1. Field of the Invention
The present invention relates to a semiconductor laser device which is improved in light-emitting characteristics by reducing a resistance of the device.
2. Description of the Related Art
In recent years, an amount information which must be processed by an information communication machine is vast. Therefore, the demand for a recording device operated at a high speed and a large-capacity recording medium are increasing. In a DVD-R drive device which is one of such recording devices, a high-output and high-efficient semiconductor laser is used. This device records information on a DVD-R serving as a large-capacity recording medium by using a semiconductor laser and reads out the recorded information.
Since further demands for a high speed and a large capacity are possessed in the field of future information communication, a high-output and high-efficient semiconductor laser is necessary. In fact, an AlGaInP-based semiconductor laser of output 140 mW to 200 mW class is being developed.
The structure of a semiconductor laser will be described below. An AlGaInP-based laser immediately after crystal growth is constituted by sequentially laminating a buffer layer (GaAs/AlGaAs), an n-type cladding layer (AlGaInP), a well layer (GaInP), a barrier layer (AlGaInP), an MQW active layer, a p-type cladding layer (AlGaInP), and a p-type GaAs cap layer (contact layer) on an n-type GaAs layer substrate. Such a structure is fabricated by a crystal growing method such as an MOCVD (Metalorganic Chemical Vapor Deposition) method or an MBE (Molecular Beam Epitaxy) method. As a p-type dopant, Zn which is one of the group-II elements is used. Electrodes are arranged on the upper and lower sides of the structure described above, so that a semiconductor laser device is obtained.
In order to obtain a high-output and high-efficient semiconductor laser, the contact resistance of the semiconductor laser must be reduced. The carrier concentration of a p-type GaAs cap layer (contact layer) is set to be high to reduce the contact resistance of the device.
For example, Japanese Laid-open Patent Publication No. H11-54828 describes a semiconductor laser device constituted by a compound semiconductor obtained by separately doping Zn or Si into a cap layer (contact layer). Japanese Laid-open Patent Publication No. H9-51140 describes a semiconductor laser having a p-type ZnSe cap layer. In these semiconductor laser devices, Zn and Se are not used as p-type dopants. Japanese Laid-open Patent Publication No. 2002-261321 discloses a technique for doping C at a predetermined concentration. This C functions as a barrier for suppressing other impurities such as Zn and the like from being diffused.
Zn serving as a p-type dopant has a tendency to be easily diffused in a growth process or a thermal treatment process. For this reason, in a conventional structure in which a p-type GaAs cap layer is doped with Zn at a high concentration, Zn is disadvantageously diffused to an active layer which essentially serves as an undoped layer. When an active layer which essentially serves as an undoped layer is doped, problems such as deterioration of crystal quality, a reduction in emission intensity, and movement (difference from a design value) of a p-n junction position are posed. For this reason, a semiconductor laser having preferable emitting characteristics can not obtain. As a cause of diffusion of Zn, the following is considered. That is, for example, in GaAs, Zn+1 located at an interstitial position is coupled with a hole at a Ga position which is a group-III element or excludes a Ga atom to the interstitial position to tend to occupy the Ga position.
Although Mg which is used as a p-type dopant like Zn has a degree of diffusion which is lower than that of Zn, Mg is saturated at a concentration of about 1.0×1018 cm−3 in doping. For this reason, Mg cannot be easily achieve high-concentration doping which must be performed to reduce a contact resistance.
It is an object of the present invention to prevent or suppress a p-type dopant of a p-type GaAs layer which is doped at a high concentration from being diffused in an active layer to obtain a contact layer having a high carrier concentration and, conclusively, to obtain a high-output and high-efficient semiconductor laser device having a reduced device resistance.
In accordance with one aspect of the present invention, there is a semiconductor laser device in which an active layer, a p-type cladding layer, and a p-type cap layer are sequentially stacked. The p-type cap layer includes both a p-type dopant and an n-type dopant.
In another aspect of the present invention, there is a semiconductor laser device in which an active layer, a p-type cladding layer, and a p-type cap layer are sequentially stacked. The p-type cap layer includes a first layer having a first p-type dopant and a second layer having a second p-type dopant having a diffusion coefficient smaller than that of the first p-type dopant. The first layer is far from the active layer and the second layer is close to the active layer.
In a further aspect of the present invention, there is a semiconductor laser device including an active layer, a p-type cladding layer, and a p-type cap layer. The layers are sequentially stacked, and the p-type cap layer includes at least carbon (C) as a p-type dopant.
In the semiconductor laser device according to the present invention, an active layer, a p-type cladding layer, and a p-type cap layer are sequentially stacked, and the p-type cap layer includes both a p-type dopant and an n-type dopant. In this manner, the p-type dopant is prevented from being diffused in the active layer and the p-type cladding layer, so that the semiconductor laser device can efficiently emit light with a high output power.
In another semiconductor laser device according to the present invention, an active layer, a p-type cladding layer, and a p-type cap layer are sequentially stacked, and the p-type cap layer includes a first layer which is formed by a first p-type dopant and is far from an active layer and a second layer which is formed by a second p-type dopant having a diffusion coefficient smaller than that of the first p-type dopant and which is close to the active layer. In this manner, the p-type dopant is prevented from being diffused in the active layer and the p-type cladding layer, so that the semiconductor laser device can efficiently emit light with a high output power.
In still another semiconductor laser device according to the present invention, an active layer, a p-type cladding layer, and a p-type cap layer are sequentially stacked, and the p-type cap layer includes carbon (C) as a p-type dopant. Carbon (c) has a small diffusion coefficient, and is not easily diffused even if C is doped at a high concentration. Therefore, the p-type dopant can be suppressed from being diffused in an active layer and a p-type cladding layer. Therefore, the semiconductor laser device can efficiently emit light with a high output power.
The present invention will become readily understood from the following description of preferred embodiments thereof made with reference to the accompanying drawings, in which like parts are designated by like reference numeral and in which:
Embodiments of the present invention will be described below with reference to the accompanying drawings. The constituent elements numbered the same reference numeral in the drawings denote the constituent elements having a same function.
The detailed configuration is as follows. The semiconductor laser device 10 includes a p-type GaAs cap layer 1, a p-type cladding layer 2 (AlGaInP) a multi-quantum-well (MQW) active layer 3, an n-type cladding layer 4 (AlGaInP), a buffer layer 5 (GaAs/AlGaAs), and an n-type GaAs substrate 6. These layers are sequentially stacked on the n-type GaAs substrate 6 from the buffer layer 5 in the reverse order using a crystal growth method such as a metal organic chemical vapor deposition (MOCVD) method or a molecular beam epitaxy (MBE) method.
The p-type GaAs cap layer 1 is doped with Zn at a high concentration. The multi-quantum-well active layer 3 is a layer formed by a multi-quantum-well structure. The multi-quantum-well structure is obtained by laminating a large number of quantum-well structures each of which is obtained by sandwiching a small well layer 3b (well layer; GaInP) having a small band gap between barrier layers 3a (AlGaInP) having a large band gap. According to this structure, emission efficiency can be improved.
On the surface of the substrate 6 opposing the buffer layer 5 and the surface of the cap layer 1 opposing the p-type cladding layer 2, electrodes (not shown) are arranged. The electrodes supply holes and electrons for causing the semiconductor laser device to emit light. The holes and electrons are coupled to each other in the multi-quantum-well active layer 3 to emit light. An example of the finished semiconductor laser device is shown in
Zn which is generally used as a p-type dopant has a tendency to be easily diffused. On the other hand, it is considered that Zn is not easily diffused in a region in which Si is doped at a high concentration. This is because (1) Si used as an n-type dopant also occupies a Ga position and becomes Si+Ga and (2) and it is considered that, since both Zn+I located at an interstitial position and Si+Ga located at a Ga position are positively charged, Coulomb repulsion is generated between Zn+I and Si+Ga. More specifically, it is because the polarities of ionization of the p-type dopant and the n-type dopant are equal to each other.
In the cap layer 1 having the above configuration, the Zn+Si—GaAs layer 1b doped with Zn and Si are arranged on the active layer 3 side of the cap layer doped with Zn at a high concentration. For this reason, Zn doped in the upper Zn—GaAs layer 1a can be suppressed by the effect of the Coulomb repulsion from being diffused in the active layer 3.
The semiconductor laser device 20 is different from the semiconductor laser device 10 (
The reason why the Mg—GaAs layer 1c is formed using Mg serving as a p-type dopant like Zn is that a p-type dopant (Zn, Mg) can be prevented from being diffused in the active layer 3 by doping Mg because Mg has a diffusion coefficient smaller than that of Zn. On the other hand, since the semiconductor laser device 20 has the Zn—GaAs layer 1a doped with Zn at a high concentration, as in the first embodiment, a contact resistance can be reduced to realize a high-output and high-efficient laser. Although it is difficult to dope at a high concentration to reduce a contact resistance by applying Mg alone, when the Zn—GaAs layer 1a and the Mg—GaAs layer 1c coexist, diffusion of the p-type dopant into the active layer 3 can be reduced, and the contact resistance can also be reduced.
The semiconductor laser device 30 is different from the semiconductor laser device 10 (
The reason why the Zn+Se—GaAs layer 1d is formed is to prevent Zn doped in a region 1a′ on an active layer side from being diffused in an active layer 3 side. Although Zn serving as a p-type dopant generally has a tendency to be easily diffused, Zn is diffused easier in the GaAs layer id than in the active layer 3 side for the following reason. That is, since Se is generally used as an n-type dopant and is a group-VI element, Se easily occupies the position of As which is a group-V element in GaAs. In this case, Se has negative charges. It is considered that Zn is easily diffused in a region doped with Se for the following reasons. That is, Se occupies a lattice position different from that of Zn (Zn occupies a (Se—As)Ga position), and Coulombic attraction acts between Se and Zn because Se located at a Ga position is negatively charged and because Zn is positively charged. Therefore, the Zn+Se—GaAs layer 1d is formed, so that Zn doped in the region 1a′ on the active layer 3 side can be prevented from being diffused in the active layer 3.
The reason why the semiconductor laser device 60 is different from the semiconductor laser device 10 (
The reason why the C—GaAs layer 1e is employed is that C has a small diffusion coefficient and is not easily diffused in the active layer even though C is doped at a high concentration. When C is doped, diffusion of the p-type dopant into the active layer 3 can be reduced while keeping the high carrier concentration of the p-type GaAs cap layer 1.
The semiconductor laser device 50 is different from the semiconductor laser device 10 (
When Zn doped in the Zn—GaAs layer 1a on the upper side (opposite side of the active layer 3) of the cap layer is diffused in the n-type GaAs layer 1f on the lower side (p-type cladding layer 2 side), a diffusion rate of Zn which is downwardly diffused from the n-type GaAs layer If reduced while carriers are compensated. Therefore, when the thickness of the n-type GaAs layer 1f and the concentration of the n-type dopant are adjusted, Zn doped in the Zn—GaAs layer 1a on the upper side of the cap layer at a high concentration can be prevented and suppressed from being diffused in the active layer 3.
The embodiments of the present invention have been described above. In the first embodiment (
The concentration of carbon doped in the GaAs cap layer will be noted as follows. The concentration of carbon as p-type dopant is preferably more than 1019 cm−3 for high carrier concentration so that the contact resistance can be reduced. Even though the carbon is doped as p-type dopant having a higher concentration in the GaAs cap layer, the carbon is not diffused over the active layer 3 while maintaining high carrier concentration in the cap layer 1e. Therefore, the semiconductor laser device having high power and high performance can be provided.
Method of fabricating the semiconductor laser device is noted as follows. For example, n-type GaAs buffer layer 5, n-type AlGaInP cladding layer 4, multiple quantum well layer 3, p-type AlGaInP cladding layer 2, p-type GaAs cap layer (contact layer) 1a are deposited in turn on the n-type GaAs substrate by using any thin film deposition methods such as MOCVD so that the 5 semiconductor laser device can be provided.
MOCVD can be performed at growth temperature, e.g. 700° C., growth pressure, e.g. 100 mbar (100 hPa). Regarding with source gas used in MOCVD, e.g. trimethyl-indium (TMI) gas, trimethyl-gallium (TMG) gas, trimethyl-aluminum (TMA) gas, phosphine (PH3) gas, arsine (AsH3) gas, silane (SiH4) gas, cyclopentadienyl-magnesium (Cp2Mg) can be used. The source gases are flow controlled by mass flow controller so that desired composition is deposited.
The p-type GaAs cap layer 1e, in which the carbon is doped, is deposited by MOCVD at growth temperature, e.g. more than 542° C., at flow ratio (V/III) of arsine gas/trimethyl gallium gas higher than 0.6, preferably 1.0. On the other hand, in the conventional method, the GaAs layer is deposited at growth temperature ranging from 600° C. to 750° C., and at flow ratio of V/III ranging from 10 to several hundreds by MOCVD. Comparing with the conventional method, carbon derived from a methyl group of trimethylgallium is doped as p-type dopant in the GaAs cap layer without using any specific dopant materials. The above doping method without any specific dopant materials is referred as intrinsic doping method (F. Brunner, J. Crystal Growth 221 (2000), pp53-58). It is noted that a conventional doping method using tetra-bromide carbon as dopant of carbon may be used instead of the intrinsic doping method in the GaAs cap layer.
Although the present invention has been described in connection with the preferred embodiments thereof with reference to the accompanying drawings, it is to be noted that various changes and modifications are apparent to those skilled in the art. Such changes and modifications are to be understood as included within the scope of the present invention as defined by the appended claims, unless they depart therefrom.
Number | Date | Country | Kind |
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2002-362007 | Dec 2002 | JP | national |
2003-276127 | Jul 2003 | JP | national |
Number | Date | Country | |
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Parent | 10732351 | Dec 2003 | US |
Child | 11923751 | Oct 2007 | US |