The present disclosure is related to high-pressure pumps and, more particularly, to improved segmented fluid ends for high-pressure plunger pumps.
It is common practice in the oil and gas industry to use high-pressure positive displacement or reciprocating pumps (also known as plunger pumps) in a variety of field operations relating to the exploration, preparation, and extraction of hydrocarbons. For example, plunger pumps are often used in cementing a wellbore as part of a completion operation. Plunger pumps are also used in acidizing and hydraulically fracturing subterranean formations during wellbore treatment operations. The fluid end of such pumps is the portion of the pump where a fluid is drawn in via a suction valve and subsequently discharged under pressure. Within the fluid end of a plunger pump, a plunger or piston compresses the fluid and pushes it under pressure through a discharge valve. The discharge valve is typically designed to open upon experiencing a predetermined pressure differential across the valve.
Such pumps are frequently used in pumping two-phase slurries where solid particles are suspended in a liquid (e.g., proppant suspended in a fracturing fluid). At least one problem with pumping such two-phase slurries is that the slurry oftentimes makes the fluid end susceptible to damage in the form of erosion, wear and tear, hoop stress, and fatigue. Ultimately, such damage can result in bore enlargement or cracking of the fluid end, which may decrease efficiencies or otherwise require the pump to be shut down and repaired or replaced altogether. As can be appreciated, this may prove to be quite costly and time-consuming.
The following figures are included to illustrate certain aspects of the present disclosure, and should not be viewed as exclusive embodiments. The subject matter disclosed is capable of considerable modifications, alterations, combinations, and equivalents in form and function, without departing from the scope of this disclosure.
The present disclosure is related to high-pressure pumps and, more particularly, to improved segmented fluid ends for high-pressure plunger pumps.
Disclosed is a segmented fluid end that replaces conventional mono-block fluid ends requiring modifications to the power end of the pump. The presently disclosed segmented fluid end includes several fluid end modules arranged side-by-side and each fluidly and operatively coupled to an external discharge manifold. Corresponding grooves defined in each of the fluid end modules and the external discharge manifold are configured to cooperatively receive a ring joint gasket or ring joint type (RJT) gasket that helps to precisely align the discharge manifold laterally with respect to each of the modules. Advantageously, individual fluid end modules may be removed from the fluid end assembly when required without disturbing the remaining fluid end modules. Also, a strain bolt assembly or system may be included in each fluid end module in order to preload the intersection of vertical and horizontal bores defined within each fluid end module. The strain bolt assembly may help reduce hoop stress in the modules during operation.
Referring to
As used herein, the term “high-pressure” used to characterize the pumps described herein refers to fluid pumping pressures ranging between about 1000 psi to about 20,000 psi (about 6.89 MPa to about 137.89 MPa).
The pump 100 is illustrated as a quintuplex pump where the fluid end 104 provides or otherwise comprises five fluid end segments or modules 106 (shown as fluid end modules 106a, 106b, 106c, 106d, and 106e), generally arranged in a side-by-side relationship. Those skilled in the art will readily appreciate that the embodiments disclosed herein may equally be employed on high-pressure pumps having more or less than five fluid end modules 106a-e (including one), without departing from the scope of the disclosure. The fluid end modules 106a-e may be identical and interchangeable. The design and construction of the fluid end modules 106a-e will be explained in greater detail below.
The fluid end 104 includes a suction manifold 108 configured to feed or otherwise provide a working fluid into each fluid end module 106a-e. The fluid end 104 also provides or otherwise defines a discharge manifold 110 fluidly and operatively coupled to each fluid end module 106a-e. As discussed in greater detail below, the discharge manifold 110 is an external manifold system that is attached to each individual fluid end module 106a-e using a series of mechanical fasteners 112 (e.g., bolt and nut configuration). Each mechanical fastener 112 may extend through the body of the discharge manifold 110 and be threaded at least partially into each fluid end module 106a-e. Properly torquing and otherwise securing a nut to the end of each mechanical fastener (as depicted) ensures that the discharge manifold 110 is secured to each fluid end module 106a-e for operation.
Exemplary working fluids that may be used in the pump 100 may include, but are not limited, to fracturing fluids, fracturing slurries (i.e., solid particles suspended in a fracturing fluid), acids, cements, drilling fluids, and the like. In operation, the fluid end modules 106a-e collectively receive and pressurize the working fluid provided through the suction manifold 108, and subsequently feed the pressurized working fluid to the discharge manifold 110, which conveys the pressurized working fluid downstream to a wellbore, for example, via one or more discharge flanges 114.
Referring now to
The body 202 may provide a top surface 208a, a bottom surface 208b, a front surface 208c, a back surface 208d, and opposing side surfaces 208e and 208f. The top surface 208a may define or otherwise provide a discharge cover orifice 210. In some embodiments, the discharge cover orifice 210 may be configured to receive a discharge valve cover 438 (
The body 202 may further define a suction orifice 212 (also known as a suction valve cover opening or cylinder head opening) in the front surface 208c. The suction orifice 212 may provide user access into the interior of the body 202. During operation, however, the suction orifice 212 may be occluded with a suction valve cover 440 (
One or more threaded holes 216 may be defined in the front surface 208c and used to secure the discharge manifold 110 the module 106. More particularly, as described above, the mechanical fasteners 112 (
The body 202 may further provide a module seal groove 218 defined on the front surface 208c. As illustrated, the module seal groove 218 extends about the discharge outlet 214. As will be described in greater detail below, the module seal groove 218 may be configured to at least partially receive a ring joint gasket 402 (
In some embodiments, the body 202 may further provide or otherwise define a ledge 220 configured to receive or seat a portion of the discharge manifold 110 (
While the foregoing description provides the discharge manifold 110 as being coupled or otherwise attached to the front surface 208c of the body 202, it is further contemplated herein to attach the discharge manifold 110 to other surfaces or portions of the module 106. For instance, in some embodiments, the discharge outlet 214 may instead be provided on the body 202 at the back surface 208d of the body 202 such that the discharge manifold 110 may be coupled to the module 106 at the back surface 208b rather that at the front surface 208c. In other embodiments, the relative locations of the discharge cover orifice 210 and the discharge outlet 214 may be reversed such that the discharge manifold 110 may be coupled to the module 106 at the top surface 208a of the body 202, without departing from the scope of the disclosure. Those skilled in the art will readily recognize several structural variations that may be possible in coupling the external discharge manifold to the fluid end modules 106a-e (
The module 106 may further include a strain bolt assembly 222 including one or more strain bolts 224 and corresponding nuts 226. As illustrated, each strain bolt 224 may be configured to extend laterally through the body 202 of the module 106, from one side 208e to the other side 208f, and be secured therein at opposing ends using the nuts 226. Accordingly, each end of the strain bolts 224 may be threaded and configured to threadably receive a corresponding nut 226 thereon. While four strain bolts 224 and eight corresponding nuts 226 are depicted in
The strain bolt assembly 222 may be configured to preload the module 106 and, more particularly, preload the intersection of the bores defined in the interior of the module 106. To accomplish this, the strain bolts 224 may be made of a material configured to provide an amount of tensile give while reducing hoop or circumferential stress within the internal bores of the body 202. For instance, in at least one embodiment, the strain bolts 224 may be grade seven (7) mechanical tensioner studs and the nuts 226 may be heavy hex nuts or torque nuts, each component being commercially-available under the name SUPERBOLT®. As will be appreciated, preloading the bores within the body 102 may prove advantageous in increasing the fatigue life for each module 106.
In some embodiments, the strain bolt assembly 222 may be installed at the time of manufacture of each module 106 and each strain bolt 224 may at that time be torqued to a predetermined and/or precise tensile value corresponding to a percentage of the yield strength of each strain bolt 224. After installation, the strain bolt assembly 222 need not be altered again, which takes the responsibility away from the user and thereby ensures proper torquing of the strain bolts 224 throughout operational use of the fluid end 106. In some embodiments, the strain bolt assembly 222 may be installed by the manufacturer using a thread locking adhesive so that a user will be unable to subsequently alter the torque value of each strain bolt 224.
Referring now to
Each end 304a,b of the manifold body 302 may be configured to be coupled to either a discharge flange 114 (
As mentioned above, the discharge manifold 110 may be arranged external to the modules 106a-e (
As illustrated, the manifold body 302 of the discharge module 110 may include a back face 310 that defines one or more discharge inlets 312. The discharge inlets 312 extend into the manifold body 302 and otherwise fluidly communicate with the discharge bore 306. Each discharge inlet 312 may be configured to mate with and otherwise sealingly engage a corresponding discharge outlet 214 (
One or more discharge seal grooves 314 may be defined on the back face 308 of the discharge manifold 110 and otherwise associated with each discharge inlet 312. Each discharge seal groove 314 may be configured to align with a corresponding module seal groove 218 (
The discharge manifold 110 further defines or otherwise provides a bottom surface 316. In some embodiments, at least a portion of the bottom surface 316 may be seated on or otherwise received by the ledge 220 (
Referring now to
One or more seals or compression packing assemblies 407 may be arranged about the plunger 406 within the plunger bore 404 to provide a sealing engagement between the body 202 and the plunger 406. During operation, as the plunger 406 reciprocates within the plunger bore 404, the compression packing assembly 407 prevents the working fluid from migrating along the length of the plunger 406 and out of the body 202 via the plunger bore 404.
The plunger bore 404 may be characterized as a horizontal bore, and the body 202 may further define or otherwise provide a vertical bore 410 that intersects the plunger bore 404 generally perpendicularly. At the intersection of the horizontal and vertical bores 404, 410, the body 202 may define or otherwise provide one or more strain bolt holes 412 (four shown), each configured to receive a corresponding strain bolt 224 from the strain bolt assembly 222 (
Within the vertical bore 410, the body 202 may further define a suction valve pocket 414 and a discharge valve pocket 416, each of which are in fluid communication with the plunger bore 404 at the bore intersection. It should be noted that, while the discharge valve pocket 416 is depicted as being arranged within the vertical bore 410 and otherwise axially aligned with the suction valve pocket 414, embodiments are also contemplated herein where the discharge valve pocket 416 is axially aligned with the plunger bore 404, without departing from the scope of the disclosure.
The suction valve pocket 414 has an inlet valve assembly 418 arranged therein, and the inlet valve assembly 418 generally includes a suction valve 420 biased by a spring 422 against a suction valve seat 424. The suction manifold 108 may define or otherwise provide a suction inlet conduit 428 configured to be aligned with the suction valve pocket 414 and the inlet valve assembly 418. The suction manifold 108 may be coupled to the body 202 of the module 106 using one or more mechanical fasteners 426 (two shown). In operation, the suction manifold 108 feeds working fluid into the suction valve pocket 414 via the suction inlet conduit 428 to be compressed.
Referring briefly again to
Referring once again to
As illustrated, a suction valve cover 440 may be received or otherwise secured within the suction orifice 212 on the front surface 208c of the body 202. Moreover, a portion of the discharge manifold 110 (i.e., the bottom surface 316) may be seated on or otherwise received by the ledge 220 such that the discharge inlet 312 may be axially and laterally aligned with the discharge outlet 214.
In other embodiments, however, the ledge 220 may be omitted and the ring joint gasket 402 may be used to help accurately align the discharge manifold 110 with the fluid end module 106. More particularly, as indicated above, the ring joint gasket 402 may be configured to be at least partially received or seated within both the discharge seal groove 314 and the module seal groove 218. As the mechanical fasteners 112 are tightened, the back face 310 of the discharge manifold 110 is brought into engagement with the front surface 208c of the body 202. During this movement, the ring joint gasket 402 may be cooperatively received within each of the module and discharge seal grooves 218, 314, thereby helping to axially align the discharge inlet 312 accurately with the discharge outlet 214.
The ring joint gasket 402 may be any type of sealing element configured to seal a joint or interface. In some embodiments, for example, the ring joint gasket 402 may be a soft iron API ring or a joint seal known to those skilled in the art. As the mechanical fasteners 112 are torqued, the ring joint gasket 402 may be configured to deform or otherwise be crushed within the module and discharge seal grooves 218, 314, thereby resulting in a generally fluid tight and/or sealed interface between the discharge outlet 214 and the discharge inlet 312. In other embodiments, however, one or more of the ring joint gaskets 402 may be an elastomeric sealing element, such as an O-ring or the like, without departing from the scope of the disclosure. The sealed interface provided by the ring joint gasket 402 provides sealed fluid communication between the fluid end module 106 and the discharge module 110.
As will be appreciated, arranging the ring joint gasket 402 in each of the grooves 218, 314 helps a user precisely align the discharge manifold 110 to each fluid end module 106a-e (
In exemplary operation of the fluid end module 106, working fluid is provided to the body 202 of the fluid end module 106 from the suction manifold 108 and via the inlet valve assembly 418 arranged in the suction valve pocket 414. The plunger 406 is powered to reciprocate toward and away from the intersection of the horizontal and vertical bores 404, 410 in order to pressurize the incoming working fluid. In this manner, the plunger 406 affects high and low pressures on the discharge valve pocket 416. For example, as the plunger 406 is thrust toward the intersection of the bores 404, 410, the pressure within the discharge valve pocket 416 is increased.
At some point, the pressure increase will be sufficient to open the discharge valve 432 and thereby allow the release of the pressurized working fluid from the discharge valve pocket 416, through the discharge outlet 214, and into the discharge inlet 312, which feeds the discharge bore 306 of the discharge manifold 110. The amount of pressure required to open the discharge valve 432 may be determined, at least in part, by the spring 436, which maintains the discharge valve 432 in its closed position until the requisite pressure is achieved in the discharge valve pocket 416.
The plunger 406 may also affect a low pressure on the discharge valve pocket 416. That is, as the plunger 406 retracts away from its advanced discharge position near the intersection of the bores 404, 410, the pressure at the intersection will decrease, thereby decreasing the pressure within the discharge valve pocket 416 and forcing the discharge valve 432 to close and otherwise return the discharge valve pocket 416 to a sealed state. As the plunger 406 continues to move away from the discharge valve pocket 416, the pressure therein will continue to drop, and eventually a low or negative pressure will be achieved within the discharge valve pocket 416.
The pressure decrease will eventually be sufficient to affect an opening of the suction valve 420 arranged within the inlet valve assembly 418. Opening the suction valve 420 allows the uptake of working fluid into the suction valve pocket 414 from the suction inlet conduit 428 of the suction manifold 108 fluidly coupled thereto. The amount of pressure required to open the suction valve 420 may be determined by the spring 422, which keeps the suction valve 420 in its closed position until the requisite low pressure is achieved in the suction valve pocket 414.
Accordingly, the reciprocating or cycling motion of the plunger 406 within the plunger bore 406 controls the pressure within the body 202. The suction and discharge valves 420, 432 respond accordingly in order to dispense pressurized working fluid from the discharge valve pocket 416, through the discharge outlet 214, and into the discharge bore 306 of the discharge manifold 110 via the discharge inlet 312. The discharged working fluid is then replaced with additional working fluid derived from the suction manifold 108.
Besides the several advantages already mentioned above, those skilled in the art will readily appreciate the several additional advantages that the presently disclosed segmented fluid end module 106 and fluid end 104 (
Moreover, the external discharge manifold 110 of the module 106 supplies a degree of rigidity to the fluid end 104. More particularly, mechanically fastening the discharge manifold 110 to each fluid end module 106a-e serves to structurally couple each module 106a-e together. Such rigidity and robustness is lost on typical systems that separate mono-block cylinders into individual segments. Also, the external discharge manifold 110 does not generate axial reaction forces that could damage the fluid end module 106. For instance, conventional systems typically use hollow cylindrical manifold segments that connect individual fluid end modules together in a common discharge, but also generate axial forces much the same way that a hydraulic or pneumatic cylinder creates force. In order to retain these forces, bulky clamping systems or restraining bolts that run the complete width of the fluid end assembly are typically used. As can be appreciated, these clamping systems and/or restraining bolts can be problematic because they rely on the user to properly install and tighten them to the proper torque values to ensure their proper function.
Embodiments disclosed herein include:
A. A segmented fluid end that includes one or more fluid end modules, each fluid end module including a body providing a plunger bore configured to receive a plunger therein and a discharge outlet in fluid communication with the plunger bore, wherein a pressurized working fluid may exit the body of each fluid end module via the discharge outlet, a discharge manifold having an elongate manifold body configured to be operatively coupled to each fluid end module, the manifold body providing a first end, a second end, a discharge bore extending between the first and second ends, and one or more discharge inlets that fluidly communicate with the discharge bore, and a ring joint gasket arranged between each discharge inlet of the discharge manifold and a corresponding discharge outlet of the one or more fluid end modules.
B. A method of operating a segmented fluid end. The method may include reciprocating a plunger within a plunger bore defined within a body of one or more fluid end modules, discharging a pressurized working fluid via a discharge outlet defined in each body of the one or more fluid end modules, receiving the pressurized working fluid with a discharge manifold having an elongate manifold body coupled to the body of each fluid end module, the manifold body providing a first end, a second end, a discharge bore extending between the first and second ends, and one or more discharge inlets that fluidly communicate with the discharge bore and a corresponding discharge outlet of each fluid end module, and laterally aligning each discharge inlet of the discharge manifold with the corresponding discharge outlet of each fluid end module with a corresponding ring joint gasket arranged between each discharge inlet and the corresponding discharge outlet.
C. A pump that includes a power end, at least two fluid end modules arranged in a side-by side relationship and operatively coupled to the power end, each fluid end module including a body providing a plunger bore configured to receive a plunger therein and a discharge outlet in fluid communication with the plunger bore, wherein a pressurized working fluid may exit the body of each fluid end module via the discharge outlet, a discharge manifold having an elongated manifold body configured to be operatively coupled to the at least two fluid end modules, the manifold body providing a first end, a second end, a discharge bore extending between the first and second ends, and one or more discharge inlets that fluidly communicate with the discharge bore, and a ring joint gasket arranged between each discharge inlet of the discharge manifold and a corresponding discharge outlet of the one or more fluid end modules.
Each of embodiments A, B, and C may have one or more of the following additional elements in any combination: Element 1: further comprising a module seal groove extending about the discharge outlet of each fluid end module, and one or more discharge seal grooves defined on the manifold body, each discharge seal groove extending about a corresponding discharge inlet, wherein each ring joint gasket is at least partially received within each adjacent module seal grooves and discharge seal grooves and configured to laterally align the manifold body with each fluid end module. Element 2: wherein each ring joint gasket is at least one of a soft iron API ring and an elastomeric sealing element, and the ring joint gasket is configured to seal an interface between the manifold body and each fluid end module. Element 3: wherein the ring joint gasket is one of annular or polygonal in shape. Element 4: further comprising a suction manifold having an elongate suction body operatively and fluidly coupled to each of the fluid end modules. Element 4: wherein the manifold body is fastened to the body of each fluid end module using one or more mechanical fasteners that extend through the manifold body and are received by one or more corresponding holes defined in the body of each fluid end module. Element 5: wherein the body of each fluid end module defines a ledge configured to seat a portion of the discharge manifold and thereby vertically align the discharge inlets with each discharge outlet. Element 6: wherein the discharge outlet of each fluid end module is defined on a front surface of the body of each fluid end module and the discharge manifold is coupled to the front surface of the body of each fluid end module. Element 7: wherein the discharge outlet of each fluid end module is defined on a back surface of the body of each fluid end module and the discharge manifold is coupled to the back surface of the body of each fluid end module. Element 8: further comprising a strain bolt assembly configured to preload the body of each fluid end module. Element 9: wherein the plunger bore is a horizontal bore and the body further defines a vertical bore, and wherein the strain bolt assembly comprises one or more strain bolts configured to extend through the body at or near an intersection between the horizontal and vertical bores, and a plurality of nuts threadably received at one or both ends of each of the one or more strain bolts and configured to secure the one or more strain bolts within the body, wherein the one or more strain bolts are torqued to a predetermined tensile value in order to preload the horizontal and vertical bores and thereby reduce hoop stress therein.
Element 10: wherein a module seal groove extends about the discharge outlet of each fluid end module and each discharge inlet includes a corresponding discharge seal groove defined thereabout, the method further comprising arranging the corresponding ring joint gasket at least partially within adjacent module seal grooves and discharge seal grooves. Element 11: further comprising fastening the manifold body to the body of each fluid end module using one or more mechanical fasteners, and sealing an interface between the discharge manifold and the body of each fluid end module with the ring joint gasket as the mechanical fasteners are torqued, wherein the ring joint gasket is at least one of a soft iron API ring and an elastomeric sealing element. Element 12: further comprising seating a portion of the discharge manifold on a ledge defined on the body of each fluid end module, and thereby vertically aligning the one or more discharge inlets with the discharge outlet of each fluid end module. Element 13: wherein the discharge outlet of each fluid end module is defined on a front surface of the body of each fluid end module, the method further comprising coupling the discharge manifold to the front surface of the body of each fluid end module. Element 14: wherein the discharge outlet of each fluid end module is defined on a back surface of the body of each fluid end module, the method further comprising coupling the discharge manifold to the back surface of the body of each fluid end module. Element 15: wherein the plunger bore is a horizontal bore and the body of each fluid end module further defines a vertical bore, the method further comprising preloading an intersection between the horizontal and vertical bores in each fluid end module. Element 16: wherein preloading the intersection between the horizontal and vertical bores comprises extending one or more strain bolts through the body of each fluid end module at or near the intersection between the horizontal and vertical bores, threadably attaching nuts at one or both ends of each of the one or more strain bolts, and torquing each of the one or more strain bolts to a predetermined tensile value.
Element 17: further comprising a module seal groove extending about the discharge outlet of each fluid end module, and one or more discharge seal grooves defined on the manifold body, each discharge seal groove extending about a corresponding discharge inlet, wherein each ring joint gasket is at least partially received within each adjacent module seal groove and discharge seal groove and configured to laterally align the manifold body with each fluid end module. Element 18: wherein the ring joint gasket is at least one of a soft iron API ring and an elastomeric sealing element, and wherein the ring joint gasket is configured to provide a fluid tight interface between adjacent discharge outlets and discharge inlets. Element 19: further comprising a suction manifold having an elongate suction body operatively and fluidly coupled to each of the at least two fluid end modules. Element 20: further comprising a strain bolt assembly configured to preload the body of each fluid end module. Element 21: wherein the plunger bore is a horizontal bore and the body further defines a vertical bore, and wherein the strain bolt assembly comprises one or more strain bolts configured to extend through the body at or near an intersection between the horizontal and vertical bores, and nuts threadably received at one or both ends of each of the one or more strain bolts and configured to secure the one or more strain bolts within the body, wherein the one or more strain bolts are torqued to a predetermined tensile value in order to preload the horizontal and vertical bores and thereby reduce hoop stress therein.
Therefore, the disclosed systems and methods are well adapted to attain the ends and advantages mentioned as well as those that are inherent therein. The particular embodiments disclosed above are illustrative only, as the teachings of the present disclosure may be modified and practiced in different but equivalent manners apparent to those skilled in the art having the benefit of the teachings herein. Furthermore, no limitations are intended to the details of construction or design herein shown, other than as described in the claims below. It is therefore evident that the particular illustrative embodiments disclosed above may be altered, combined, or modified and all such variations are considered within the scope of the present disclosure. The systems and methods illustratively disclosed herein may suitably be practiced in the absence of any element that is not specifically disclosed herein and/or any optional element disclosed herein. While compositions and methods are described in terms of “comprising,” “containing,” or “including” various components or steps, the compositions and methods can also “consist essentially of” or “consist of” the various components and steps. All numbers and ranges disclosed above may vary by some amount. Whenever a numerical range with a lower limit and an upper limit is disclosed, any number and any included range falling within the range is specifically disclosed. In particular, every range of values (of the form, “from about a to about b,” or, equivalently, “from approximately a to b,” or, equivalently, “from approximately a-b”) disclosed herein is to be understood to set forth every number and range encompassed within the broader range of values. Also, the terms in the claims have their plain, ordinary meaning unless otherwise explicitly and clearly defined by the patentee. Moreover, the indefinite articles “a” or “an,” as used in the claims, are defined herein to mean one or more than one of the element that it introduces. If there is any conflict in the usages of a word or term in this specification and one or more patent or other documents that may be incorporated herein by reference, the definitions that are consistent with this specification should be adopted.
As used herein, the phrase “at least one of” preceding a series of items, with the terms “and” or “or” to separate any of the items, modifies the list as a whole, rather than each member of the list (i.e., each item). The phrase “at least one of” does not require selection of at least one item; rather, the phrase allows a meaning that includes at least one of any one of the items, and/or at least one of any combination of the items, and/or at least one of each of the items. By way of example, the phrases “at least one of A, B, and C” or “at least one of A, B, or C” each refer to only A, only B, or only C; any combination of A, B, and C; and/or at least one of each of A, B, and C.
The present application claims priority to U.S. Provisional Patent Application Ser. No. 61/715,140, entitled “Segmented Fluid End” and filed on Oct. 17, 2012, the contents of which are incorporated in their entirety.
Filing Document | Filing Date | Country | Kind |
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PCT/US2013/065182 | 10/16/2013 | WO | 00 |
Number | Date | Country | |
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61715140 | Oct 2012 | US |