1. Field of the Invention
The present invention relates to a semiconductor light emitting device in which a Pd electrode is formed on the p-type contact layer, and also relates to a method for manufacturing such a semiconductor light emitting device.
2. Background Art
Semiconductor light emitting devices having a ridge structure are designed such that a voltage is applied to the p-type contact layer at the top of the ridge to supply power to the active layer (see, e.g., JP-A-2007-27181). An electrode is formed on the p-type contact layer to receive this voltage. The requirements of the electrode material include providing good ohmic characteristics and a low contact resistance with the contact layer (see, e.g., JP-A-2006-237476). Further, the electrode material should preferably not come off during the manufacturing process in order to ensure good yield and reliability of the semiconductor light emitting device. That is, the electrode material must have low resistance ohmic characteristics and the property of firmly adhering to the underlying layer without the possibility of peeling off (see, e.g., JP-A-2003-198065 and JP-A-2006-128622).
A problem with nitride semiconductor light emitting devices used as blue-violet LDs is that the use of Ni, etc. as the p-type electrode material prevents the electrode from having good ohmic characteristics and other desirable electrical characteristics, as is known in the art. To avoid this problem, it is common to use Pd as the p-type electrode material in nitride semiconductor light emitting devices of GaN, etc. Pd and Pd-based material are especially used to form a low resistance ohmic electrode in GaN devices (see, e.g., JP-A-2005-340625).
It is common for a p-type electrode of Pd to be formed to contact the underlying insulating film as well as the underlying p-contact layer. In such a case, an adhesive layer is additionally formed between the Pd electrode and the insulating film, since the Pd electrode has poor adhesion to the insulating film and hence may peel off. The above JP-A-2006-128622 discloses semiconductor light emitting devices including an adhesive layer made of a degenerate semiconductor such as ITO (indium tin oxide), or made of a platinum group metal or an oxide thereof.
It has been found, however, that the adhesive layers disclosed in this patent publication still cannot provide sufficient adhesion between the Pd electrode and the underlying insulating film, and hence a portion of the Pd electrode may peel off. On the other hand, there is a need to increase the output power and reduce the operating current of blue-violet LDs formed of a nitride semiconductor. That is, the Pd electrodes (or p-type electrodes) in these LDs must have a lower resistance and better ohmic characteristics than conventional Pd electrodes. It should be noted that the electrode configurations disclosed in the above patent publication cannot satisfy these requirements.
The present invention has been devised to solve the above problems. It is, therefore, an object of the present invention to provide a semiconductor light emitting device in which the Pd electrode (or p-type electrode) is firmly adhered to the underlying insulating film without the possibility of coming off and has improved low resistance ohmic characteristics, which allows the device to deliver higher power and to operate at a lower current than prior laser devices of the same type. The present invention also provides a method for manufacturing such a semiconductor light emitting device.
According to one aspect of the present invention, a semiconductor light emitting device includes a semiconductor layer, an insulating film formed on said semiconductor layer and having an opening therein, a multilayer adhesive layer formed on said insulating film, and a Pd electrode formed in contact with said semiconductor layer through said opening and in contact with said multilayer adhesive layer. The multilayer adhesive layer includes an Au layer at the top. An alloy of Au and Pd is formed at the interface between said Au layer and said Pd electrode.
According to another aspect of the present invention, a method for manufacturing a semiconductor light emitting device includes the following steps. A wafer providing step of providing a wafer which includes a semiconductor layer having a ridge structure which includes a contact layer at the top. A resist forming step of forming a resist on said contact layer. An insulating film forming step of forming an insulating film on a surface of said wafer after said resist forming step. A multilayer adhesive layer forming step of forming a multilayer adhesive layer on said insulating film. A lift-off step of removing said resist after said multilayer adhesive layer forming step. A Pd electrode forming step of, after said lift-off step, forming a Pd electrode continuously covering said contact layer and said multilayer adhesive layer. A sintering heat treatment step of applying a sintering heat treatment to said wafer after said Pd electrode forming step. The multilayer adhesive layer includes an Au layer at the top and further includes a Ti layer or a Cr layer in contact with said insulating film. The application of said sintering heat treatment is such that an alloy of Au and Pd is formed at the interface between said Au layer and said Pd electrode.
Other and further objects, features and advantages of the invention will appear more fully from the following description.
A embodiment of the present invention provides a semiconductor light emitting device in which the p-type electrode (or Pd electrode) is adapted not to peel off the underlying contact layer and the underlying insulating film and have improved low resistance ohmic characteristics. This embodiment also provides a method for manufacturing such a semiconductor light emitting device.
A Pd electrode 31 (described later) is formed on and electrically coupled to the p-type contact layer 88 of the p-type semiconductor layer 27. The p-type contact layer 88 is disposed at the top of a ridge portion 10, as shown in
Channel portions 12 approximately 10 μm wide are disposed adjacent the ridge portion 10. That is, these channel portions 12, formed in and from the p-type semiconductor layer 27, sandwich and define the ridge portion 10, as shown in
The semiconductor light emitting device of the present embodiment further includes a first insulating film 16 disposed to cover and contact the surfaces of the channel portions 12 formed in and from the p-type semiconductor layer 27. In the present embodiment, the first insulating film 16 is made of SiO2. In other embodiments, however, it may be made of a material selected from the group consisting of SiN, SiON, TEOS (tetraethyl orthosilicate), ZrO2, TiO2, Ta2O5, Al2O3, Nb2O5, Hf2O5, and AlN.
A second insulating film 20 is disposed to cover the first insulating film 16 on the channel portions 12 and to cover the terrace portions 14 formed in and from the p-type semiconductor layer 27. In the present embodiment, the second insulating film 20 is made of SiO2. In other embodiments, however, it may be made of a material selected from the group consisting of SiN, SiON, TEOS (tetraethyl orthosilicate), ZrO2, TiO2, Ta2O5, Al2O3, Nb2O5, Hf2O5, and AlN.
Further, a Ti layer 22 covers the surface of the second insulating film 20, and an Au layer 23 covers the surface of the Ti layer 22. In the present embodiment, the Ti layer 22 has a thickness of 30 nm and the Au layer 23 has a thickness of 40 nm. The Ti layer 22 and the Au layer 23 serve to improve the adhesion between the second insulating film 20 and the Pd electrode 31 (described later). The Ti layer 22 and the Au layer 23 are collectively referred to hereinafter as the “multilayer adhesive layer 25.” As shown in
Further, the Pd electrode 31 covers the p-type contact layer 88 and partially covers the Au layer 23. The Pd electrode 31 is used to supply power to the p-type semiconductor layer 27. Thus, in the present embodiment, the Pd electrode 31 is formed in contact with the p-type contact layer 88 at the top of the ridge portion 10 and in contact with the Au layer 23 on the channel portions 12. (The Pd electrode 31 continuously extends over the p-type contact layer 88 and the Au layer 23.) It should be noted that the Pd electrode 31 does not completely cover the channel portions 12. It extends to approximately an intermediate point between the ridge portion 10 and each terrace portion 14, thus covering the ridge portion 10 and a portion of the bottom of each channel portion 12. An alloy, or ally portion, 29 of Pd and Au is formed at the interface between the Pd electrode 31 and the Au layer 23, as shown in
This completes the description of the configuration of the semiconductor light emitting device of the present embodiment. A method for manufacturing the semiconductor light emitting device shown in
Referring to
Next, a resist is applied over the wafer and exposed and developed to leave a resist 18 on the ridge portion 10, as shown in
A second insulating film 20 is then formed on the wafer shown in
Referring now to
Next, the resist 18 and the overlying portions of the multilayer adhesive layer 25 and the second insulating film 20 are removed by lift-off, thereby exposing the p-type contact layer 88 at the top of the ridge portion 10.
A resist 24 is then formed by photolithography to cover the terrace portions 14 and partially cover the channel portions 12, as shown in
Next, a layer 26 of Pd is deposited onto the wafer shown in
The resist 24 and the overlying portion of the Pd layer 26 are then removed by lift-off.
Next, the wafer shown in
The semiconductor light emitting device of the present invention is characterized in that it includes the alloy portion 29 formed at the interface between the Pd electrode 31 and the Au layer 23. The effect of this alloy portion 29 will now be described. Increasing the output power and reducing the current consumption of a laser requires that the p-type electrode in contact with the underlying p-type semiconductor layer (or contact layer) be a low resistance ohmic electrode. For example, the p-type electrode of blue-violet lasers of a GaN-based material is preferably a low resistance ohmic electrode made of Pd. However, it is difficult, due to process limitation, to form this Pd electrode in such a way that the electrode is only in contact with the underlying p-type semiconductor layer (or contact layer). That is, it happens that the formed Pd electrode is also in contact with the underlying insulating film. It has been found, however, that in such a case the Pd electrode has poor adhesion to the insulating film and peels off. This peeling of the Pd electrode tends to occur after the sintering heat treatment, although it may occur any time after the formation of the Pd electrode.
The semiconductor light emitting device of the present embodiment is designed such that the Pd electrode (or p-type electrode) does not peel off the underlying contact layer and the underlying insulating film and has low resistance ohmic characteristics, which allows the device to deliver higher power and to operate with a lower current consumption than prior devices of the same type. The method of the present embodiment as described above allows the manufacture of such a semiconductor light emitting device. Specifically, in the semiconductor light emitting device of the present embodiment, the alloy portion 29 is formed at the interface between the Pd electrode 31 and the Au layer 23 to improve the adhesion between them as shown in
According to the present embodiment, a sintering heat treatment is performed in such a way as to enhance the adhesion between the Pd electrode 31 and the p-type contact layer 88 while at the same time forming the alloy portion 29 at the interface between the Pd electrode 31 and the Au layer 23. This means that the method of the present embodiment does not require an additional process step to form the alloy portion 29.
It should be noted that a pad electrode may be formed over the surface of the wafer after the above sintering heat treatment. This pad electrode is used to supply power to the p-type semiconductor layer (or contact layer).
On the other hand, the semiconductor light emitting device of the present embodiment is substantially immune to this problem, since it includes, in addition to the above straight current path via the electrode surface oxide layer 156, other current paths from the pad electrode above the ridge portion 10 to the p-type semiconductor layer 150 via the multilayer adhesive layer 25 and the alloy portion 29 (i.e., not via the electrode surface oxide layer 156), as shown in
The configuration of the semiconductor light emitting device of the present embodiment, in which the roundabout current paths along both sides of the ridge portion 10 are provided, allows the device to have a lower device resistance, as compared not only to the configuration shown in
It should be noted that the roundabout current paths along both sides of the ridge portion 10 have the effect of increasing the power supply to the active layer even when the Pd electrode has substantially no electrode surface oxide layer formed thereon. That is, this current path configuration of the present embodiment allows the device resistance to be reduced even when the Pd electrode has no electrode surface oxide layer thereon, resulting in an increase in the output power and a reduction in the current consumption of the semiconductor light emitting device.
It should be noted that the end face portions or even other portions of a semiconductor light emitting device may heat up during its operation. If the temperature of the semiconductor light emitting device exceeds an allowable value, the characteristics and reliability of the device may degrade. However, the semiconductor light emitting device of the present embodiment is less likely to suffer such a problem than prior devices, since it includes a multilayer adhesive layer made of a metal and hence has higher heat dissipation capability.
Although the semiconductor light emitting device of the present embodiment has been described as including terrace portions, it is to be understood that the device may include no terrace portions. The present embodiment requires only that the semiconductor light emitting device have a basic construction such as that shown in
Although the semiconductor light emitting device of the present embodiment has been described as including a multilayer adhesive layer that covers the second insulating film on the entire surfaces of the channel portions, it is to be understood that multilayer adhesive layers having different configurations may be substituted therefor. For example, the semiconductor light emitting device may have a construction such as that shown in
In this case it may happen that the Pd electrode 186 does not have sufficient adhesion to the first insulating film 16. However, the alloy portion 188 may compensate for this by firmly bonding the Pd electrode and the Au layer together. That is, this configuration may still retain the advantages of the present invention. However, since as shown in
Incidentally, the semiconductor light emitting devices shown in
Referring to
Although the semiconductor light emitting device of the present embodiment has been described as including a multilayer adhesive layer that includes a Ti layer and an Au layer formed on the Ti layer, it is to be understood that multilayer adhesive layers having different structures may be substituted therefor. For example, the semiconductor light emitting device may include the multilayer adhesive layer 100 shown in
In the case of the multilayer adhesive layer in which the Au layer is formed on the Ti layer, Ti may diffuse to the alloy portion between the Au layer and the Pd electrode and then may oxidize into an oxide, which is not desirable since it may increase the resistance of the semiconductor light emitting device. The multilayer adhesive layer 100 shown in
Further, the semiconductor light emitting device of the present embodiment may include one of the two multilayer adhesive layers shown in
It should be noted that the present embodiment does not require that the layers in the multilayer adhesive layer be of any particular thickness. Therefore, the thickness of each layer may be determined by the adhesion strength required.
Further, the Pd electrode may be made up of only a single layer of Pd, or may have a multilayer structure that includes a first layer of Pd and a layer(s) of a different material(s) formed on the first layer, with the first layer being in contact with the p-type contact layer. For example, the Pd electrode may have a two layer structure of Pd/Ta (i.e., Ta over Pd), a three layer structure of Pd/Ta/Pd (i.e., Pd over Ta over Pd), or a four or more layer structure (made up of a three layer structure of Pd/Ta/Pd with a layer(s) of a suitable material(s) formed thereon). It has been found from experimentation that a two layer structure of Pd/Ta has a lower contact resistance than a single layer of Pd. More specifically, when used in the configuration shown in
It will be appreciated that various modifications and alterations may be made to the semiconductor light emitting device and the manufacturing method therefor of the present embodiment without departing from the spirit and scope of the present invention. That is, the present invention encompasses any semiconductor light emitting device having the following basic configuration. A multilayer adhesive layer made up of one or more metal layers is formed between the Pd electrode (p-type electrode) and the underlying insulating film, and an alloy portion is formed at the interface between the Pd electrode and the multilayer adhesive layer to enhance the adhesion between the Pd electrode and the underlying p-type semiconductor layer and the underlying insulating film as well as to improve the electrical characteristics of the device. Therefore, although the semiconductor light emitting device of the present embodiment has been described as including a GaN semiconductor layer, the present invention is not limited to this particular material system and can be applied to various material systems.
The entire disclosure of a Japanese Patent Application No. 2008-013131, filed on Jan. 23, 2008 including specification, claims, drawings and summary, on which the Convention priority of the present application is based, are incorporated herein by reference in its entirety.
Thus, the present invention provides a semiconductor light emitting device in which the Pd electrode (or p-type electrode) is adapted not to come off the underlying contact layer and the underlying insulating film and has improved low resistance ohmic characteristics. Further, the present invention also provides a method for manufacturing such a semiconductor light emitting device.
Number | Date | Country | Kind |
---|---|---|---|
2008-013131 | Jan 2008 | JP | national |