The present disclosure relates to secondary battery assemblies, and more particularly to electrode plate assemblies comprising a plurality of cells arranged in a vertical stack.
Rechargeable or secondary batteries find widespread use as electrical power supplies and energy storage systems. For example, in automobiles, battery packs formed of a plurality of battery modules, wherein each battery module includes a plurality of electrochemical cells, are provided as a means of effective utilization of electric power, also in the viewpoint of air pollution prevention. Several different form factors exist for the electrochemical cells applied in secondary batteries depending on their intended application field. In automotive applications, the most common cell types are cylindrical, prismatic and pouch cells. A further concept for automotive applications is large format flat, thin cells, which in general include a single positive electrode and a single negative electrode and in which the upper and lower surfaces are formed by the electrodes, which serve as cell housing and also act as the terminals for the cell. However, there is still a need for alternative and improved cell designs and battery packs, in particular in view of electrical monitoring of the cells and challenges relating to mechanical movement during cell swelling.
According to a first aspect, a secondary battery module, or battery pack, comprising a plurality of cells arranged in a vertical stack is provided. Each of the cells of the stack comprises a positive electrode plate (also referred to as a positive electrode), a negative electrode plate (also referred to as a negative electrode) and a separator interposed between the positive electrode plate and the negative electrode plate. The separator is configured to allow ions to move between the positive electrode and the negative electrode. Thus, the positive electrode, the negative electrode and the separator may be arranged in a single positive electrode-separator-single negative electrode stack.
According to some embodiments the cells may be serially stacked on top of each other, such that the electrodes of two neighbouring cells are brought in electrical contact with each other. The electrical contact may for instance be achieved by a direct mechanical contact between adjacent cells, in which the bottom electrode of the upper cell is abutting the upper electrode of the lower cell. Alternatively, or additionally an intermediate layer may be provided between the cells to facilitate mechanical and/or electrical contact between the cells. The intermediate layer may for example comprise an electrically conductive adhesive.
According to some embodiments the positive electrode (that is, the cathode) may include a first foil substrate, which may be formed of a first electrically-conducive material, and a first active material layer disposed on an inward facing side of the first foil substrate (that is, a side facing the separator and the negative electrode of the cell). The first foil substrate may preferably be a metal foil substrate formed of a first electrically conductive material such as aluminium, without being limited thereto. The first active material layer preferably comprises a first active material selected from a lithiated metal oxide, and in particular from a lithium transition metal composite oxide, wherein the metal preferably includes one or more of nickel (Ni), cobalt (Co) and manganese (Mn). According to a preferred example, the positive electrode is formed of an aluminium foil and has an active material layer comprising a lithium transition metal composite oxide disposed on the inward facing side. In embodiments, the first electrically conductive material of the first foil substrate may be coated on one or both sides thereof with an oxidation-preventing metal, such as chromium. In further embodiments, a conductive material layer may additionally be disposed on an inward facing side of the first foil substrate, such that the conductive material layer is sandwiched between the first foil substrate and the first active material layer in order to enhance cell performance.
According to some embodiments the negative electrode (that is, the anode) may include a second foil substrate, which may be formed of a second electrically conducive material and a second active material layer disposed on an inward facing side thereof (that is, a side facing the separator and the positive electrode in the cell). The second foil substrate may preferably be a metal foil substrate formed of a second electrically conducive material such as copper or copper-clad aluminium, without being limited thereto. The second active material layer preferably comprises a second active material selected from graphite or silicon, or mixtures thereof. According to a preferred example, the negative electrode may be formed of a copper foil and has an active material layer comprising graphite disposed on the inward facing side. In embodiments, the second electrically conducive material of the second foil substrate can be coated on one or both sides thereof with an oxidation-preventing metal, such as chromium.
The outward facing sides of first and second foil substrates of the respective electrodes can act as the negative and positive cell terminals, respectively, and may be electrically and mechanically connected in series to neighbouring cells in the cells stack.
The positive and negative electrodes may be spaced apart from each other by the separator, which may comprise an electrically isolating and permeable material that isolates the positive electrode from the negative electrode to prevent electrical short-circuiting and allow ion, provided in an electrolyte, to pass therethrough. In an example, the separator may comprise a three-layer structure comprising for example a base film, including a polyolefin and a non-woven material, a ceramic layer coated on the base film, and a layer including polyvinylidenfluorid and acrylate binder coated on the ceramic layer. The separator may have a peripheral shape that conforms to the peripheral shape of the positive electrode and the negative electrode. Further, the separator may in some embodiments have the same dimensions as the positive and negative electrodes.
In addition, a sealing layer may be provided between a peripheral edge of the separator and a peripheral edge of the positive electrode. A sealing layer may further be disposed between a peripheral edge of the separator and a peripheral edge of the negative electrode. The sealing layer may be provided to prevent short-circuiting between the electrodes, bond the electrodes to each other and prevent any liquid electrolyte from escaping the cell.
In some embodiments, the separator has lesser dimensions than the dimensions of the positive electrode and the negative electrode so that a peripheral edge of the separator resides within peripheral edges of the positive and negative electrodes when the cell is view in a top plan view. A sealing layer may be provided between a peripheral edge of the positive electrode and a peripheral edge of the negative electrode such that the positive electrode is sealed to the negative electrode, and the sealing layer surrounds a periphery of the separator.
The present electrode plate assembly provides a relatively large format flat cell in which the top and bottom surfaces, facing away from the separator, may act as positive and negative terminals. This allows for the cells to be stacked serially, eliminating the need for busbars of complex terminal attachments between the cells. By arranging the cells in direct contact with each other, or indirect via an electrically conducting intermediate layer, a relatively large contact area can be utilised to reduce electrical resistance between the series connected cells.
According to a second aspect, the electrode plate assembly may comprise a plurality of contacting means for electrical monitoring of the cells. Each of the contacting means may be electrically connected to at least one of the positive and negative electrode plates of a respective one of the cells and arrange to protrude laterally from a side edge of the cell. The contacting means may be distributed spatially along a width of the stack to facilitate physical an electrical access to the contacting means, as will be discussed in further detail in the following.
The contacting means may be substantially plate shaped and may be understood as a flap or strip of electrically conductive material attached to or projecting from an electrode. The contacting means may also be referred to as a tab, or voltage pickup tab. The tabs may be attached to a peripheral portion of the electrode, for instance by welding, soldering or conductive adhesive, or formed from a portion of the electrode. Thus, the electrode plate may in some embodiments be cut, or formed into a shape allowing a protruding portion of the electrode to function as a contacting means.
The contacting means 140 may comprise a main portion 142 protruding from the cell 100, and a contacting portion 144 attached to the main portion 142 and configured to facilitate electrical access by e.g. a battery management system.
The contacting means 140 may be distributed spatially along a width W of the stack, as illustrated in
It will be appreciated that the above-disclosed configurations are merely exemplary embodiments illustrating a possible implementation of the inventive concept. Other configurations and distributions of the contacting means 140 are however conceivable. Further, it will be appreciated that each of the cells may not necessarily be connected to a respective contacting means 140. On the contrary, the contacting means may in some embodiments be connected to a subset of cells, such as to every second or third cell of the stack.
According to some embodiments, the electrode plate assembly may comprise access points instead of the contacting means as discussed above with reference to
According to some embodiments, the electrode plate assembly may comprise a plurality of sensors configured to be coupled to a respective contacting means or access point. The sensor may for example be connected to the access point by means of an electrical lead, by a contacting means, or be attached directly to the electrode.
The electrode plate assembly may further comprise a plurality of wireless transmitters, wherein each of the transmitters is configured to receive a signal from one or several of the sensors and transmit the signal to an external receiver. The sensor may be configured to generate a signal that is indicative of an operation parameter of one or several cells of the stack. The operational parameter may for example relate to a current, voltage or temperature of the cell.
According to an embodiment, the electrode plate assembly, or battery pack, may comprise a side frame part configured to be arranged at a side of the stack. The side frame part may comprise a plurality of slots, wherein each of the slots may be configured to receive a respective contacting means as the side frame part is being arranged at the side of the stack. The side frame part may form a part of a modular side frame assembly, comprising two or more parts which can be assembled into a frame at least partly enclosing the sides of the stack.
As illustrated in the present figure, the side frame part 210 may comprise a plurality of slits, or through-holes 215, configured to receive a respective contacting means 140 as the side frame part 210 is being arranged at the side of the stack. Thus, the slits 215 may have a shape corresponding to a cross sectional shape of the contacting means 140 to allow the contacting means 140 to extend through the side frame part 210 and be attached to the outer side of the side frame 210, i.e., the side of the side frame facing away from the stack. The slits 215 may hence be distributed spatially along a length direction of the side frame part 210 in a similar way as the contacting means 140 are distributed over the side of the stack.
The contacting means 140, or tabs 140, may be arranged to extend through the slits 215 and then be folded to contact the contact points, or contact pads 216, of the side frame part 210.
The slits 215 may be slightly larger than the cross section of the corresponding contacting means 140, extending therethrough, to provide some margin or tolerance for a relative movement between the contacting means 140 and the side frame part 210. The tolerance may facilitate the assembly process, reducing the requirements on alignment precision. Further, the tolerance may be introduced to address relative movement during operation of the battery pack. In particular, the height of the slits 215 (as measured along the stacking direction) may be larger than a thickness of the contacting means 140 to allow the contacting means to move along the stacking direction during swelling of the cells.
A plurality of cells arranged in a vertical stack, such as the stack described above with reference to the first and second aspect, may be subject to expansion due to cell swelling. As multiple cells are stacked to increase voltage, the cell swelling over the stack may result in a relatively large mechanical movement or expansion in the stacking direction. The swelling may be challenging for the designers of the battery pack, as the swelling may cause problems relating to the electrical as well as mechanical performance of the battery pack, as will be exemplified in the following.
According to a third aspect, an electrode plate assembly for a secondary battery module is provided, comprising a plurality of cells arranged in a vertical stack. The stack may be similarly configured as the stack discussed above in connection with the first and second aspect. Hence, each of the cells of the stack comprises a positive electrode plate, a negative electrode plate and a separator, wherein the separator is interposed between the positive electrode plate and the negative electrode plate and configured to allow ions to move between the positive and negative electrode plate. Further, neighbouring or adjacent cells of the stack are arranged such that the positive electrode plate of a first one of the neighbouring cells is contacting the negative electrode plate of the other one of the neighbouring cells, thereby allowing for the cells of the stack to be series connected along the stacking direction.
According to the present aspect, the electrode plate assembly may further comprise a top terminal plate, which is arranged above the stack and in electrical contact with a top one of the cells, a bottom terminal plate arrange below the stack and in electrical contact with a bottom one of the cells, and a housing configured to accommodate the bottom terminal plate, the stack, and the top terminal. The housing comprises a base plate and a top cover configured to be attached to each other to form the housing. Further, an elastic means may be arranged between the top cover and the top terminal to exert a compressing force on the stack in the stacking directions.
A merit of the present aspect is that the housing may allow for an improved cooling of the stack. The improved cooling may be achieved at least partly due to the relatively large surface-to-volume of the housing, facilitating heat dissipation from outer surfaces of the housing.
An example of such a housing is disclosed in
The battery pack of
As will be discussed in further detail below, the top terminal contact 322 may be connected to the top terminal plate 321 by means of a flexible busbar allowing the top terminal plate to move relative to the side frame part, to which the terminal contact 322 is attached.
The battery pack may further comprise an elastic means 330 configured to be arranged between the top cover 312 and the top terminal plate 321. The elastic means 330 may be biased between the top cover 312 and the top terminal plate 321 in order to exert a compressing force on the stack, along the stacking direction. The compressing force may be provided to improve the electrical contact between the series connected cells. Further, since the elastic means 330 is elastic, it is capable of maintaining a compressive force on the stack also during swelling and shrinking of the stack. Put differently, the elastic means 330 is configured to deform as the top terminal plate moves along the stacking direction, thereby absorbing the movement while maintaining a compression of the stack.
The elastic means 330 may be substantially plate-shaped, having a shape and size corresponding to the lateral size and shape of the stack to allow a substantially uniform load distribution over the cells. The elastic means 330 may thus be referred to as a compression plate and may for instance comprise a spring plate as illustrated in
According to a fourth aspect, an electrode plate assembly is provided, which may be similarly configured as the electrode plate assembly according to the first aspect, with the addition of a top terminal plate arranged above the stack and in electrical contact with a top one of the cells, a top terminal contact, and a flexible busbar arranged to electrically connect the top terminal plate. The flexible busbar is further configured to allow the top terminal plate to move relative the top terminal contact in response to the stack moving, or expanding and contracting, in the stacking direction. The terminal plates, the terminal contacts and the flexible busbar may be similarly configured as the embodiments discussed above with reference to
Further, it will be appreciated that the terminal plates and/or the busbar may serve the additional purpose of dissipating heat from the electrode plate assembly. Thus, the present aspect is advantageous in that it may allow for an improved cooling of the stack.
While the top terminal contact 322 may be fixed to the side frame 210, it is appreciated that the top terminal plate 321 may move in the stacking direction due to expansion and contraction of the cell stack. A flexible connection between the top terminal plate 321 and the top terminal contact 322 may therefore be provided. The flexible connection, also referred to as a flexible busbar 325 or flexible conductor, may be configured to absorb relative mechanical movements between the (fixed) top terminal contact 322 and the (moving) top terminal plate 321. The flexible connection 325 may for example comprise a flexible or bendable material allowing for the flexible connection 325 to vary its length in the stacking direction. The flexibility, i.e., the ability of allow a relative movement between the terminals connected by the flexible connection 325, may be achieved by the mechanical configuration of the connection (such as folds or a braiding), and/or inherent properties of the material of the connection (such as a bendable or flexible material). In some examples, the connection 325 may comprise one or several sheets or wires that can be bent to allow the flexible connection 325 to vary its length or be formed as a braided conductor.
According to a fifth aspect, an electrode plate assembly is provided, which may be similarly configured as the disclosure of the first aspect. Thus, a plurality of cells may be arranged in a vertical stack, wherein each cell comprises a positive electrode plate, a negative electrode plate and a separator interposed between the electrode plates. Further, an intermediate layer may be arranged between neighbouring or adjacent cells of the stack, wherein the intermediate layer is configured to electrically connect the neighbouring cells to each other. The cells of the stack may hence be connected in series, which the electrical contact at least partly provided by means of the intermediate layer. Thus, the adjacent cells may be arranged such that the positive electrode plate of a first one of the neighbouring cells is facing the negative electrode plate of the other one of the neighbouring cells, and the intermediate layer arranged in electrical contact with the positive and the negative electrode plate.
The intermediate layer may for instance comprise an electrically conductive adhesive. Examples of electrically conductive adhesives, or glues, include an electrically conductive component suspended in a continuous phase material, or matrix. The electrically conductive component may for instance comprise particles of a metal such as silver, nickel or copper, or another electrical conductor such as e.g. graphite. The matrix, or adhesive component may in some examples comprise a polymer, such as epoxy, resin or silicone.
The intermediate layer may be provided as a continuous layer or a patterned layer covering a substantial part of the surface of the electrode plates and may in some example be applied by spray coating or laminated onto the cell. The thickness of the intermediate layer may for instance be of 10-100 μm, such as about 50 μm, depending on the cell stack configuration and the conductive properties of the intermediate layer.
Several effects may be achieved by providing the intermediate layer between adjacent cells. Firstly, the intermediate layer may be provided to join the cells electrically. The intermediate layer may be provided to fill out any irregularities between the adjoining surfaces and thereby improve the electrical contact. A pure mechanical contact, without any intermediate layer, may be more dependent on a low surface roughness to ensure a good electrical contact. The intermediate layer may thus serve the purpose of increasing the contact between the surfaces and compensate for any surface irregularities. Secondly, the intermediate layer may facilitate the mechanical bonding and increase the bonding strength between adjacent cells. In this way an improved mechanical contact may be achieved, reducing the need for a relatively high and constant compression along the stacking direction. The intermediate layer may thus assist in maintaining electrical and mechanical contact between adjacent cells also during expansion and contraction of the stack along the stacking direction. Further, the intermediate layer may assist in keeping the cells in a correct position also in a lateral direction, i.e., preventing the cells from being displaced orthogonally to the stacking direction.
Number | Date | Country | Kind |
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2151624-0 | Dec 2021 | SE | national |
This application is a Bypass Continuation of International Application No. PCT/EP2022/087762, filed Dec. 23, 2022, which international application claims priority to and the benefit of Swedish Application No. 2151624-0, filed Dec. 27, 2021; the contents of both of which as are hereby incorporated by reference in their entireties.
Number | Date | Country | |
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Parent | PCT/EP2022/087762 | Dec 2022 | WO |
Child | 18755901 | US |