Claims
- 1. A self-regulating heating article comprising at least two electrodes and a crosslinked electrically conductive polymer composition, the electrodes being connectable to a power supply so that current will pass between the electrodes through the conductive polymer composition, said composition having a positive temperature coefficent of resistivity and comprising (1) a first polymeric material which prior to cross-linking exhibits significant green strength corresponding to a tensile stress of at least 10 psi at 20% elongation and which exhibits elastomeric properties at ambient temperatures in the crosslinked state; (2) a second thermoplastic polymer material; and (3) conductive particles which have been dispersed in said polymeric material such that the composition exhibits increased resistance with increased temperatures at temperatures substantially above the melting point of either material.
- 2. The article of claim 1 wherein the conductive particles are carbon black.
- 3. The article of claim 1 wherein the elastomeric and thermoplastic materials are separate segments contained in a graft or block copolymer.
- 4. The article of claim 3 wherein the elastomeric material is polytetramethylene oxide and the thermoplastic material is polytetramethylene terephthalate.
- 5. The article of claim 3 wherein the elastomeric region provides 30-70% by weight of the copolymer.
- 6. The article of claim 1 wherein the elastomeric and thermoplastic materials comprise a physical blend of polymers.
- 7. The article of claim 6 wherein the elastomeric material is selected from the group consisting of chlorinated polyethylene.
- 8. The article of claim 1 wherein the elastomeric material is an ethylenepropylene rubber and the thermoplastic material is a crystalline polyolefin.
- 9. The article of claim 1 wherein the elastomeric material is an ethylenepropylene rubber and the thermoplastic material is a polystyrene.
- 10. The article of claim 1 wherein the crosslinked polymeric composition comprises an ethylene-propylene rubber, polypropylene and carbon black.
- 11. The article of claim 10 wherein the polypropylene is in the range of from 5 to 40% of the composition, the ethylene-propylene rubber is from 40 to 90% and the carbon black ranges from 5 to 35%.
- 12. The article of claim 1 wherein the amount of the elastomeric material is from about 3 to about 75% by weight of the combined weight of elastomeric material and thermoplastic material.
- 13. The article of claim 12 wherein the amount of the elastomeric material is from about 4 to about 40% by weight of elastomeric material and thermoplastic material.
- 14. The article of claim 1 wherein the amount of the conductive material is from about 4 to 60% by weight of the composition.
- 15. The article of claim 14 wherein the amount of the conductive material is from about 5 to 50% by weight of the composition.
- 16. The article of claim 1 wherein the amount of the elastomeric material is from about 4 to 40% by weight of the combined weight of the elastomeric material and the thermoplastic material, and the amount of the conductive filler is from 5 to 50% by weight of the composition.
- 17. The article of claim 1 which has been cross-linked by ionizing radiation.
- 18. The article of claim 1 which has been annealed to obtain minimum resistance.
CROSS-REFERENCE TO RELATED APPLICATION
This application is a divisional of copending commonly assigned application Ser. No. 84,352 filed Oct. 12, 1979, now U.S. Pat. No. 4,560,498 which is a continuation of application Ser. No. 601,639 filed Aug. 4, 1975, now abandoned, which is a continuation-in-part of application Ser. No. 510,035, filed Sept. 27, 1974, now abandoned. The disclosure of each of said applications is incorporated herein by reference.
US Referenced Citations (4)
Divisions (1)
|
Number |
Date |
Country |
Parent |
084352 |
Oct 1979 |
|
Continuations (1)
|
Number |
Date |
Country |
Parent |
601639 |
Aug 1975 |
|
Continuation in Parts (1)
|
Number |
Date |
Country |
Parent |
510035 |
Sep 1974 |
|