The present invention relates to a semiconductor device, and more particularly, to a semiconductor device having a buried bit line and a method for fabricating the same.
As semiconductor devices are increasingly becoming more highly integrated, individual circuit patterns are becoming smaller in order to implement more semiconductor devices in the same area. That is, as the degree of integration of the semiconductor device increases, design rules for the components of the semiconductor device are decreasing. New structures and methods of manufacturing are therefore needed for maintaining or improving reliability and performance of such highly integrated semiconductor devices.
Various embodiments of the present invention are directed to a semiconductor device exhibiting improved reliability and performance, and to a method for fabricating the same.
According to an embodiment of the present invention, a semiconductor device comprises an active region formed in a substrate, the active region including flat surfaces and hole-shaped recess portions; upper-level plugs disposed over the flat surfaces; a spacer disposed between the upper-level plugs, the spacer including a trench exposing the hole-shaped recess portions; a lower-level plug filling the hole-shaped recess portions; and a buried conductive line disposed over the lower-level plug and partially filling the trench.
A semiconductor device according to an embodiment of the present invention comprises an active region formed in a substrate, the active region including flat surfaces and hole-shaped recess portions; a gate trench formed in the active region between the hole-shaped recess portions and the flat surfaces; a buried word line partially filling the gate trench; upper-level plugs disposed over the flat surfaces; a spacer disposed between the upper-level plugs, the spacer including a trench exposing the hole-shaped recess portions; a lower-level plug filling the hole-shaped recess portions; and a buried bit line disposed over the lower-level plug and partially filling the trench.
A method of fabricating a semiconductor device according to an embodiment of the present invention comprises forming a device isolation layer defining a plurality of active regions in a substrate; forming a conductive layer over the device isolation layer and the active regions; etching the conductive layer, and forming conductive lines extending in a first direction and trenches between the conductive lines; forming a spacer on sidewalls of the trenches; forming hole-shaped recess portions by etching active regions disposed below the trenches so that the active regions are aligned with the spacer; forming lower-level plugs filling the hole-shaped recess portions; forming buried bit lines over the lower-level plugs; and forming upper-level plugs between the buried bit lines by etching the conductive lines along a second direction, the second direction intersecting the first direction.
A method of fabricating a semiconductor device according to an embodiment of the present invention comprises forming an active region and a device isolation layer in a substrate; forming conductive lines over the active region and trenches extending between the conductive lines; etching the active region under the trenches to form hole shaped-recess portions; filling lower-level plugs in the hole-shaped recess portions; forming buried bit lines over the lower-level plugs; and etching the conductive lines to form upper-level plugs between the buried bit lines.
Since the present invention forms a buried bit line of a damascene structure, residues and seams of bit line contact plugs can be minimized.
In addition, the present invention can form the storage node contact plugs void-free.
In addition, since the present invention forms a spacer including a low-k material between the bit line and the storage node contact plugs, it is possible to reduce parasitic capacitance.
Various embodiments described herein will be described with reference to cross-sectional views, plan views and block diagrams, which are schematic views of the present invention. Therefore, the structures of the drawings may be modified by fabricating technology and/or tolerances. Various embodiments of the present invention are not limited to the specific structures shown in the drawings, but include any changes in the structures that may be produced according to the fabricating process. Also, any regions and shapes of regions illustrated in the drawings have schematic views, are intended to illustrate specific examples of structures of regions of the various elements, and are not intended to limit the scope of the invention.
Referring to
The semiconductor device 100 will be described in detail.
A device isolation layer 102 and an active region 103 may be formed in the substrate 101. A plurality of active regions 103 may be defined by the device isolation layers 102. The substrate 101 may be a material suitable for semiconductor processing. The substrate 101 may include a semiconductor substrate. The substrate 101 may be made of a material containing silicon. The substrate 101 may include silicon, monocrystalline silicon, polysilicon, amorphous silicon, silicon germanium, monocrystalline silicon germanium, polycrystalline silicon germanium, carbon doped silicon, a combination thereof, or multiple layers thereof. The substrate 101 may include other semiconductor materials such as germanium. The substrate 101 may include a III/V group semiconductor substrate, for example, a compound semiconductor substrate such as GaAs. The substrate 101 may include a silicon on insulator (SOI) substrate. The device isolation layer 102 may be formed by a shallow trench isolation (STI) process.
A gate trench 104 crossing the device isolation layer 102 and the active region 103 may be formed in the substrate 101. A gate dielectric layer 105 is formed on the surface of the gate trench 104. A first buried conductive line 106 partially filling the gate trench 104 may be formed on the gate dielectric layer 105. A buried capping layer 107 may be formed on the first buried conductive line 106. The upper surface of the first buried conductive line 106 may be at a level lower than the surface of the substrate 101, that is, the upper surface of the active region 103. The first buried conductive line 106 may be made of a low-resistivity metal material. Titanium nitride and tungsten may be sequentially stacked on the first buried conductive line 106. In another embodiment, the first buried conductive line 106 may be formed of titanium nitride only (TiN only). The first buried conductive line 106 may be referred to as a ‘buried gate electrode’ or a ‘buried word line’. The first buried conductive line 106 may extend in a first direction D1.
First and second impurity regions 108 and 109 may be formed on the substrate 101. The first and second impurity regions 108 and 109 may be spaced apart from each other by the gate trench 104. The first and second impurity regions 108 and 109 may be referred to as source/drain regions. The first and second impurity regions 108 and 109 may include N-type impurities such as arsenic (As) or phosphorus (P). Accordingly, the first buried conductive line 106 and the first and second impurity regions 108 and 109 may become cell transistors. The cell transistor may improve the short channel effect by the first buried conductive line 106. The first impurity region 108 may be positioned at a level lower than the upper surface of the active region 103. The first impurity region 108 may be shallower than the second impurity region 109.
A lower-level plug 110 may be formed over the substrate 101. The lower-level plug 110 may be connected to the first impurity region 108. A lower surface of the lower-level plug 110 may be at a lower level than upper surfaces of the device isolation layer 102 and the active region 103. The lower-level plug 110 may be embedded in the substrate 101. The lower-level plug 110 may include an epitaxial silicon layer. A second buried conductive line 111 may be formed on the lower-level plug 110. A buried hard mask 112 may be formed on the second buried conductive line 111. The stacked structure of the lower-level plug 110, the second buried conductive line 111, and the buried hard mask 112 may be referred to as a damascene structure DBL. The second buried conductive line 111 may extend along the second direction D2 crossing the first buried conductive lines 106. A portion of the second buried conductive line 111 may be connected to the lower-level plug 110. The second buried conductive line 111 may include a metal material such as tungsten. The buried hard mask 112 may include a dielectric material such as silicon nitride.
A spacer 113 may be formed on a sidewall of the damascene structure DBL. The spacer 113 may be extended on and parallel to both sidewalls of the damascene structure DBL. The spacer 113 may include a dielectric layer or a stack of different dielectric layers. For example, the spacer 113 may include an oxide, a nitride, a low-k material, or a combination thereof. The spacer 113 may include nitride and a low-k material over the nitride. The low-k material may include SiCO, SiCN, SiOCN, SiBN or SiBCN. The spacer 113 may include NKOK, NKN, NKON, NK, NO or KO, where K may refer to a low-k material, N may refer to a nitride, and O may refer to an oxide. In another embodiment, the spacer 113 may include an air gap. For example, the spacer 113 may have an N-A-N structure in which an air gap is positioned between nitrides.
A vertical plug SNC may be formed between adjacent damascene structures DBL. The vertical plug SNC may be connected to the second impurity region 109. The vertical plug SNC may include an upper-level plug 114 and a top-level plug 115. The vertical plug SNC may further include an ohmic contact layer (not shown) between the upper-level plug 114 and the top-level plug 115. The ohmic contact layer may include metal silicide. For example, the upper-level plug 114 may include polysilicon, and the top-level plug 115 may include a metal nitride, a metal material, or a combination thereof.
When viewed in a direction parallel to the damascene structure DBL, the plug isolation layer 116 may be formed between the neighboring vertical plugs SNC. The plug isolation layer 116 may be formed between neighboring damascene structures DBL. The neighboring vertical plugs SNC may be spaced apart by the plug isolation layer 116. The plurality of plug isolation layers 116 and the plurality of vertical plugs SNC may be alternately disposed between neighboring damascene structures DBL.
A memory element (not shown) may be formed on the top-level plug 115. The memory element may include a capacitor including a storage node. The storage node may include a pillar type. Although not shown, a dielectric layer and a plate node may be further formed on the storage node. The storage node may be a cylinder type as well as a pillar type.
The damascene structure DBL may be referred to as a damascene bit line structure, and the vertical plug SNC may be referred to as a storage node contact plug. The lower-level plug 110 may be referred to as a bit line contact plug, and the second buried conductive line 111 may be referred to as a bit line. The buried hard mask 114 may be referred to as a bit line hard mask.
A trench extending in the second direction D2 may be defined by the spacers 113 disposed between the upper-level plugs 114 arranged in the first direction D1. The damascene structure DBL extending in the second direction D2 may be buried in the trench. The second buried conductive line 111 may include an active conductive line 111A contacting the lower-level plug 110 and a passing conductive line 111P extending from the active conductive line 111A. The spacer 113 may extend along sidewalls and a bottom surface of the passing conductive line 111P. The spacer 113 may extend along sidewalls of the active conductive line 111A and surround sidewalls of the lower-level plug 110. Active conductive lines 111A and passing conductive lines 111P may be alternately disposed along the A-A′ direction. The bottom surface of the passing conductive line 111P of the second buried conductive line 111 may be at a higher level than the bottom surface of the lower-level plug 110. The bottom surface of the active conductive line 111A of the second buried conductive line 111 may be at a higher level than the bottom surface of the spacer 113. The bottom surface of the spacer 113 may be at a higher level than the bottom surface of the lower-level plug 110. The bottom surface of the spacer 113 may be at a lower level than the top surface of the upper-level plug 114.
The active region 103 may be formed in the substrate 101, and may include a hole-shaped recess portion 108R and protrusions 109P. A flat surface may be provided between the hole-shaped recess portion 108R and the protrusions 109P. The flat surface may refer to the upper surface of the device isolation layer 102. The upper surface of the hole-shaped recess portion 108R may be located at a lower horizontal level than the flat surface, and the upper surface of the protrusions 109P may be located at a higher horizontal level than the flat surface. The upper surface of the hole-shaped recess portion 108R may be located at a lower horizontal level than the upper surface of the device isolation layer 102, and the upper surface of the protrusions 109P may be located at a higher horizontal level than the upper surface of the device isolation layer 102. The upper surface of the hole-shaped recess portion 108R may be located at a lower horizontal level than the upper surface of the buried capping layer 107, and the upper surface of the protrusion 109P may be located at a higher horizontal level than the upper surface of the buried capping layer 107. The upper surface of the device isolation layer 102 and the upper surface of the buried capping layer 107 may be located at the same horizontal level. The upper surface of the protrusions 109P may also include a flat surface. The flat surface of the protrusions 109P may be located at a higher horizontal level than the upper surface of the device isolation layer 102.
The active region 103 may include first impurity regions 108 and second impurity regions 109. An upper surface of the first impurity regions 108 may be located at a lower horizontal level than a top surface of the device isolation layer 102, and an upper surface of the second impurity regions 109 may be located at a higher horizontal level than an upper surface of the device isolation layer 102. Upper surfaces of the first impurity regions 108 may be positioned at a lower horizontal level than upper surfaces of the second impurity regions 109. Bottom surfaces of the first impurity regions 108 and bottom surfaces of the second impurity regions 109 may be positioned at the same horizontal level. In another embodiment, bottom surfaces of the first impurity regions 108 may be positioned at a lower horizontal level than bottom surfaces of the second impurity regions 109. The height (or depth) of the first impurity regions 108 may be smaller than the height (or depth) of the second impurity regions 109.
Each of the first impurity regions 108 may include a hole-shaped recess portion 108R, and the lower-level plug 110 may contact the hole-shaped recess portion 108R of the first impurity region 108. The contact area between the lower-level plug 110 and the first impurity region 108 may be increased by the hole-shaped recess portion 108R.
Each of the second impurity regions 109 may include a protrusion 109P, and the upper-level plug 114 may cover the protrusions 109P. For example, the upper-level plug 114 may contact the upper surface and sidewalls of the protrusion 109P. The contact area between the upper-level plug 114 and the second impurity region 109 may be increased by the protrusion 109P.
The upper-level plug 114 may extend to the upper surface of the device isolation layer 102 while contacting the protrusion 109P of the second impurity region 109. The bottom surfaces of the upper-level plugs 114 may contact the protrusions 109P and the device isolation layer 102 at the same time. A step may be formed between the protrusions 109P and the device isolation layer 102.
In the lower-level plug 110, a portion in contact with the first buried conductive line 111 may have a greater line width than a portion filling the hole-shaped recess portion 108R.
The lower-level plug 110 and the upper-level plug 114 may include an epitaxial silicon layer.
As shown in
Next, a gate trench 15 in the substrate 11, a gate dielectric layer 16 covering the bottom surface and sidewalls of the gate trench 15, and buried word line partially filling the gate trench 15 on the gate dielectric layer 16 may be sequentially formed.
First, a gate trench 15 may be formed in the substrate 11. The gate trench 15 may have a line shape crossing the active regions 13 and the device isolation layer 12. The gate trench 15 may be formed by forming the hard mask layer 14 on the substrate 11 and by performing an etching process using the hard mask layer 14 as an etch barrier. The hard mask layer 14 may include silicon oxide. The hard mask layer 14 may include tetra ethyl ortho silicate (TEOS). The bottom surface of the gate trench 15 may be located at a higher level than the bottom surface of the device isolation layer 12.
Although not shown, a portion of the device isolation layer 12 may be recessed to protrude the active region 13 under the gate trench 15. Accordingly, a fin region (reference numeral omitted) may be formed under the gate trench 15. The fin region may be a part of the channel region.
Next, a gate dielectric layer 16 may be formed on the bottom surface and sidewalls of the gate trench 15. Before forming the gate dielectric layer 16, any etch damage on the surface of the gate trench may be cured. For example, after the sacrificial oxide is formed on the surface of the gate trench 15 by thermal oxidation, the sacrificial oxide may be removed.
The gate dielectric layer 16 may be formed by a thermal oxidation process. For example, the gate dielectric layer 16 may be formed by oxidizing the bottom and sidewalls of the gate trench 15.
In another embodiment, the gate dielectric layer 16 may be formed by a deposition method such as chemical vapor deposition (CVD) or atomic layer deposition (ALD). The gate dielectric layer 16 may include a high-k material, oxide, nitride, oxynitride, or a combination thereof. The high-k material may include a hafnium-containing material. The hafnium-containing material may include hafnium oxide, hafnium silicon oxide, hafnium silicon oxynitride, or a combination thereof. In another embodiment, the high-k material may include lanthanum oxide, lanthanum aluminum oxide, zirconium oxide, zirconium silicon oxide, zirconium silicon oxynitride, aluminum oxide, and a combination thereof.
In another embodiment, the gate dielectric layer 16 may be formed by depositing a liner polysilicon layer and then radically oxidizing the liner polysilicon layer.
In yet another embodiment, the gate dielectric layer 16 may be formed by forming a liner silicon nitride layer and then radically oxidizing the liner silicon nitride layer after.
Next, a buried word line 17 may be formed on the gate dielectric layer 16. To form the buried word line 17, a recessing process may be performed after a conductive layer (not shown) is formed to fill the gate trench 15. The recessing process may include performing an etch back process or sequentially performing a chemical mechanical polishing (CMP) process and an etch back process. The buried word line 17 may have a recessed shape partially filling the gate trench 15. That is, the upper surface of the buried word line 17 may be at a lower level than the upper surface of the active region 13. The buried word line 17 may include a metal, a metal nitride, or a combination thereof. For example, the buried word line 17 may be formed of titanium nitride (TiN), tungsten (W), or titanium nitride/tungsten (TiN/W) stack. The titanium nitride/tungsten (TiN/W) stack may have a structure in which titanium nitride is conformally formed and then the gate trench 15 is partially filled with tungsten. As the buried word line 17, titanium nitride may be used alone, and this may be referred to as the buried word line 17 having a “TiN Only” structure. A double gate structure of a titanium nitride/tungsten (TiN/W) stack and a polysilicon layer may be used as the buried word line 17. The buried word line 17 may correspond to the first buried conductive line 106 as referenced in
As shown in
As shown in
After the formation of the buried capping layer 18, impurity regions 19 and 20 may be formed. The impurity regions 19 and 20 may be formed by a doping process such as implantation. The impurity regions 19 and 20 may include a first impurity region 19 and a second impurity region 20. The first and second impurity regions 19 and 20 may be doped with impurities of the same conductivity type. The first and second impurity regions 19 and 20 may have the same depth. In another embodiment, the first impurity region 19 may be deeper than the second impurity region 20. The first and second impurity regions 19 and 20 may be referred to as source/drain regions. The first impurity region 19 may be a region to which a lower-level plug is to be connected, and the second impurity region 20 may be a region to which a storage node contact plug is to be connected. The first impurity region 19 and the second impurity region 20 may be disposed in different active regions 13. Also, the first impurity region 19 and the second impurity region 20 may be spaced apart from each other by the gate trenches 15 and disposed in each of the active regions 13.
A cell transistor of the memory cell may be formed by the buried word line 17 and the first and second impurity regions 19 and 20.
As shown in
As described above, a portion of the active region 13 may protrude by recessing a portion of the gate dielectric layer 16 and a portion of the device isolation layer 12. For example, upper regions 19P of the first impurity regions 19 and upper regions 20P of the second impurity regions 20 may protrude. Hereinafter, upper regions of the first impurity regions 19 are abbreviated as first protrusions 19P, and upper regions of the second impurity regions 20 are abbreviated as second protrusions 20P. Upper surfaces of the first protrusions 19P and upper surfaces of the second protrusions 20P may be at the same level. Upper surfaces of the first protrusions 19P and upper surfaces of the second protrusions 20P may be at a higher level than upper surfaces of the gate dielectric layer 16 and upper surfaces of the device isolation layer 12. Sidewalls of the first protrusions 19P and sidewalls of the second protrusions 20P may be non-covered by the gate dielectric layer 16 and the device isolation layer 12.
The second impurity regions 20 have an elevated source/drain structure by the second protrusions 20P, and accordingly, the depth of the buried word line 17 and the depth of the device isolation layer 12 may be reduced.
As shown in
Next, a first mask layer 22 may be formed on the initial conductive layer 21A. When viewed from top, the first mask layer 22 may have a line shape extending in either direction. The first mask layer 22 may include a photoresist pattern or a hard mask material.
As shown in
The first line-shaped recess portions 19R may be formed by etching the first protrusions 19P, and the second line-shaped recess portions 20R may be formed by partially etching the second protrusions 20P. During the formation of the first and second line-shaped recess portions 19R and 20R, portions of the device isolation layer 12 may be etched by being self-aligned with the sidewalls of the conductive lines 21B.
As shown in
A sacrificial material 24 may be formed on the spacer layer 23. The sacrificial material 24 may include a carbon-containing material. The sacrificial material 24 may be formed by a spin-on coating method. The sacrificial material 24 may include a carbon layer formed by a spin-on coating method. The sacrificial material 24 may fill the trenches 21T between neighboring conductive lines 21B and on the spacer layer 23.
As shown in
The sacrificial material 24 and the spacer layer 23 may be etched using the second mask layer 25. Accordingly, hole-shaped openings 26 may be formed between the conductive lines 21B. The hole-shaped openings 26 may be formed as portions of the sacrificial material 24 are etched between the conductive lines 21B. The hole-shaped openings 26 may expose the first impurity regions 19. Subsequently, the exposed first impurity regions 19 may be recessed to a predetermined depth, and thus, hole-shaped recess portions 27 may be formed. The hole-shaped recess portions 27 may be formed by being self-aligned with sidewalls of the spacer layer 23.
As shown in
Next, lower-level plugs 28 filling the hole-shaped recess portions 27 may be formed. The lower-level plugs 28 may be formed by selective epitaxial growth (SEG). The lower-level plugs 28 may include an epitaxial silicon layer. The lower-level plugs 28 may include an epitaxial silicon layer doped with phosphorus. For example, the lower-level plugs 28 may include SEG SiP. In this way, the lower-level plugs 28 may be formed void-free by selective epitaxial growth. In another embodiment, the lower-level plugs 28 may be formed by deposition and etch back processes of a polysilicon layer. The upper surface of the lower-level plugs 28 may be at a higher level than the bottom surface of the spacer layer 23. Upper surfaces of the lower-level plugs 28 may be at a lower level than upper surfaces of the device isolation layer 12 and upper surfaces of the second impurity region 20.
As such, the lower-level plugs 28 may be embedded in the substrate 11. Accordingly, the lower-level plugs 28 may have a recessed shape disposed at a lower level than the upper surface of the substrate 11, that is, the upper surface of the second impurity region 20. The lower-level plugs 28 and the conductive lines 21B may be spaced apart from each other by the spacer layer 23. The upper surface of the lower-level plugs 28 and the bottom surface of the conductive lines 21B may not be disposed at the same horizontal level. Bottom surfaces of the conductive lines 21B may be disposed at a higher horizontal level than the upper surface of the lower-level plugs 28.
The second impurity regions 20 and the lower-level plugs 28 may not contact each other. The lower-level plugs 28 may not be formed on the second impurity region 20 covered by the sacrificial material 24 and the spacer layer 23.
As shown in
The buried bit line 29 includes a metal-containing material. The buried bit line 29 may include a metal, a metal nitride, a metal silicide, or a combination thereof. In this embodiment, the buried bit line 29 may include tungsten (W). In another embodiment, the buried bit line 29 may include a stack of titanium nitride and tungsten (TiN/W). In this case, the titanium nitride may serve as a barrier.
The buried bit lines 29 may include an active bit line 29A and a passing bit line 29P. The active bit line 29A may refer to a portion connected to the lower-level plug 28, and the passing bit line 29P may refer to a portion not connected to the lower-level plug 28. Sidewalls and a bottom surface of the passing bit line 29P may be covered by the spacer layer 23. Sidewalls of the active bit line 29A may be covered by the spacer layer 23, and a bottom surface of the active bit line 29A may be connected to the lower-level plug 28. An ohmic contact layer (not shown) between the lower-level plugs 28 and the buried bit line 29 may be further included. The ohmic contact layer may include metal silicide.
As shown in
When viewed from a top view, the bit line structures and the conductive lines 21B may be parallel to each other. The conductive lines 21B may be disposed between the bit line structures.
As shown in
The conductive lines 21B may be selectively etched using the third mask layer 31. Accordingly, island-shaped conductive patterns 21C may be formed. Isolation grooves 32 may be formed between the island-shaped conductive patterns 21C. The island-shaped conductive patterns 21C may cover upper surfaces and sidewalls of the second protrusions 20P. Some island-shaped conductive patterns 21C may extend to be disposed on the device isolation layer 12.
As shown in
As shown in
Portions of the spacer 23 exposed by the island-shaped conductive patterns 21D may be trimmed to form a trim portion 34.
As shown in
Through the above-described series of processes, the conductive lines 21B of
As shown in
As shown in
Referring to
According to the above-described embodiment, it is possible to prevent residues and seams of the bit line contact plugs. In addition, voids in the storage node contact plug can be suppressed.
The present invention described above is not limited to the above-described embodiments and the accompanying drawings, and it will be apparent to those skilled in the art that various substitutions, modifications, and changes may be made thereto without departing from the spirit and scope of the present invention.
Number | Date | Country | Kind |
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10-2021-0130237 | Sep 2021 | KR | national |
This application is a division of U.S. patent application Ser. No. 17/719,990 filed on Apr. 13, 2022, which claims priority to and the benefit of Korean Patent Application No. 10-2021-0130237, filed on Sep. 30, 2021, which is incorporated herein by reference in its entirety.
Number | Date | Country | |
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Parent | 17719990 | Apr 2022 | US |
Child | 18542779 | US |