The present invention relates generally to apparatus and methods for injecting chemicals into pipelines and, more specifically, to apparatus and methods for adding odorant to natural gas or liquefied petroleum gas flowing in a pipeline.
There are many instances in which it is desirable to inject chemicals of various types into fluids (gas and liquids) flowing in pipelines. One such example is in the area of natural gas pipelines. In addition to substances such as corrosion inhibitors and alcohol to inhibit freezing, odorants are commonly injected into natural gas pipelines. Natural gas is odorless. Odorant is injected into natural gas in order to provide a warning smell for consumers. Commonly used odorants include tertiary butyl mercaptan (TBM). Such odorants are typically injected in relatively small volumes normally ranging from about 0.5 to 1.0 lbs/mmscf.
The odorants are typically provided in liquid form and are added to the gas at a location where distribution gas is taken from a main gas pipeline and provided to a distribution pipeline. In such circumstances, the gas pressure may be stepped down through a regulator from, for example, 600 psi or more, to a lower pressure in the range of 100 psi or less. The odorants can also be added to the main transmission pipeline in some situations.
As will be apparent from the above discussion, the odorants which are added to natural gas are extremely concentrated. Odorants such as TBM and other blends are mildly corrosive and are also very noxious. If the job of injecting odorant is not performed accurately, lives are sometimes endangered. It would be possible for a homeowner to have a gas leak with a leak not being realized until an explosion had resulted if the proper amount of odorant was not present. Also, if a leak of odorant occurs at an injection site, people in the surrounding area will assume that a gas leak has occurred with areas being evacuated and commerce being interrupted. Contrarily, if such mistakes become common, people in the surrounding area will become desensitized to the smell of a potential gas leak and will fail to report legitimate leaks.
Two techniques are commonly used for providing odorization to natural gas in a main distribution pipeline. The first technique involves the injection of liquid odorant directly into the pipeline through the use of a high pressure injection pump. The odorant is pumped from a liquid storage tank into a small pipe which empties directly into the main gas pipeline. Because odorant is extremely volatile, drops injected to the pipeline immediately disperse and spread throughout the gas in the pipeline. In this way, within a few seconds, the drops of liquid odorant are dispersed in gaseous form. U.S. Pat. No. 6,208,913 (Marshall et al.) and U.S. Pat. No. 5,490,766 (Zeck) both show state-of-the-art fluid pumps for injecting odorant.
There are several disadvantages with this prior art technique. As mentioned above, the odorant liquid is extremely noxious. The injection pump must therefor be designed so that no odorant can leak. This requires a pump design which is relatively expensive and complex in order to meet the required operating conditions. In even such sophisticated systems, there is an unpleasant odor present when working on the pump which can make people think that there is a natural gas leak.
Another technique for odorizing a natural gas pipeline involves bypassing a small amount of natural gas at a slightly higher pressure than the pressure of the main distribution pipeline, through a tank containing liquid odorant. This bypass gas absorbs relatively high concentrations of odorant while it is in the tank. This heavily odorized bypass gas is then placed back into the main pipeline. The odorant, now volatilized, is placed back into the main pipeline and diffuses throughout the pipeline in much the same manner as described with respect to the liquid injection system. U.S. Pat. No. 6,142,162 (Arnold), shows such a method for odorizing natural gas in a pipeline utilizing bypass piping in conjunction with a liquid odorant storage tank.
There are also a number of disadvantages associated with the bypass system for odorizing pipelines. One disadvantage of the bypass system is the fact that the bypass gas picks up large and inconsistent amounts of odorant from the liquid in the tank and becomes completely saturated with odorant gas. As a result it is necessary to carefully monitor the small amounts of bypass gas which are used. Also, natural gas streams typically have contaminates such as compressor oils or condensates which can fall out into the odorant vessel in bypass systems. These contaminates create a layer that reduces the contact area between the liquid and the bypass stream. This necessarily degrades the absorption rate of the stream.
In U.S. Pat. No. 7,056,360 (Zeck) is on an improved system for odorizing natural gas flowing through a pipeline by injecting odorant into the pipeline at a controlled rate. The system includes an odorant storage tank containing an odorant to be injected. A pressurized source of inert gas, such as nitrogen, communicates with the odorant storage tank for maintaining the tank at a desired positive pressure above the pressure of the natural gas pipeline. An injection conduit communicates the odorant storage tank with the pipeline. A photooptic metering means, located within the injection conduit, meters odorant to be injected into the pipeline.
The odorization system described in issued U.S. Pat. No. 7,056,360, was extremely simple as compared to existing positive displacement pump systems. The system offered improved ease of understanding, operation and maintenance. As compared to the prior art systems, the system described therein offered more accurate control, verification (drop counting) and communication (alarms, status, etc) than the prior art systems. The system offered generally smell free operation and maintenance. However, despite these many advantages, the previously described system also required that the odorant storage tank be pressurized to a pressure above the pipeline pressure of the pipeline being odorized.
U.S. Pat. No. 7,389,786 (Zeck), represented a further advance in the art and offered certain advantages over the previously described optic system in some situations in that an ultrasonic measuring unit allows the odorant to be metered on a drop wise basis with drops of chemical being counted as they pass through the flow vale into the injection conduit and into the natural gas pipeline. The ultrasonic measuring unit also allows steady state flow conditions to be measured accurately. Such a sonic measuring unit can advantageously be utilized in a wide range of flow situations. However, the system continued to require that the odorant tank be maintained above the pressure of the gas pipeline being odorized, however.
There continues to be a need for improvements in odorization systems of the above described types.
The present invention has as its object to provide even further advantages over the previously described systems. The present system provides distinct advantages in situations in which high volume odorization is required. High volume odorizer's have depended on traditional positive displacement pumps or solenoid valves to deliver discrete doses of odorant to natural gas or LPG streams for the purpose of bringing these streams to safe perception levels. These methods can leave dangerous dead time between doses. By-pass style systems fail to accurately measure and control the amount of odorant being added to the stream. This absorption amount can change radially as condensates and other contaminates fall out and change the absorption boundary layer.
The present invention solves many of the previously encountered problems of dead time and/or accuracy in high volume systems of the type under consideration. The method and apparatus of the invention provide the safest method presently available to accurately odorize mid to large gas streams. In addition, as will be apparent from the written description which follows, the system of the present invention also has the added benefit of providing a means for small odorizers, such as the Z9000.™ unit referenced in the following Detailed Description Of The Invention, to odorize small streams without requiring the storage tank to be maintained above pipeline pressure.
The odorizing system of the invention is used for injecting a chemical, such as an odorant, from a chemical supply into a natural gas or liquefied petroleum gas pipeline at a desired injection rate. The system includes a chemical storage tank containing a chemical, such as the odorant to be injected. An injection conduit communicates the chemical storage tank with the pipeline. A hydraulic pressure booster is located in the injection conduit for pressurizing the chemical to a pressure above that of the pipeline. The hydraulic pressure booster has a first side which communicates with the chemical in the injection conduit and a second, isolated side which is exposed to hydraulic pressure but which is isolated from the chemical being injected. A flow-control valve may be located within the injection conduit for metering chemical to be injected into the pipeline. Preferably, the hydraulic pressure booster is a diaphragm pump having an isolated fluid which acts upon the diaphragm, the isolated fluid being a hydraulic fluid.
Unlike certain of the prior art systems, the chemical storage tank in the present system is preferably maintained at a pressure above ambient, but below the pressure of the pipeline. In one form of the invention, the chemical leaving the diaphragm pump passes to a motor driven flow-control valve, the position of the valve being controlled by an electric motor, whereby opening of the valve causes a stream of chemical to be injected into the pipeline at a desired flow rate. In another form of the invention, the chemical leaving the diaphragm pump feeds a drip style metering valve, the valve being adjustable between a drop wise setting for metering chemical into the pipeline on a drop by drop basis and a steady flow setting for metering chemical on a steady state flow basis. In a third form of the invention, the chemical leaving the diaphragm pump feeds both a motor controlled flow valve which allows larger volumes of chemical to be injected into the pipeline, and a drop wise flow valve for metering smaller volumes of chemical being injected.
In yet another aspect of the invention, an electronic controller controls a linear thruster. This option has the ability to deliver small to large volume/stroke by precisely controlling the displacement rod of the linear thruster and measuring the force. This arrangement eliminates the need for a separate metering unit. In addition to monitoring the forces of the linear thruster, an optional pressure transmitter monitors the hydraulic and/or odorant pressures of the system. This information is fed directly to the primary controller to verify and/or augment the data from the linear thruster.
Additional objects, features and advantages will be apparent in the written description which follows.
The present invention has as its object to provide a system for injecting chemicals into a pipeline, such as for injecting an odorant of the type used for odorizing natural gas, which is simpler in design and more economical in operation than the prior art systems, which is more reliable, and which can be used in both small and large flow applications as well as to inject chemicals into liquefied petroleum gas (LPG) pipelines.
The present invention offers several unique advantages over existing chemical injection and odorization systems in both small and larger flow rate applications. It has particular applicability to odorization systems for natural gas pipelines and LPG pipelines but those skilled in the art will understand that the system can also be used to inject other chemical substances, such as alcohol to inhibit freezing, corrosion inhibitors, and the like.
A number of problems inherent in the prior art systems are overcome with the odorization system of the invention. As mentioned under the “Background” discussion above, low flow rate systems such as those typically found in city distribution systems have typically been difficult to odorize accurately. A low pressure environment does not provide a positive seating action for positive displacement (fluid pump) type odorization systems. Such systems require a pump inlet pressure that is precariously close to the natural gas pipeline pressure, thereby inviting free flow or volume surges in the system. In the low flow rate situation, the amount of odorant per stroke is extremely small. The current systems tend to vapor lock or have such a long time between injections that gas is not evenly odorized. These low flow rate systems also need to be located where the distribution system is located. Thus, they are commonly surrounded by hospitals, schools, metro areas and other residential areas. The currently available injection systems are complex and do not contain fugitive emissions during maintenance. During operation, many of these systems exhaust natural gas into the air with every stroke of the injection pump.
There are also known disadvantages associated with the high flow rate applications. These high flow rate applications are typically found on interstate gas pipelines, for example. One disadvantage is the turn down ratio associated with such systems. On theses systems gas flow rate can range considerably. When a positive displacement pump is sized for lower end capacity, it is required to work too hard at the upper end. This causes wear on the equipment prematurely. Sometimes the upper end demand cannot be met and desired odorization levels cannot be met. As a result, hybrid dual pump configurations have been tried in the past, resulting in expensive and complex system designs. When the pump is sized for the higher end of demand, the time between strokes is excessive. This results in dead spots. As a result, the gas is not evenly odorized.
Another disadvantage of the high flow applications is the fact that the larger pumps suffer a greater failure rate with subsequent leakage. Considerable actuation gas (normally natural gas) is required to actuate the pump. These systems also suffer from winter freeze blockages and exhaust natural gas to the atmosphere.
In order to better understand the operation and advantages offered by the present invention, reference will first be had to
The odorant contained within the tank 11 must be at a positive pressure which exceeds the pressure of the natural gas pipeline 17 into which the odorant is to be injected. For this reason, a pressurized gas source 19 communicates with the chemicals storage tank 11 by means of conduit 21 and regulator valve 23 for maintaining the tank 11 at a desired positive pressure above the pressure of the natural gas pipeline 17. For example, if the pipeline 17 is maintained in the range of 300 to 400 psi, the storage tank 11 can be maintained in the range of 500 psi by means of nitrogen blanket provided by the nitrogen tank 17. An isolation valve 25 can also be present in the conduit 21. The storage tank 11 will also typically be equipped with a level float 27 and a sensor unit 29.
In the system illustrated in
Odorant flows through the injection conduit 13 to the odorant regulator valve 35 which drops the odorant pressure to a desired pressure slightly above the pipeline pressure. The flow-control valve 37 controls the odorant flow rate. If high flow rates are anticipated, a flow meter 39 measures the odorant flow as the drops begin to turn into a stream. The flow-control valve 37 continues to control odorant flow during this period. If the flow rate falls below a preset minimum of control valve 37, a timing mechanism closes and reopens to compensate. Drop size can be verified using the optional level monitor 27 located within the storage tank 11 or by the meter 39. Other empirical data, either current or historical, can also be utilized. A controller calculates drop size based on temperature, pressures, physical constants of the odorant blend and orifice size. The drop size can be verified and adjusted.
In the particular system illustrated in
The particular system illustrated in
An electronic controller, operative under the control of a program stored therein, is provided to precisely adjust the servo driven needle valve used for metering individual drops of chemical. The controller has inputs connected to a flow meter 49 of the type commonly present in the pipeline. A temperature sensor (not shown) is located in the odorant stream. As will be familiar to those skilled in the art, flow meter 49 generates a signal proportional to the flow of gas within the pipeline 17. The flow meter 49 can provide a digital pulse, or an analog signal, each time a known quantity of gas flows through pipeline 17.
As has been explained in the Background of the Invention, the above described system offers several advantages over the prior art and can be especially advantageously utilized in lower volume flow rate situations. The Z9000.™ unit can also be incorporated into the system of the invention, as will be further described in the discussion which follows.
Turning now to
As the piston 67 moves to the right as viewed in
In the version of the system illustrated in
A principal advantage of the system illustrated in
The system of the invention illustrated in
In the system shown in
When the shaft of electronic linear actuator 87 moves to the right, connecting rod 91 enables positive displacement unit 59 to be charged with liquid odorant. When actuator 87 reaches the end of its travel, it reverse direction. A preset force or travel is transmitted through connecting rod 91 causing the positive displacement unit 57 to apply pressure to the liquid odorant, thereby moving it past discharge check valve 73.
Thus, in
Linear thruster 99 can control the position of rod 101 as desired. It can measure and control the force involved to do the work. In the preferred system illustrated in
The pressure transmitter 96 can be used, for example, to read the output side of the odorant pump 105. A suitable pressure transmitter unit can be obtained commercially, such as the Rosemont 4600.™ Oil and Gas Panel Pressure Transmitter, available from Emerson Process Management, Rosemont, Inc. Chanhassen, Minn.
As will be appreciated from
The system of the invention illustrated in
An invention has been provided with several advantages. The odorization system of the invention is extremely simple as compared to existing positive displacement pump systems. The system offers improved ease of understanding, operation and maintenance. As compared to the prior art systems, the present system offers more accurate control, verification and communication than the prior art systems. Compared to the prior art systems, the system of the invention offers a smell free operation and maintenance. No gas is exhausted to the atmosphere.
While the invention has been shown in several of its forms, it is not thus limited but is susceptible to various changes and modifications without departing from the spirit thereof.
The present application claims priority from U.S. patent application Ser. No. 12/407,387, filed Mar. 19, 2009, which claims priority from Provisional Patent Application Ser. No. 61/039,606, filed Mar. 26, 2008, and Provisional Patent Application Ser. No. 61/039,610, filed Mar. 26, 2008.
Number | Name | Date | Kind |
---|---|---|---|
4611294 | Stanfill | Sep 1986 | A |
7056360 | Zeck | Jun 2006 | B2 |
7389786 | Zeck | Jun 2008 | B2 |
20010014840 | Marshall et al. | Aug 2001 | A1 |
20010047621 | Arnold | Dec 2001 | A1 |
Number | Date | Country | |
---|---|---|---|
20120167465 A1 | Jul 2012 | US |
Number | Date | Country | |
---|---|---|---|
61039606 | Mar 2008 | US | |
61039610 | Mar 2008 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 12407387 | Mar 2009 | US |
Child | 13418977 | US |