The present application claims priority under 35 U.S.C. §119 to Korean Patent Application No. 10-2014-0010877, filed on Jan. 28, 2014, in the Korean Intellectual Property Office, and entitled: “Secondary Battery,” which is incorporated by reference herein in its entirety.
1. Field
Embodiments relate to a secondary battery.
2. Description of the Related Art
A secondary battery is generally rechargeable and dischargeable. The secondary battery is used as an energy source of a mobile device, an electric vehicle, a hybrid vehicle, an electric bicycle, an uninterruptible power supply, etc. According to the type of an external device using the secondary battery, the secondary battery may be used in the form of a single battery or in the form of a battery module obtained by connecting a plurality of secondary batteries in one unit.
A small mobile device, such as a cellular phone, may operate for a predetermined time period by using the output and capacity of a single battery. However, when an extended driving period or high-power driving is necessary, as in an electric vehicle or a hybrid vehicle, a battery module may be used due to its output and capacity. The output voltage and/or the output current of the battery module may be increased according to the number of batteries included in the battery module.
Embodiments are directed to a battery, including a case having an electrode assembly in an interior thereof, a first electrode unit having a first polarity, the first electrode unit having a first portion exposed to an exterior of the case, and having a second portion electrically coupled to the electrode assembly at a position in the interior of the case, the first and second portions being formed of different metal materials, and a resin seal molding surrounding a joining portion where the first and second portions are joined together.
The first portion may directly contact the second portion at the joining portion.
An entire contact area between the first and second portions may be enclosed by the resin seal molding.
The battery may further include a cap plate closing an opening of the case. The seal molding may be interposed between the first electrode unit and the cap plate and may electrically isolate the first electrode unit from the cap plate.
The cap plate may include a hole therein, the first electrode unit may be the cap plate via the hole, and the seal molding may seal the hole in the cap plate.
The seal molding may be molded after the first electrode unit is installed through the hole in the cap plate.
The seal molding may extend from the interior of the case to the exterior of the case.
The battery may further include a cap plate that closes an opening in the case. The joining portion may extend at least partially above the cap plate.
The first and second portions may be combined together at the joining portion using one or more selected from the group of caulking, welding, sheet metal joining, riveting, and punching.
The first portion may include a first hole and the second portion may include a second hole that overlaps the first hole, and a resin material may be disposed in the holes.
The seal molding may surround the first electrode unit where the first and second holes overlap. The seal molding may be formed of the resin material. The seal molding may be interposed between the first electrode unit and a cap plate that closes an opening of the case, and may electrically isolate the first electrode unit from the cap plate.
The first portion may be in contact with a bus bar that is electrically coupled to an adjacent battery cell. The bus bar may be formed of a metal material that is different from that of the second portion.
The battery may further include a second electrode unit electrically coupled to the electrode assembly and having a second polarity that is opposite the first polarity. The second electrode unit may extend from the interior of the case to the exterior of the case.
The second electrode unit may include a first portion and a second portion. The first and second portions may be formed of a same metal material. The first portion may be exposed to the exterior of the case. The second portion may be electrically coupled to the electrode assembly.
The first portion of the first electrode unit and each of the first and second portions of the second electrode unit may be formed of the same metal material.
First and second battery cells may be disposed adjacent to each other, each including respective first and second electrode units, and the first portion of the first electrode unit of the first battery cell may be coupled to the first portion of the second electrode unit of the second battery cell by a bus bar, and the first portion of the first electrode unit of the first battery cell, the first portion of the second electrode unit of the second battery cell, and the bus bar may be formed of the same metal material.
The electrode assembly may include first and second electrode plates and a separator therebetween. The first and second electrode plates may have respective active materials coated thereon.
The seal molding may include a first block portion, a second block portion, and a groove portion. The groove portion may be interposed between the first block portion and the second block portion. The groove portion may be engaged with a cap plate that closes an opening in the case.
The second portion may extend from the first portion in a direction substantially perpendicular from the cap plate, and the groove portion may encircle the second portion in a circumferential direction of the second portion.
Features will become apparent to those of skill in the art by describing in detail example embodiments with reference to the attached drawings in which:
Example embodiments will now be described more fully hereinafter with reference to the accompanying drawings; however, they may be embodied in different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey example implementations to those skilled in the art. In the drawing figures, the dimensions of layers and regions may be exaggerated for clarity of illustration. Like reference numerals refer to like elements throughout.
The secondary battery 10 may include at least one battery cell 100. In the example embodiment shown in
Referring to
The cap plate 130 includes a vent portion 135 for releasing the internal pressure by rupturing (upon an abnormal operation, in which the internal pressure of the case 180 exceeds a previously set point), and an electrolyte injection hole sealing 138 for sealing an electrolyte injection hole.
Referring to
The cap plate 130 is coupled onto an upper opening, in which the electrode assembly 150 is accommodated, to seal the electrode assembly 150. The electrode terminals 111 and 121 electrically connected to the electrode assembly 150 may be formed at the outside of cap plate 130 for an electric connection between the electrode assembly 150 and an external circuit (not shown) or between the electrode assembly 150 and the neighboring battery cell 100. The electrode terminals 111 and 121 may include the first electrode terminal 111 and the second electrode terminal 121 having different polarities, and may be electrically connected to the first and second electrode plates of the electrode assembly 150, respectively.
For example, the first and second electrode terminals 111 and 121 may be electrically connected to the electrode assembly 150 accommodated in the case 180, and may be electrically connected to the first and second electrode plates of the electrode assembly 150 and function as negative and positive terminals, respectively. For example, the first and second electrode terminals 111 and 121 may be formed on both the left and right sides of the electrode cell 100, respectively.
The first and second electrode terminals 111 and 121 constitute parts of first and second electrode units 110 and 120. For example, the first and second electrode units 110 and 120 may constitute an electric path extending from the electrode assembly 150 so as to supply discharge power accumulated in the electrode assembly 150 to the outside, or may constitute an electric path connected to the electrode assembly 150 so as to receive recharging power from the outside.
The first and second electrode units 110 and 120 may constitute negative and positive electrodes of the battery cell 100. The first and second electrode units 110 and 120 may be formed to have substantially the same structure. The technical specifications of the electrode units 110 and 120 that will be described below may be applied to the first and second electrode units 110 and 120 in common. In other embodiments, the following technical specifications may be only applied to one electrode unit 110 or 120 selected from between the first and second electrode units 110 and 120.
The structure of the first electrode unit 110 will be described below first, and then the second electrode unit 120 will be described.
Referring to
Regarding connection to the busbar 15, when the electrode terminal 111 is formed of a metal material different from that of the current collecting member 112, a joint between the electrode terminal 111 and the busbar 15 may be formed of the same kind of metals. For example, when both the electrode terminal 111 and the busbar 15 are formed of the first metal material, that is, the same material, the joint between the electrode terminal 111 and the busbar 15 may be formed of the same kind of metals.
The current collecting member 112 may be formed of the second metal material different from the first metal material for a stable connection with the electrode assembly 150. Thus, while a joint between different kinds of metals may be formed between the current collecting member 112 formed of the second metal material and the electrode terminal 111 formed of the first metal material, a joint between the same kind of metals may be formed between the electrode terminal 111 formed of the first metal material and the busbar 15 formed of the first metal material.
As a detailed example, when the first electrode unit 110 constitutes a negative electrode, the current collecting member 112 may be formed of a copper material and the electrode terminal 111 may be formed of an aluminum material, so that a joint between different kinds of metals (joining portion 113) is formed between the current collecting member 112 and the electrode terminal 111. In this way, a joint between different kinds of metals (joining portion 113) is formed between the current collecting member 112 formed of copper and the electrode terminal 111 formed of aluminum, and as will be described below, the current collecting member 112 and the electrode terminal 111 may be joined to each other by, e.g., a caulking method such as Tox sheet metal joining or riveting, or by welding, etc.
Both the electrode terminal 111 and the busbar 15 may be formed of an aluminum material, that is, the same material, so that a joint between the same kind of metals may be formed between the electrode terminal 111 and the busbar 15.
The electrode terminal 111 and the current collecting member 112 are joined to each other at the joining portion 113. At the joining portion 113, the electrode terminal 111 and the current collecting member 112 may be joined to each other by various joining techniques, such as sheet metal joining (Tox), riveting, caulking, or welding.
In the example embodiment shown in
In the example embodiment shown in
Referring to
Referring to
As shown in the drawing, the two members to be joined, that is, the electrode terminal 311 and the current collecting member 312, may be disposed to overlap each other and then aligned so that joint holes respectively formed in the electrode terminal 311 and the current collecting member 312 correspond to each other. Subsequently, a rivet member 314 may be inserted into the joint holes of the electrode terminal 311 and the current collecting member 312. A shaping tool (not shown), such as a hammer, may be positioned on one end side of the rivet member 314, and a die (not shown) may be positioned on the other end side of the rivet member 314. Then, end portions of the rivet member 314 may be pressed around the joint holes by hammering the rivet with the shaping tool so that the two members 311 and 312 are pressed and joined together.
For example, the rivet member 314 may have head portions 314a having a large diameter and a body portion 314b having a small diameter. By hammering ends of the body portion 314b, a predetermined pressure may be applied to the ends of the body portion 314b so that the head portions 314a having a larger diameter than the joint holes may be formed at the ends of the body portion 314b. In this way, the members 311 and 312 may be fixed together between the two head portions 314a and may be joined together. Reference numeral 315 indicates a seal molding, and will be described in detail below. Reference numeral 310 indicates a first electrode unit.
As described above, the electrode terminal 111 and the current collecting member 112 may constitute the joining portion 113 by various joining methods. Methods besides those particularly described herein may also be used, and thus the joining portion 113 may be formed by various joining methods.
The seal molding 115 (corresponding to a first seal molding) is described now with reference to
The joining portion 113 between the electrode terminal 111 and the current collecting member 112 may be surrounded and sealed by the seal molding 115. The seal molding 115 may cover and protect the joining portion 113 including an interface between the different kinds of metals and blocks infiltration of moisture, which may help prevent corrosion at a dissimilar metal interface. For example, the seal molding 115 may insulate the joining portion 113 between the electrode terminal 111 and the current collecting member 112 from surroundings, which may help prevent corrosion of the joining portion 113.
Referring to
The seal molding 115 may be interposed between the electrode terminal 111 and the cap plate 130 to electrically insulate them from each other. For example, the electrode terminal 111 and the cap plate 130 may have different polarities, and may be electrically insulated from each other by interposing the seal molding 115 therebetween. For example, the seal molding 115 may be formed of a polymer resin material having an electrically insulating characteristic.
The seal molding 115 may completely seal the opening 130′ of the cap plate 130 penetrated by the electrode unit 110. For example, the seal molding 115 may seal the electrode assembly 150 and an electrolyte (not shown) contained in the case 180, and protect them from external harmful substances.
As an example, by inserting the electrode unit 110 in the opening 130′ of the cap plate 130 and then injecting molding resin (not shown) between the opening 130′ and the electrode unit 110, the seal molding 115 may be formed. For example, the seal molding 115 may be formed by insert injection molding. The cap plate 130, in which the electrode unit 110 is inserted, may be positioned in a mold (not shown) into which molding resin will be injected. Then, by insert injection molding for temporarily fixing the electrode unit 110 and the cap plate 130 in the mold and injecting molding resin into the mold, the seal molding 115 as shown in
Referring to
The seal molding 115 may be seamlessly formed as one body. For example, the joint groove portion 115c, the upper block 115a, and the lower block 115b of the seal molding 115 may be seamlessly connected in one body, and the respective portions may be simultaneously formed together by insert injection molding.
The upper block 115a may be interposed between the electrode terminal 111 and the cap plate 130, and may insulate the electrode terminal 111 from the cap plate 130.
The joining portion 113 between the electrode terminal 111 and the current collecting member 112 may be surrounded by at least the joint groove portion 115c and the lower block 115b. For example, the joining portion 113 may extend over the joint groove portion 115c and the lower block 115b, and the joint groove portion 115c and the lower block 115b may surround the joining portion 113 to protect the dissimilar metal interface from corrosion and improve a joining strength. In various example embodiments, the joining portion 113 may be formed over the joint groove portion 115c, the upper block 115a, and the lower block 115b, and the joint groove portion 115c, the upper block 115a, and the lower block 115b all may surround and protect the joining portion 113 of the electrode terminal 111 and the current collecting member 112 in cooperation.
The second electrode unit 120 is described now.
Referring to
For example, when the second electrode unit 120 constitutes a positive electrode, the electrode terminal 121 and the current collecting member 122 may be formed of an aluminum material and formed as one member in one body.
The electrode unit 120 may be assembled to penetrate the opening 130′ of the cap plate 130, and a seal molding 125 (corresponding to a second seal molding) may be interposed between the electrode unit 120 and the cap plate 130.
Referring to
The seal molding 125 may be seamlessly formed as one body. For example, the joint groove portion 125c, the upper block 125a, and the lower block 125b of the seal molding 125 may be seamlessly connected in one body, and the respective portions may be simultaneously formed together by insert injection molding.
The upper block 125a may electrically insulate the electrode terminal 121 disposed on the cap plate 130 and the cap plate 130 from each other.
Referring to
Referring to
For example, a joint between the first electrode terminal 111 and the busbar 15, and a joint between the second electrode terminal 121 and the busbar 15, may be formed by welding between the same kind of metals. In an example embodiment, the joints between the first and second electrode terminals 111 and 121 and the busbar 15 may be formed by aluminum welding. As will be described below, aluminum welding may provide better weldability than copper welding, and thus may be advantageous in terms of production yield rate and weld strength.
Referring to
For example, similar-metal welding of copper may be performed between the busbar 5 and the first electrode terminal 11, and similar-metal welding of aluminum may be performed between the busbar 5 and the second electrode terminal 12. However, copper-copper weld strength may be significantly lower than aluminum-aluminum weld strength. Thus, the connection structure of the busbar 5 according to the comparative example involves copper-copper welding, and the low weldability due to material characteristics may require a special welding technology and make it difficult to ensure sufficient weld strength.
In an example embodiment, the first and second electrode terminals 111 and 121 and the busbar 15 all are formed of an aluminum material, so that copper-copper welding may be avoided, and aluminum-aluminum welding which shows better weldability may be used.
As shown in
As described above, embodiments may provide a secondary battery in which a terminal unit including a joining portion between different kinds of metals has improved corrosion resistance and joint strength. Embodiments may provide a secondary battery in which a busbar electrically connecting neighboring battery cells has an improved connection structure, which may avoid difficulties weldability due to material characteristics. Embodiments may provide a secondary battery in which the corrosion resistance and joining strength of a terminal unit including a joining portion between different kinds of metals are improved.
Example embodiments have been disclosed herein, and although specific terms are employed, they are used and are to be interpreted in a generic and descriptive sense only and not for purpose of limitation. In some instances, as would be apparent to one of ordinary skill in the art as of the filing of the present application, features, characteristics, and/or elements described in connection with a particular embodiment may be used singly or in combination with features, characteristics, and/or elements described in connection with other embodiments unless otherwise specifically indicated. Accordingly, it will be understood by those of skill in the art that various changes in form and details may be made without departing from the spirit and scope of the present invention as set forth in the following claims.
Number | Date | Country | Kind |
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10-2014-0010877 | Jan 2014 | KR | national |