Patent Application
20220336898
The present application claims priority to Korean Patent Application No. 10-2021-0049365 filed on Apr. 15, 2021, and Korean Patent Application No. 10-2021-0191701 filed on Dec. 29, 2021, the disclosures of which are incorporated herein by reference in their entirety.
The present disclosure relates to a secondary battery, and more particularly, to a secondary battery having a vent member.
Secondary batteries which are highly applicable to various products and exhibit superior electrical properties such as high energy density, etc. Secondary batteries are commonly used not only in portable devices but also in electric vehicles (EVs) or hybrid electric vehicles (HEVs) driven by electrical power sources. The secondary battery is drawing attention as a new energy source for enhancing environment friendliness and energy efficiency in that the use of fossil fuels can be reduced greatly and no byproduct is generated during energy consumption.
Secondary batteries widely used at present include lithium ion batteries, lithium polymer batteries, nickel cadmium batteries, nickel hydrogen batteries, nickel zinc batteries and the like.
The secondary battery generally has a structure in which an electrode assembly including at least one unit cell having a positive electrode/separator/negative electrode structure is accommodated in a battery case of a laminate sheet in which an outer layer, a metal barrier layer and a sealant layer are sequentially laminated, and a sealant resin of the sealant layer is fused to seal the electrode assembly is sealed.
In the conventional secondary battery, the battery may ignite due to various causes such as a short circuit inside the secondary battery, overcharge or overdischarge, temperature control, or the like. At this time, thermal propagation where the temperature inside the secondary battery rises rapidly and simultaneously the heat is transferred to neighboring cells may be generated, which may further increase the fire.
In order to minimize damage to the electrode caused by gas when thermal propagation occurs—i.e., when the internal temperature of the secondary battery rises, directional venting characteristic is required to discharge the gas in one direction. However, the conventional secondary battery has a problem in that it is difficult to induce gas discharge in a specific direction.
Disclosed herein are secondary batteries with vent members.
In accordance with an aspect of the present disclosure, a secondary battery is provided. A secondary battery according to this aspect, may include an electrode an electrode assembly, a case including an accommodation portion to receive the electrode assembly, an electrode lead attached to the electrode assembly and a vent member. The case may include a sealing portion to seal the electrode assembly therein. The sealing portion may include a sealant resin to form a seal around the electrode assembly. The electrode lead may extend away from the case along a first direction. The sealing portion may include an inclined sealing portion adjacent the electrode lead. The inclined sealing portion may extend along a second direction. The second direction may be non-orthogonal to the first direction. The vent member may be disposed in the inclined sealing portion. The vent member may include a resin (hereinafter referred to as a “vent resin”) having a lower melting point than the sealant resin.
Continuing in accordance with this aspect, the inclined sealing portion may have an inclination angle of 10° to 80°. The inclination angle may be defined as an angle between the first direction and the second direction. The vent member may include a first side extending parallel to the second direction. A vent may form along a direction perpendicular to the first side of the vent member.
Continuing in accordance with this aspect, the secondary battery may include a lead film surrounding an outer surface of the electrode lead. The lead film may be interposed between the electrode lead and the sealing portion. The vent member may extend through the accommodation portion such that the vent member may at least partially overlap or contact the lead film in the accommodation portion.
Continuing in accordance with this aspect, the vent member may include a first portion and a second portion. The first portion of the vent member may extend along the second direction such that the first portion may at least partially overlap or contact the lead film in the accommodation portion. The second portion may extend along a third direction orthogonal to the second direction. The vent member may define an L shape. The second portion may include a tapered edge that extends into the accommodation space along the electrode assembly. An outer end of the first portion may be spaced apart from an inner end of the sealing portion adjacent the lead film. The outer end of the first portion may be located in the accommodation portion. The second portion may not overlap or contact the lead film. An area of a region of the vent member overlapping or contacting the lead film may be 1% to 30% of an area of a region of the lead film not contacting or overlapping the electrode lead.
Continuing in accordance with this aspect, a width of the vent member may vary in a direction perpendicular to the second direction.
Continuing in accordance with this aspect, the vent member may define any of a circular, oval, stepped, triangular and quadrilateral shape.
Continuing in accordance with this aspect, a thickness of the vent member may vary in a direction perpendicular to the second direction.
Continuing in accordance with this aspect, the vent resin may include a linear low-density polyethylene having a comonomer with a carbon number of 6 or more. The linear low-density polyethylene may be polymerized in the presence of a metallocene catalyst. A content of the comonomer with a carbon number of 6 or more may be 15 weight % or less based on 100 weight % of the linear low-density polyethylene. A content of the comonomer with the carbon number of 6 or more may be from 5 weight % to 15 weight % based on 100 weight % of the linear low-density polyethylene.
Continuing in accordance with this aspect, the vent member may melt at 100° C. to 120° C. to vent gases from the accommodation portion to an exterior of the secondary battery. The vent member may vent gases from the accommodation portion when the accommodation portion is at a pressure of 0.7 atm or above.
Continuing in accordance with this aspect, the vent member may have a maximum sealing strength of less than 6 kgf/15 mm at 100° C. or above.
Continuing in accordance with this aspect, the vent member may have an average sealing strength of less than 4.5 kgf/15 mm at 100° C. or above.
Continuing in accordance with this aspect, the vent member may have a maximum sealing strength of 6 kgf/15 mm or more at room temperature to 60° C.
Continuing in accordance with this aspect, the vent member may have an average sealing strength of 4.5 kgf/15 mm or more at room temperature to 60° C. Continuing in accordance with this aspect, the vent resin may have a poly dispersity index (PDI) of 4 or less.
Continuing in accordance with this aspect, a difference between a crystallization temperature of the sealant resin and a crystallization temperature of the vent resin may be 10° C. or less. The vent resin may have a melting point of 100° C. to 130° C.
Continuing in accordance with this aspect, the vent resin may have a weight-average molecular weight of 100,000 g/mol to 400,000 g/mol.
Continuing in accordance with this aspect, the secondary battery may be a pouch-type secondary battery.
Continuing in accordance with this aspect, the vent member may have a maximum sealing strength of less than 6 kgf/15 mm at 100° C. to 120° C.
Continuing in accordance with this aspect, the vent member may have an average sealing strength of less than 4.5 kgf/15 mm at 100° C. to 120° C.
Continuing in accordance with this aspect, the vent member may have a maximum sealing strength of less than 3 kgf/15 mm at 120° C. or more.
Continuing in accordance with this aspect, the vent member may have an average sealing strength of less than 2 kgf/15 mm at 120° C. or more.
In accordance with another aspect of the present disclosure, a secondary battery is provided. A secondary battery according to this aspect, may include an electrode assembly, an electrode lead, a case, and a vent member. The case may include an accommodation portion to receive the electrode assembly and a sealing portion to seal the electrode assembly therein. The sealing portion may include a sealant resin to form a seal around the electrode assembly. The electrode lead may be attached to the electrode assembly. The electrode lead may extend away from the case along a first direction. The sealing portion may include a quadrilateral sealing portion adjacent the electrode lead. At least one side of the quadrilateral sealing portion may extend along a second direction. The second direction may be nonparallel to the first direction. The vent member may be disposed at least partially in the quadrilateral sealing portion. The vent member may include a vent resin having a lower melting point than the sealant resin.
In accordance with another aspect of the present disclosure, a secondary battery is provided. A secondary battery according to this aspect, may include an electrode assembly, an electrode lead, a case and a vent member. The case may include an accommodation portion to receive the electrode assembly and a sealing portion to seal the electrode assembly therein. The sealing portion may include a sealant resin to form a seal around the electrode assembly. The electrode lead may be attached to the electrode assembly. The electrode lead may extend away from the case along a first direction. The sealing portion may include a convex sealing portion adjacent the electrode lead. The convex sealing portion may extend along a convex curve from the first direction to a second direction. The second direction may be orthogonal to the first direction. The vent member may be disposed in the convex sealing portion. The vent member may include a vent resin having a lower melting point than the sealant resin.
In accordance with another aspect of the present disclosure, a secondary battery is provided. A secondary battery according to this aspect, may include an electrode assembly, an electrode lead, a case and a vent member. The case may include an accommodation portion to receive the electrode assembly and a sealing portion to seal the electrode assembly therein. The sealing portion may include a sealant resin to form a seal around the electrode assembly. The electrode lead may be attached to the electrode assembly. The electrode lead may extend away from the case along a first direction. The sealing portion may include a concave sealing portion adjacent the electrode lead. The concave sealing portion may extend along a concave curve from a second direction toward the first direction. The second direction may be orthogonal to the first direction. The vent member may be disposed in the concave sealing portion. The vent member may include a vent resin having a lower melting point than the sealant resin.
In accordance with another aspect of the present disclosure, a secondary battery is provided. A secondary battery according to this aspect, may include an electrode assembly, an electrode lead, a case and a vent member. The case may include an accommodation portion to receive the electrode assembly and a sealing portion to seal the electrode assembly therein. The sealing portion may include a sealant resin to form a seal around the electrode assembly. The electrode lead may be attached to the electrode assembly. The electrode lead may extend away from the case in first direction. The sealing portion may include a first sealing portion and a second sealing portion. The first and second sealing portions may be defined by a seal along an outer circumference of the accommodation portion. The second sealing portion may be disposed between adjacent sides of the first sealing portion. An exterior side of the second sealing portion may be defined by a line or a curve joining the adjacent sides of the first sealing portion. The line may be nonparallel to the first direction. The second sealing portion may include the vent member containing a vent resin having a lower melting point than the sealant resin.
Since the secondary battery according to an embodiment of the present disclosure includes a vent member containing a vent resin having a lower melting point than the sealant resin of the sealing portion, gas discharge may be induced toward the vent member.
Since the secondary battery according to an embodiment of the present disclosure includes the vent member in an inclined sealing portion, it is possible to minimize the amount of gas vented to directly contact the electrode lead, thereby improving the safety of the battery.
Since the secondary battery according to an embodiment of the present disclosure includes the vent member in the inclined sealing portion, gas may be discharged easily, compared to the case where the vent member is provided in a straight sealing portion.
The accompanying drawings illustrate a preferred embodiment of the present disclosure and together with the foregoing disclosure, serve to provide further understanding of the technical features of the present disclosure, and thus, the present disclosure is not construed as being limited to the drawings shown herein.
Hereinafter, preferred embodiments of the present disclosure will be described in detail with reference to the accompanying drawings. Prior to the description, it should be understood that the terms used in the specification and the appended claims should not be construed as limited to general and dictionary meanings, but interpreted based on the meanings and concepts corresponding to technical aspects of the present disclosure on the basis of the principle that the inventor is allowed to define terms appropriately for the best explanation.
Therefore, the description proposed herein is just a preferable example for the purpose of illustrations only, not intended to limit the scope of the disclosure, so it should be understood that other equivalents and modifications could be made thereto without departing from the scope of the disclosure.
The electrode lead is a component whose temperature rises rapidly in abnormal situations such as overcharge or internal short circuit. Therefore, if the direct contact between the vented gas and the electrode lead is minimized, safety may be improved.
The inventors of the present disclosure have completed the present disclosure by finding that if an inclined sealing portion is provided at the corner of the sealing portion and a vent member is inserted to be at least partially overlapped with the inclined sealing portion, a vent may be easily generated at the sealing portion corner.
A secondary battery according to an embodiment of the present disclosure includes an electrode assembly to which an electrode lead is attached; a case including an accommodation portion for accommodating the electrode assembly and a sealing portion containing a sealant resin and formed to seal the electrode assembly;, wherein the sealing portion includes an inclined sealing portion at a corner thereof, and a vent member containing a resin having a lower melting point than the sealant resin is included in the inclined sealing portion.
The term “inclined sealing portion” may refer to a region formed between an outer inclined sealing line of the sealing portion and an inner inclined sealing line of the sealing portion in some embodiments disclosed herein. The outer inclined sealing line is away from the electrode assembly and the inner inclined sealing line is closer to the electrode assembly.
The term “inclination” may refer to some embodiments where the inclined sealing portion forms an acute angle, or an obtuse angle (second direction) with respect to a direction of the electrode lead (first direction)—i.e., a non-orthogonal angle with respect to a direction of the electrode lead.
Throughout this specification, including a vent member in the inclined sealing portion means that the inclined sealing portion and the vent member may be at least partially overlapped.
In describing preferred embodiments of the disclosure, reference will be made to directional nomenclature used in describing the secondary battery. It is noted that this nomenclature is used only for convenience and that it is not intended to be limiting with respect to the scope of the present disclosure.
The positive electrode plate may include a positive electrode current collector made of a metal thin film having excellent conductivity, for example an aluminum (Al) foil, and a positive electrode active material layer coated on at least one surface thereof. In addition, the positive electrode plate may include a positive electrode tab made of a metal material, for example an aluminum (Al) material, at one side end thereof. The positive electrode tab may protrude from one side end of the positive electrode plate, be welded to one side end of the positive electrode plate, or be bonded thereto using a conductive adhesive.
The negative electrode plate may include a negative electrode current collector made of a conductive metal thin film, for example a copper (Cu) foil, and a negative electrode active material layer coated on at least one surface thereof. In addition, the negative electrode plate may include a negative electrode tab formed of a metal material, for example a copper (Cu) or nickel (Ni) material, at one side end thereof. The negative electrode tab may protrude from one side end of the negative electrode plate, be welded to one side end of the negative electrode plate, or be bonded thereto using a conductive adhesive.
The separator is interposed between the positive electrode plate and the negative electrode plate to electrically insulate the positive electrode plate and the negative electrode plate from each other, and may be formed in a porous membrane form so that lithium ions can pass between the positive electrode plate and the negative electrode plate. The separator may include, for example, a porous membrane using polyethylene (PE), or polypropylene (PP), or a composite film thereof.
An inorganic coating layer may be provided on the surface of the separator. The inorganic coating layer may have a structure in which inorganic particles are bonded to each other by a binder to form an interstitial volume between the particles.
Electrode assembly 12 may be a jelly-roll (winding-type) electrode assembly having a structure in which long sheet-type positive and negative electrodes are wound with a separator being interposed therebetween, a stacked (stack-type) electrode assembly having a structure in which a plurality of positive and negative electrodes cut into units of a predetermined size are sequentially stacked with a separator being interposed therebetween, a stack/folding type electrode assembly having a structure in which bi-cells or full-cells where positive and negative electrodes of a predetermined unit are stacked with a separator being interposed therebetween are wound, or the like.
Referring to
Sealing portion 13b refers to a portion that is fused along the outer circumferential surface of the accommodation portion 13a to seal electrode assembly 12 as shown in
A vent member 16 is provided in the inclined sealing portion 14 as shown in
Since the vent member 16 contains the vent resin having a lower melting point than the sealant resin of the sealing portion 13b, the vent member 16 melts before the sealant resin at high temperature. The sealing strength of the portion where the vent member 16 is inserted is further lowered compared to the sealing strength of the case portion containing the sealant resin at high temperature, so that the venting characteristic may be readily implemented. Accordingly, when thermal propagation occurs, it is possible to improve the safety of the battery by inducing the gas to be discharged in a specific direction.
Referring to
The vent member 16 and the inclined sealing portion 14 may be overlapped or connected to each other by thermal fusion or other means. In another example, the vent member 16 and the inclined sealing portion 14 may be overlapped or connected to each other through an adhesive such as glue or other similar means. In another example, the vent member 16 and the inclined sealing portion 14 may be physically coupled to each other through a clip or the like. In another example, a part of the vent member 16 may be embedded in a film constituting the inclined sealing portion 14.
Since the vent member 16 is located in the inclined sealing portion 14 to minimize the amount of gas vented to directly contact the electrode lead 11, namely toward a side portion of the electrode lead 11, it is possible to further improve the safety of the battery.
In addition, since the vent member 16 is located in the inclined sealing portion 14, namely an inner end of the inclined sealing portion 14 is inclined, an area where the inner end of the inclined sealing portion 14 is exposed to the accommodation portion 13a is smaller than the adjacent sealing portions 13b which form orthogonal corners. Accordingly, the pressure applied while the battery swells may be concentrated on the inclined sealing portion 14 at the corner of the sealing portion more easily, and thus the gas may be induced more easily to be discharged toward the corner of the sealing portion. Here, the inner end of the inclined sealing portion 14 refers to an end of the inclined sealing portion 14 that is closer to the accommodation portion 13a.
Referring to
Referring to
In an embodiment of the present disclosure, a vent may occur in a direction perpendicular to the direction of the vent member. A vent may form along a direction perpendicular to the first side of the vent member 16 as shown in
In an embodiment of the present disclosure, the vent member 16 maybe located in the inclined sealing portion 14. In another embodiment of the present disclosure, the vent member 16 may be extend through the accommodation portion 13a. In another embodiment of the present disclosure, the vent member 16 may be located to be exposed out of the case 13 through the inclined sealing portion 14 (not shown).
In an embodiment of the present disclosure, the vent member 16 may not be overlapped with the lead film 15.
In another embodiment of the present disclosure, the vent member 16 may partially overlap lead film 15 as shown in
The vent member 16 may be positioned to be spaced apart from the electrode lead 11 by a predetermined distance. Accordingly, it is easier to minimize the amount of gas vented in a direction that may directly contact the electrode lead 11, namely toward the side portion of the electrode lead 11, thereby further improving the safety of the battery.
In an embodiment of the present disclosure, the vent member 16 may be spaced apart from the lead film 15 in the sealing portion 13b or 14, and the vent member 16 may be at least partially overlap or contact the lead film 15 in the accommodation portion 13a. As the vent member 16 does not overlap or contact the lead film 15 in the sealing portion 13b or 14—i.e., vent member 16 being located away from the electrode lead 11, the amount of gas vented toward the side portion of electrode lead 11 may be further minimized, thereby further improving safety of the battery.
In an embodiment of the present disclosure, the outer and inner sealing lines of the inclined sealing portion 14 may be formed by one or more straight lines. Referring to
Referring to
In another embodiment of the present disclosure, the sealing portion may include a first sealing portion 13b and a second sealing portion 14. The first sealing portion 13b is a sealing portion that is sealed along the outer circumference of the accommodation portion. The second sealing portion 14 is disposed between adjacent sides of the first sealing portion 13b. The second sealing portion 14 is a sealing portion in which extension lines of two first sealing portions 13b adjacent to each other do not meet orthogonally with respect to the two first sealing portions but are connected with a straight line (ex.
If the secondary battery according to an embodiment of the present disclosure includes the second sealing portion 14, since an inner end of the second sealing portion is inclined or curved, an area where the inner end of the second sealing portion is exposed to the accommodation portion is smaller than an area where the inner end of the adjacent sealing portions which form orthogonal corners is exposed to the accommodation portion, and accordingly, the pressure may be concentrated on the inner end of the second sealing portion more easily. Here, the inner end of the second sealing portion refers to an end of the second sealing portion that is closer to the accommodation portion.
In an embodiment of the present disclosure, the vent member 16 may have an L shape as shown in
Here, a vent may occur substantially in the second portion 16a, and a vent may not substantially occur in the first portion 16b.
In an embodiment of the present disclosure, the first portion 16b may have a rectangular shape. For example, a long side may of the first portion be positioned in the third direction and a short side of the first portion may be positioned in the second direction.
In an embodiment of the present disclosure, the second portion 16a may have a rectangular shape. For example, a short side of the second portion may be positioned in the third direction and a long side of the second portion may be positioned in the second direction.
Referring to
The second portion 16a of the vent member 16 and the lead film 15 may not overlap or contact each other as shown in
In an embodiment of the present disclosure, the region where the vent member overlaps or contacts the lead film may be 1% to 30%, or 1.3% to 23%, or 1.5% to 12%, or 2% to 9% of the region where the lead film does not overlap the electrode lead. Here, the region where the lead film does not overlap the electrode lead refers to the sum of both regions of the electrode lead and the lead film that do not overlap. The outer end of the first portion 16b may be spaced apart from an inner end of the inclined sealing portion 14 as shown in
Referring to
Specifically, in a region where the outer sealing line may include a first linear portion 14a orthogonal to the first direction, an inclined portion 14b extending from the first linear portion 14a and inclined toward the electrode lead 11, and a second linear portion 14c extending from the inclined portion 14b and extending toward one end of the case 13 in contact with the lead film 15, a region formed by connecting one side end and the other side end of the inclined portion 14b to one side end and the other side end of the inclined portion of the inner sealing line, respectively, may be referred to as the inclined sealing portion.
The inclined sealing portion may have an inclination angle of 10° to 80°, or 20° to 60°, or 40° to 50°. When the inclination angle of the inclined sealing portion satisfies the above-mentioned range, the gas may be more easily induced to be discharged in a direction that can minimize direct contact with the electrode lead.
Referring to
Specifically, in a region where the outer sealing line may include a first linear portion 14a orthogonal to the first direction, a second linear portion 14b having a right angle to the first linear portion 14a and extending from the first linear portion 14a , and a third linear portion 14c having a right angle to the second linear portion 14b and extending from the second linear portion 14b to one end of the case 13 in contact with the lead film 15, a region formed by connecting one side end and the other side end of the second linear portion 14b to one side end and the other side end of the inner sealing line parallel to the first direction, respectively, may be referred to as the quadrilateral sealing portion.
Referring to
Referring to
Specifically, in a region where the outer sealing line may include a first inclined portion 14d extending from the end of the sealing portion 13b toward the electrode lead 11, a first linear portion 14e extending from the first inclined portion 14d and orthogonal to the first direction, a second inclined portion 14f extending from the first linear portion 14e and inclined toward the electrode lead 11, and a second linear portion 14g extending from the second inclined portion 14f and extending to one end of the case 13 in contact with the lead film 15, a region formed by connecting one side end of the first inclined portion 14d and the other side end of the second inclined portion 14f respectively to one side end of the inclined portion extending from the sealing portion 13b in the inner sealing line and inclined toward the electrode lead 11 and the other side end of the inner sealing line extending from the inner sealing line overlapped with the lead film 15 and extending toward the sealing portion 13b may be referred to as the inclined sealing portion.
Referring to
The inclination angles of the first inclined portion 14d and the second inclined portion 14f may be the same or different.
The first inclined portion 14d and/or the second inclined portion 14f may have an inclination angle of 10° to 80°, or 20° to 60°, or 40° to 50°. When the inclination angle of the inclined sealing portion satisfies the above-mentioned range, the gas may be more easily induced to be discharged in a direction that can minimize direct contact with the electrode lead.
In another embodiment of the present disclosure, the outer and inner sealing lines of the inclined sealing portion 14 may have one or more curves.
Referring to
Referring to
In another embodiment of the present disclosure, the outer and inner sealing lines of a curved sealing portion 14 may have two or more consecutive curves. In this case, the two or more curves may have different radii of curvature.
In another embodiment of the present disclosure, the outer and inner sealing lines of the inclined sealing portion 14 may have one or more straight lines and one or more curves.
In an embodiment of the present disclosure, the vent member 16 may be vented at 100° C. to 120° C. by allowing the gases in accommodation portion 13a to exit outside the secondary battery through vent member 16.
Since at least a part of the vent member 16 overlaps or disposed in the inclined sealing portion 14, venting may occur at a lower pressure, compared to the case of a conventional secondary battery including a sealing portion without an inclined, quadrilateral or curved sealing portions. For example, the vent member 16 may be vented at 100° C. to 120° C. and at a pressure of 0.7 atm or more.
As the vent member 16 is vented in the aforementioned temperature range and/or the aforementioned pressure condition, it is eaiser to seal the battery during normal operation of the battery and to induce the gas to be discharged only during abnormal operation of the battery.
Referring to
In an embodiment of the present disclosure, the vent member 16 may have a circular, oval, stepped, triangular, or quadrilateral shape.
In an embodiment of the present disclosure, the vent member 16 may be an asymmetric stepped structure as shown in
In an embodiment of the present disclosure, a thickness of the vent member 16 may decrease continuously or discontinuously along a direction perpendicular to the second direction of the inclined sealing portion 14.
In an embodiment of the present disclosure, the vent resin having a lower melting point than the sealant resin may contain linear low-density polyethylene having a comonomer with a carbon number of 6 or more.
As the vent resin having a lower melting point than the sealant resin contains linear low-density polyethylene having a comonomer with a carbon number of 6 or more, excellent fusion with the sealant resin may be secured in the normal temperature range, and the sealing strength of the sealing portion including the vent member 16 may be lowered at high temperatures to realize vent characteristics.
In an embodiment of the present disclosure, the vent resin having a lower melting point than the sealant resin may contain linear low-density polyethylene having a comonomer with a carbon number of 6 to 8.
In an embodiment of the present disclosure, the vent resin having a lower melting point than the sealant resin may have a melting point of 100° C. to 130° C., or 105° C. to 125° C., or 110° C. to 120° C. If the melting point of the vent resin having a lower melting point than the sealant resin satisfies the above-mentioned range, the sealing strength of the sealing portion including the vent member 16 may be lowered at a high temperature, for example 100° C. or higher, so that the vent characteristic may be implemented more easily.
The melting point of the vent resin having a lower melting point than the sealant resin may be measured using a differential scanning calorimeter (DSC). For example, the temperature of a sample is increased from 30° C. to 280° C. at 10° C./min, maintained at 280° C. for 10 minutes, cooled to 30° C. at 10° C./min, and then maintained at 30° C. for 10 minutes. Then, after increasing the temperature of the sample from 30° C. to 280° C. at 10° C./min, the melting point may be measured by maintaining the temperature at 280° C. for 10 minutes.
In an embodiment of the present disclosure, the vent member may have a maximum sealing strength of less than 6 kgf/15 mm or less than 5 kgf/15 mm or less than 4.5 kgf/15 mm at 100° C. or higher. In an embodiment of the present disclosure, the vent member 15 may have a maximum sealing strength of less than 6 kgf/15 mm or less than 5 kgf/15 mm or less than 4.5 kgf/15 mm at 100° C. to 120° C. In an embodiment of the present disclosure, the vent member 15 may have a maximum sealing strength of less than 3 kgf/15 mm or less than 2 kgf/15 mm or less than 1 kgf/15 mm or less than 0.5 kgf/15 mm at 120° C. or higher. If the vent member satisfies the above-mentioned sealing strength in the above-mentioned temperature range, the sealing strength of the sealing portion including the vent member 16 may be lowered at a high temperature, for example 100° C. or higher, so that the vent characteristic may be implemented more easily.
In addition, in an embodiment of the present disclosure, the vent member may have a maximum sealing strength of 6 kgf/15 mm or more or 8 kgf/15 mm or more or 10 kgf/15 mm or more at room temperature to 60° C. If the vent member satisfies the above-mentioned sealing strength in the above temperature range, excellent sealing strength may be secured during normal operation of the battery, which may easily secure the sealing property of the battery.
In an embodiment of the present disclosure, the vent member may have a maximum sealing strength of less than 6 kgf/15 mm at 100° C. or higher, and the vent member may have a maximum sealing strength of 6 kgf/15 mm or more at room temperature to 60° C. If the vent member satisfies the sealing strength described above, the sealing strength of the sealing portion including the vent member 16 may be lowered at a high temperature, so that the vent characteristic may be implemented more easily. In addition, since excellent sealing strength is secured during normal operation of the battery, the sealing property of the battery may be easily secured.
In an embodiment of the present disclosure, the vent member may have an average sealing strength of less than 4.5 kgf/15 mm or less than 3 kgf/15 mm at 100° C. or above. In an embodiment of the present disclosure, the vent member 15 may have an average sealing strength of less than 4.5 kgf/15 mm or less than 3 kgf/15 mm at 100° C. to 120° C. In an embodiment of the present disclosure, the vent member 15 may have an average sealing strength of less than 2 kgf/15 mm or less than 1 kgf/15 mm or less than 0.5 kgf/15 mm at 120° C. or higher. If the vent member satisfies the above-mentioned sealing strength in the above-mentioned temperature range, the sealing strength of the sealing portion including the vent member 16 may be lowered at a high temperature, so that the vent characteristic may be implemented more easily.
In an embodiment of the present disclosure, the vent member may have an average sealing strength of 4.5 kgf/15 mm or more or 5 kgf/15 mm or more or 6 kgf/15 mm or more or 7 kgf/15 mm or more at room temperature to 60° C. If the vent member satisfies the above-mentioned sealing strength in the above temperature range, excellent sealing strength may be secured during normal operation of the battery, thereby easily securing the sealing property.
In an embodiment of the present disclosure, the vent member may have an average sealing strength of less than 4.5 kgf/15 mm at 100° C. or above, and the vent member may have an average sealing strength of 4.5 kgf/15 mm or more at room temperature to 60° C. If the vent member has the above-mentioned sealing strength in the above-mentioned temperature range, the sealing strength of the sealing portion including the vent member 16 may be lowered at a high temperature, so that the vent characteristic may be easily implemented. In addition, since excellent sealing strength may be secured during normal operation of the battery, the sealing property of the battery may be easily secured.
The sealing strength of the vent member according to temperature may be measured by conducting a tensile test at a speed of 5 mm/min, after cutting the part of the case in which the vent member is inserted into a width of 15 mm and a length of 5 cm and then grasping both ends thereof using a UTM jig in a state where both ends are spread to 180°.
At this time, a “maximum sealing strength” means a maximum value when the case is broken, and an “average sealing strength” means an average value when the case is stretched by 8 mm at 4.5 kgf/15 mm when the maximum sealing strength is 4.5 kgf/15 mm or more and an average value when the case is stretched by 8 mm at the maximum sealing strength when the maximum sealing strength is less than 4.5 kgf/15 mm.
In an embodiment of the present disclosure, the linear low-density polyethylene having a comonomer with a carbon number of 6 or more may be polymerized in the presence of a metallocene catalyst. If the linear low-density polyethylene having a comonomer with a carbon number of 6 or more is polymerized in the presence of a metallocene catalyst, it may be more advantageous in terms of sealing strength and properties, compared to the case where it is polymerized in the presence of a Ziegler-Natta catalyst.
In an embodiment of the present disclosure, the content of the comonomer with a carbon number of 6 or more in the linear low-density polyethylene having a comonomer with a carbon number of 6 or more may be 15 weight % or less, or 12 weight % or less, or 11.8 weight % or less, or 10 weight % or less, or 9 weight % or less, or 8 weight % or less, or 7.6 weight % or less, based on 100 weight % of the linear low-density polyethylene having a comonomer with a carbon number of 6 or more. At the same time, it may be 5 weight % or more, or 7.6 weight % or more, or 8 weight % or more, or 9.0 weight % or more, or 10 weight % or more, or 11.8 weight % or more, or 12 weight % or more. If the content of the comonomer with a carbon number of 6 or more satisfies the above-mentioned range, it may be easy to prevent a problem that the sealing strength is lowered during normal operation of the battery due to a decreased packing density between molecules.
The content of the comonomer with a carbon number of 6 or more may be measured using an H-NMR. For example, after about 10 mg of a sample is completely dissolved in about 0.6 mL of trichloroethylene solvent using a heat gun, it may be sampled in an NMR tube and measured using the 1H-NMR or 13C-NMR analysis method.
In an embodiment of the present disclosure, the resin having a lower melting point than the sealant resin may have a weight-average molecular weight of 100,000 g/mol to 400,000 g/mol, or 200,000 g/mol to 350,000 g/mol, or 230,000 g/mol to 300,000 g/mol. If the resin having a lower melting point than the sealant resin satisfies the above-described range, the sealing strength with the sealant resin may be more excellent during normal operation of the battery.
In an embodiment of the present disclosure, the resin having a lower melting point than the sealant resin may have a poly dispersity index (PDI) of 4 or less, or 3.8 or less, or 3.796 or less, or 3.5 or less, or 3.023 or less, or 3 or less, or 2.7 or less, or 2.674 or less. In addition, the poly dispersity index (PDI) may be 1.0 or more. If the resin having a lower melting point than the sealant resin satisfies the above range, the molecular weight distribution is narrow, so the sealing strength with the sealant resin and the properties may be superior during normal operation of the battery.
The weight-average molecular weight and the poly dispersity index of the vent resin having a lower melting point than the sealant resin may be measured by gel permeation chromatography (GPC) under the following conditions:
column: Tosoh, HLC-8321 GPC/HT
solvent: TCB (Trichlorobenzene)+0.04% BHT (after drying with 0.1% CaCl2)
flow velocity: 1.0 ml/min
sample concentration: 1.5 mg/ml
dose: 300 μl
column temperature: 160° C.
Detector: RI detector
Standard: Polystyrene (calibrated with a third-order function)
In an embodiment of the present disclosure, the crystallization temperature of the sealant resin and the crystallization temperature of the vent resin having a lower melting point than the sealant resin may be similar. For example, the difference between the crystallization temperature of the sealant resin and the crystallization temperature of the vent resin having a lower melting point than the sealant resin may be 10° C. or less, or 5° C. or less. In addition, the difference between the crystallization temperature of the sealant resin and the crystallization temperature of the vent resin having a lower melting point than the sealant resin may be 0.1° C. or more. If the difference between the crystallization temperature of the sealant resin and the crystallization temperature of the vent resin having a lower melting point than the sealant resin satisfies the above range, the sealant resin and the vent resin having a lower melting point than the sealant resin may have improved fusion characteristics during normal operation of the battery.
In an embodiment of the present disclosure, the vent resin having a lower melting point than the sealant resin may have a crystallization temperature of 90° C. to 115° C., or 95° C. to 110° C., or 100° C. to 110° C., or 105° C. to 110° C. If the crystallization temperature of the vent resin having a lower melting point than the sealant resin satisfies the above range, the sealant resin and the vent resin having a lower melting point than the sealant resin may have more excellent fusion characteristics.
The crystallization temperature may be measured using a differential scanning calorimeter (DSC). For example, the temperature of the sample may be increased from 30° C. to 280° C. at 10° C./min, maintained at 280° C. for 10 minutes, cooled to 30° C. at 10° C./min, and then maintained at 30° C. for 10 minutes. Then, after increasing the temperature of the sample from 30° C. to 280° C. at 10° C./min, the crystallization temperature may be measured by maintaining the temperature at 280° C. for 10 minutes.
In an embodiment of the present disclosure, the vent member 16 may have a thickness of a film. The vent member 16 may be formed to have a predetermined thickness of a preset size. In addition, the vent member 16 may be inserted into the inclined sealing portion, quadrilateral sealing portion or curve sealing portion 14 so that its insertion length may be varied or its venting pressure and position may be controlled depending on the design.
In an embodiment of the present disclosure, the vent member 16 may further include an adhesive layer for improved sealing between the sealant resin and the vent resin having a lower melting point than the sealant resin.
Since the secondary battery according to an embodiment of the present disclosure includes a partially overlapping inclined, quadrilateral, or curved sealing portion at the corner of the sealing portion with the vent member containing the vent resin, directional venting for discharging gas in one direction by lowering the sealing strength at high temperature may be implemented more readily and efficiently.
In an embodiment of the present disclosure, the case 13 may be in a pouch form.
In an embodiment of the present disclosure, when the battery case 13 is in the form of a pouch, the battery case 13 may include an upper pouch and a lower pouch. When the battery case 13 includes an upper pouch and a lower pouch, after the upper pouch and the lower pouch are disposed so that the sealant resins thereof face each other, the facing sealant resins are fused with each other by heat and pressure to seal the battery.
The fusion may be thermal fusion, ultrasonic fusion, or the like to fuse the sealing portion.
The sealing portion 13b may be sealed on four sides or sealed on three sides of the battery case. When the case 13 has a three-sided sealing structure, after the upper pouch and the lower pouch are formed on one pouch sheet, the boundary surface between the upper pouch and the lower pouch is bent so that the electrode assembly accommodation portions 13a formed on the upper pouch and the lower pouch are overlapped, and in this state, the edges of the remaining three sides are sealed except for the bending portion.
In an embodiment of the present disclosure, the inclined sealing portion, the quadrilateral sealing portion or the curved sealing portion may be located at the corner of the sealing portion at an edge connected to the bent portion among the edges of the three sealed sides.
In an embodiment of the present disclosure, the case 13 may be provided in a film form having a multilayer structure including an outer layer for protection against external impacts, a metal barrier layer for blocking moisture, and a sealant layer for sealing the case.
The outer layer may include a polyester-based film using polyethylene terephthalate (PET), polybutylene terephthalate, polyethylene naphthalate, polybutylene naphthalate, co-polyester, polycarbonate, nylon, or the like, and may be configured in a single layer or multiple layers.
The metal barrier layer may include aluminum, copper, or the like.
The sealant layer may be configured in a single layer or multiple layers.
The sealant resin may include polypropylene (PP), acid-modified polypropylene (PPa), random polypropylene, ethylene propylene copolymer, or two or more thereof. The ethylene propylene copolymer may include, but is not limited to, ethylene-propylene rubber, ethylene-propylene block copolymer, and the like.
In an embodiment of the present disclosure, the secondary battery may be a cylindrical, prismatic, or pouch-type secondary battery. Among them, the secondary battery may be a pouch-type secondary battery.
Even though preferred embodiments of the present disclosure has been illustrated and described above, the present disclosure is not limited to the specific embodiments described above, and the present disclosure can be modified in various ways by those skilled in the art without departing from the gist of the present disclosure defined in the claims, and these modifications should not be individually understood from the technical idea or prospect of the present disclosure.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10-2021-0049365 | Apr 2021 | KR | national |
| 10-2021-0191701 | Dec 2021 | KR | national |
