The present invention relates to a display device including an oxide semiconductor.
A thin film transistor formed over a flat plate such as a glass substrate is manufactured using amorphous silicon or polycrystalline silicon, as typically seen in a liquid crystal display device. A thin film transistor manufactured using amorphous silicon has low field effect mobility, but such a transistor can be formed over a glass substrate with a larger area. On the other hand, a thin film transistor manufactured using polycrystalline silicon has high field effect mobility, but a crystallization step such as laser annealing is necessary and such a transistor is not always suitable for a larger glass substrate.
In view of the foregoing, attention has been drawn to a technique by which a thin film transistor is manufactured using an oxide semiconductor, and such a transistor is applied to an electronic device or an optical device. For example, Patent Document 1 and Patent Document 2 disclose a technique by which a thin film transistor is manufactured using zinc oxide (ZnO) or an In—Ga—Zn—O based oxide semiconductor as an oxide semiconductor film and such a transistor is used as a switching element or the like of an image display device.
A thin film transistor in which a channel formation region is formed using an oxide semiconductor has characteristics as follows: the operation speed is higher than that of a thin film transistor including amorphous silicon and the manufacturing process is simpler than that of a thin film transistor including polycrystalline silicon. That is, the use of an oxide semiconductor makes it possible to manufacture a thin film transistor with high field effect mobility even at low temperatures of 300° C. or lower.
In order to take advantage of the features of a display device including an oxide semiconductor, which is superior in operating characteristics and capable of manufacture at low temperatures, a protective circuit and the like including appropriate structures are necessary. Moreover, it is important to ensure the reliability of the display device including an oxide semiconductor.
An object of an embodiment of the present invention is to provide a structure which is suitable as a protective circuit.
In a display device intended for a variety of purposes manufactured by stacking, in addition to an oxide semiconductor, an insulating film and a conductive film, an object of an embodiment of the present invention is to prevent a defect due to peeling of a thin film.
An embodiment of the present invention is a display device in which a protective circuit is formed using a non-linear element including an oxide semiconductor. This non-linear element includes a combination of oxide semiconductors with different oxygen contents.
An illustrative embodiment of the present invention is a display device which includes scan lines and signal lines provided over a substrate having an insulating surface so as to intersect with each other, a pixel portion in which pixel electrodes are arranged in matrix, and a non-linear element formed from an oxide semiconductor in a region outside the pixel portion. The pixel portion includes a thin film transistor in which a channel formation region is formed in a first oxide semiconductor layer. The thin film transistor in the pixel portion includes a gate electrode connected to the scan line, a first wiring layer which is connected to the signal line and which is in contact with the first oxide semiconductor layer, and a second wiring layer which is connected to the pixel electrode and which is in contact with the first oxide semiconductor layer. Moreover, the non-linear element is provided between the pixel portion and a signal input terminal disposed at the periphery of the substrate. The non-linear element includes a gate electrode; a gate insulating layer covering the gate electrode; a pair of a first wiring layer and a second wiring layer each of which is formed by stacking a conductive layer and a second oxide semiconductor layer and whose end portions overlap with the gate electrode over the gate insulating layer; and a first oxide semiconductor layer which overlaps with at least the gate electrode and which is in contact with the gate insulating layer, side face portions and part of top face portions of the conductive layer and side face portions of the second oxide semiconductor layer in the first wiring layer and the second wiring layer. The gate electrode of the non-linear element is connected to the scan line or the signal line and the first wiring layer or the second wiring layer of the non-linear element is connected to the gate electrode via a third wiring layer so that the potential of the gate electrode is applied to the first wiring layer or the second wiring layer.
An illustrative embodiment of the present invention is a display device which includes scan lines and signal lines provided over a substrate having an insulating surface so as to intersect with each other, a pixel portion including pixel electrodes arranged in matrix, and a protective circuit in a region outside the pixel portion. The pixel portion includes a thin film transistor in which a channel formation region is formed in a first oxide semiconductor layer. The thin film transistor in the pixel portion includes a gate electrode connected to the scan line, a first wiring layer which is connected to the signal line and which is in contact with the first oxide semiconductor layer, and a second wiring layer which is connected to the pixel electrode and which is in contact with the first oxide semiconductor layer. In the region outside the pixel portion, a protective circuit for connecting the scan line and a common wiring to each other and a protective circuit for connecting the signal line and a common wiring to each other are provided. The protective circuit includes a non-linear element, which includes a gate electrode; a gate insulating layer covering the gate electrode; a pair of a first wiring layer and a second wiring layer which is formed by stacking a conductive layer and a second oxide semiconductor layer and whose end portions overlap with the gate electrode over the gate insulating layer; and a first oxide semiconductor layer which overlaps with at least the gate electrode and which is in contact with the gate insulating layer, side face portions and part of top face portions of the conductive layer and side face portions of the second oxide semiconductor layer in the first wiring layer and the second wiring layer. Moreover, the gate electrode of the non-linear element is connected to the first wiring layer or the second wiring layer via a third wiring layer.
Here, the first oxide semiconductor layer includes oxygen at higher concentration than the second oxide semiconductor layer. That is, the first oxide semiconductor layer is oxygen-excess type, while the second oxide semiconductor layer is oxygen-deficiency type. The second oxide semiconductor layer has n-type conductivity and the first oxide semiconductor layer has lower electrical conductivity than the second oxide semiconductor layer. The first oxide semiconductor layer and the second oxide semiconductor layer are non-single-crystal; preferably, the first oxide semiconductor layer has an amorphous structure and the second oxide semiconductor layer includes a crystal grain (nanocrystal) in an amorphous structure in some cases.
Note that the ordinal numbers such as “first” and “second” in this specification are used for convenience and do not denote the order of steps and the stacking order of layers. In addition, the ordinal numbers in this specification do not denote particular names which specify the invention.
In this specification, a semiconductor film formed from an oxide semiconductor including In, Ga, and Zn is also referred to as “an IGZO semiconductor film” and a semiconductor layer formed from such an oxide semiconductor is also referred to as “an IGZO semiconductor layer.”
According to an embodiment of the present invention, a display device having a structure suitable as a protective circuit can be provided by forming the protective circuit with use of a non-linear element including an oxide semiconductor. When the non-linear element has a stacked structure where the gate insulating layer and the oxide semiconductor layer are in contact with each other, a defect of a protective circuit which is caused by peeling of a thin film can be prevented.
Hereinafter, embodiments of the present invention are described below with reference to the drawings. The present invention is not limited to the description below and it is easily understood by those skilled in the art that the mode and details can be changed variously without departing from the scope and spirit of the present invention. Therefore, the present invention should not be interpreted as being limited to what is described in the embodiments described below. Note that a reference numeral denoting the same portion in all figures is used in common in the structures of the present invention which is explained below.
In Embodiment 1, an example of a display device including a pixel portion and a protective circuit including a non-linear element provided around the pixel portion is described with reference to drawings.
The pixel portion 17 includes a plurality of pixels 18 arranged in matrix. The pixel 18 includes a pixel transistor 19 connected to the scan line 13 and the signal line 14, a storage capacitor portion 20, and a pixel electrode 21.
In the pixel structure illustrated here, one electrode of the storage capacitor portion 20 is connected to the pixel transistor 19 and the other electrode is connected to a capacitor line 22. Moreover, the pixel electrode 21 forms one electrode which drives a display element (such as a liquid crystal element, a light-emitting element, or a contrast medium (electronic ink)). The other electrode of such a display element is connected to a common terminal 23.
A protective circuit is provided between the pixel portion 17, and a scan line input terminal 11 and a signal line input terminal 12. In Embodiment 1, a plurality of protective circuits is provided. Therefore, even though surge voltage due to static electricity and the like is applied to the scan line 13, the signal line 14, and a capacitor bus line 27, the pixel transistor 19 and the like are not broken. Accordingly, the protective circuit has a structure for releasing charge to a common wiring 29 or a common wiring 28 when surge voltage is applied to the protective circuit.
In Embodiment 1, a protective circuit 24 is provided on the scan line 13 side, a protective circuit 25 is provided on the signal line 14 side, and a protective circuit 26 is provided on the capacitor bus line 27 side. Needless to say, the structures of the protective circuits are not limited to those above.
A first terminal (gate) and a third terminal (drain) of the non-linear element 30 are connected to the scan line 13, and a second terminal (source) thereof is connected to the common wiring 29. A first terminal (gate) and a third terminal (drain) of the non-linear element 31 are connected to the common wiring 29, and a second terminal (source) thereof is connected to the scan line 13. That is, the protective circuit illustrated in
In the protective circuit illustrated in
Note that in
The non-linear element 30a and the non-linear element 30b include a gate electrode 15 and a gate electrode 16, respectively, which are formed using the same layer as the scan line 13. A gate insulating layer 37 is formed over the gate electrode 15 and the gate electrode 16. A first wiring layer 38 and a second wiring layer 39 are provided over the gate insulating film 37 so as to face with each other over the gate electrode 15. Note that the non-linear element 30a and the non-linear element 30b have the same structure in the main portion.
A first oxide semiconductor layer 36 is provided so as to cover a region between the first wiring layer 38 and the second wiring layer 39 which face with each other. That is, the first oxide semiconductor layer 36 is provided so as to overlap with the gate electrode 15 and be in contact with the gate insulating layer 37, and side face portions and part of top face portions of and the first wiring layer 38 and the second wiring layer 39. Here, the first wiring layer 38 and the second wiring layer 39 each have a structure in which a second oxide semiconductor layer 40 and a conductive layer 41 are stacked in that order from the gate insulating layer 37 side. The gate insulating layer 37 is formed from an oxide such as silicon oxide or aluminum oxide.
The first oxide semiconductor layer 36 has higher oxygen concentration than the second oxide semiconductor layer 40. In other words, the first oxide semiconductor layer 36 is oxygen-excess type, while the second oxide semiconductor layer 40 is oxygen-deficiency type. Since the donor-type defects can be reduced by increasing the oxygen concentration of the first oxide semiconductor layer 36, there are advantageous effects of longer carrier lifetime and higher mobility. On the other hand, when the oxygen concentration of the second oxide semiconductor layer 40 is made lower than that of the first oxide semiconductor layer 36, the carrier concentration can be increased and the second oxide semiconductor layer 40 can be utilized for forming a source region and a drain region.
An oxide semiconductor is non-single-crystal, and preferably, the first oxide semiconductor layer 36 has an amorphous structure and the second oxide semiconductor layer 40 includes a crystal grain (nanocrystal) in an amorphous structure in some cases. Then, the first oxide semiconductor layer 36 has a characteristic that the electrical conductivity thereof is lower than that of the second oxide semiconductor layer 40. Therefore, the second oxide semiconductor layers 40 used as the components of the first wiring layer 38 and the second wiring layer 39 in the non-linear element 30a and the non-linear element 30b of Embodiment 1 can have functions similar to those of a source region and a drain region of a transistor.
The first oxide semiconductor layer 36 and the second oxide semiconductor layer 40 are formed from a non-single-crystal oxide semiconductor, typically, zinc oxide (ZnO), or an oxide semiconductor material including In, Ga, and Zn.
End portions of the first wiring layer 38 and the second wiring layer 39 overlap with the gate electrode 15, and the first wiring layer 38 and the second wiring layer 39 each have a structure in which the second oxide semiconductor layer 40 and the conductive layer 41 are stacked in that order from the gate insulating layer 37 side. The second oxide semiconductor layer 40 is provided in contact with the gate insulating layer 37 and the first oxide semiconductor layer 36 is provided in contact with side face portions of the second oxide semiconductor layer 40 and side face portions and part of top face portions of the conductive layer 41. Over the gate insulating layer 37, the oxide semiconductor layers having different physical properties as above are bonded to each other. When the non-linear element 30a and the non-linear element 30b have such a bonding structure, the operation can be made stable as compared to a non-linear element having Schottky junction formed in the case where the first wiring layer 38 and the second wiring layer 39 are formed using only metal layers. Moreover, the amount of junction leakage can be reduced and the characteristics of the non-linear element 30a and the non-linear element 30b can be improved.
The adhesion between the gate insulating layer 37, and the first oxide semiconductor layer 36 and the second oxide semiconductor layer 40 is favorable and peeling of a thin film does not easily occur. That is, the first wiring layer 38 and the second wiring layer 39 are in close contact with each other as compared with the case where a metal wiring of aluminum or the like is directly formed in contact with the gate insulating layer 37; therefore, a defect of a protective circuit which is caused by peeling of a thin film can be prevented.
An interlayer insulating layer 42 is provided over the first oxide semiconductor layer 36. The interlayer insulating layer 42 is formed from an oxide such as silicon oxide or aluminum oxide. When silicon nitride, aluminum nitride, silicon oxynitride, or aluminum oxynitride is stacked over silicon oxide or aluminum oxide, the function as the protective film can be enhanced.
In any case, when the interlayer insulating layer 42 being in contact with the first oxide semiconductor layer 36 is an oxide, it is possible to prevent oxygen from being extracted from the first oxide semiconductor layer 36 and prevent the first oxide semiconductor layer 36 from changing into an oxygen-deficiency type.
The interlayer insulating layer 42 is provided with a contact hole 43 where the scan line 13 formed using the same layer as the gate electrode 15 is connected to a third terminal (drain) of the non-linear element 30a. This connection is made by a third wiring layer 44 formed using the same material as the pixel electrode of the pixel portion. The third wiring layer 44 is formed from a material which is used for forming a transparent electrode, for example, from indium tin oxide (ITO), zinc oxide (ZnO), tin oxide (SnO2), or the like. Thus, the third wiring layer 44 has higher resistance than a wiring formed from a metal material. When the protective circuit includes the wirings including such a resistance component, it is possible to prevent an excessive amount of current from flowing through the non-linear element 30a and the non-linear element 30a from being destroyed.
Although
According to Embodiment 1, by the provision of the protective circuit including the non-linear element formed from the oxide semiconductor in this manner, a display device having a structure which is suitable as a protective circuit can be provided. Further, a defect of a protective circuit which is caused by peeling of a thin film can be prevented.
In Embodiment 2, an embodiment of a process for manufacturing the protective circuit illustrated in
In
Next, a conductive layer is formed entirely over the substrate 100. After that, a resist mask is formed by a first photolithography process, and an unnecessary portion is removed by etching to form wirings and an electrode (such as a gate wiring including a gate electrode 101, a capacitor wiring, and a terminal). At this time, the etching is performed so that at least an end portion of the gate electrode 101 is tapered. Also, a scan line 108 is formed using the same layer as the gate electrode 101.
The gate wiring including the gate electrode 101, the capacitor wiring, and the terminal of a terminal portion are desirably formed from a low-resistance conductive material such as aluminum (Al) or copper (Cu); however, since aluminum alone has disadvantages such as low heat resistance and a tendency to be corroded, it is used in combination with a conductive material having heat resistance. As the conductive material having heat resistance, an element selected from titanium (Ti), tantalum (Ta), tungsten (W), molybdenum (Mo), chromium (Cr), and neodymium (Nd), an alloy containing the above element as its component, an alloy film in which some of the above elements are combined, or a nitride containing the above element as its component may be used.
Subsequently, a gate insulating layer 102 is formed entirely over the gate electrode 101. The gate insulating layer 102 is formed by a sputtering method or the like to a thickness of 50 to 250 nm.
For example, a silicon oxide film is formed by a sputtering method to a thickness of 100 nm as the gate insulating layer 102. Needless to say, the gate insulating layer 102 is not limited to such a silicon oxide film and may be a single layer or a stack of layers including another insulating film such as a silicon oxynitride film, a silicon nitride film, an aluminum oxide film, or a tantalum oxide film.
Next, a second oxide semiconductor film is formed over the gate insulating layer 102 by a sputtering method. Here, sputtering deposition is performed under the condition where a target includes indium oxide (In2O3), gallium oxide (Ga2O3), and zinc oxide (ZnO) at a composition ratio of 1:1:1 (═In2O3:Ga2O3:ZnO), the pressure in a deposition chamber is set at 0.4 Pa, the electric power is set at 500 W, the deposition temperature is set to room temperature, and the argon gas flow rate is set at 40 sccm. Thus, a semiconductor film including In, Ga, Zn, and oxygen is formed as the second oxide semiconductor film. Although the target where the composition ratio is In2O3:Ga2O3:ZnO=1:1:1 is used intentionally, an oxide semiconductor film including a crystal grain which has a size of 1 nm to 10 nm just after the deposition is often obtained. It can be said that the presence or absence of crystal grains and the density of crystal grains can be controlled and the diameter of the crystal grain can be adjusted within 1 nm to 10 nm, all by adjusting as appropriate, the deposition condition of reactive sputtering, such as the target composition ratio, the deposition pressure (0.1 Pa to 2.0 Pa), the electric power (250 W to 3000 W: 8 inchesϕ), the temperature (room temperature to 100° C.), and the like. The thickness of the second oxide semiconductor film is set to 5 nm to 20 nm. Needless to say, in the case where the film includes crystal grains, the size of the crystal grain does not exceed the film thickness. In Embodiment 2, the second oxide semiconductor film has a thickness of 5 nm.
Next, a conductive film is formed from a metal material over the second oxide semiconductor film by a sputtering method or a vacuum evaporation method. As the material of the conductive film, there are an element selected from Al, Cr, Ta, Ti, Mo, and W, an alloy including the above element, an alloy film in which some of the above elements are combined, and the like. Here, the conductive film has a three-layer structure in which a Ti film is formed, an aluminum (Al) film is stacked over the Ti film, and another Ti film is stacked over the Al film. Alternatively, the conductive film may have a two-layer structure in which a titanium film is stacked over an aluminum film. Further alternatively, the conductive film may have a single-layer structure of an aluminum film including silicon or a titanium film.
The gate insulating layer, the second oxide semiconductor film, and the conductive film can be formed by a sputtering method successively without exposure to the air by changing the gas introduced to the chamber and the target set in the chamber as appropriate. The successive deposition without exposure to the air can prevent impurity mixture. In the case of successive deposition without exposure to the air, a manufacturing apparatus of multichamber type is preferable.
Next, a second photolithography process is performed to form a resist mask, and an unnecessary portion of the conductive film is removed by etching. Thus, a source electrode layer 105a and a drain electrode layer 105b are formed. The etching may be wet etching or dry etching. Here, dry etching is performed using as a reactive gas, a mixed gas of SiCl4, Cl2, and BCl3 to etch the conductive film in which the Ti film, the Al film, and the Ti film are stacked in this order. Thus, the source electrode layer 105a and the drain electrode layer 105b are formed.
Next, the second oxide semiconductor film is etched in a self-aligning manner by using the source electrode layer 105a and the drain electrode layer 105b as masks. Here, wet etching is performed using ITO07N (product of Kanto Chemical Co., Inc.) to remove an unnecessary portion; thus, a source region 106a and a drain region 106b are formed. Note that the etching performed here may be dry etching instead of wet etching. A cross-sectional view after the resist mask is removed is shown in
Next, plasma treatment is performed. Here, reverse sputtering where plasma is generated after introduction of an oxygen gas and an argon gas into a deposition chamber is performed, so that the exposed gate insulating layer is irradiated with oxygen radicals or oxygen. Thus, dust adhering to the surface is removed and moreover the surface of the gate insulating layer is modified into an oxygen-excess region. It is effective to perform the oxygen radical treatment on the surface of the gate insulating layer so that the surface is made into an oxygen-excess region, in point of that an oxygen source for modifying the interface of the first oxide semiconductor layer is made in thermal treatment (200° C. to 600° C.) for increasing the reliability in a later step. A cross-sectional view when this step is completed is shown in
Next, the first oxide semiconductor film is formed in such a manner that the substrate on which the plasma treatment has been performed is not exposed to the air. The first oxide semiconductor film formed in such a manner that the substrate on which the plasma treatment has been performed is not exposed to the air can avoid the trouble that dust or moisture adheres to the interface between the gate insulating layer and the semiconductor film. Here, the first oxide semiconductor film is formed in an oxygen atmosphere under the condition where the target is an oxide semiconductor target including In, Ga, and Zn (composition ratio is In2O3:Ga2O3:ZnO=1:1:1) with a diameter of 8 inches, the distance between the substrate and the target is set at 170 mm, the pressure is set at 0.4 Pa, and the direct current (DC) power supply is set at 0.5 kW. Note that a pulse direct current (DC) power supply is preferable because dust can be reduced and the film thickness can be uniform. The thickness of the first oxide semiconductor film is set to 5 nm to 200 nm. The thickness of the first oxide semiconductor film in Embodiment 2 is 100 nm.
When the first oxide semiconductor film is formed under a condition different from that of the second oxide semiconductor film, the first oxide semiconductor film has a different composition from that of the second oxide semiconductor film; for example, the first oxide semiconductor film has higher oxygen concentration than the second oxide semiconductor film. In this case, the ratio of the oxygen gas flow rate to the argon gas flow rate in the deposition condition of the first oxide semiconductor film is set higher than that of the second oxide semiconductor film. Specifically, the second oxide semiconductor film is formed in a rare gas (such as argon or helium) atmosphere (or a gas including oxygen at 10% or less and argon at 90% or more), while the first oxide semiconductor film is formed in an oxygen atmosphere (or a mixed gas of oxygen and argon with the flow rate of oxygen being more than that of argon). When the first oxide semiconductor film includes more oxygen than the second oxide semiconductor film, the first oxide semiconductor film can have lower electrical conductivity than the second oxide semiconductor film. Moreover, when the first oxide semiconductor film includes a large amount of oxygen, the amount of off current can be reduced; therefore, a thin film transistor with a high on/off ratio can be provided.
The first oxide semiconductor film may be formed in the same chamber as the chamber where the reverse sputtering is performed previously, or may be formed in a different chamber from the chamber where the reverse sputtering is performed previously as long as the deposition can be performed without exposure to the air.
Next, thermal treatment at 200° C. to 600° C., typically 300° C. to 500° C., is preferably performed. Here, thermal treatment is performed in a furnace at 350° C. for an hour in a nitrogen atmosphere. This thermal treatment allows atoms of the IGZO semiconductor films to be rearranged. Since the distortion that interrupts carrier movement is released by this thermal treatment, the thermal treatment here (including photo-annealing) is important. There is no particular limitation on when to perform the thermal treatment as long as it is performed after the formation of the first oxide semiconductor film; for example, it may be performed after the formation of the pixel electrode.
Next, a third photolithography process is performed to form a resist mask, and an unnecessary portion is removed by etching. Thus, the first oxide semiconductor layer 103 is formed. Here, wet etching is performed using ITO07N (product of Kanto Chemical Co., Inc.); thus, the first oxide semiconductor layer 103 is formed. Note that since the first oxide semiconductor film and the second oxide semiconductor film are dissolved in the same etchant, the etching performed here removes part of the second oxide semiconductor film. A portion of the second oxide semiconductor film (IGZO semiconductor film), which is covered with the resist mask and the first oxide semiconductor film, is protected; however, an end portion of the second oxide semiconductor film which is exposed is slightly etched. Therefore, the shape of the end portion thereof changes. Note that the etching of the first oxide semiconductor layer 103 is not limited to wet etching and may be dry etching. Then, the resist mask is removed. Through these steps, the non-linear element 30a in which the first oxide semiconductor layer 103 is a channel formation region is completed. A cross-sectional view at this point is shown in
Next, a protective insulating film 107 covering the non-linear element 30a is formed. The protective insulating film 107 can be formed using a silicon nitride film, a silicon oxide film, a silicon oxynitride film, an aluminum oxide film, a tantalum oxide film, or the like which can be deposited by a sputtering method or the like.
Next, a fourth photolithography process is performed to form a resist mask, and the protective insulating film 107 is etched. Thus, a contact hole 125 that reaches the drain electrode layer 105b is formed. It is preferable that a contact hole 126 that reaches the gate electrode be formed by etching the gate insulating layer 102 with the use of the same resist mask, because the number of photomasks can be reduced. The resist mask is removed and a cross-sectional view at this point is shown in
Next, a third wiring layer 128 is formed. When the third wiring layer 128 is formed using a transparent conductive film, a pixel electrode can be formed together with a film to be the third wiring layer 128. As the material of the transparent conductive film, there are indium oxide (In2O3), indium oxide-tin oxide alloy (In2O3—SnO2, abbreviated as ITO), and the like and the third wiring layer is formed by a sputtering method, a vacuum evaporation method, or the like. Etching treatment of such materials is performed using a chlorinated acid based solution. However, since etching of ITO particularly tends to leave residue, an alloy of indium oxide and zinc oxide (In2O3—ZnO) may be used in order to improve etching processability. The transparent conductive film is etched in this manner to be the third wiring layer 128.
Next, a fifth photolithography process is performed to form a resist mask, and an unnecessary portion of the transparent conductive film is removed by etching. Thus, a pixel electrode is formed in a pixel portion which is not shown.
In the fifth photolithography process, a storage capacitor is formed by the capacitor wiring and the pixel electrode in a capacitor portion which is not shown, using the gate insulating layer 102 and the protective insulating film 107 as dielectrics.
In the fifth photolithography process, the terminal portion is covered with the resist mask so that the transparent conductive film formed in the terminal portion remains. The transparent conductive film is used for an electrode or a wiring for connection with an FPC or used for a terminal electrode or the like for connection which functions as an input terminal of a source wiring.
Moreover, in Embodiment 2, the drain electrode layer 105b of the non-linear element 30a is connected to the scan line 108 in the contact holes 125 and 126 via the third wiring layer 128 formed using the transparent conductive film.
Next, the resist mask is removed. A cross-sectional view at this point is shown in
Through the five photolithography processes performed in the above manner, the protective circuit having the plurality of non-linear elements (in Embodiment 2, the two non-linear elements 30a and 30b) can be completed by using the five photomasks. According to Embodiment 2, a plurality of TFTs can be completed by a similar method together with the non-linear elements. Therefore, a pixel portion including bottom-gate n-channel TFTs and a protective circuit can be manufactured at the same time. In other words, a board for an active matrix display device, on which a protective diode having few defects in a protective circuit due to peeling of a thin film is mounted, can be manufactured in accordance with the steps described in Embodiment 2.
Embodiment 3 illustrates an example of electronic paper in which a protective circuit and a TFT in a pixel portion are provided over one substrate, as a display device to which an embodiment of the present invention is applied.
The electronic paper in
The thin film transistor 581 has a bottom-gate structure in which the source electrode layer or the drain electrode layer is electrically connected to a first electrode layer 587 in an opening formed in an insulating layer 585. Between the first electrode layer 587 and a second electrode layer 588, spherical particles 589 are provided. Each spherical particle 589 includes a black region 590a, a white region 590b, and a cavity 594 filled with liquid around the black region 590a and the white region 590b. The circumference of the spherical particle 589 is filled with filler 595 such as a resin or the like (see
Further, instead of the twisting ball, an electrophoretic element can be used. A microcapsule having a diameter of about 10 μm to 200 μm, which is filled with transparent liquid, positively-charged white microparticles and negatively-charged black microparticles, is used. In the microcapsule which is provided between the first electrode layer and the second electrode layer, when an electric field is applied by the first electrode layer and the second electrode layer, the white microparticles and the black microparticles move to opposite sides to each other, so that white or black can be displayed. A display element using this principle is an electrophoretic display element, and is called electronic paper in general. The electrophoretic display element has higher reflectance than a liquid crystal display element, and thus, an assistant light is unnecessary. Moreover, power consumption is low and a display portion can be recognized in a dusky place. Furthermore, an image which is displayed once can be retained even when power is not supplied to the display portion. Accordingly, a displayed image can be stored even though a semiconductor device having a display function (which is also referred to simply as a display device or a semiconductor device provided with a display device) is distanced from an electric wave source which serves as a power supply.
According to Embodiment 3, a display device having a structure suitable as a protective circuit can be provided by forming the protective circuit with use of the non-linear element including the oxide semiconductor. In the connection structure between the first oxide semiconductor layer of the non-linear element and the wiring layers, the provision of the region which is bonded with the second oxide semiconductor layer, which has higher electrical conductivity than the first oxide semiconductor layer, allows stable operation as compared with the case of using only metal wirings. Accordingly, a defect due to peeling of a thin film does not easily occur. In this manner, according to Embodiment 3, electronic paper with high reliability as a display device can be completed.
Embodiment 3 can be implemented in combination with the structure described in another Embodiment as appropriate.
Embodiment 4 describes an example of manufacturing at least a protective circuit, part of a driver circuit, and a thin film transistor of a pixel portion over one substrate in a display device which is an example of a semiconductor device according to an embodiment of the present invention.
The thin film transistor in the pixel portion is formed in a manner similar to the non-linear element described in Embodiment 2. The thin film transistor is formed to be an n-channel TFT; therefore, part of a driver circuit, which can be formed using an n-channel TFT, is formed over the same substrate as the thin film transistor in the pixel portion.
The pixel portion 5301 is connected to the signal line driver circuit 5303 with a plurality of signal lines S1 to Sm (not shown) extending in a column direction from the signal line driver circuit 5303 and connected to the scan line driver circuit 5302 with a plurality of scan lines G1 to Gn (not shown) extending in a row direction from the scan line driver circuit 5302. The pixel portion 5301 includes a plurality of pixels (not shown) arranged in matrix corresponding to the signal lines S1 to Sm and the scan lines G1 to Gn. In addition, each of the pixels is connected to a signal line Sj (any one of the signal lines S1 to Sm) and a scan line Gi (any one of the scan lines G1 to Gn).
The thin film transistor can be formed as an n-channel TFT by a method similar to that of the non-linear element described in Embodiment 2, and a signal line driver circuit including an n-channel TFT is described with reference to
The signal line driver circuit in
The driver IC 5601 is connected to the first wiring 5611, the second wiring 5612, the third wiring 5613, and the wirings 5621_1 to 5621_M. Each of the switch groups 5602_1 to 5602_M is connected to the first wiring 5611, the second wiring 5612, the third wiring 5613, and one of the wirings 5621_1 to 5621_M corresponding to the switch groups 5602_1 to 5602_M, respectively. Each of the wirings 5621_1 to 5621_M is connected to three signal lines through the first thin film transistor 5603a, the second thin film transistor 5603b, and the third thin film transistor 5603c. For example, the wiring 5621_J of the J-th column (one of the wirings 5621_1 to 5621_M) is connected to a signal line Sj−1, a signal line Sj, and a signal line Sj+1 through the first thin film transistor 5603a, the second thin film transistor 5603b, and the third thin film transistor 5603c of the switch group 5602_J.
Note that a signal is input to each of the first wiring 5611, the second wiring 5612, and the third wiring 5613.
Note that the driver IC 5601 is preferably formed on a single-crystal substrate. The switch groups 5602_1 to 5602_M are preferably formed over the same substrate as the pixel portion. Therefore, the driver IC 5601 is preferably connected to the switch groups 5602_1 to 5602_M through an FPC or the like.
Next, operation of the signal line driver circuit in
Note that the timing chart in
The timing chart of
In the first sub-selection period T1, the second sub-selection period T2, and the third sub-selection period T3, different video signals are input to the wirings 5621_1 to 5621_M. For example, a video signal input to the wiring 5621_J in the first sub-selection period T1 is input to the signal line Sj−1, a video signal input to the wiring 5621_J in the second sub-selection period T2 is input to the signal line Sj, and a video signal input to the wiring 5621_J in the third sub-selection period T3 is input to the signal line Sj+1. The video signals input to the wiring 5621_J in the first sub-selection period T1, the second sub-selection period T2, and the third sub-selection period T3 are denoted by Data_j−1, Data_j, and Data_j+1, respectively.
As shown in
As described above, in the signal line driver circuit of
Note that there is no particular limitation on the arrangement, number, driving method, and the like of the thin film transistors, as long as one gate selection period is divided into a plurality of sub-selection periods and video signals are input to a plurality of signal lines from one wiring in each of the plurality of sub-selection periods as shown in
For example, when video signals are input to three or more signal lines from one wiring in each of three or more sub-selection periods, a thin film transistor and a wiring for controlling the thin film transistor may be added as needed. Note that when one gate selection period is divided into four or more sub-selection periods, one sub-selection period becomes short. Therefore, one gate selection period is preferably divided into two or three sub-selection periods.
As another example, as shown in a timing chart of
As described above, in the signal line driver circuit of
Now, a constitution of the scan line driver circuit is described. The scan line driver circuit includes a shift register and a buffer. Also, a level shifter may be included in some cases. In the scan line driver circuit, when a clock signal (CLK) and a start pulse signal (SP) are input to the shift register, a selection signal is produced. The generated selection signal is buffered and amplified by the buffer, and the resulting signal is supplied to a corresponding scan line. Gate electrodes of transistors in pixels corresponding to one line are connected to the scan line. Further, since the transistors in the pixels of one line have to be turned on at the same time, a buffer which can feed a large amount of current is used.
An example of a shift register used as part of the scan line driver circuit is described with reference to
Connection relationships of the shift register in
Further, a fourth wiring 5504 shown in
Note that the first wiring 5501 shown in
The first wiring 5711, the second wiring 5712, the third wiring 5713, and the sixth wiring 5716 may be referred to as a first signal line, a second signal line, a third signal line, and a fourth signal line, respectively. The fourth wiring 5714 and the fifth wiring 5715 may be referred to as a first power supply line and a second power supply line, respectively.
Now, a connection structure of the flip-flop shown in
A first electrode (one of a source electrode or a drain electrode) of the first thin film transistor 5571 is connected to the fourth wiring 5504, and a second electrode (the other of the source electrode or the drain electrode) of the first thin film transistor 5571 is connected to the third wiring 5503.
A first electrode of the second thin film transistor 5572 is connected to the sixth wiring 5506. A second electrode of the second thin film transistor 5572 is connected to the third wiring 5503.
A first electrode of the third thin film transistor 5573 is connected to the fifth wiring 5505. A second electrode of the third thin film transistor 5573 is connected to a gate electrode of the second thin film transistor 5572. A gate electrode of the third thin film transistor 5573 is connected to the fifth wiring 5505.
A first electrode of the fourth thin film transistor 5574 is connected to the sixth wiring 5506. A second electrode of the fourth thin film transistor 5574 is connected to the gate electrode of the second thin film transistor 5572. A gate electrode of the fourth thin film transistor 5574 is connected to a gate electrode of the first thin film transistor 5571.
A first electrode of the fifth thin film transistor 5575 is connected to the fifth wiring 5505. A second electrode of the fifth thin film transistor 5575 is connected to the gate electrode of the first thin film transistor 5571. A gate electrode of the fifth thin film transistor 5575 is connected to the first wiring 5501.
A first electrode of the sixth thin film transistor 5576 is connected to the sixth wiring 5506. A second electrode of the sixth thin film transistor 5576 is connected to the gate electrode of the first thin film transistor 5571. A gate electrode of the sixth thin film transistor 5576 is connected to the gate electrode of the second thin film transistor 5572.
A first electrode of the seventh thin film transistor 5577 is connected to the sixth wiring 5506. A second electrode of the seventh thin film transistor 5577 is connected to the gate electrode of the first thin film transistor 5571. A gate electrode of the seventh thin film transistor 5577 is connected to the second wiring 5502. A first electrode of the eighth thin film transistor 5578 is connected to the sixth wiring 5506. A second electrode of the eighth thin film transistor 5578 is connected to the gate electrode of the second thin film transistor 5572. A gate electrode of the eighth thin film transistor 5578 is connected to the first wiring 5501.
Note that the point at which the gate electrode of the first thin film transistor 5571, the gate electrode of the fourth thin film transistor 5574, the second electrode of the fifth thin film transistor 5575, the second electrode of the sixth thin film transistor 5576, and the second electrode of the seventh thin film transistor 5577 are connected is referred to as a node 5543. The point at which the gate electrode of the second thin film transistor 5572, the second electrode of the third thin film transistor 5573, the second electrode of the fourth thin film transistor 5574, the gate electrode of the sixth thin film transistor 5576, and the second electrode of the eighth thin film transistor 5578 are connected is referred to as a node 5544.
The first wiring 5501, the second wiring 5502, the third wiring 5503, and the fourth wiring 5504 may be referred to as a first signal line, a second signal line, a third signal line, and a fourth signal line, respectively. The fifth wiring 5505 and the sixth wiring 5506 may be referred to as a first power supply line and a second power supply line, respectively.
Alternatively, the signal line driver circuit and the scan line driver circuit can be manufactured using only n-channel TFTs, which can be manufactured by a method similar to the method for manufacturing the non-linear element and together with the non-linear element described in Embodiment 2. Since the n-channel TFTs which can be formed by a method similar to the method for manufacturing the non-linear element described in Embodiment 2 have high mobility, the driving frequency of the driver circuits can be increased. Further, the n-channel TFTs which can be formed by a method similar to the method for manufacturing the non-linear element and together with the non-linear element described in Embodiment 2 include source regions or drain regions which are formed using an oxygen-deficiency oxide semiconductor layer including indium, gallium, and zinc. Therefore, the parasitic capacitance is decreased and the frequency characteristic (called f-characteristic) is increased. For example, the scan line driver circuit including the n-channel TFTs which can be formed by a method similar to the method for manufacturing the non-linear element and together with the non-linear element described in Embodiment 2 can operate at high speed; therefore, it is possible to increase the frame frequency or to achieve insertion of a black screen, for example.
In addition, when the channel width of the transistor in the scan line driver circuit is increased or a plurality of scan line driver circuits is provided, for example, higher frame frequency can be realized. When a plurality of scan line driver circuits is provided, a scan line driver circuit for driving even-numbered scan lines is provided on one side and a scan line driver circuit for driving odd-numbered scan lines is provided on the opposite side; thus, increase in frame frequency can be realized.
In the case of manufacturing an active matrix type light-emitting display device, which is an example of a semiconductor device to which an embodiment of the present invention is applied, a plurality of scan line driver circuits is preferably arranged because a plurality of thin film transistors is arranged in at least one pixel. An example of a block diagram of an active matrix light-emitting display device is illustrated in
The light-emitting display device illustrated in
In the case of inputting a digital video signal to the pixel of the light-emitting display device of
Since the response time of light-emitting elements is shorter than that of liquid crystal elements or the like, the light-emitting elements are suitable for a time ratio grayscale method. Specifically, in the case of displaying by a time grayscale method, one frame period is divided into a plurality of subframe periods. Then, in accordance with video signals, the light-emitting element in the pixel is put in a light-emitting state or a non-light-emitting state in each subframe period. By dividing a frame into a plurality of subframes, the total length of time in which pixels actually emit light in one frame period can be controlled with video signals to display grayscales.
Note that in the light-emitting display device of
Even in the light-emitting display device, part of the driver circuit which can be formed using the n-channel TFT can be provided over one substrate together with the thin film transistor of the pixel portion. Moreover, the signal line driver circuit and the scan line driver circuit can be manufactured using only the n-channel TFTs which can be formed by a method similar to the method for manufacturing the non-linear element and together with the non-linear element described in Embodiment 2.
The aforementioned driver circuit may be used for not only a liquid crystal display device or a light-emitting display device but also electronic paper in which electronic ink is driven by utilizing an element electrically connected to a switching element. The electronic paper is also called an electrophoretic display device (electrophoretic display) and has advantages in that it has the same level of readability as regular paper, it has less power consumption than other display devices, and it can be set to have a thin and light form.
There are a variety of modes of electrophoretic displays. The electrophoretic display is a device in which a plurality of microcapsules each including first particles having positive charge and second particles having negative charge are dispersed in a solvent or a solute, and an electrical field is applied to the microcapsules so that the particles in the microcapsules move in opposite directions from each other, and only a color of the particles gathered on one side is displayed. Note that the first particles or the second particles include a colorant, and does not move when there is not electric field. Also, a color of the first particles is different from a color of the second particles (the particles may also be colorless).
Thus, the electrophoretic display utilizes a so-called dielectrophoretic effect, in which a substance with high dielectric constant moves to a region with high electric field. The electrophoretic display does not require a polarizing plate and a counter substrate, which are necessary for a liquid crystal display device, so that the thickness and weight thereof are about half.
That which the microcapsules are dispersed in a solvent is called electronic ink, and this electronic ink can be printed on a surface of glass, plastic, fabric, paper, or the like. Color display is also possible with the use of a color filter or particles including a coloring matter.
In addition, an active matrix type display device can be completed by providing as appropriate, a plurality of the microcapsules over an active matrix substrate so as to be interposed between two electrodes, and can perform display by application of electric field to the microcapsules. For example, the active matrix substrate obtained using the thin film transistors which can be formed by a method similar to the method for manufacturing the non-linear element and together with the non-linear element described in Embodiment 2 can be used.
Note that the first particles and the second particles in the microcapsule may be formed from one of a conductive material, an insulating material, a semiconductor material, a magnetic material, a liquid crystal material, a ferroelectric material, an electroluminescent material, an electrochromic material, and a magnetophoretic material or a composite material thereof.
According to Embodiment 4, the protective circuit is formed using the non-linear element including an oxide semiconductor. Thus, a display device having a structure suitable as a protective circuit can be provided. In the connection structure between the first oxide semiconductor layer of the non-linear element and the wiring layers, the provision of the region which is bonded with the second oxide semiconductor layer, which has higher electrical conductivity than the first oxide semiconductor layer, allows stable operation as compared with the case of using only metal wirings. Accordingly, a defect due to peeling of a thin film does not easily occur. In this manner, according to Embodiment 4, a display device with high reliability can be manufactured.
Embodiment 4 can be combined with the structure disclosed in another Embodiment as appropriate.
A thin film transistor can be manufactured together with a non-linear element according to an embodiment of the present invention, and the thin film transistor can be used for a pixel portion and further for a driver circuit, so that a semiconductor device having a display function (also called a display device) can be manufactured. Moreover, a thin film transistor and a non-linear element according to an embodiment of the present invention can be used for part of a driver circuit or an entire driver circuit formed over one substrate together with a pixel portion, so that a system-on-panel can be formed.
The display device includes a display element. As the display element, a liquid crystal element (also referred to as a liquid crystal display element) or a light-emitting element (also referred to as a light-emitting display element) can be used. A light-emitting element includes, in its scope, an element whose luminance is controlled by current or voltage, and specifically includes an inorganic electroluminescent (EL) element, an organic EL element, and the like. Further, a display medium whose contrast is changed by an electric effect, such as electronic ink, can be used.
In addition, the display device includes a panel in which a display element is sealed, and a module in which an IC and the like including a controller are mounted on the panel. An embodiment of the present invention relates to one mode of an element substrate before the display element is completed in a process for manufacturing the display device, and the element substrate is provided with a means for supplying current to the display element in each of a plurality of pixels. Specifically, the element substrate may be in a state provided with only a pixel electrode of the display element, a state after a conductive film to be a pixel electrode is formed and before the conductive film is etched to form the pixel electrode, or any other states.
A display device in this specification refers to an image display device, a display device, or a light source (including a lighting device). Further, the display device includes any of the following modules in its category: a module including a connector such as an flexible printed circuit (FPC), a tape automated bonding (TAB) tape, or a tape carrier package (TCP); a module having a TAB tape or a TCP which is provided with a printed wiring board at the end thereof; and a module having an integrated circuit (IC) which is directly mounted on a display element by a chip-on-glass (COG) method.
The appearance and a cross section of a liquid crystal display panel, which corresponds to one mode of a display device according to an embodiment of the present invention, will be described in Embodiment 5 with reference to
The sealant 4005 is provided so as to surround a pixel portion 4002 and a scan line driver circuit 4004 which are provided over the first substrate 4001. The second substrate 4006 is provided over the pixel portion 4002 and the scan line driver circuit 4004. Thus, the pixel portion 4002 and the scan line driver circuit 4004 as well as a liquid crystal layer 4008 are sealed with the sealant 4005 between the first substrate 4001 and the second substrate 4006. A signal line driver circuit 4003 that is formed using a single crystal semiconductor film or a polycrystalline semiconductor film over a substrate which is prepared separately is mounted in a region that is different from the region surrounded by the sealant 4005 over the first substrate 4001.
Note that there is no particular limitation on a connection method of the driver circuit which is separately formed, and a known COG method, wire bonding method, TAB method, or the like can be used.
Each of the pixel portion 4002 and the scan line driver circuit 4004 which are provided over the first substrate 4001 includes a plurality of thin film transistors.
Each of the thin film transistors 4010 and 4011 has high electrical characteristics and includes a gate insulating layer on which plasma treatment has been performed, a source region and a drain region which include an IGZO semiconductor film of oxygen-deficiency type, a source electrode layer and a drain electrode layer which are in contact with the source region and the drain region respectively, and an IGZO semiconductor layer of oxygen-excess type which is in contact with the source region and the drain region. The thin film transistors 4010 and 4011 can be manufactured by a method similar to the method for manufacturing the non-linear element and together with the non-linear element described in Embodiment 2. In Embodiment 5, the thin film transistors 4010 and 4011 are n-channel thin film transistors.
A pixel electrode layer 4030 included in the liquid crystal element 4013 is electrically connected to the thin film transistor 4010. A counter electrode layer 4031 of the liquid crystal element 4013 is formed on the second substrate 4006. A portion where the pixel electrode layer 4030, the counter electrode layer 4031, and the liquid crystal layer 4008 overlap with each other corresponds to the liquid crystal element 4013. Note that the pixel electrode layer 4030 and the counter electrode layer 4031 are provided with an insulating layer 4032 and an insulating layer 4033 serving as orientation films, respectively, and hold the liquid crystal layer 4008 with the insulating layers 4032 and 4033 interposed therebetween.
Note that the first substrate 4001 and the second substrate 4006 can be formed from glass, metal (typically, stainless steel), ceramic, or plastic. As plastic, a fiberglass-reinforced plastics (FRP) plate, a polyvinyl fluoride (PVF) film, a polyester film, or an acrylic resin film can be used. In addition, a sheet with a structure in which an aluminum foil is sandwiched between PVF films or polyester films can be used.
A columnar spacer 4035, which is formed by etching an insulating film selectively, is provided to control a distance (a cell gap) between the pixel electrode layer 4030 and the counter electrode layer 4031. Alternatively, a spherical spacer may be used.
Alternatively, a blue phase liquid crystal without an orientation film may be used. A blue phase is a type of liquid crystal phase, which appears just before a cholesteric liquid crystal changes into an isotropic phase when the temperature of the cholesteric liquid crystal is increased. A blue phase appears only within narrow temperature range; therefore, the liquid crystal layer 4008 is formed using a liquid crystal composition in which a chiral agent of 5 wt. % or more is mixed in order to expand the temperature range. The liquid crystal composition including a blue phase liquid crystal and a chiral agent has a short response time of 10 μs to 100 μs, and is optically isotropic; therefore, orientation treatment is not necessary and viewing angle dependence is small.
Note that Embodiment 5 describes an example of a transmissive liquid crystal display device; however, an embodiment of the present invention can be applied to a reflective liquid crystal display device or a semi-transmissive liquid crystal display device.
Although a liquid crystal display device of Embodiment 5 has a polarizer provided outer than the substrate (the viewer side) and a color layer and an electrode layer of a display element provided inner than the substrate, which are arranged in that order, the polarizer may be inner than the substrate. The stacked structure of the polarizer and the color layer is not limited to that shown in Embodiment 5 and may be set as appropriate in accordance with the materials of the polarizer and the color layer and the condition of the manufacturing process. Further, a light-blocking film serving as a black matrix may be provided.
In Embodiment 5, in order to reduce the unevenness of the surface of the thin film transistors and to improve the reliability of the thin film transistors, the non-linear element described in Embodiment 2 and the thin film transistors which can be formed by a method similar to the method for manufacturing the non-linear element are covered with protective films or insulating layers (the insulating layers 4020 and 4021) serving as planarizing insulating films. Note that the protective film is provided to prevent entry of a contaminant impurity such as an organic substance, a metal substance, or moisture floating in the atmosphere, and therefore a dense film is preferable. The protective film may be formed using a single layer or a stack of layers of a silicon oxide film, a silicon nitride film, a silicon oxynitride film, a silicon nitride oxide film, an aluminum oxide film, an aluminum nitride film, an aluminum oxynitride film, or an aluminum nitride oxide film by a sputtering method. Although the protective film is formed by a sputtering method in Embodiment 5, the method is not limited to a particular method and may be selected from a variety of methods.
Here, the insulating layer 4020 is formed to have a stacked structure as the protective film. Here, a silicon oxide film is formed by a sputtering method as a first layer of the insulating layer 4020. The use of a silicon oxide film for the protective film provides an advantageous effect of preventing hillock of an aluminum film used for a source electrode layer and a drain electrode layer.
Moreover, a silicon nitride film is formed by a sputtering method as a second layer of the insulating layer 4020. When a silicon nitride film is used for the protective film, it is possible to prevent movable ions such as sodium from entering a semiconductor region to vary the electrical characteristics of the TFT.
Further, after the protective film is formed, the oxide semiconductor layer may be annealed (at 300° C. to 400° C.).
Further, the insulating layer 4021 is formed as the planarizing insulating film. The insulating layer 4021 can be formed from an organic material having heat resistance, such as polyimide, acrylic, benzocyclobutene, polyamide, or epoxy. As an alternative to such organic materials, it is possible to use a low-dielectric constant material (a low-k material), a siloxane-based resin, PSG (phosphosilicate glass), BPSG (borophosphosilicate glass), or the like. A siloxane-based resin may include as a substituent at least one of fluorine, an alkyl group, and an aryl group, as well as hydrogen. Note that the insulating layer 4021 may be formed by stacking a plurality of insulating films formed of these materials.
Note that a siloxane-based resin is a resin formed from a siloxane-based material as a starting material and having the bond of Si—O—Si. The siloxane-based resin may include as a substituent at least one of fluorine, an alkyl group, and aromatic hydrocarbon, as well as hydrogen.
The method for the formation of the insulating layer 4021 is not limited to a particular method and the following method can be used depending on the material of the insulating layer 4021: a sputtering method, an SOG method, spin coating, dip coating, spray coating, a droplet discharge method (e.g., an inkjet method, screen printing, or offset printing), a doctor knife, a roll coater, a curtain coater, a knife coater, or the like. In the case of forming the insulating layer 4021 with the use of a material solution, annealing (300° C. to 400° C.) may be performed on the oxide semiconductor layer at the same time as a baking step. When the baking of the insulating layer 4021 and the annealing of the oxide semiconductor layer are performed at the same time, a semiconductor device can be manufactured efficiently.
The pixel electrode layer 4030 and the counter electrode layer 4031 can be formed from a light-transmitting conductive material such as indium oxide containing tungsten oxide, indium zinc oxide containing tungsten oxide, indium oxide containing titanium oxide, indium tin oxide containing titanium oxide, indium tin oxide (hereinafter referred to as ITO), indium zinc oxide, or indium tin oxide to which silicon oxide is added.
A conductive composition including a conductive high molecule (also referred to as a conductive polymer) can be used for the pixel electrode layer 4030 and the counter electrode layer 4031. The pixel electrode formed of the conductive composition has preferably a sheet resistance of 10000 ohm/square or less and a transmittance of 70% or more at a wavelength of 550 nm. Further, the resistivity of the conductive high molecule included in the conductive composition is preferably 0.1 Ω·cm or less.
As the conductive high molecule, a so-called π-electron conjugated conductive polymer can be used. As examples thereof, polyaniline or a derivative thereof, polypyrrole or a derivative thereof, polythiophene or a derivative thereof, a copolymer of two or more kinds of them, and the like can be given.
Further, a variety of signals and potentials are supplied from an FPC 4018 to the signal line driver circuit 4003 which is formed separately, the scan line driver circuit 4004, and the pixel portion 4002.
In Embodiment 5, a connecting terminal electrode 4015 is formed using the same conductive film as the pixel electrode layer 4030 included in the liquid crystal element 4013. A terminal electrode 4016 is formed using the same conductive film as the source and drain electrode layers included in the thin film transistors 4010 and 4011.
The connecting terminal electrode 4015 is electrically connected to a terminal of the FPC 4018 through an anisotropic conductive film 4019.
Although
For the liquid crystal display module, a TN (Twisted Nematic) mode, an IPS (In-Plane-Switching) mode, an FFS (Fringe Field Switching) mode, an MVA (Multi-domain Vertical Alignment) mode, a PVA (Patterned Vertical Alignment) mode, an ASM (Axially Symmetric aligned Micro-cell) mode, an OCB (Optically Compensated Birefringence) mode, an FLC (Ferroelectric Liquid Crystal) mode, an AFLC (AntiFerroelectric Liquid Crystal) mode or the like can be used.
According to Embodiment 5, a protective circuit is formed using a non-linear element including an oxide semiconductor; thus, a display device having a structure suitable as a protective circuit can be provided. In the connection structure between the first oxide semiconductor layer of the non-linear element and the wiring layers, the provision of the region which is bonded with the second oxide semiconductor layer, which has higher electrical conductivity than the first oxide semiconductor layer, allows stable operation as compared with the case of using only metal wirings. Moreover, a defect due to peeling of a thin film does not easily occur. In this manner, according to Embodiment 5, a liquid crystal display panel with high reliability can be manufactured.
Embodiment 5 can be combined with the structure disclosed in another Embodiment as appropriate.
Embodiment 6 describes an example of a light-emitting display device as a display device according to an embodiment of the present invention. As an example of a display element of the display device, here, a light-emitting element utilizing electroluminescence is used. Light-emitting elements utilizing electroluminescence are classified according to whether a light emitting material is an organic compound or an inorganic compound. In general, the former is referred to as an organic EL element, the latter as an inorganic EL element.
In an organic EL element, by application of voltage to a light-emitting element, electrons and holes are separately injected from a pair of electrodes into a layer containing a light-emitting organic compound, and thus current flows. Then, those carriers (i.e., electrons and holes) are recombined, and thus, the light-emitting organic compound is excited. When the light-emitting organic compound returns to a ground state from the excited state, light is emitted. Owing to such a mechanism, such a light emitting element is referred to as a current-excitation light emitting element.
The inorganic EL elements are classified according to their element structures into a dispersion type inorganic EL element and a thin-film type inorganic EL element. A dispersion type inorganic EL element has a light-emitting layer where particles of a light-emitting material are dispersed in a binder, and its light emission mechanism is donor-acceptor recombination type light emission that utilizes a donor level and an acceptor level. A thin-film type inorganic EL element has a structure where a light-emitting layer is sandwiched between dielectric layers, which are further sandwiched between electrodes, and its light emission mechanism is localized type light emission that utilizes inner-shell electron transition of metal ions. Note that an organic EL element is used as a light-emitting element in this example.
A structure and operation of a pixel to which digital time grayscale driving can be applied are described. In this example, one pixel includes two n-channel transistors in each of which a channel formation region includes a first oxide semiconductor layer and which can be formed by a method similar to the method for manufacturing the non-linear element described in Embodiment 2.
A pixel 6400 includes a switching transistor 6401, a driver transistor 6402, a light-emitting element 6404, and a capacitor 6403. A gate of the switching transistor 6401 is connected to a scan line 6406, a first electrode (one of a source electrode and a drain electrode) of the switching transistor 6401 is connected to a signal line 6405, and a second electrode (the other of the source electrode and the drain electrode) of the switching transistor 6401 is connected to a gate of the driver transistor 6402. The gate of the driver transistor 6402 is connected to a power supply line 6407 through the capacitor 6403, a first electrode of the driver transistor 6402 is connected to the power supply line 6407, and a second electrode of the driver transistor 6402 is connected to a first electrode (pixel electrode) of the light-emitting element 6404. A second electrode of the light-emitting element 6404 corresponds to a common electrode 6408.
The second electrode (common electrode 6408) of the light-emitting element 6404 is set to a low power supply potential. The low power supply potential is a potential satisfying the low power supply potential<a high power supply potential when the high power supply potential set to the power supply line 6407 is a reference. As the low power supply potential, GND, 0 V, or the like may be employed, for example. A potential difference between the high power supply potential and the low power supply potential is applied to the light-emitting element 6404 and current is supplied to the light-emitting element 6404, so that the light-emitting element 6404 emits light. Here, in order to make the light-emitting element 6404 emit light by feed of current, each potential is set so that the potential difference between the high power supply potential and the low power supply potential is greater than or equal to a forward threshold voltage.
Gate capacitance of the driver transistor 6402 may be used as a substitute for the capacitor 6403, so that the capacitor 6403 can be omitted. The gate capacitance of the driver transistor 6402 may be formed between the channel region and the gate electrode.
In the case of a voltage-input voltage driving method, a video signal is input to the gate of the driver transistor 6402 so that the driver transistor 6402 is in either of two states of being sufficiently turned on and turned off. That is, the driver transistor 6402 operates in a linear region. Since the driver transistor 6402 operates in a linear region, a voltage higher than the voltage of the power supply line 6407 is applied to the gate of the driver transistor 6402. Note that a voltage higher than or equal to (voltage of the power supply line+Vth of the driver transistor 6402) is applied to the signal line 6405.
In the case of performing analog grayscale driving instead of digital time grayscale driving, the same pixel structure as that in
In the case of performing analog grayscale driving, a voltage higher than or equal to (forward voltage of the light-emitting element 6404+Vth of the driver transistor 6402) is applied to the gate of the driver transistor 6402. The forward voltage of the light-emitting element 6404 indicates a voltage at which a desired luminance is obtained, and includes at least forward threshold voltage. The video signal by which the driver transistor 6402 operates in a saturation region is input, so that current can be supplied to the light-emitting element 6404. In order for the driver transistor 6402 to operate in a saturation region, the potential of the power supply line 6407 is set higher than the gate potential of the driver transistor 6402. When an analog video signal is used, it is possible to feed current to the light-emitting element 6404 in accordance with the video signal and perform analog grayscale driving.
The pixel structure shown in
Next, structures of a light-emitting element are described with reference to
In addition, in order to extract light emitted from the light-emitting element, at least one of an anode and a cathode is required to transmit light. A thin film transistor and a light-emitting element are formed over a substrate. A light-emitting element can have a top-emission structure in which light emission is extracted through the surface opposite to the substrate; a bottom-emission structure in which light emission is extracted through the surface on the substrate side; or a dual-emission structure in which light emission is extracted through the surface opposite to the substrate and the surface on the substrate side. The pixel structure according to an embodiment of the present invention can be applied to a light-emitting element having any of these emission structures.
A light-emitting element with a top-emission structure is described with reference to
The light-emitting element 7002 corresponds to a region where the cathode 7003 and the anode 7005 sandwich the light-emitting layer 7004. In the case of the pixel shown in
Next, a light-emitting element having the bottom-emission structure is described with reference to
The light-emitting element 7012 corresponds to a region where the cathode 7013 and the anode 7015 sandwich the light-emitting layer 7014. In the case of the pixel shown in
Next, a light-emitting element having a dual-emission structure is described with reference to
The light-emitting element 7022 corresponds to a region where the cathode 7023, the light-emitting layer 7024, and the anode 7025 overlap with each other. In the pixel illustrated in
Although an organic EL element is described here as a light-emitting element, an inorganic EL element can be alternatively provided as a light-emitting element.
Note that Embodiment 6 describes the example in which a thin film transistor (driver TFT) which controls the driving of a light-emitting element is electrically connected to the light-emitting element, but a structure may be employed in which a current control TFT is connected between the driver TFT and the light-emitting element.
The semiconductor device described in Embodiment 6 is not limited to the structures illustrated in
Next, the appearance and cross section of a light-emitting display panel (also referred to as a light-emitting panel) which corresponds to one mode of a semiconductor device according to the present invention will be described with reference to
A sealant 4505 is provided so as to surround a pixel portion 4502, signal line driver circuits 4503a and 4503b, and scan line driver circuits 4504a and 4504b, which are provided over a first substrate 4501. In addition, a second substrate 4506 is formed over the pixel portion 4502, the signal line driver circuits 4503a and 4503b, and the scan line driver circuits 4504a and 4504b. Accordingly, the pixel portion 4502, the signal line driver circuits 4503a and 4503b, and the scan line driver circuits 4504a and 4504b are sealed, together with filler 4507, with the first substrate 4501, the sealant 4505, and the second substrate 4506. In this manner, it is preferable that the pixel portion 4502, the signal line driver circuits 4503a and 4503b, and the scan line driver circuits 4504a and 4504b be packaged (sealed) with a protective film (such as an attachment film or an ultraviolet curable resin film) or a cover material with high air-tightness and little degasification so that the pixel portion 4502, the signal line driver circuits 4503a and 4503b, and the scan line driver circuits 4504a and 4504b are not exposed to external air.
The pixel portion 4502, the signal line driver circuits 4503a and 4503b, and the scan line driver circuits 4504a and 4504b formed over the first substrate 4501 each include a plurality of thin film transistors, and the thin film transistor 4510 included in the pixel portion 4502 and the thin film transistor 4509 included in the signal line driver circuit 4503a are illustrated as an example in
Each of the thin film transistors 4509 and 4510 has high electrical characteristics and includes a gate insulating layer on which plasma treatment has been performed, a source region and a drain region which are formed using an IGZO semiconductor film of oxygen-deficiency type, a source electrode layer and a drain electrode layer which are in contact with the source region and the drain region respectively, and an IGZO semiconductor layer of oxygen-excess type which is in contact with the source region and the drain region. The thin film transistors 4509 and 4510 can be manufactured in a manner similar to the method for manufacturing the non-linear element and together with the non-linear element described in Embodiment 2. In Embodiment 6, the thin film transistors 4509 and 4510 are n-channel thin film transistors.
Moreover, reference numeral 4511 denotes a light-emitting element. A first electrode layer 4517 which is a pixel electrode included in the light-emitting element 4511 is electrically connected to source and drain electrode layers of the thin film transistor 4510. Note that although the light-emitting element 4511 has a stacked structure of the first electrode layer 4517, an electroluminescent layer 4512, and a second electrode layer 4513, the structure of the light-emitting element 4511 is not limited to the structure shown in Embodiment 6. The structure of the light-emitting element 4511 can be changed as appropriate depending on a direction in which light is extracted from the light-emitting element 4511, or the like.
A partition wall 4520 is formed using an organic resin film, an inorganic insulating film, or organic polysiloxane. It is particularly preferable that the partition wall 4520 be formed using a photosensitive material to have an opening portion on the first electrode layer 4517 so that a sidewall of the opening portion is formed as a tilted surface with continuous curvature.
The electroluminescent layer 4512 may be formed using a single layer or a plurality of layers stacked.
In order to prevent entry of oxygen, hydrogen, moisture, carbon dioxide, or the like into the light-emitting element 4511, a protective film may be formed over the second electrode layer 4513 and the partition wall 4520. As the protective film, a silicon nitride film, a silicon nitride oxide film, a DLC (diamond like carbon) film, or the like can be formed.
In addition, a variety of signals and potentials are supplied from FPCs 4518a and 4518b to the signal line driver circuits 4503a and 4503b, the scan line driver circuits 4504a and 4504b, or the pixel portion 4502.
In Embodiment 6, a connecting terminal electrode 4515 is formed using the same conductive film as the first electrode layer 4517 included in the light-emitting element 4511. A terminal electrode 4516 is formed using the same conductive film as the source and drain electrode layers included in the thin film transistors 4509 and 4510.
The connecting terminal electrode 4515 is electrically connected to a terminal included in the FPC 4518a through an anisotropic conductive film 4519.
The second substrate 4506 located in the direction in which light is extracted from the light-emitting element 4511 needs to have a light-transmitting property. In that case, a light-transmitting material such as a glass plate, a plastic plate, a polyester film, or an acrylic film is used.
As the filler 4507, an ultraviolet curable resin or a thermosetting resin as well as inert gas such as nitrogen or argon can be used. For example, polyvinyl chloride (PVC), acrylic, polyimide, an epoxy resin, a silicone resin, polyvinyl butyral (PVB), or ethylene vinyl acetate (EVA) can be used. In Embodiment 6, nitrogen is used for the filler 4507.
In addition, if needed, optical films such as a polarizing plate, a circularly polarizing plate (including an elliptically polarizing plate), a retarder plate (a quarter-wave plate, a half-wave plate), and a color filter may be provided on an emission surface of the light-emitting element, as appropriate. Further, the polarizing plate or the circularly polarizing plate may be provided with an anti-reflection film. For example, anti-glare treatment can be performed by which reflected light is diffused in the depression/projection of the surface and glare can be reduced.
As the signal line driver circuits 4503a and 4503b and the scan line driver circuits 4504a and 4504b, driver circuits formed by using a single crystal semiconductor film or polycrystalline semiconductor film over a substrate separately prepared may be mounted. In addition, only the signal line driver circuit or only part thereof, or only the scan line driver circuit or only part thereof may be separately formed to be mounted. Embodiment 6 is not limited to the structure shown in
According to Embodiment 6, a protective circuit is formed using a non-linear element including an oxide semiconductor; thus, a display device having a structure suitable as a protective circuit can be provided. In the connection structure between the first oxide semiconductor layer of the non-linear element and the wiring layers, the provision of the region which is bonded with the second oxide semiconductor layer, which has higher electrical conductivity than the first oxide semiconductor layer, allows stable operation as compared with the case of using only metal wirings. Moreover, a defect due to peeling of a thin film does not easily occur. In this manner, according to Embodiment 6, a light-emitting display device (display panel) with high reliability can be manufactured.
Embodiment 6 can be combined with the structure disclosed in another Embodiment as appropriate.
A display device according to an embodiment of the present invention can be applied as electronic paper. Electronic paper can be used for electronic appliances of every field for displaying information. For example, electronic paper can be used for electronic book (e-book), posters, advertisement in vehicles such as trains, display in a variety of cards such as credit cards, and so on. Examples of such electronic appliances are illustrated in
A display portion 2705 is incorporated in the housing 2701 and a display portion 2707 is incorporated in the housing 2703. The display portion 2705 and the display portion 2707 may display a series of images, or may display different images. In the structure where different images are displayed in different display portions, for example, the right display portion (the display portion 2705 in
Further, the electronic book device 2700 may send and receive information wirelessly. Desired book data can be purchased and downloaded from an electronic book server wirelessly.
As described in Embodiment 7, when a display device including a protective circuit whose function has been improved by the use of a non-linear element including an oxide semiconductor and whose operation has been made stable is mounted on an electronic appliance, it is possible to manufacture an electronic appliance including a display device with high reliability, on which a protective circuit including a non-linear element in which a defect due to peeling of a thin film does not easily occur is mounted.
Embodiment 7 can be combined with the structure disclosed in another Embodiment as appropriate.
A semiconductor device according to an embodiment of the present invention can be applied to a variety of electronic appliances (including game machines). As the electronic appliances, there are, for example, a television device (also called TV or a television receiver), a monitor for a computer or the like, a digital camera, a digital video camera, a digital photo frame, a cellular phone (also called a mobile phone or a portable telephone device), a portable game machine, a portable information terminal, an audio playback device, and a large game machine such as a pachinko machine.
The television device 9600 can be operated by an operation switch of the housing 9601 or a separate remote controller 9610. The channel and volume can be controlled with operation keys 9609 of the remote controller 9610 and the images displayed in the display portion 9603 can be controlled. Moreover, the remote controller 9610 may have a display portion 9607 in which the information outgoing from the remote controller 9610 is displayed.
Note that the television device 9600 is provided with a receiver, a modem, and the like. With the use of the receiver, general television broadcasting can be received. Moreover, when the display device is connected to a communication network with or without wires via the modem, one-way (from a sender to a receiver) or two-way (between a sender and a receiver or between receivers) information communication can be performed.
Note that the digital photo frame 9700 is provided with an operation portion, an external connection terminal (such as a USB terminal or a terminal which can be connected to a variety of cables including a USB cable), a storage medium inserting portion, and the like. These structures may be incorporated on the same plane as the display portion; however, they are preferably provided on the side surface or rear surface of the display portion because the design is improved. For example, a memory including image data taken with a digital camera is inserted into the storage medium inserting portion of the digital photo frame and the image data is imported. Then, the imported image data can be displayed in the display portion 9703.
The digital photo frame 9700 may send and receive information wirelessly. In this case, desired image data can be wirelessly imported into the digital photo frame 9700 and can be displayed therein.
Information can be input to the cellular phone 1000 illustrated in
There are mainly three screen modes of the display portion 1002. The first mode is a display mode mainly for displaying an image. The second mode is an input mode mainly for inputting information such as text. The third mode is a display-and-input mode in which two modes of the display mode and the input mode are mixed.
For example, in the case of making a call or text messaging, the display portion 1002 is set to a text input mode where text input is mainly performed, and text input operation can be performed on a screen. In this case, it is preferable to display a keyboard or number buttons on almost the entire screen of the display portion 1002.
When a detection device including a sensor for detecting inclination, such as a gyroscope or an acceleration sensor, is provided inside the cellular phone 1000, display in the screen of the display portion 1002 can be automatically switched by judging the direction of the cellular phone 1000 (whether the cellular phone 1000 is placed horizontally or vertically for a landscape mode or a portrait mode).
Further, the screen modes are switched by touching the display portion 1002 or operating the operation button 1003 of the housing 1001. Alternatively, the screen modes can be switched depending on kinds of images displayed in the display portion 1002. For example, when a signal for an image displayed in the display portion is data of moving images, the screen mode is switched to the display mode. When the signal is text data, the screen mode is switched to the input mode.
Moreover, in the input mode, when input by touching the display portion 1002 is not performed within a specified period while a signal detected by an optical sensor in the display portion 1002 is detected, the screen mode may be controlled so as to be switched from the input mode to the display mode.
The display portion 1002 can also function as an image sensor. For example, an image of a palm print, a fingerprint, or the like is taken by touching the display portion 1002 with the palm or the finger, whereby personal authentication can be performed. Moreover, when a backlight which emits near-infrared light or a sensing light source which emits near-infrared light is provided in the display portion, a finger vein, a palm vein, or the like can be taken.
As described in Embodiment 8, when a display device including a protective circuit whose function has been improved by the use of a non-linear element including an oxide semiconductor and whose operation has been made stable is mounted on an electronic appliance, it is possible to manufacture an electronic appliance including a display device with high reliability, on which a protective circuit including a non-linear element in which a defect due to peeling of a thin film does not easily occur is mounted.
Embodiment 8 can be combined with the structure disclosed in another Embodiment as appropriate.
This application is based on Japanese Patent Application serial no. 2008-235105 filed with Japan Patent Office on Sep. 12, 2008, the entire contents of which are hereby incorporated by reference.
10: SUBSTRATE, 11: SCAN LINE INPUT TERMINAL, 12: SIGNAL LINE INPUT TERMINAL, 13: SCAN LINE, 14: SIGNAL LINE, 15: GATE ELECTRODE, 16: GATE ELECTRODE, 17: PIXEL PORTION, 18: PIXEL, 19: PIXEL TRANSISTOR, 20: STORAGE CAPACITOR PORTION, 21: PIXEL ELECTRODE, 22: CAPACITOR LINE, 23: COMMON TERMINAL, 24: PROTECTIVE CIRCUIT, 25: PROTECTIVE CIRCUIT, 26: PROTECTIVE CIRCUIT, 27: CAPACITOR BUS LINE, 28: COMMON WIRING, 29: COMMON WIRING, 30: NON-LINEAR ELEMENT, 30a: NON-LINEAR ELEMENT, 30b: NON-LINEAR ELEMENT, 31: NON-LINEAR ELEMENT, 31a: NON-LINEAR ELEMENT, 31b: NON-LINEAR ELEMENT, 36: OXIDE SEMICONDUCTOR LAYER, 37: GATE INSULATING LAYER, 38: WIRING LAYER, 39: WIRING LAYER, 40: OXIDE SEMICONDUCTOR LAYER, 41: CONDUCTIVE LAYER, 42: INTERLAYER INSULATING LAYER, 43: CONTACT HOLE, 44: WIRING LAYER, 100: SUBSTRATE, 101: GATE ELECTRODE, 102: GATE INSULATING LAYER, 103: OXIDE SEMICONDUCTOR LAYER, 105a: SOURCE ELECTRODE LAYER, 105b: DRAIN ELECTRODE LAYER, 106a: SOURCE REGION, 106b: DRAIN REGION, 107: PROTECTIVE INSULATING FILM, 108: SCAN LINE, 125: CONTACT HOLE, 126: CONTACT HOLE, 128: WIRING LAYER, 580: SUBSTRATE, 581: THIN FILM TRANSISTOR, 583: INTERLAYER INSULATING LAYER, 584: PROTECTIVE FILM, 585: INSULATING LAYER, 587: ELECTRODE LAYER, 588: ELECTRODE LAYER, 589: SPHERICAL PARTICLE, 590a: BLACK REGION, 590b: WHITE REGION, 594: CAVITY, 595: FILLER, 596: SUBSTRATE, 650: SCAN LINE, 651: COMMON WIRING, 730a: NON-LINEAR ELEMENT, 730b: NON-LINEAR ELEMENT, 730c: NON-LINEAR ELEMENT, 740a: NON-LINEAR ELEMENT, 740b: NON-LINEAR ELEMENT, 740c: NON-LINEAR ELEMENT, 740d: NON-LINEAR ELEMENT, 1000: CELLULAR PHONE, 1001: HOUSING, 1002: DISPLAY PORTION, 1003: OPERATION BUTTON, 1004: EXTERNAL CONNECTION PORT, 1005: SPEAKER, 1006: MICROPHONE, 2600: TFT SUBSTRATE, 2601: COUNTER SUBSTRATE, 2602: SEALANT, 2603: PIXEL PORTION, 2604: DISPLAY ELEMENT, 2605: COLOR LAYER, 2606: POLARIZING PLATE, 2607: POLARIZING PLATE, 2608: WIRING CIRCUIT PORTION, 2609: FLEXIBLE WIRING BOARD, 2610: COLD CATHODE TUBE, 2611: REFLECTING PLATE, 2612: CIRCUIT BOARD, 2613: DIFFUSER PLATE, 2631: POSTER, 2632: ADVERTISEMENT IN VEHICLE, 2700: ELECTRONIC BOOK DEVICE, 2701: HOUSING, 2703: HOUSING, 2705: DISPLAY PORTION, 2707: DISPLAY PORTION, 2711: AXIS PORTION, 2721: POWER SUPPLY, 2723: OPERATION KEY, 2725: SPEAKER, 4001: SUBSTRATE, 4002: PIXEL PORTION, 4003: SIGNAL LINE DRIVER CIRCUIT, 4004: SCAN LINE DRIVER CIRCUIT, 4005: SEALANT, 4006: SUBSTRATE, 4008: LIQUID CRYSTAL LAYER, 4010: THIN FILM TRANSISTOR, 4011: THIN FILM TRANSISTOR, 4013: LIQUID CRYSTAL ELEMENT, 4015: CONNECTING TERMINAL ELECTRODE, 4016: TERMINAL ELECTRODE, 4018: FPC, 4019: ANISOTROPIC CONDUCTIVE FILM, 4020: INSULATING LAYER, 4021: INSULATING LAYER, 4030: PIXEL ELECTRODE LAYER, 4031: COUNTER ELECTRODE LAYER, 4032: INSULATING LAYER, 4033: INSULATING LAYER, 4035: SPACER, 4501: SUBSTRATE, 4502: PIXEL PORTION, 4503a: SIGNAL LINE DRIVER CIRCUIT, 4503b: SIGNAL LINE DRIVER CIRCUIT, 4504a: SCAN LINE DRIVER CIRCUIT, 4504b: SCAN LINE DRIVER CIRCUIT 4505: SEALING MATERIAL, 4506: SUBSTRATE, 4507: FILLER, 4509: THIN FILM TRANSISTOR, 4510: THIN FILM TRANSISTOR, 4511: LIGHT-EMITTING ELEMENT, 4512: ELECTRIC FIELD LIGHT-EMITTING LAYER, 4513: ELECTRODE LAYER, 4515: CONNECTION TERMINAL ELECTRODE, 4516: TERMINAL ELECTRODE, 4517: ELECTRODE LAYER, 4518a: FPC, 4518b: FPC, 4519: ANISOTROPIC CONDUCTIVE FILM, 4520: PARTITION WALL, 5300: SUBSTRATE, 5301: PIXEL PORTION, 5302: SCAN LINE DRIVER CIRCUIT, 5303: SIGNAL LINE DRIVER CIRCUIT, 5400: SUBSTRATE, 5401: PIXEL PORTION, 5402: SCAN LINE DRIVER CIRCUIT, 5403: SIGNAL LINE DRIVER CIRCUIT, 5404: SCAN LINE DRIVER CIRCUIT, 5501: WIRING, 5502: WIRING, 5503: WIRING, 5504: WIRING, 5505: WIRING, 5506: WIRING, 5543: NODE, 5544: NODE, 5571: THIN FILM TRANSISTOR, 5572: THIN FILM TRANSISTOR, 5573: THIN FILM TRANSISTOR, 5574: THIN FILM TRANSISTOR, 5575: THIN FILM TRANSISTOR, 5576: THIN FILM TRANSISTOR, 5577: THIN FILM TRANSISTOR, 5578: THIN FILM TRANSISTOR, 5601: DRIVER IC, 5602: SWITCH GROUP, 5603a: THIN FILM TRANSISTOR, 5603b: THIN FILM TRANSISTOR, 5603c: THIN FILM TRANSISTOR, 5611: WIRING, 5612: WIRING, 5613: WIRING, 5621: WIRING, 5701: FLIP-FLOP, 5703a: TIMING, 5703b: TIMING, 5703c: TIMING, 5711: WIRING, 5712: WIRING, 5713: WIRING, 5714: WIRING, 5715: WIRING, 5716: WIRING, 5717: WIRING, 5721: SIGNAL, 5803a: TIMING, 5803b: TIMING, 5803c: TIMING, 5821: SIGNAL, 6400: PIXEL, 6401: SWITCHING TRANSISTOR, 6402: DRIVER TRANSISTOR, 6403: CAPACITOR, 6404: LIGHT-EMITTING ELEMENT, 6405: SIGNAL LINE, 6406: SCAN LINE, 6407: POWER SUPPLY LINE, 6408: COMMON ELECTRODE, 7001: DRIVER TFT, 7002: LIGHT-EMITTING ELEMENT, 7003: CATHODE, 7004: LIGHT-EMITTING LAYER, 7005: ANODE, 7011: DRIVER TFT, 7012: LIGHT-EMITTING ELEMENT, 7013: CATHODE, 7014: LIGHT-EMITTING LAYER, 7015: ANODE, 7016: LIGHT-BLOCKING FILM, 7017: CONDUCTIVE FILM, 7021: DRIVER TFT, 7022: LIGHT-EMITTING ELEMENT, 7023: CATHODE, 7024: LIGHT-EMITTING LAYER, 7025: ANODE, 7027: CONDUCTIVE FILM, 9600: TELEVISION DEVICE, 9601: HOUSING, 9603: DISPLAY PORTION, 9605: STAND, 9607: DISPLAY PORTION, 9609: OPERATION KEY, 9610: REMOTE CONTROLLER, 9700: DIGITAL PHOTO FRAME, 9701: HOUSING, 9703: DISPLAY PORTION, 9881: HOUSING, 9882: DISPLAY PORTION, 9883: DISPLAY PORTION, 9884: SPEAKER PORTION, 9885: OPERATION KEY, 9886: STORAGE MEDIUM INSERTING PORTION, 9887: CONNECTION TERMINAL, 9888: SENSOR, 9889: MICROPHONE, 9890: LED LAMP, 9891: HOUSING, 9893: CONNECTOR, 9900: SLOT MACHINE, 9901: HOUSING, AND 9903: DISPLAY PORTION.
Number | Date | Country | Kind |
---|---|---|---|
2008-235105 | Sep 2008 | JP | national |
Number | Name | Date | Kind |
---|---|---|---|
5289030 | Yamazaki et al. | Feb 1994 | A |
5373377 | Ogawa et al. | Dec 1994 | A |
5585949 | Yamazaki et al. | Dec 1996 | A |
5606340 | Suzuki et al. | Feb 1997 | A |
5731856 | Kim et al. | Mar 1998 | A |
5744864 | Cillessen et al. | Apr 1998 | A |
5847410 | Nakajima | Dec 1998 | A |
5909035 | Kim | Jun 1999 | A |
6172733 | Hong et al. | Jan 2001 | B1 |
6294274 | Kawazoe et al. | Sep 2001 | B1 |
6563174 | Kawasaki et al. | May 2003 | B2 |
6586346 | Yamazaki et al. | Jul 2003 | B1 |
6727522 | Kawasaki et al. | Apr 2004 | B1 |
6791632 | Lee et al. | Sep 2004 | B2 |
6960812 | Yamazaki et al. | Nov 2005 | B2 |
7049190 | Takeda et al. | May 2006 | B2 |
7061014 | Hosono et al. | Jun 2006 | B2 |
7064346 | Kawasaki et al. | Jun 2006 | B2 |
7105868 | Nause et al. | Sep 2006 | B2 |
7189992 | Wager, III et al. | Mar 2007 | B2 |
7211825 | Shih et al. | May 2007 | B2 |
7282782 | Hoffman et al. | Oct 2007 | B2 |
7297977 | Hoffman et al. | Nov 2007 | B2 |
7301211 | Yamazaki et al. | Nov 2007 | B2 |
7323356 | Hosono et al. | Jan 2008 | B2 |
7339187 | Wager, III et al. | Mar 2008 | B2 |
7385224 | Ishii et al. | Jun 2008 | B2 |
7402506 | Levy et al. | Jul 2008 | B2 |
7411209 | Endo et al. | Aug 2008 | B2 |
7453065 | Saito et al. | Nov 2008 | B2 |
7453087 | Iwasaki | Nov 2008 | B2 |
7453420 | Watanabe et al. | Nov 2008 | B2 |
7462862 | Hoffman et al. | Dec 2008 | B2 |
7468304 | Kaji et al. | Dec 2008 | B2 |
7501293 | Ito et al. | Mar 2009 | B2 |
7576394 | Furuta et al. | Aug 2009 | B2 |
7601984 | Sano et al. | Oct 2009 | B2 |
7674650 | Akimoto et al. | Mar 2010 | B2 |
7732819 | Akimoto et al. | Jun 2010 | B2 |
7760309 | Ahn et al. | Jul 2010 | B2 |
7888207 | Wager, III et al. | Feb 2011 | B2 |
7889189 | Fujita | Feb 2011 | B2 |
7893431 | Kim et al. | Feb 2011 | B2 |
7968884 | Yamazaki et al. | Jun 2011 | B2 |
8054279 | Umezaki et al. | Nov 2011 | B2 |
8072565 | Ahn et al. | Dec 2011 | B2 |
8134156 | Akimoto | Mar 2012 | B2 |
8158464 | Akimoto | Apr 2012 | B2 |
8334959 | Hirabayashi et al. | Dec 2012 | B2 |
8368079 | Akimoto | Feb 2013 | B2 |
8421070 | Kim et al. | Apr 2013 | B2 |
8525165 | Akimoto | Sep 2013 | B2 |
8735882 | Kim et al. | May 2014 | B2 |
8743044 | Umezaki et al. | Jun 2014 | B2 |
8902145 | Umezaki et al. | Dec 2014 | B2 |
8941114 | Yamazaki et al. | Jan 2015 | B2 |
9130049 | Sano et al. | Sep 2015 | B2 |
20010046027 | Tai et al. | Nov 2001 | A1 |
20020056838 | Ogawa | May 2002 | A1 |
20020132454 | Ohtsu et al. | Sep 2002 | A1 |
20030020845 | Lee et al. | Jan 2003 | A1 |
20030189401 | Kido et al. | Oct 2003 | A1 |
20030218222 | Wager et al. | Nov 2003 | A1 |
20040038446 | Takeda et al. | Feb 2004 | A1 |
20040127038 | Carcia et al. | Jul 2004 | A1 |
20050012097 | Yamazaki | Jan 2005 | A1 |
20050017302 | Hoffman | Jan 2005 | A1 |
20050164423 | Maekawa et al. | Jul 2005 | A1 |
20050199959 | Chiang et al. | Sep 2005 | A1 |
20050285198 | Chang et al. | Dec 2005 | A1 |
20060035452 | Carcia et al. | Feb 2006 | A1 |
20060043377 | Hoffman et al. | Mar 2006 | A1 |
20060091793 | Baude et al. | May 2006 | A1 |
20060108529 | Saito et al. | May 2006 | A1 |
20060108636 | Sano et al. | May 2006 | A1 |
20060110867 | Yabuta et al. | May 2006 | A1 |
20060113536 | Kumomi et al. | Jun 2006 | A1 |
20060113539 | Sano et al. | Jun 2006 | A1 |
20060113549 | Den et al. | Jun 2006 | A1 |
20060113565 | Abe et al. | Jun 2006 | A1 |
20060145951 | Watanabe et al. | Jul 2006 | A1 |
20060169973 | Isa et al. | Aug 2006 | A1 |
20060170111 | Isa et al. | Aug 2006 | A1 |
20060197092 | Hoffman et al. | Sep 2006 | A1 |
20060208977 | Kimura | Sep 2006 | A1 |
20060228974 | Thelss et al. | Oct 2006 | A1 |
20060231882 | Kim et al. | Oct 2006 | A1 |
20060238135 | Kimura | Oct 2006 | A1 |
20060244107 | Sugihara et al. | Nov 2006 | A1 |
20060284171 | Levy et al. | Dec 2006 | A1 |
20060284172 | Ishii | Dec 2006 | A1 |
20060292777 | Dunbar | Dec 2006 | A1 |
20070024187 | Shin et al. | Feb 2007 | A1 |
20070046191 | Saito | Mar 2007 | A1 |
20070052025 | Yabuta | Mar 2007 | A1 |
20070054507 | Kaji et al. | Mar 2007 | A1 |
20070072439 | Akimoto et al. | Mar 2007 | A1 |
20070090365 | Hayashi et al. | Apr 2007 | A1 |
20070108446 | Akimoto | May 2007 | A1 |
20070152217 | Lai et al. | Jul 2007 | A1 |
20070172591 | Seo et al. | Jul 2007 | A1 |
20070187678 | Hirao et al. | Aug 2007 | A1 |
20070187760 | Furuta et al. | Aug 2007 | A1 |
20070194379 | Hosono et al. | Aug 2007 | A1 |
20070252928 | Ito et al. | Nov 2007 | A1 |
20070272922 | Kim et al. | Nov 2007 | A1 |
20070287296 | Chang | Dec 2007 | A1 |
20070296881 | Choi et al. | Dec 2007 | A1 |
20080006877 | Mardilovich et al. | Jan 2008 | A1 |
20080038882 | Takechi et al. | Feb 2008 | A1 |
20080038929 | Chang | Feb 2008 | A1 |
20080050595 | Nakagawara et al. | Feb 2008 | A1 |
20080073653 | Iwasaki | Mar 2008 | A1 |
20080083950 | Pan et al. | Apr 2008 | A1 |
20080106191 | Kawase | May 2008 | A1 |
20080108198 | Wager et al. | May 2008 | A1 |
20080128689 | Lee et al. | Jun 2008 | A1 |
20080129195 | Ishizaki et al. | Jun 2008 | A1 |
20080131822 | Liao et al. | Jun 2008 | A1 |
20080166834 | Kim et al. | Jul 2008 | A1 |
20080182358 | Cowdery-Corvan et al. | Jul 2008 | A1 |
20080197350 | Park et al. | Aug 2008 | A1 |
20080203387 | Kang et al. | Aug 2008 | A1 |
20080224133 | Park et al. | Sep 2008 | A1 |
20080254569 | Hoffman et al. | Oct 2008 | A1 |
20080258139 | Ito et al. | Oct 2008 | A1 |
20080258140 | Lee et al. | Oct 2008 | A1 |
20080258141 | Park et al. | Oct 2008 | A1 |
20080258143 | Kim et al. | Oct 2008 | A1 |
20080284709 | Yamazaki | Nov 2008 | A1 |
20080296568 | Ryu et al. | Dec 2008 | A1 |
20080308796 | Akimoto et al. | Dec 2008 | A1 |
20080308797 | Akimoto et al. | Dec 2008 | A1 |
20080308804 | Akimoto et al. | Dec 2008 | A1 |
20080308805 | Akimoto et al. | Dec 2008 | A1 |
20080308806 | Akimoto et al. | Dec 2008 | A1 |
20090008639 | Akimoto et al. | Jan 2009 | A1 |
20090065771 | Iwasaki et al. | Mar 2009 | A1 |
20090068773 | Lai et al. | Mar 2009 | A1 |
20090073325 | Kuwabara et al. | Mar 2009 | A1 |
20090114910 | Chang | May 2009 | A1 |
20090134399 | Sakakura et al. | May 2009 | A1 |
20090152506 | Umeda et al. | Jun 2009 | A1 |
20090152541 | Maekawa et al. | Jun 2009 | A1 |
20090179199 | Sano et al. | Jul 2009 | A1 |
20090186437 | Akimoto | Jul 2009 | A1 |
20090186445 | Akimoto | Jul 2009 | A1 |
20090189155 | Akimoto | Jul 2009 | A1 |
20090189156 | Akimoto | Jul 2009 | A1 |
20090278122 | Hosono et al. | Nov 2009 | A1 |
20090280600 | Hosono et al. | Nov 2009 | A1 |
20100003783 | Akimoto | Jan 2010 | A1 |
20100025678 | Yamazaki et al. | Feb 2010 | A1 |
20100065838 | Yamazaki et al. | Mar 2010 | A1 |
20100065840 | Yamazaki et al. | Mar 2010 | A1 |
20100065842 | Yamazaki et al. | Mar 2010 | A1 |
20100065844 | Tokunaga | Mar 2010 | A1 |
20100092800 | Itagaki et al. | Apr 2010 | A1 |
20100109002 | Itagaki et al. | May 2010 | A1 |
20110254004 | Yamazaki et al. | Oct 2011 | A1 |
20150325707 | Sano et al. | Nov 2015 | A1 |
Number | Date | Country |
---|---|---|
0556989 | Aug 1993 | EP |
1737044 | Dec 2006 | EP |
1770788 | Apr 2007 | EP |
1906414 | Apr 2008 | EP |
1995787 | Nov 2008 | EP |
1998373 | Dec 2008 | EP |
1998374 | Dec 2008 | EP |
1998375 | Dec 2008 | EP |
2226847 | Sep 2010 | EP |
2453480 | May 2012 | EP |
2453481 | May 2012 | EP |
2455975 | May 2012 | EP |
60-198861 | Oct 1985 | JP |
63-210022 | Aug 1988 | JP |
63-210023 | Aug 1988 | JP |
63-210024 | Aug 1988 | JP |
63-215519 | Sep 1988 | JP |
63-239117 | Oct 1988 | JP |
63-265818 | Nov 1988 | JP |
03-231472 | Oct 1991 | JP |
05-152330 | Jun 1993 | JP |
05-251705 | Sep 1993 | JP |
06-148688 | May 1994 | JP |
07-056191 | Mar 1995 | JP |
08-264794 | Oct 1996 | JP |
09-232585 | Sep 1997 | JP |
09-265110 | Oct 1997 | JP |
09-265111 | Oct 1997 | JP |
09-281525 | Oct 1997 | JP |
10-303431 | Nov 1998 | JP |
11-505377 | May 1999 | JP |
11-183876 | Jul 1999 | JP |
11-288007 | Oct 1999 | JP |
2000-044236 | Feb 2000 | JP |
2000-150900 | May 2000 | JP |
2002-076356 | Mar 2002 | JP |
2002-289859 | Oct 2002 | JP |
2003-069028 | Mar 2003 | JP |
2003-086000 | Mar 2003 | JP |
2003-086808 | Mar 2003 | JP |
2003-107528 | Apr 2003 | JP |
2004-103957 | Apr 2004 | JP |
2004-246202 | Sep 2004 | JP |
2004-273614 | Sep 2004 | JP |
2004-273732 | Sep 2004 | JP |
2004-361571 | Dec 2004 | JP |
2005-352479 | Dec 2005 | JP |
2006-502597 | Jan 2006 | JP |
2006-165527 | Jun 2006 | JP |
2006-245093 | Sep 2006 | JP |
2007-041096 | Feb 2007 | JP |
2007-065615 | Mar 2007 | JP |
2007-096055 | Apr 2007 | JP |
2007-123861 | May 2007 | JP |
2007-150158 | Jun 2007 | JP |
2007-165861 | Jun 2007 | JP |
2007-250983 | Sep 2007 | JP |
2008-089915 | Apr 2008 | JP |
2008-152084 | Jul 2008 | JP |
2008-166744 | Jul 2008 | JP |
2008-176089 | Jul 2008 | JP |
2009-533884 | Sep 2009 | JP |
2001-0045688 | Jun 2001 | KR |
2001-0045866 | Jun 2001 | KR |
2007-0090182 | Sep 2007 | KR |
WO-2004038757 | May 2004 | WO |
WO-2004072941 | Aug 2004 | WO |
WO-2004114391 | Dec 2004 | WO |
WO-2006051993 | May 2006 | WO |
WO-2007058329 | May 2007 | WO |
WO-2007119386 | Oct 2007 | WO |
WO-2007120010 | Oct 2007 | WO |
Entry |
---|
Taiwanese Office Action (Application No. 98130557) dated Jun. 24, 2014. |
International Search Report (Application No. PCT/JP2009/065129) dated Nov. 2, 2009. |
Written Opinion (Application No. PCT/JP2009/065129) dated Nov. 2, 2009. |
Dembo.H et al., “RFCPUS on Glass and Plastic Substrates Fabricated by TFT Transfer Technology”, IEDM 05: Technical Digest of International Electron Devices Meeting, Dec. 5, 2005, pp. 1067-1069. |
Ikeda.T et al., “Full-Functional System Liquid Crystal Display Using CG-Silicon Technology”, SID Digest '04 : SID International Symposium Digest of Technical Papers, 2004, vol. 35. pp. 860-863. |
Nomura.K et al., “Room-Temperature Fabrication of Transparent Flexible Thin-Film Transistors Using Amorphous Oxide Semiconductors”, Nature, Nov. 25, 2004, vol. 432, pp. 488-492. |
Takahashi.M et al., “Theoretical Analysis of IGZO Transparent Amorphous Oxide Semiconductor”, IDW '08 : Proceedings of the 15th International Display Workshops, Dec. 3, 2008, pp. 1637-1640. |
Prins.M et al., “A Ferroelectric Transparent Thin-Film Transistor”, Appl. Phys. Lett. (Applied Physics Letters) , Jun. 17, 1996, vol. 68, No. 25, pp. 3650-3652. |
Nakamura.M et al., “The phase relations in the In2O3—Ga2ZnO4—ZnO system at 1350° C.”, Journal of Solid State Chemistry, Aug. 1, 1991, vol. 93, No. 2, pp. 298-315. |
Kimizuka.N et al., “Syntheses and Single-Crystal Data of Homologous Compounds, In2O3(ZnO)m (m=3, 4, and 5), InGaO3(ZnO)3, and Ga2O3(ZnO)m (m=7, 8, 9, and 16) in the In2O3—ZnGa2O4—ZnO System”, Journal of Solid State Chemistry, Apr. 1, 1995, vol. 116, No. 1, pp. 170-178. |
Nomura.K et al., “Thin-Film Transistor Fabricated in Single-Crystalline Transparent Oxide Semiconductor”, Science, May 23, 2003, vol. 300, No. 5623, pp. 1269-1272. |
Osada.T et al., “15.2: Development of Driver-Integrated Panel using Amorphous In—Ga—Zn-Oxide TFT”, SID Digest '09 : SID International Symposium Digest of Technical Papers, May 31, 2009, pp. 184-187. |
Li.C et al., “Modulated Structures of Homologous Compounds InMO3(ZnO)m (M=In,Ga; m=Integer) Described by Four-Dimensional Superspace Group”, Journal of Solid State Chemistry, 1998, vol. 139, pp. 347-355. |
Lee.J et al., “World's Largest (15-Inch) XGA AMLCD Panel Using IGZO Oxide TFT”, SID Digest '08 SID International Symposium Digest Of Technical Papers, May 20, 2008, vol. 39, pp. 625-628. |
Nowatari.H et al., “60.2: Intermediate Connector With Suppressed Voltage Loss for White Tandem OLEDs”, SID Digest '09 : SID International Symposium Digest of Technical Papers, May 31, 2009, vol. 40, pp. 899-902. |
Kanno.H et al., “White Stacked Electrophosphorecent Organic Light-Emitting Devices Employing MoO3 As a Charge-Generation Layer”, Adv. Mater. (Advanced Materials), 2006, vol. 18, No. 3, pp. 339-342. |
Tsuda.K et al., “Ultra Low Power Consumption Technologies for Mobile TFT-LCDs”, IDW '02 : Proceedings of the 9th International Display Workshops, Dec. 4, 2002, pp. 295-298. |
Jeong.J et al., “3.1: Distinguished Paper: 12.1-Inch WXGA AMOLED Display Driven by Indium-Gallium-Zinc Oxide TFTs Array”, SID Digest '08 : SID International Symposium Digest of Technical Papers, May 20, 2008, vol. 39, No. 1, pp. 1-4. |
Kurokawa.Y et al., “UHF RFCPUS on Flexible and Glass Substrates for Secure RFID Systems”, Journal of Solid-State Circuits . 2008. vol. 43, No. 1. pp. 292-299 |
Ohara.H et al., “Amorphous In—Ga—Zn-Oxide TFTs with Suppressed Variation for 4.0 inch QVGA AMOLED Display”, AM-FPD '09 Digest of Technical Papers, Jul. 1, 2009, pp. 227-230, The Japan Society of Applied Physics. |
Coates.D et al., “Optical Studies of the Amorphous Liquid-Cholesteric Liquid Crystal Transition:The “Blue Phase””, Physics Letters, Sep. 10, 1973, vol. 45A. No. 2, pp. 115-116. |
Cho.D et al., “21.2:Al and Sn-Doped Zinc Indium Oxide Thin Film Transistors for AMOLED Back-Plane”, SID Digest '09 : SID International Symposium Digest of Technical Papers, May 31, 2009, pp. 280-283. |
Lee.M et al., “15.4:Excellent Performance of Indium-Oxide-Based Thin-Film Transistors by DC Sputtering”, SID Digest '09 : SID International Symposium Digest of Technical Papers, May 31, 2009, pp. 191-193. |
Jin.D et al., “65.2:Distinguished Paper:World-Largest (6.5″) Flexible Full Color Top Emission AMOLED Display On Plastic Film and its Bending Properties”, SID Digest '09 : SID International Symposium Digest Of Technical Papers, May 31, 2009, pp, 983-985. |
Sakata.J et al., “Development of 4.0-In. AMOLED Display With Driver Circuit Using Amorphous In—Ga—Zn-Oxide TFTs”, IDW '09 : Proceedings of the 16th International Display Workshops, 2009, pp. 689-692. |
Park.J et al., “Amorphous Indium-Gallium-Zinc Oxide TFTs and Their Application for Large Size AMOLED”, AM-FPD '08 Digest of Technical Papers, Jul. 2, 2008, pp. 275-278. |
Park.S et al., “Challenge to Future Displays: Transparent AM-OLED Driven by Peald Grown ZnO TFT”, IMID '07 Digest, 2007, pp. 1249-1252. |
Godo.H et al., “Temperature Dependence of Characteristics and Electronic Structure for AMORPHOUS IN—Ga—Zn-OXIDE TFT”, AM-FPD '09 Digest of Technical Papers, July 1, 2009, pp. 41-44. |
Osada.T et al., “Development of Driver-Integrated Panel Using Amorphous In—Ga—Zn-Oxide TFT”, AM-FPD '09 Digest of Technical Papers, Jul. 1, 2009, pp. 33-36. |
Hirao.T et al., “Novel Top-Gate Zinc Oxide Thin-Film Transistors (Zno TFTs) for AMLCDS”, Journal of the SID, 2007, vol. 15, No. 1, pp. 17-22. |
Hosono.H, “68.3:Invited Paper:Transparent Amorphous Oxide Semiconductors for High Performance TFT”, SID Digest '07 : SID International Symposium Digest of Technical Papers, 2007, vol. 38, pp. 1830-1833. |
Godo.H et al., “P-9:Numerical Analysis on Temperature Dependence of Characteristics of Amorphous In—Ga—Zn-Oxide TFT”, SID Digest '09 : SID International Symposium Digest of Technical Papers, May 31, 2009, pp. 1110-1112. |
Ohara.H et al., “21.3:4.0 In. QVGA AMOLED Display Using In—Ga—Zn-Oxide TFTs With a Novel Passivation Layer”, SID Digest '09 : SID International Symposium Digest of Technical Papers, May 31, 2009, pp. 284-287. |
Miyasaka.M, “SUFTLA Flexible Microelectronics on Their Way to Business”, SID Digest '07 : SID International Symposium Digest of Technical Papers, 2007, vol. 38, pp. 1673-1676. |
Chern.H et al., “An Analytical Model for the Above-Threshold Characteristics of Polysilicon Thin-Film Transistors”, IEEE Transactions on Electron Devices, Jul. 1, 1995, vol. 42, No. 7, pp. 1240-1246. |
Kikuchi.H et al., “39.1:Invited Paper:Optically Isotropic Nano-Structured Liquid Crystal Composites for Display Applications”, SID Digest '09 : SID International Symposium Digest of Technical Papers, May 31, 2009, pp. 578-581. |
Asaoka.Y et al., “29.1:Polarizer-Free Reflective LCD Combined With Ultra Low-Power Driving Technology”, SID Digest '09 : SID International Symposium Digest of Technical Papers, May 31, 2009, pp. 395-398. |
Lee.H et al., “Current Status of, Challenges to, and Perspective View of AM-OLED”, IDW '06 : Proceedings of the 13th International Display Workshops, Dec. 7, 2006, pp. 663-666. |
Kikuchi.H et al., “62.2:Invited Paper:Fast Electro-Optical Switching in Polymer-Stabilized Liquid Crystalline Blue Phases For Display Application”, SID Digest '07 : SID International Symposium Digest of Technical Papers, 2007, vol. 38, pp. 1737-1740. |
Kikuchi.H et al., “Polymer-Stabilized Liquid Crystal Blue Phases”, Nature Materials, Sep. 2, 2002, vol. 1, pp. 64-68. |
Kimizuka.N et al., “SPINEL,YbFe2O4, and Yb2Fe3O7 Types of Structures for Compounds in the In2O3 and Sc2O3—A2O3—BO Systems [A; Fe, Ga, or Al; 8: Mg, Mn, Fe, Ni, Cu,or Zn] at Temperatures Over 1000° C.”, Journal of Solid State Chemistry, 1985, vol. 60, pp. 382-384. |
Kitzerow.H et al., “Observation of Blue Phases in Chiral Networks”, Liquid Crystals, 1993, vol. 14, No. 3, pp. 911-916. |
Costello.M et al., “Electron Microscopy of a Cholesteric Liquid Crystal and Its Blue Phase”, Phys. Rev. A (Physical Review. A), May 1, 1984, vol. 29, No. 5, pp. 2957-2959. |
Meiboom.S et al., “Theory of the Blue Phase of Cholesteric Liquid Crystals”, Phys. Rev. Lett. (Physical Review Letters), May 4, 1981, vol. 46, No. 18, pp. 1216-1219. |
Nakamura.M, “Synthesis of Homologous Compound with New Long-Period Structure”, NIRIM Newsletter, Mar. 1, 1995, vol. 150, pp. 1-4. |
Hosono.H et al., “Working hypothesis to explore novel wide band gap electrically conducting amorphous oxides and examples”, J. Non-Cryst. Solids (Journal of Non-Crystalline Solids), 1996, vol. 198-200, pp. 165-169. |
Orita.M et al., “Mechanism of Electrical Conductivity of Transparent InGaZnO4”, Phys. Rev. B (PHYSICAL REVIEW. B), Jan. 15, 2000, vol. 61, No. 3, pp. 1811-1816. |
Van de Walle.C, “Hydrogen as a Cause of Doping in Zinc Oxide”, Phys. Rev. Lett. (Physical Review Letters), Jul. 31, 2000, vol. 85, No. 5, pp. 1012-1015. |
Orita.M et al., “Amorphous transparent conductive oxide InGaO3(ZnO)m (m<4):a Zn4s conductor”, Philosophical Magazine, 2001, vol. 81, No. 5, pp. 501-515. |
Janotti.A et al., “Oxygen Vacancies in ZnO”, Appl. Phys. Lett. (Applied Physics Letters) , 2005, vol. 87, pp. 122102-1-122102-3. |
Clark.S et al., “First Principles Methods Using CASTEP”, Zeitschrift fur Kristallographie, 2005, vol. 220, pp. 567-570. |
Nomura.K et al., “Amorphous Oxide Semiconductors for High-Performance Flexible Thin-Film Transistors”, Jpn. J. Appl. Phys. (Japanese Journal of Applied Physics) , 2006, vol. 45, No. 5B, pp. 4303-4308. |
Janotti.A et al., “Native Point Defects in ZnO”, Phys. Rev. B (Physical Review. B), Oct. 4, 2007, vol. 76, No. 16, pp. 165202-1-165202-22. |
Lany.S et al., “Dopability, Intrinsic Conductivity, and Nonstoichiometry of Transparent Conducting Oxides”, Phys. Rev. Lett. (Physical Review Letters), Jan. 26, 2007, vol. 98, pp. 045501-1-045501-4. |
Park.J et al., “Improvements in the Device Characteristics of Amorphous Indium Gallium Zinc Oxide Thin-Film Transistors by Ar Plasma Treatment”, Appl. Phys. Lett. (Applied Physics Letters), Jun. 26, 2007, vol. 90, No. 26, pp. 262106-1-262106-3. |
Park.J et al., “Electronic Transport Properties of Amorphous Indium-Gallium-Zinc Oxide Semiconductor Upon Exposure to Water”, Appl. Phys. Lett. (Applied Physics Letters) , 2008, vol. 92, pp. 072104-1-072104-3. |
Hsieh.H et al., “P-29:Modeling of Amorphous Oxide Semiconductor Thin Film Transistors and Subgap Density of States”, SID Digest '08 : SID International Symposium Digest of Technical Papers, May 20, 2008, vol. 39, pp. 1277-1280. |
Oba.F et al., “Defect energetics in ZnO: A hybrid Hartree-Fock density functional study”, Phys. Rev. B (Physical Review. B), 2008, vol. 77, pp. 245202-1-245202-6. |
Kim.S et al., “High-Performance oxide thin film transistors passivated by various gas plasmas”, 214th ECS Meeting, 2008, No. 2317, ECS. |
Hayashi.R et al., “42.1: Invited Paper: Improved Amorphous In—Ga—Zn—O TFTs”, SID Digest '08 : SID International Symposium Digest of Technical Papers, May 20, 2008, vol. 39, pp. 621-624. |
Son.K et al., “42.4L: Late-News Paper: 4 Inch QVGA AMOLED Driven by the Threshold Voltage Controlled Amorphous GIZO (Ga2O3—In2O3—ZnO) TFT”, SID Digest '08 : SID International Symposium Digest of Technical Papers, May 20, 2008, vol. 39, pp. 633-636. |
Park.Sang-Hee et al., “42.3: Transparent ZnO Thin Film Transistor for the Application of High Aperture Ratio Bottom Emission AM-OLED Display”, SID Digest '08 : SID International Symposium Digest of Technical Papers, May 20, 2008, vol. 39, pp. 629-632. |
Fung.T et al., “2-D Numerical Simulation of High Performance Amorphous In—Ga—Zn—O TFTs for Flat Panel Displays”, AM-FPD '08 Digest of Technical Papers, Jul. 2, 2008, pp. 251-252, The Japan Society of Applied Physics. |
Mo.Y et al., “Amorphous Oxide TFT Backplanes for Large Size AMOLED Displays”, IDW '08 : Proceedings of the 6th International Display Workshops, Dec. 3, 2008, pp. 581-584. |
Asakuma.N et al., “Crystallization and Reduction of Sol-Gel-Derived Zinc Oxide Films by Irradiation With Ultraviolet Lamp”, Journal of SOL-Gel Science and Technology, 2003, vol. 26, pp. 181-184. |
Fortunato.E et al., “Wide-Bandgap High-Mobility ZnO Thin-Film Transistors Produced at Room Temperature”, Appl. Phys. Lett. (Applied Physics Letters) , Sep. 27, 2004, vol. 85, No. 13, pp. 2541-2543. |
Masuda.S et al., “Transparent thin film transistors using ZnO as an active channel layer and their electrical properties”, J. Appl. Phys. (Journal of Applied Physics) , Feb. 1, 2003, vol. 93, No. 3, pp. 1624-1630. |
Oh.M et al., “Improving the Gate Stability of ZnO Thin-Film Transistors With Aluminum Oxide Dielectric Layers”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2008, vol. 155, No. 12, pp. H1009-H1014. |
Park.J et al., “Dry etching of ZnO films and plasma-induced damage to optical properties”, J. Vac. Sci. Technol. B (Journal of Vacuum Science & Technology B), Mar. 1, 2003, vol. 21, No. 2, pp. 800-803. |
Ueno.K et al., “Field-Effect Transistor on SrTiO3 With Sputtered Al2O3 Gate Insulator”, Appl. Phys. Lett. (Applied Physics Letters) , Sep. 1, 2003, vol. 83, No. 9, pp. 1755-1757. |
Nomura.K et al., “Carrier transport in transparent oxide semiconductor with intrinsic structural randomness probed using single-crystalline InGaO3(ZnO)5 films”, APPL. PHYS. Lett (Applied Physics Letters) , Sep. 13, 2004, vol. 85, No. 11, pp. 1993-1995. |
International Search Report (Application No. PCT/JP2009/065134) dated Nov. 2, 2009. |
Written Opinion (Application No. PCT/JP2009/065134) dated Nov. 2, 2009. |
Park.J et al., “High performance amorphous oxide thin film transistors with self-aligned top-gate structure”, IEDM 09: Technical Digest of International Electron Devices Meeting, Dec. 7, 2009, pp. 191-194. |
International Search Report (Application No. PCT/JP2009/065374) dated Nov. 17, 2009. |
Written Opinion (Application No. PCT/JP2009/065374) dated Nov. 17, 2009. |
International Search Report (Application No. PCT/JP2009/065018) dated Nov. 17, 2009. |
Written Opinion (Application No. PCT/JP2009/065018) dated Nov. 17, 2009. |
Korean Office Action (Application No. 2011-7008207) dated Jan. 8, 2016. |
Korean Office Action (Application No. 2016-7018835) dated Oct. 7, 2016. |
Number | Date | Country | |
---|---|---|---|
20140264329 A1 | Sep 2014 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 12553122 | Sep 2009 | US |
Child | 14290216 | US |