stacked in proper order and compressed with a predetermined compression pressure, as shown in
The above disclosure is related to the detailed technical contents and inventive features thereof. People skilled in this field may proceed with a variety of modifications and replacements based on the disclosures and suggestions of the invention as described without departing from the characteristics thereof. Nevertheless, although such modifications and replacements are not fully disclosed in the above descriptions, they have substantially been covered in the following claims as appended.
| Number | Date | Country | Kind |
|---|---|---|---|
| 92135318 A | Dec 2003 | TW | national |
| Number | Name | Date | Kind |
|---|---|---|---|
| 6699613 | Inoue et al. | Mar 2004 | B2 |
| 6852439 | Frank et al. | Feb 2005 | B2 |
| 6893767 | Hatano et al. | May 2005 | B2 |
| Number | Date | Country | |
|---|---|---|---|
| 20050130016 A1 | Jun 2005 | US |
