The present specification generally relates to thermal management based on heat radiation, and more particularly, to near-field radiative heat transfer.
Passive radiative cooling, as one of the radiation-based thermal management techniques, is known for improving energy efficiencies by providing a path to dissipate heat from a structure into an atmosphere. Further, it is known to use radiative cooling via pigmented paints, dielectric coating layers, metallized polymer films, and organic gases because of their intrinsic thermal emission properties. Additionally, known thermal switch devices may be designed by placing two parallel Weyl semimetal planar objects distancing a nanoscale gap and rotating one object with respect to the other. As the rotation angle increases, the amount of heat transfer will decrease. However, such designs do not permit for automatic change in thermal switching properties in combination with rotation of the bodies.
In one embodiment, a thermal cooling system is provided. The thermal cooling system includes a first body, a second body, and a third body. The second body has a first layer and a second layer formed from a Weyl semimetal and a third layer sandwiched between the first layer and the second layer. The third layer is formed from a vanadium dioxide film. The second body is spaced apart from the first body. The third body is spaced apart from the second body. The second body is a modulator configured to transition between a metallic phase and an insulating phase dependent on a temperature to regulate a heat from the first body to the third body through the second body in a self-adaptive manner dependent on the temperature.
In another embodiment, a method for forming a thermal cooling system is provided. The method includes positioning a first body having a first plurality of Weyl semimetal nanostructures, positioning a second body spaced apart from the first body, the second body having a first layer and a second layer formed from a Weyl semimetal and a third layer sandwiched between the first layer and the second layer, the third layer formed from a vanadium dioxide film; and positioning a third body having a second plurality of Weyl semimetal nanostructures. Wherein the second body is a modulator configured to transition between a metallic phase and an insulating phase dependent on a temperature to regulate a heat from the first body to the third body through the second body in a self-adaptive manner dependent on the temperature.
In yet another embodiment, a thermal cooling system is provided. The thermal cooling system includes a first body, a second body, and a third body. The first body is configured as a heat source that transfers heat and has first plurality of Weyl semimetal nanostructures. The second body has a first layer and a second layer formed from a Weyl semimetal and a third layer sandwiched between the first layer and the second layer. The third layer is formed from a vanadium dioxide film. The second body is spaced apart from the first body. The second body is a heat modulator configured to transition between a metallic phase and an insulating phase dependent on a temperature. The third body has a second plurality of Weyl semimetal nanostructures. The third body is spaced apart from the second body. The second body is positioned between the first body and the third body. The third body is a heat sink configured to receive the heat when the second body is in the insulating phase. Wherein the first body, the second body, and the third body are each configured to independently rotate with respect to a common axis to change optical properties of the first plurality of Weyl semimetal nanostructures, optical properties of the second plurality of Weyl semimetal nanostructures, and optical properties of the Weyl semimetal and the second body is configured to regulate a heat from the first body to the third body through the second body in a self-adaptive manner dependent on the temperature.
These and additional features provided by the embodiments described herein will be more fully understood in view of the following detailed description, in conjunction with the drawings.
The embodiments set forth in the drawings are illustrative and exemplary in nature and not intended to limit the subject matter defined by the claims. The following detailed description of the illustrative embodiments can be understood when read in conjunction with the following drawings, where like structure is indicated with like reference numerals and in which:
Embodiments of the present disclosure are directed to thermal management systems that include a first body having a first plurality of Weyl semimetal nanostructures, a second body having a pair of Weyl semimetal layers sandwiching a phase change material layer, and a third body having a second plurality of Weyl semimetal nanostructures that form a three-body system. The second body is spaced apart from the first body and the third body is spaced apart from the second body. As such, the second body is positioned between the first and third bodies such that the first body, the second body and the third body are arranged in a linear arrangement along a same plane. Each of the bodies are configured to independently rotate about a common axis to change optical properties of the first plurality of Weyl semimetal nanostructures, the second plurality of Weyl semimetal nanostructures, and the pair of Weyl semimetal layers.
The rotation of any of the bodies' changes an optical property of the Weyl semimetal nanostructures to create a mismatch in a permittivity of the optical properties between the bodies such that an increase or decrease in a near-field radiative heat transfer may be achieved compared to a static state of the bodies.
The phase change material layer of the second body is configured to automatically transition, or switch, between a metallic phase and an insulating phase dependent on a temperature of the phase change material layer such that the second body is a heat modulator. When a heat received by the second body causes the temperature of the second body to be equal to or greater than a predetermined temperature, the second body automatically transitions to the metallic phase to reduce a heat transfer from the first body to the third body. When the heat received by the second body causes the temperature of the second body to be less than a predetermined temperature, the second body automatically transitions to the insulating phase to increase the heat transfer from the first body to the third body.
Various embodiments of optical metamaterials system to tune radiative management are described in detail herein.
As used herein, the term “communicatively coupled” means that coupled components are capable of exchanging data signals and/or electric signals with one another such as, for example, electrical signals via conductive medium, electromagnetic signals via air, optical signals via optical waveguides, electrical energy via conductive medium or a non-conductive medium, data signals wirelessly and/or via conductive medium or a non-conductive medium and the like.
Further, as used herein, the term “system lateral direction” refers to the forward-rearward direction of the system (i.e., in a +/−Y direction of the coordinate axes depicted in
Referring now to
The first body 102 has an outer surface 108 that includes a first plurality of Weyl semimetal nanostructures 110. As used herein, “Weyl semimetal nanostructures” may be three-dimensional topological materials where valence band and conduction band touch at finite specific points in momentum space. The first plurality of Weyl semimetal nanostructures 110 may be any shape including, for example, bicone shaped, dicone shaped, cone shaped, frustoconical shaped, cylindrical shaped, tetragonal shaped, hexagonal shaped, and/or the like.
The second body 104 is formed by three layers, a first layer 111, a second layer 113 and a third layer 117. The first layer 111 and the second layer 113 may be formed with the same material and are positioned to sandwich the third layer 117. As such, the third layer 117 is positioned between the first layer 111 and the second layer 113. The first layer 111 includes an outer surface 112a and the second layer includes an outer surface 112b, which may be formed of identical material. For example, the outer surfaces 112a, 112b and/or portions of the first layer 111 and the second layer 113, respectively, may each be formed from and/or include a Weyl semimetal nanostructures film 115a, 115b, respectively. The Weyl semimetal nanostructures film 115a, 115b may include a plurality of Weyl semimetal nanostructures 119. Each of the Weyl semimetal nanostructures 119 may be any shape including, for example, bicone shaped, dicone shaped, cone shaped, frustoconical shaped, cylindrical shaped, tetragonal shaped, hexagonal shaped, and/or the like. The Weyl semimetal nanostructures 119 may be the same or different from those of the first plurality of Weyl semimetal nanostructures 110.
The third layer 118 may be formed with a vanadium dioxide (VO2) film. That is, a phase change material may be used as the third layer 117 in the multilayer structure of the second body 104. Example VO2 films that may be deposited directly between two Weyl semimetal layers, or on various substrate that are infrared transparent, include, but not limited to, silicon (Si), Barium Fluoride (BaF2), Cadmium Telluride (CdTe), and Gallium Arsenide (GaAs), and the like. It should be understood that VO2 undergoes a reversible phase transition from a low-temperature monoclinic VO2(M1) semi-conductive phase or insulating phase to a high-temperature tetragonal VO2(R) metallic phase at a transition temperature (Ttr). In some embodiments, the transition temperature (Ttr) is dependent on the material used for the emitter device, which may be the first body 102, as discussed in greater detail herein. For example, in some embodiments, the transition temperature (Ttr) of the first body 102 may be between 20 degrees Celsius to 70 degrees Celsius for the third layer 118 to remain in the low emissivity state (e.g., with the heat received by the second body 104 and dispersed to the third body 106) and a minimum temperature of 50 degrees Celsius for third layer 118 to transition into the metallic phase, inhibiting the second body 104 from receiving the heat from the first body 102 and reducing the dispersion of the heat to the third body 106. It should be appreciated that these are non-limiting examples of temperatures and/or temperature ranges and that these temperatures may change or vary based on various parameters, such as, without limitation, doping (e.g., with Tungsten), future material or substrate combinations.
As such, the second body 104 is a self-adaptive thermal switching system that uses a phase change material to transition the example thermal management system 100 between the insulating phase, where the optical properties permit or allow more heat transfer from the first body 102 to the third body 106 through the second body 104, and the metallic phase where the optical properties inhibit or significantly limit the amount of heat transferred from the first body 102 to the third body 106 through the second body 104. That is, the heat transfer from the first body 102 to the third body 106 through the second body 104 is regulated in a self-adaptive manner dependent on the temperature and thus the phase of the vanadium dioxide in the second body 104, which changes with the heat received from the first body 102.
In some embodiments, a thickness t1 of the first layer 111 and a thickness t3 of the second layer 113 may be equal, or otherwise symmetric. In this embodiment, a thickness t2 of the third layer 117 may be greater than either the thickness t1 of the first layer 111 and/or the thickness t3 of the second layer 113. As such, in some embodiments, the thickness t2 of the third layer 117 may be larger than the sum of the thickness t1 of the first layer 111 and the thickness t3 of the second layer 113. In a non-limiting example, the thickness t1 of the first layer 111 and the thickness t3 of the second layer 113 may each be 100 nm, while the thickness t2 is 300 nm. In other embodiments, the thickness t1 of the first layer 111 and the thickness t3 of the second layer 113 may be different, unequal, or otherwise asymmetric. Further, in other embodiments, the thickness t2 of the third layer 117 may be equal to, or less than either the thickness t1 of the first layer 111 and/or the thickness t3 of the second layer 113 and/or a sum of the thickness t1 of the first layer 111 and the thickness t3 of the second layer 113 may equal the thickness t3 of the third layer 117.
The third body 106 has an outer surface 116 that includes a second plurality of Weyl semimetal nanostructures 120. The second plurality of Weyl semimetal nanostructures 120 may be any shape including, for example, bicone shaped, dicone shaped, cone shaped, frustoconical shaped, cylindrical shaped, tetragonal shaped, hexagonal shaped, and/or the like. The second plurality of Weyl semimetal nanostructures 120 may be the same as or different from those of the first plurality of Weyl semimetal nanostructures 110 and/or the Weyl semimetal nanostructures 119 of the first layer 111 and/or the second layer 113.
In some embodiments, the thickness of the first body 102 and the third body 106 are equal, as illustrated by t4. The second body 104 has an overall thickness less than that of the first body 102 and the second body 104, as illustrated by t5. In a non-limiting example, the thickness t4 of the first body 102 and the third body 106 may each be 500 μm while the thickness t5 of the second body 104 may be 200 nm. In other embodiments, the thickness t4 of the first body 102 and the third body 106 may be different where either the thickness t4 of the first body 102 is greater than the thickness t4 of the third body 106 or the thickness t4 of the third body 106 is greater than the thickness t4 of the first body 102.
In some embodiments, the first body 102 may be a heat source to generate a heat, the second body 104 may be a heat modulator to receive/modulate the heat, and the third body 106 may be a heat sink. Further, in some embodiments, a controller 107, such as a microprocessor may be communicatively coupled to the first body 102, the second body 104, and/or the third body 106. It should be appreciated that more than one microprocessor may be communicatively coupled to the first body 102, the second body 104, and/or the third body 106 (e.g., one microprocessor for each body or one microprocessor that is shared between the second body 104 and the third body 106, and the like). The microprocessor of the controller 107 may be a computer processor where the data processing logic and control is included on a single integrated circuit, or a small number of integrated circuits and contains the arithmetic, logic, and control circuitry required to perform the functions of a computer's central processing unit.
Still referring to
That is, in some embodiments, the space between the first body 102 and the second body 104 defined by the vacuum gap d12 may be equal to the space between the second body 104 and the third body 106 defined by the vacuum gap d23. In a non-limiting example, the space of the vacuum gap d12 and the space of the vacuum gap d23 may each be 100 nm. In other embodiments, the space between the first body 102 and the second body 104 defined by the vacuum gap d12 may be different than the space between the second body 104 and the third body 106 defined by the vacuum gap d23. Further, in some embodiments, the space between the first body 102 and the second body 104 defined by the vacuum gap d12 and the space between the second body 104 and the third body 106 defined by the vacuum gap d23 may be less than the thickness ts of the second body 104. In other embodiments, the space between the first body 102 and the second body 104 defined by the vacuum gap d12 and the space between the second body 104 and the third body 106 defined by the vacuum gap d23 may be the same or equal to the thickness ts of the second body 104.
Still referring to
That is, the first body 102, the second body 104 and the third body 106 are each configured to independently rotate along the Z-axis, depicted in
Further, the rotation of the first body 102, the second body 104 and/or the third body 106 increases or decreases a near-field radiative heat transfer compared to a static state of the first body 102, the second body 104 and/or the third body 106, as discussed in greater detail herein. Further, the position of the first body 102, the second body 104, and the third body 106 may be changed. As such, changing the position and/or rotation of the first body 102, the second body 104, and the third body 106, such that the first body 102, the second body 104, and the third body 106 switch between a symmetric arrangement and an asymmetric arrangement change the near-field radiative heat transfer to either increase or decrease the near-field radiative heat transfer, as discussed in greater detail herein. That is, the first body 102, the second body 104 and/or the third body 106 may be either rotated, the positioned changed, and/or a combination of both rotation and changing the position to switch between the symmetric arrangement and the asymmetric arrangement to change the near-field radiative heat transfer to either increase or decrease the near-field radiative heat transfer.
In other embodiments, the first body 102, the second body 104, and/or the third body 106, while illustrated as plates and square or rectangular, is non-limiting and the first body 102, the second body 104, and/or the third body 106 may be any shape, such as an octagon, circular, hexagonal, spherical, elliptical, and the like.
Still referring to
where m=2, 3 correspond to the second body 104 or the third body 106, and
Therefore,
In Equation 2, ϵb is the background permittivity, EF is the chemical potential with the temperature dependence captured by Equation 3 below:
where EF(0)=0.163 eV is the chemical potential at T=0 K such that EF=0.15 eV at T=300 K,
is the normalized real frequency,
is the normalized complex frequency, τ−1 is the Drude damping rate, G(E)=n(−E)−n(E), with n(E) being the Fermi distribution function
is the effective fine-structure constant, νF is the Fermi velocity, g is the number of Weyl nodes, and
where Ec is the cutoff energy beyond which the band dispersion is no longer linear. As such, for calculation and/or simulation purposes the flowing parameters are used: ϵb=6.2, ηc=3, τ=1×10−12 s, g=2, b=2×109 m−1, and νF=0.83×105 m/s.
For the example thermal management system 100, the total heat flux Qtot from the first body 102, the second body 104, and the third body 106 may be evaluated as the summation of the heat fluxes from the first body 102 to the second body 104, Q12, and the second body 104 to the third body 106, Q13, respectively. The expression is given by the fluctuational electrodynamics defined by Equation 4:
where s and p represent the polarization of the incident electromagnetic wave, β is the wave vector component that is parallel to the xy-plane, ω is the angular frequency, Θ12(ω, T, ΔT1)=Θ1(ω, T−ΔT1)−Θ2(ω, T) and Θ13(ω, T, ΔT1, ΔT2)=Θ1(ω, T−ΔT1)−Θ3(ω, T+ΔT3) represent the difference between the mean energy of Planck's oscillators for each body
and ξ1,2(ω, β, ϕ, θ1, θ2, θ3) [ ] is the photon tunneling probability from the first body 102 to the second body 104 and ξ1,3(ω, β, ϕ, θ1, θ2, θ3) is the photon tunneling probability from the first body 102 to the third body 106 through the second body 104, both of which are determined by the rotation angles θ1, θ2, and θ3 for the incident angle ϕ. These probabilities may be obtained by a scattering matrix defined by Equations 5 and 6 below:
where Tr{ . . . } denotes the matrix trace, and the auxiliary functions are defined by Equation 7 below:
where =eik
eik
=
, and
=eik
eik
,
, and
, which correspond to the interfaces between the first body 102 and vacuum gap d12, the first body 102 and the second body 104, the second body 104 and the second vacuum gap d23, and the first body 102 to the third body 106.
The “+” and “−” symbols represent the directions pointing towards the positive and negative z-axis, respectively. and
are the scattering operators when treating the first and second bodies and the second and third bodies as an individual or a single body. The two reflection matrices under such treatment follow the expressions,
=
+
eik
eik
and
=
+
eik
eik
, where
=(
−
)−1 and
=(
−
+
)−1 are Fabry-Pérot-type matrices. Similarly,
=(
−
)−1 and
=(
−
+
)−1.
Still referring to
Still referring to (
) as the reflection (transmission) matrix at the interface between the body i and the vacuum cavity, where α indicates “+” or “−”, the matrix may be determined by solving the Maxwell's equation by matching the boundary conditions at the corresponding interfaces. These matrices take the form
where the reflection coefficients and transmission coefficients account for s and p polarizations.
Referring back to
It should be understood that when assuming ΔT1→0 and ΔT2→0, the thermal equilibrium is automatically satisfied. As such, but the first body 102, the second body 104 and the third body 106 are rotated by angles θ1, θ2, θ3, respectively, ranging from 0 to π, the heat transfer coefficient h12 corresponds to the vacuum gap d12 and the heat transfer coefficient h23 corresponds to the vacuum gap d23.
Now referring to
This demonstrates the self-adaptive functionality of either reducing or increasing the heat transfer based on a temperature of the third layer 118 of the second body 104, which is an improvement over conventional systems where the heat transfer may only be change by rotation of the bodies. Further, it should be appreciated that the heat transfer coefficients h (e.g., h12, h13, and h23 defined in Equations 9-11) as a function of rotation angles θ1, θ2, and θ3 account for cavity size asymmetries. That is, the first body 102, the second body 104, the third body 106, the vacuum gap d12 and/or the vacuum gap d23 may be in an asymmetric arrangement. As such, an asymmetric arrangement of the first body 102, the second body 104, and the third body 106 increases or decreases a near-field radiative heat transfer compared to a symmetric arrangement.
Now referring to
That is, in this embodiment, each of the plurality of heat flow controls 502 may be independently rotated to change optical properties and each first body 102 of each of the plurality of heat flow controls 502 may be at a different temperature as the heat source. As such, each of the plurality of heat flow controls 502 form a local modulator set to control the heat flow transporting in that channel. Therefore, it is conceivable that at some instance in time, some of the plurality of heat flow controls 502 may be in the insulating phase while other one of the plurality of heat flow controls 502 may be in the metallic phase. As such, each channel is independent from one another and may transition between the insulating phase and the metallic phase, and vice versa, independently based on the temperature of that channel. Further, while the first body 102 described above is the heat source of the channel, an emitter may be positioned to in the example heat flow control system 500 to direct heat to each of the first body 102 of each of the plurality of heat flow controls 502. In some embodiments, the emitter may be centrally located to disperse an even amount of heat between each of the plurality of heat flow controls 502. In other embodiments, the emitter may be offset to disperse a different amount of heat to each of the plurality of heat flow controls 502.
Further, each of the plurality of heat flow controls 502 may independently rotate about a local origin, depicted as OL. Further, the heat flow control system 500 may globally rotate about the global origin, depicted as OG. The rotations within each modulator set controls the local thermal energy, while when the entire heat flow control system 500 rotates, the heat flow control system 500 controls thermal energy in multiple channels (e.g., four channels in the current drawing). In addition, since the thermal radiation depends on the view factors, when the global rotation occur, each of the units in each local modulator (e.g., each of the plurality of heat flow controls 502) do not overlap, which further modifies the thermal energy. As discussed, the number of the plurality of heat flow controls 502 can be increased or decreased depending on the application and the distance between the center of each local modulator set to the center of the global origin can be different, depending on the location of the heat channel in the application.
Now referring to
Further, when the first body 102 is rotated 180 degrees (or π rad), the second body 104 is static (e.g., θ2=0) and the third body 106 is rotated between 0 and 180 degrees, there is a much smaller amount of heat transfer compared to the example above with the dash and dotted lines. That is, in this example, in the insulating phase, depicted as a triangle and in the metallic phase, depict as a square, along with rotation described in this example, there is much less amount of heat transfer than that compared to above where only the third body 106 is rotated. As such, by changing the rotation angles, different phase of the phase change material of the third layer 118 of the second body 104 may have varying heat modulating characteristics.
where Qi and Qf denote the heat fluxes of the initial and final states of the switching. The depicted dashed line is the switching ratio with only rotation of the three bodies (e.g., the first body 102, the second body 104, and the third body 106) and the depicted dotted line is the rotation of only two bodies (e.g., a system that only has two bodies instead of three bodies as depicted in
The switching ratio that includes both the phase change material (e.g., the third layer 118 of the second body 104) and the rotation is depicted as the empty circle. This switching ratio is obtained by switching from the insulating phase with θ1=0, θ2=0, and θ3=π (i.e., the dashed line in
With the switching ratio optimized, it is possible to have precise temperature control when the third body 106 is a delicate temperature driven component or when the third body 106 must be maintained above a predetermined temperature, at the predetermined temperature, or less than the predetermined temperature such that only the optimal amount of heat is transferred to the third body 106 such that the third body 106 may operate at its most optimal temperature. Such application may be found in the thermal management of battery packs in electric vehicles.
At block 605, the first body is positioned. The first body may be positioned along a common axis. The first body may be formed from and/or include a plurality of Weyl semimetal nanostructures, each having an optical property that controls the radiative heat transfer. The first body may be rotatable about a rotation angle θ1 between 0 to π (or 180 degrees) to change the optical property of each of the first plurality of Weyl semimetal nanostructures of the first body such that a mismatch in a permittivity of the optical properties between the first body and the other two bodies in the example thermal management system is generated. At block 610, the second body is positioned to be spaced apart from the first body. The second body may be positioned a distance away from the first body and may be positioned along the common axis. The second body may be formed from three layers, in which the two layers positioned at either end of the second body include Weyl semimetal nanostructures and the third layer, sandwiched between the first and second layers, is formed from a phase change material. The Weyl semimetal nanostructures each have an optical property that controls the radiative heat transfer. The third layer is configured to transition between the insulating phase and metallic phase as a function of, or based on the temperature of the phase change material. The second body is independently rotatable.
At block 615, the third body is positioned to be spaced apart from the second body. The third body may be positioned a distance away from the second body that is equal to the distance that the second body is spaced apart from the first body. Further, the third body may be positioned along the common axis. The third body may be formed from and/or include a second plurality of Weyl semimetal nanostructures, each having an optical property that controls the radiative heat transfer. The third body is independently rotatable.
At block 620, in an optional step, the first body is rotated about the common axis with a rotation angle θ1 between 0 to π (or 180 degrees) to change the optical property of each of the first plurality of Weyl semimetal nanostructures of the first body such that a mismatch in a permittivity of the optical properties of the second body and the first body and/or a mismatch in a permittivity of the optical properties of the third body and the first body is generated. The generated mismatch increases or decreases a near-field radiative heat transfer compared to a static state of the first body (e.g., θ1=0).
At block 625, in an optional step, the second body is rotated about the common axis with a rotation angle θ2 between 0 to π (or 180 degrees) to change the optical property of each of the Weyl semimetal nanostructures of the first and second layers of the second body such that a mismatch in a permittivity of the optical properties of the second body and the first body is generated and/or a mismatch in a permittivity of the optical properties of the second body and the third body is generated. The generated mismatch increases or decreases a near-field radiative heat transfer compared to a static state of the second body (e.g., θ2=0).
At block 630, in an optional step, the third body is rotated about the common axis with a rotation angle θ3 between 0 to π (or 180 degrees) to change the optical property of each of the second plurality of Weyl semimetal nanostructures of the third body such that a mismatch in a permittivity of the optical properties of the third body and the second body and/or the third body and the first body is generated. The generated mismatch increases or decreases a near-field radiative heat transfer compared to a static state of the third body (e.g., θ3=0).
It should be appreciated that the illustrative method 600 may continuously be executed and continuously loop such that the example thermal management system is continuous increasing or decreasing the near-field radiative heat transfer and/or there may be a rotation of any of the first body at block 620, the second body at block 625 and/or the third body at block 630 independently and without a combination of rotation. Therefore, for example, blocks 620 and 625 may be omitted if only the third body is rotated.
It should now be understood that the embodiments of this disclosure described herein provide a self-adaptive system based on a temperature for near-field radiative heat transfer in a three body system that utilizes phase change material in the middle body and rotation of a first body, a second body and/or a third body to change optical properties of a plurality of Weyl semimetal nanostructures of the first body, the second body and/or the third body to create a mismatch in a permittivity of the optical properties of the first body, the second body, and/or the third body.
The heat transfer from the first body to the third body through the second body is regulated in a self-adaptive manner dependent on the temperature and thus the phase of the vanadium dioxide in the second body, which changes with the heat received from the first body.
While particular embodiments have been illustrated and described herein, it should be understood that various other changes and modifications may be made without departing from the spirit and scope of the claimed subject matter. Moreover, although various aspects of the claimed subject matter have been described herein, such aspects need not be utilized in combination. It is therefore intended that the appended claims cover all such changes and modifications that are within the scope of the claimed subject matter.