This relates generally to electronic devices, and, more particularly, electronic devices with optical components.
Electronic devices may have optical components. For example, electronic devices may have waveguides and other structures that are formed from transparent materials. These materials may be susceptible to chemical or moisture-induced degradation if exposed to excess moisture. Additionally, these materials may contain volatile species which induce degradation if they leave the system.
An electronic device may have a support structure that supports one or more optical components. Each optical component may have first and second transparent layers such as first and second glass layers. The glass layers may have outer surfaces that face away from each other and inner surfaces that face towards each other. A moisture-sensitive polymer layer (e.g., an organic polymer layer) may be formed between the inner surfaces of the glass layers.
Along the periphery of each optical component, a moisture barrier may be formed to protect the polymer material of the polymer layer. The moisture barrier may provide a hermetic seal that extends between the first and second glass layers. The seal may include a moisture barrier layer such as a layer of metal foil or a polymer layer coated with a moisture barrier coating such as a metal or inorganic dielectric thin-film coating.
An electronic device may have housing structures. The housing structures, which may sometimes be referred to as support structures, may be used to support and/or enclose device components such as batteries, displays, integrated circuits, sensors, other circuitry, and optical components. Examples of optical components that may be used in the electronic device include lenses and lenses with embedded waveguides, optical devices with sensitive coatings, displays such as liquid crystal displays (e.g., displays in which arrays of liquid crystal pixels are sandwiched between inner and outer glass layers and polarizers), organic light-emitting diode displays (e.g., displays with organic light-emitting diode pixels sandwiched between glass layers or other layers), and/or other optical elements. The housing structures of the device may be configured to be mounted on a stand or in a frame, may be configured to rest on a desktop or other surface, or may be configured to be worn on a body part of a user (e.g., a wrist, arm, head, or other body part). During operation, an electronic device may use sensors and other circuitry to gather user input and other data and may use displays and other output devices to provide output for a user.
A cross-sectional view of a portion of an illustrative electronic device is shown in
In the example of
Substrates 12 may be formed from glass (e.g., strengthened glass, ceramic glass, high index of refraction glass, and/or other layers of glass), transparent crystalline material such as sapphire, transparent ceramic, transparent polymer, and/or other transparent substrate material. In an illustrative configuration, which may sometimes be described herein as an example, substrates 12 are glass substrates (sometimes referred to as glass layers or glass members). The inner and outer surfaces of each substrate 12 may have planar areas (e.g., areas that lie in the X-Y plane of
Optical component 20 may serve as a lens that passes light (e.g., light traveling along the Z axis of
Polymer layer 14 may be sensitive to water. To prevent degradation of polymer layer 14 and structure 16 due to exposure to moisture in the environment, layer 14 may be hermetically sealed. In particular, the periphery of optical component 20 may be provided with a hermetic seal. The hermetic seal may prevent ingress of environmental contamination into layer 14 and may prevent egress of volatile compounds and/or moisture from layer 14 to the exterior region surrounding component 20, thereby helping to prevent degradation to layer 14.
Consider, as an example, the cross-sectional side view of optical component 20 of
In the example of
To seal edge E, layer 24 is bonded over edge E by attaching a first edge of layer 24 to a first of substrates 12, as shown by bond 30 between layer 24A and the outer surface of the first substrate 12, and by attaching an opposing second edge of layer 24 to a second of substrates 12, as shown by bond 30 between layer 24B and the outer surface of the second substrate 12. Bonds 30 may be formed by adhesive, solder, or other material for forming hermetically sealed joints between layer 24 and the glass or other material of substrates 12. For example, bonds 30 may be formed using adhesives exhibiting low water vapor transmission rates such as polyisobutylene, epoxy, acrylic core tape, silver-based glue, fluorosilicones, or other adhesives, may be formed from metal solder based on indium-tin alloys or other metals, and/or may be formed by direct bonding in which the metal foil or other material of layer 24 is directly welded to the glass or other material of substrates 12. If desired, layer 24 may be formed from solder foil, allowing solder bonds to be formed directly between foil surfaces (e.g., for soldered foil-foil joints and soldered foil-glass bonds). In some configurations, metal layers (e.g., strips of metal running along the periphery of component 20) are formed on the surfaces of substrates 12 to help allow solder bonds to be formed (e.g., to enhanced solder adhesion to substrates 12).
The thicknesses T1 and T3 of substrates 12 may be equal or the values of T1 and T2 may be different from each other. Thicknesses T1 and T3 may have values of 50 microns to 1000 microns or 100 microns to 400 microns or other suitable substrate thicknesses may be used in forming substrates 12 for element 20 (e.g., T1 and/or T3 may be at least 50 microns, at least 200 microns, at least 250 microns, less than 1000 microns, less than 700 microns, less than 350 microns, etc.). The thickness T2 of polymer layer 14 may be 400 microns to 800 microns, at least 200 microns, at least 300 microns, at least 450 microns, less than 1200 microns, less than 750 microns, less than 600 microns, etc.
Layer 24 may be formed from a material such as metal foil (e.g., foil formed from aluminum, stainless steel, copper, nickel, and/or other metals), low water vapor transmission rate plastics such as polychlorotrifluoroethylene (PCTFE), or higher water vapor transmission rate plastics which are coated in a barrier film to reduce their water transmission, or other material(s) impermeable to moisture. The thickness of layer 24 may be 5-45 microns, at least 5 microns, at least 10 microns, at least 15 microns, at least 20 microns, at least 40 microns, less than 100 microns, less than 75 microns, less than 60 microns, less than 30 microns, or other suitable thickness. Layer 24 is preferably sufficiently thin to be bent into a desired shape for seal 22 while being sufficiently thick to exhibit desired strength while serving as a moisture barrier. Thinner foils tend to offer less resistance to thermal movement. Thicker foils tend to offer better handling and moisture barrier properties. Layer 24 preferably has a thickness and composition that allows layer 24 to be formed into a desired shape (e.g., under heat and/or pressure). As an example, layer 24 may have a thickness of less than 100 microns or less than 50 microns so that a desired three-dimensional shape may be embossed and/or otherwise molded (pressed) into layer 24.
Buffer 28, which may sometimes be referred to as a buffer member, support member, moisture barrier layer support, or support structure, may be formed from an elastomeric material or other compliant material. This allows buffer 28 to expand and contract to accommodate temperature-induced changes in the thickness of element 20 (e.g., the compliant nature of buffer 28 helps avoid stress due to possible mismatch between the coefficient of thermal expansion of each of the layers of element 20 and the coefficient of thermal expansion of buffer 28).
Examples of suitable materials for buffer 28 include silicone, polyisobutylene, polyvinylidene difluoride, neoprene, and nitril rubber. These materials may exhibit desirable properties such as an ability to match temperature-induced expansion in layer 14 (e.g., if the coefficient of thermal expansion of layer 14 is greater than 200 ppm/C, buffer 28 may exhibit an approximately matched coefficient of thermal expansion of 100-300 ppm/C), a low modulus of elasticity (e.g., less than 10 MPa), chemical compatibility with layer 14, low solubility to liquid components in layer 14, a low water vapor transmission rate, satisfactory adhesion to the edge of component 20, minimal permanent deformation under applied stress (e.g., over a temperature range of −40 to 85 C or other suitable temperature range), a glass transition temperature outside of the expected operating range of device 10 (e.g., a glass transition temperature of less than −40 C or >85 C in one illustrative configuration), and a black appearance or other optically opaque appearance (e.g., less than 0.5% reflectivity) to help suppress stray light. Buffer 28 may have a C-shaped profile as shown in the example of
Layers 24A and 24B of seal 22 may have the same shape and size (e.g., so that layer 24 is symmetrical about bond 26) or layers 24A and 24B may have different shapes and/or sizes (e.g., so that the shape of layer 24 is asymmetrical). The portions of layers 24A and 24B that are joined at bond 26 may be bent upwards or downwards to help reduce the lateral size of seal 22.
The lateral dimension (width W) of buffer 28 may be at least 400 microns, at least 800 microns, at least 1600 microns, less than 4000 microns, less than 2000 microns, less than 1100 microns, less than 550 microns, less than 350 microns, or other suitable width. The support that buffer 28 provides to layer 24 may help prevent damage to layer 24 during assembly and use of device 10. If desired, buffer 28 may be omitted (e.g., so that an air gap is present between the inner surface of layer 24 and edge E of element 20). This can ease assembly of the structure.
The portion of housing 18 that supports element 20 may be mounted over an edge portion of layer 24 (see, e.g., housing 18A of
Using a hermetic sealing arrangement of the type shown in
Optical performance can also be preserved by configuring the hermetic seal to preserve the shape of element 20 over a range of operating temperatures (e.g., by ensuring that the edge does not become overly compressed or expanded relative to the center of element 20 during temperature fluctuations. Consider, as an example, a scenario in which element 20 has planar layers 12 and 14 or other layers 12 and 14 that are characterized by a center thickness (e.g., a first thickness CT1 that is measured in center of element 20) and an edge thickness (e.g., a second thickness CT2 that is measured adjacent to the periphery of element 20). Optical performance can be maintained for element 20 by configuring the hermetic seal of element 20 so that the change in CT1 over a given temperature range does not differ too much from the change in CT2 over the same given temperature range.
With an illustrative configuration, buffer 28 is formed from a low modulus (less than 10 MPa, as an example) elastomeric polymer such as silicone that exhibits a coefficient of thermal expansion of 100-300 ppm/° C., layers 12 are glass layers, and layer 14 is a polymer with thickness of about 600 microns and a lateral dimension of about 4-6 cm, and layer 24 is a one-part or multi-part barrier film having a metal layer (e.g., 10 microns of aluminum) on a polymer substrate (e.g., a 40 micron thick polypropylene film). With this illustrative configuration, seal 22 helps ensure that the change in CT1 differs from the change in CT2 by less than 0.5% and preferably by less than 0.1% over a temperature range of 0-45° C.
Bonds 30 of
The hermetic bonds 30 may provide a first amount of mechanical bonding strength, whereas the non-hermetic bonds 31 may provide a second level of mechanical bonding strength greater than the first level of mechanical bonding strength (e.g., hermetic bonds 30 provide weaker mechanical support than non-hermetic bonds 31). The non-hermetic bonds 31 can therefore provide improved structural support for ensuring that the connection between layers 12 and 24 is mechanically sound. The hermetic bonds 30 are therefore sometimes referred to and defined herein as structural or load-bearing joints, whereas the non-hermetic bonds 31 are sometimes referred to and defined herein as non-structural or non-load-bearing joints. The use of load-bearing bonds 31 in addition to the non-load-bearing but hermetic bonds 30 can help relieve mechanical stress that might otherwise be applied to the hermetic bonds 30, which can be beneficial and technically advantageous to prevent cracks, damage to substrate 12, or other mechanical failure in seal 22 of optical component 20.
In the example of
In general, load-bearing bonds 31 may be formed by adhesive, solder, or other material for forming non-hermetically sealed joints between layer 24 and the glass or other material of substrates 12. For example, bonds 31 may be formed using adhesives exhibiting low water vapor transmission rates such as polyisobutylene, epoxy, acrylic core tape, silver-based glue, fluorosilicones, or other adhesives, may be formed from metal solder based on indium-tin alloys or other metals, and/or may be formed by direct bonding in which the metal foil or other material of layer 24 is directly welded to the glass or other material of substrates 12. Bonds 31 may be continuous or discrete laser welds. Bonds 30 may be formed using a first laser welding process, whereas bonds 31 may be formed using a second laser welding process separate from the first laser welding process.
The configurations for seal 22 that are shown in
As shown in
The example of
In the example of
In the illustrative arrangement of
The example of
Layer 24 may be formed from one or more materials (organic materials, inorganic materials, elemental metals and/or metal alloys forming metal foil, thin-film metal coatings, or other metal layers, low-water-vapor-transmission polymer, hybrid organic/inorganic materials, and/or other materials). As shown in
In general, layer 24 may be formed entirely of metal (e.g., layer 24 may be a metal foil), may include one or more polymer layers (e.g., for providing layer 24 with strength) and/or may include one or more metal thin-film layers and/or dielectric thin-film layers (e.g., for providing layer 24 with a moisture resistant coating). Layer 24 may, if desired, include sufficient opaque material (e.g., opaque polymer, metal, etc.) to make layer 24 opaque so that layer 24 can serve as a light seal in addition to serving as a moisture barrier seal.
If desired, planar seam sealing arrangements may be used in hermetically sealing the structures of seal 22 to component 20. Consider, as an example, the arrangement of
In the example of
As shown in
A top view of layer 58C is shown in
Alternatives to using an adhesive with an embedded mesh coated with a barrier layer are shown in
In the illustrative sealing arrangement of
In the illustrative sealing arrangement of
If desired, multilayer coatings may be used in forming seal 22. Consider, as an, the illustrative seals of
As shown in
Innermost layer 80 may be a polymer layer that prepares the edge of component 20 for subsequent hermetic sealing layers. Layer 80 may be deposited using low-injection pressure overmolding (LIPO) deposition techniques, needle dispensing techniques, three-dimensional dispensing techniques, or other suitable deposition techniques. The polymer material forming layer 80 may be epoxy, acrylic, a composite such as a polymer with embedded particles (e.g., epoxy with embedded silica particles or other filler particles, acrylic with embedded silica particles or other filler particles, etc.). The thickness of layer 80 may be 0.05 microns to 1 mm, micron to 500 microns, at least 0.1 micron, at least 1 micron, at least 10 microns, less than 2000 microns, less than 1000 microns, less than 500 microns, less than 200 microns, or other suitable thickness. The coefficient of thermal expansion of layer 80 may be less than 100 ppm or other suitable value. The elastic modulus of layer 80 may be 10-2000 MPa, at least 1 MPa, at least 10 MPa, at least 100 MPa, less than 10,000 MPa, less than 3000 MPa, less than 1000 MPa, less than 300 MPa, less than 50 MPa, or other suitable value. Layer 80 may exhibit a critical strain of at least 5%.
Middle layer 82, which forms a moisture barrier layer, may contain one or more sublayers of material that help enhance the hermetic sealing properties of seal 22. Each sublayer may be a metal oxide layer, a ceramic layer, a polymer layer, or other suitable hermetic sealing layer. In an illustrative single-layer configuration, layer 82 contains a single layer of metal oxide or ceramic deposited by plasma-enhanced atomic layer deposition. In an illustrative dual-layer configuration, a first of two sublayers in layer 82 may be a metal oxide or ceramic layer deposited by plasma-enhanced atomic layer deposition and a second of the two sublayers in layer 82 may be another metal oxide or ceramic layer deposited by plasma-enhanced atomic layer deposition (e.g., a different material than the first sublayer of the dual layer). In an illustrative configuration involving more than two sublayers, a stack of two or more pairs of sublayers may be used to form layer 82. Each pair of sublayers may have a first sublayer formed from metal oxide, ceramic, or polymer and may have a second sublayer formed from metal oxide or ceramic. These materials may be deposited by plasma-enhanced atomic layer deposition (as an example). Examples of metal oxide and ceramic materials (inorganic materials) that may be used for forming layer 82 include aluminum oxide, titanium oxide, zinc oxide, zirconium oxide, silicon oxide, silicon nitride, and aluminum nitride. Examples of multiple-layer inorganic and/or organic hybrid films that may be deposited (e.g., when forming a stack of sublayers pairs) include films based on sublayer pairs such as an aluminum-oxide/titanium-oxide pair, aluminum-oxide/silicon-oxide pair, an aluminum-oxide/alucone pair, an aluminum-oxide/polymer pair, etc. The thickness of layer 82 is generally less than the thickness of layer 80 and less than the thickness of layer 84. As an example, the thickness of layer 82 may be 0.05 nm to 1 micron, 0.1 nm to 500 nm, at least 0.1 nm, at least 1 nm, at least 10 nm, less than 2000 nm, less than 1000 nm, less than 500 nm, less than 200 nm, or other suitable thickness.
Outer layer 84, which may optionally be the outermost layer of seal 22, may be a polymer protection layer that is dispensed using a three-dimensional dispersion deposition technique or other suitable deposition technique. Layer 84 may be formed from a polymer such as silicone, acrylate, or other polymer that may help protect underlying layers in seal 22 such as layers 80 and 82. The thickness of layer 84 may be 0.05 microns to 1 mm, 0.1 micron to 500 microns, at least 0.1 micron, at least 1 micron, at least 10 microns, less than 2000 microns, less than 1000 microns, less than 500 microns, less than 200 microns, or other suitable thickness. The coefficient of thermal expansion of layer 84 may be less than 500 ppm or other suitable value. The elastic modulus of layer 84 may be 0.1-100 MPa, at least 0.01 MPa, at least 0.1 MPa, at least 1 MPa, less than 1000 MPa, less than 300 MPa, less than 100 MPa, less than 30 MPa, less than 5 MPa, or other suitable value. In an illustrative configuration the elastic modulus of layer 84 is less than the elastic modulus of layer 80 (e.g., layer 80 may be rigid polymer, whereas layer 84 may be formed from an elastomeric polymer). Layer 80 may exhibit a critical strain of at least 100%.
As shown in
If desired, the layers of seal 22 may have tapered profiles as shown in
In accordance with an embodiment, an optical component is provided that includes first and second glass layers, a polymer layer between the first and second glass layers, and a seal formed from a barrier layer that hermetically seals a peripheral edge of the polymer layer, the barrier layer includes a layer of metal and the barrier layer is attached to the first glass layer and the second glass layer.
In accordance with another embodiment, the optical component includes the barrier layer is attached to a first surface of the first glass layer and is attached to a second surface of the second glass layer, the seal includes an elastomeric buffer configured to support the barrier layer, and the layer of metal has a first portion with a first edge that is bonded to the first surface and a second edge and has a second portion with a third edge that is bonded to the second surface and a fourth edge that is bonded to the second edge.
In accordance with another embodiment, the layer of metal is attached to a first surface of the first glass layer and is attached to a second surface of the second glass layer.
In accordance with another embodiment, the seal includes adhesive that bonds the layer of metal to the first and second surfaces.
In accordance with another embodiment, the seal includes solder that bonds the layer of metal to the first and second surfaces.
In accordance with another embodiment, the layer of metal is welded to the first and second surfaces using welds.
In accordance with another embodiment, the barrier layer has a polymer substrate covered with the layer of metal.
In accordance with another embodiment, the seal includes adhesive.
In accordance with another embodiment, the adhesive bonds the layer of metal to the first and second glass layers.
In accordance with another embodiment, the barrier layer includes a polymer layer and the layer of metal includes a plated metal layer on the polymer layer.
In accordance with another embodiment, the barrier layer includes a polymer layer coated with the layer of metal, the seal includes a first metal strip on a first surface of the first glass layer, first solder that seals a first edge of the layer of metal to the first metal strip, a second metal strip on a second surface of the second glass layer, and second solder that seals a second edge of the layer of metal to the second metal strip.
In accordance with another embodiment, the first and second glass layers each have an outer surface and an opposing inner surface and the inner surfaces of the first and second glass layers face each other.
In accordance with another embodiment, the barrier layer is bonded to the outer surfaces of the first and second glass layers.
In accordance with another embodiment, barrier layer has a first edge bonded to the outer surface of the first glass layer and has a second edge bonded to a peripheral edge surface of the second glass layer and the peripheral edge surface that extends between the inner surface of the second glass layer and the outer surface of the second glass layer.
In accordance with another embodiment, the barrier layer has opposing first and second surfaces, a first area of the first surface is bonded to the inner surface of the first glass layer, and has a second area of the first surface is bonded to the inner surface of the second glass layer.
In accordance with another embodiment, the layer of metal is attached to the first and second glass layers using first and second sealing strips, the sealing strips each include a substrate layer, a mesh embedded in a layer of adhesive, and a metal layer between the substrate layer and the layer of adhesive.
In accordance with another embodiment, the optical component includes metal strips on the first and second glass layers, the metal mesh of the first and second sealing strips includes a solder coating that forms solder bonds with the metal strips.
In accordance with an embodiment, an optical component is provided that includes first and second glass layers, a first polymer layer between the first and second glass layers, and a seal formed along a peripheral edge of the first polymer layer, the seal includes a barrier layer having a second polymer layer coated with a barrier coating, the barrier layer has a first edge attached to the first glass layer and a second edge attached to the second glass layer.
In accordance with another embodiment, the barrier coating includes a moisture barrier coating selected from the group consisting of a metal thin-film layer and an inorganic dielectric thin-film layer.
In accordance with an embodiment, an electronic device is provided that includes a support structure, an optical component supported by the support structure, the optical component has first and second glass layers, and has a polymer layer between the first and second glass layers, and a hermetic seal formed along a peripheral edge of the optical component, the hermetic seal includes a first metal layer portion that is attached to the first glass layer and a second metal layer portion that is attached to the second glass layer and a bond is formed between the first and second metal layer portions.
In accordance with an embodiment, an optical component having a periphery and center is provided that includes first and second glass layers, a polymer layer between the first and second glass layers, and a hermetic seal formed along a peripheral edge of the polymer layer, the seal includes a barrier layer having a polymer film coated with a barrier coating, the barrier layer has a first edge attached to the first glass layer and a second edge attached to the second glass layer, there is an edge thickness associated with a distance through the first and second glass layers and the polymer layer at the periphery, there is a center thickness associated with a distance through the first and second glass layers and polymer layer in the center, and the hermetic seal is configured so that over a temperature range of 0° C. to 45° C., the edge thickness exhibits a first thickness change, the center thickness exhibits a second thickness change, and there is a difference between the first and second thickness changes of less than 0.05%.
In accordance with an embodiment, an optical component is provided that includes first and second transparent layers, a polymer layer between the first and second transparent layers, and a seal that hermetically seals a peripheral edge of the polymer layer, the seal includes a first layer, a second layer, and a third layer, the second layer is between the first and third layers, the first layer includes polymer, the second layer includes a barrier layer and includes at least one inorganic material, and the third layer includes polymer.
In accordance with another embodiment, the first layer includes a polymer layer selected from the group consisting of an epoxy layer, an epoxy layer with embedded particles, an acrylic layer, and an acrylic layer with embedded particles.
In accordance with another embodiment, the first layer has a coefficient of thermal expansion of less than 100 ppm.
In accordance with another embodiment, the first layer has an elastic modulus of 10-2000 MPa.
In accordance with another embodiment, the first layer includes a polymer layer selected from the group consisting of silicone and acrylate.
In accordance with another embodiment, the first layer has a first elastic modulus and the third layer has a second elastic modulus that is less than the first elastic modulus.
In accordance with another embodiment, the third layer has a coefficient of thermal expansion of less than 500 ppm.
In accordance with another embodiment, the third layer has an elastic modulus of 0.1-100 MPa.
In accordance with another embodiment, the second layer is a layer of metal oxide or ceramic.
In accordance with another embodiment, the second layer includes first and second sublayers and the first and second sublayers each include a material selected from the group consisting of metal oxide and ceramic.
In accordance with another embodiment, the second layer includes a stack of multiple sublayer pairs, each sublayer pair having a first sublayer and a second sublayer.
In accordance with another embodiment, each of the first sublayers includes metal oxide or ceramic.
In accordance with another embodiment, each of the second sublayers includes a material selected from the group consisting of: metal oxide, ceramic, and polymer.
In accordance with another embodiment, the second layer is thinner than the first and third layers.
In accordance with another embodiment, the first, second, and third layers have tapered profiles.
In accordance with another embodiment, the optical component includes a buffer between the peripheral edge of the polymer layer and the first layer.
The foregoing is merely illustrative and various modifications can be made to the described embodiments. The foregoing embodiments may be implemented individually or in any combination.
This application is a continuation-in-part of co-pending International Application No. PCT/US2022/042305, filed Sep. 1, 2022, which claims priority to U.S. provisional patent application No. 63/303,864, filed Jan. 27, 2022, and U.S. provisional patent application No. 63/244,181, filed Sep. 14, 2021. The above applications are hereby incorporated by reference herein in their entireties.
Number | Date | Country | |
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63303864 | Jan 2022 | US | |
63244181 | Sep 2021 | US |
Number | Date | Country | |
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Parent | PCT/US2022/042305 | Sep 2022 | US |
Child | 18447209 | US |