The present invention relates to the field of semi-transparent thin-film photovoltaic modules having a multi-cell architecture and subjected to peripheral shade effects intrinsic to the device with which they are associated. These modules are intended to produce electrical energy and/or to function as photovoltaic sensors or transducers.
A thin-film photovoltaic cell is composed of at least one substrate, a first transparent electrode, a second generally metallic electrode and an absorber layer. The term “thin-film” is understood to mean photovoltaic layers of any nature (organic, inorganic), the thickness of the absorber of which does not exceed ten micrometers.
A thin-film photovoltaic module is made up of a multitude of thin-film photovoltaic cells. Generally, it is composed of a plurality of photovoltaic cells that are arranged in series in order to increase the electric voltage across the terminals of the module. Methods are known for placing photovoltaic cells in series through successive stages of isolation and interconnection of the various constituent layers of the thin-film photovoltaic module, as described in document EP0500451-B1.
A thin-film photovoltaic cell semi-transparent to visible light may comprise a plurality of opaque active photovoltaic regions that are separated by transparent regions. The photovoltaic regions can be of any shape and size such that the human eye cannot distinguish them. To do this, the width of the photovoltaic regions is preferably less than 200 micrometers. In a known embodiment, the active photovoltaic regions and the transparent regions are organized in networks of elementary, linear, circular or polygonal geometric structures. The transparency of the photovoltaic cell is a function of the surface fraction that is occupied by the active opaque photovoltaic regions. Patent WO2014/188092-A1 presents an embodiment of a semitransparent thin-film photovoltaic monocell. In an advantageous embodiment, the transparent regions are arranged in the transparent electrode in addition to the metal electrode and the absorber in order to increase the transmission of light at the transparent regions, since by reducing the number of interfaces, the optical phenomena of reflections at the interfaces are minimized.
It is known to those skilled in the art that the electric power generated by a photovoltaic module can be greatly reduced compared to the optimum energy production conditions, in particular during partial or total shade of all or part of the photovoltaic cells making up a photovoltaic module. Semi-transparent photovoltaic modules are subject to the same type of constraints. In particular, shading part of a semi-transparent photovoltaic module whose semi-transparent cells are all connected in series drastically impacts the power-voltage curve, even if a very small part of the module or cell is shaded. Indeed, in a series architecture, the current is the same in all the cells. For example, if a single cell is shaded and experiences a 25% current loss, then the current generated by the module also suffers the same loss.
In all of the figures, two axes (X) and (Y) forming an orthonormal coordinate system are shown in order to facilitate their geometric description.
Embodiments of the invention provide a semi-transparent photovoltaic module composed of a multitude of semi-transparent thin-film cells connected in series and exhibiting an improved visual quality of the cells when they are subjected to the effects of recurrent or even permanent shade.
One feature is a semi-transparent photovoltaic module made up of a multitude of semi-transparent thin-film cells connected in series and subjected to recurrent or even permanent shade effects, whereof the active regions, the transparent regions, and the bridge interconnects between active regions are placed so that the insulation lines and the bridge interconnects are less visible, or even invisible to the naked eye for an observer placed a few centimeters from the photovoltaic surface.
In some implementations, a watch provided with such a photovoltaic module, and a glazing provided with such a photovoltaic module.
In the remainder of the document, the term “annulus” refers to a continuous region of defined thickness, constant or not, forming a closed line around a central point. For example, a ring is an annulus with circular symmetry. An annulus is characterized by:
A ring is therefore defined by its central point, which is the center C, its interior line corresponding to the minimum radius Rmin and its exterior line corresponding to the maximum radius Rmax. In the case of a ring, the width is constant; it is defined as the smallest distance separating the minimum radius Rmin from the maximum radius Rmax of the ring.
An annulus is formed from one or more materials. According to the invention, an annulus consists mainly of active materials forming active regions, advantageously active photovoltaic regions. Spaces that are not active regions will be designated by the term “vacant space.” These vacant spaces have the particularity of not being electrically conductive.
An insulating region is defined as a space forming an electrical discontinuity within the active surfaces belonging to the same annulus. This insulating region electrically insulates the adjacent active regions.
The term “annulus arc” is used to define a continuous portion of said annulus. This annulus arc is defined for example by its center, its interior line, its exterior line, its starting angle Âd and its stopping angle Âa with respect to a reference position. For example, a ring arc is therefore defined by its center, its radius Rmin, its radius Rmax, its starting angle Âd and its stopping angle Âa.
In the remainder of the document, semi-transparent photovoltaic modules will be considered. The vacant spaces correspond to the transparent regions.
Standardizing the integration of photovoltaic modules generates new problems. In the case of integrating semi-transparent modules into watches, it is advantageous to use the same module design regardless of the configuration of the flange of the watches (in order to reduce the production costs of said modules). The flange that forms the junction between the dial and the watch glass, depending on its design, may be more or less wide, more or less transparent, which generates different shade effects depending on said design. In the remainder of this document, the term “recurring flange” is used to refer to any device causing a permanent shade effect on the semi-transparent photovoltaic module integrated in a system such as a watch.
One feature of the invention is to make the inter-cell separations, more commonly called insulation lines, invisible to the naked eye, even for circular geometry modules, which are notably suitable for the manufacture of solar watches in particular.
According to the invention, a semi-transparent photovoltaic module consists of a plurality of photovoltaic cells electrically connected in series. Said cells are composed of:
Said cells are characterized in that the portions of adjacent insulating regions do not face each other.
Advantageously, the conductive bridge interconnects do not face one another either.
In order to increase transparency, the insulating region portions are transparent.
Preferably, the active annuli are all of the same geometric nature.
For example, for applications using a semi-transparent photovoltaic module integrated into electronic devices with a circular geometry such as watches, it is recommended that the active annuli and the transparent annuli be concentric rings. In order to resolve the problem of watch flanges generating partial shade of the photovoltaic module, it is desirable for the active annuli to be radially spaced by a constant pitch Pa and for them to have a constant width.
Advantageously, the annulus is only composed of active photovoltaic regions.
Advantageously, the active photovoltaic regions are of the same width as the active annuli and have a constant width CD. In order for these active regions to be imperceptible to the eye, the width of the active regions will ideally be between 10 nm and 50 μm. Advantageously, the active photovoltaic regions are included in the active annuli, but the active annulus can be made up of active regions and non-active regions.
In order to minimize the addition of material and to make the bridge interconnects invisible, it is desirable for the length of the bridge interconnects to be equal to Pa-CD. In order not to create a visual disturbance between the network of concentric rings and the network of bridge interconnects, it is necessary for the width of the concentric rings and the width of the bridge interconnects to be of the same order of magnitude. Advantageously, said widths are equal. Furthermore, in order not to create an ordered network of bridge interconnects that would be detectable with the naked eye, the bridge interconnects are distributed randomly between two active photovoltaic regions of adjacent active annuli belonging to the same cell.
Advantageously, the total area of all the bridge interconnects does not exceed 10% of the total area of all active regions of the photovoltaic module.
In order to increase the efficiency of the photovoltaic module, the bridge interconnects are formed of thin layers identical to the active photovoltaic regions so that said bridges are not only conductors, but also convert the light energy received.
In order to produce the architecture of such a photovoltaic module, the method for designing the semi-transparent photovoltaic module comprises the following steps:
1. Create a working file or image;
2. Choose the initial parameters;
3. Calculate the length of the annulus arcs;
4. Calculate the starting angles;
5. Calculate the stopping angles;
6. Draw the annulus arcs from the pre-calculated parameters;
7. Determine the placement bounds of the bridge interconnects;
8. Choose the placement of the bridge interconnects;
9. Trace the bridge interconnects.
Advantageously, the placement of the bridge interconnects is random within the bounds delimiting the placement of said bridge interconnects.
The photovoltaic module according to the invention, in particular in its circular geometry form, fits perfectly into electronic devices such as watches without being drastically affected by their flange.
This type of photovoltaic module according to the invention can also be integrated into any semi-transparent support such as a glazing, for example.
Unlike the case of
In order to simplify
The active photovoltaic regions (2) are separated by vacant spaces (3), which are transparent regions also in the form of rings. These transparent regions are openings made at least in the non-transparent materials constituting the active regions (metal electrode and absorber) in order to allow a maximum of light to pass. Advantageously, these openings are also provided in the transparent electrode. In this example, the active photovoltaic regions (2) have the same dimensions as the active annuli (1) shown in
In this example, the width CD (acronym for “critical dimension”) of the active photovoltaic regions (2) is defined as the difference between the radius Rmax of the circle (12) and the radius Rmin of the circle (11). Advantageously, this width is constant within the same ring. Preferably, all the active photovoltaic regions (2) have the same width. The latter is advantageously between 10 nm and 50 μm, which allows the network of active annuli to be imperceptible to the human eye. The line (R12) is defined equidistant from the interior (12) and exterior (11) lines. In the case of a ring, this line (R12) embodies the circle of mean radius R of the ring, such that R=(Rmax+Rmin)/2. The pitch Pa of the ring network is defined as the minimum distance between two mean radii R of adjacent rings. The pitch Pa of the active annuli can be different from the pitch Pt of the transparent annuli, in particular when the width CD is not constant. In the case of
From this single cell, it is possible to manufacture photovoltaic modules composed of several cells connected in series in order to increase the voltage across the terminals of the photovoltaic module. It is then necessary to create insulating regions within the architecture described in
Such an architecture can be obtained by the arrangement method explained below. Said method of arranging active photovoltaic regions and their interconnections is described for a semi-transparent module with four cells connected in series. In this method, the cells are formed by ring arcs interconnected by bridges. Each cell is therefore a succession of ring arcs, the mean radius R of which varies according to a constant pitch Pa. For a given radius, the four ring arcs with the same mean radius R have the same area (equal arc lengths and constant width CD).
The steps of the algorithm making it possible to design a possible structure of the photovoltaic module according to the invention are described below.
To simplify their reading, the architectures shown schematically in
By convention, in the remainder of the document, for a given mean radius R, the index i=1 is reserved for the ring arc whose starting angle Âd has the smallest value. The index i=2 is reserved for the ring arc that has the second smallest starting angle value. The method will be repeated to assign the following indices in the same way. For example, within
Âd
i,R_k;
=Âd
i−1,Rk+(2π/N)*(i−1) for i>1.
Step 4: Calculate stopping angles Âai,R_k for any integer k ranging from 1 to NB and any integer i ranging from 1 to N.
Let θk be the angle associated with the inter-arc length associated with the ring of mean radius Rk. This angle is defined by the relation: θk=Linter_arc/Rk. The stopping angle of the trace of the arc of index (i,Rk) is calculated according to the formula: Âai,R_k=Âdi+1,R_k−θk.
An example of an inter-arc angle θ2 (9) of mean radius R2 is shown in
Step 5: Trace ring arcs for any integer k ranging from 1 to NB and any integer i ranging from 1 to N.
The traces of the ring arcs of index (i,Rk) are done by considering the mean radius Rk as well as the width CD of the rings. The tracing begins for example from the starting angle Âdi,R_k and ends by considering the stopping angle Âai,R_k. Those skilled in the art will be able to trace these ring arcs by other methods using the parameters described above (starting angle, stopping angle, arc lengths, mean radius, maximum radius, minimum radius). Not all of the traces are therefore described here.
Step 6: Determine the placement bounds of the bridge interconnects.
To form a cell, it is necessary to connect, step by step, an annulus arc of mean radius Rk to an annulus arc of mean radius Rk+1, for k ranging from 1 to NB. In order to electrically optimize the cell, it is imperative to maximize the number of bridge interconnects. In order to achieve this condition, the choice of annulus arcs to be connected must be optimized. For example, the annulus arc of mean radius Rk and index 1 can be connected to the arc of circle of radius Rk+1 but of index 2. To find this optimization, one solution is to:
The bridge interconnects of width CD are placed between the bounds defined in step 7 so that the distance d between two bridge interconnects is at least equal to the pitch Pa. Advantageously, so that the density of bridges is not visible, the inter-bridge distance (d) is at least equal to ten times the value of the pitch Pa.
In particular, it is advantageous to place these bridges randomly. To this end, an angle Âaai_1 between the two bounds defined in step 7 is randomly found, and the first bridge interconnect is placed between the two arcs of circles defined by said bounds. We can repeat the step of finding a random angle from one of the bounds and the angle Âaai_1 previously calculated. If the desired angle satisfies the inter-bridge distance condition (d), the bridge interconnect is placed at this angle. The operation is repeated, and it stops when it is no longer possible to place bridges.
Nomenclature used for the description of all the figures:
The method that is the object of the invention can be implemented by considering a photovoltaic module based on amorphous silicon deposited on a glass substrate. The electrodes consist of a transparent conductive oxide on the front face and aluminum on the rear face. The stack of thin layers making up said photovoltaic module is protected by a transparent encapsulation material. Semi-transparency is achieved either by local and selective laser ablation of the material or by standard photolithography methods. The initial parameters for the design are as follows:
The present application is a continuation of, and claims priority benefit to, co-pending international application entitled, “SEMI-TRANSPARENT MULTI-CELL PHOTOVOLTAIC MODULE SUBJECTED TO RECURRENT PERIPHERAL SHADE,” International Application No. PCT/IB2019/054054, filed May 16, 2019, which is hereby incorporated by reference into the current application in its entirety.
Number | Date | Country | |
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Parent | PCT/IB2019/054054 | May 2019 | US |
Child | 17455123 | US |