Claims
- 1. A method for selectivating a zeolite, said method comprising reacting said zeolite with an organosilicon compound under vapor phase conditions, said organosilicon compound having at least two silicon atoms, the silicon atoms being connected either to one another directly or to one another through oxygen atoms, the remainder of the bonds extending from the silicon atoms being connected to hydrogen or hydrocarbyl groups having from 1 to 10 carbon atoms.
- 2. A method according to claim 1, wherein the organosilicon compound is a silicone compound and the silicon and oxygen atoms in said silicone compound form a cyclic structure.
- 3. A method according to claim 2, wherein said silicone compound is selected from the group consisting of octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane.
- 4. A method according to claim 1, wherein the organosilicon compound is a silicone compound and said silicone compound has the formula ##STR9## where R.sub.1 and R.sub.6 are independently hydrogen, methyl, or phenyl; R.sub.2, R.sub.3, R.sub.4, and R.sub.5 are independently methyl or phenyl; and m is from 1 to 10.
- 5. A method according to claim 4, wherein said silicone compound is selected from the group consisting of hexamethyldisiloxane, decamethyltetrasiloxane and diphenyltetramethyldisiloxane.
- 6. A method according to claim 1, wherein said organosilicon compound is tris-(trimethylsiloxy)-phenylsilane or tris-(trimethylsiloxy)-silane.
- 7. A method according to claim 1, wherein said organosilicon compound is a silane compound of the formula ##STR10## where R.sub.1 and R.sub.6 are independently hydrogen, methyl, or phenyl; R.sub.2, R.sub.3, R.sub.4, and R.sub.5 are independently methyl or phenyl; and m is from 1 to 10.
- 8. A method according to claim 7, wherein said silane compound is hexamethyldisilane.
- 9. A method according to claim 1, wherein said zeolite has a silica to alumina molar ratio of at least 20.
- 10. A method according to claim 9, wherein said zeolite has a silica to alumina molar ratio of 60 or less.
- 11. A method according to claim 10, wherein said zeolite has a Constraint Index of from 1 to 12.
- 12. A method according to claim 1, wherein said zeolite is ZSM-5.
- 13. A method according to claim 10, wherein said zeolite is ZSM-5.
- 14. A method according to claim 1, wherein said zeolite is combined with a binder material prior to contact with said organosilicon compound.
- 15. A method according to claim 12, wherein said zeolite is combined with a silica binder material prior to contact with said organosilicon compound.
- 16. A method according to claim 13, wherein said zeolite is combined with a silica binder material prior to contact with said organosilicon compound.
- 17. A method according to claim 4, wherein said zeolite is preselectivated by contact with an organosilicon compound, followed by calcination in an oxygen containing atmosphere, prior to contact of said zeolite with said silicone compound.
- 18. A method according to claim 1, wherein said zeolite is contacted with said silicone compound in the presence of hydrogen and an organic carrier.
- 19. A method according to claim 18, wherein said organic carrier is toluene.
- 20. A method according to claim 19, wherein said organosilicon compound is selectivated from the group consisting of hexamethyldisiloxane, decamethyltetrasiloxane, diphenyltetramethyldisiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, tris-(trimethylsiloxy)-phenylsilane, tris-(trimethylsiloxy)-silane, and hexamethyldisilane.
- 21. A method according to claim 13, wherein said zeolite is contacted with said organosilicon compound in the presence of hydrogen and an organic carrier.
- 22. A method according to claim 21, wherein said organic carrier is toluene.
- 23. A method according to claim 22, wherein said organosilicon compound is selected from the group consisting of hexamethyldisiloxane, decamethyltetrasiloxane, diphenyltetramethyldisiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, tris-(trimethylsiloxy)phenylsilane, tris-(trimethylsiloxy)-silane, and hexamethyldisilane.
CROSS-REFERENCE TO RELATED APPLICATIONS
This application is a continuation-in-part of U.S. application Ser. No. 08/223,383, filed Apr. 5, 1994, U.S. Pat. No. 5,498,814, which is a continuation of U.S. application Ser. No. 08/024,972, filed Mar. 2, 1993, now abandoned, which is a continuation-in-part of U.S. application Ser. No. 07/850,104, filed Mar. 12, 1992, now abandoned.
This application is also a continuation-in-part of U.S. application Ser. No. 08/233,542, filed May 5, 1994, now U.S. Pat. No. 5,475,179, which is a continuation of U.S. application Ser. No. 08/038,310, filed Mar. 29, 1993, now abandoned, which is a continuation-in-part of U.S. application Ser. No. 07/850,104, filed Mar. 12, 1992, now abandoned.
US Referenced Citations (10)
Foreign Referenced Citations (2)
Number |
Date |
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WO9317788 |
Sep 1993 |
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WO9317987 |
Sep 1993 |
WOX |
Non-Patent Literature Citations (1)
Entry |
Chamoumi et al. "Characterization of Offretite Modified by Silanation with Tetramethoxysilane and Octamethylcyclotetrasiloxane", Zeolites, vol. 14, Apr./May 1994, pp. 282-289. |
Related Publications (1)
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233542 |
May 1994 |
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Continuations (2)
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Continuation in Parts (3)
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