Korean Patent Application No. 10-2017-0175434, filed on Dec. 19, 2017 in the Korean Intellectual Property Office, and entitled: “Semiconductor Light Emitting Device,” is incorporated by reference herein in its entirety.
Embodiments relate to a semiconductor light emitting device.
Semiconductor light emitting devices have come to prominence as next-generation light sources due to advantages thereof, e.g., relatively long lifespans, low power consumption, fast response speeds, low environmental impact, and the like. Semiconductor light emitting devices are attracting attention as important light sources in various types of products, e.g., lighting devices and display backlights. For example, a nitride-based light emitting device based on a Group III nitride, e.g., GaN, AlGaN, InGaN, or InAlGaN, may serve an important function in outputting blue or ultraviolet light as a semiconductor light emitting device. Recently, ultraviolet (UV) light sources have been used in devices for various purposes, e.g., sterilization and disinfection equipment, UV curing devices, and the like.
According to an embodiment, a semiconductor light emitting device may include a light emitting stack including a first conductive semiconductor layer, an active layer, and a second conductive semiconductor layer, a plurality of holes passing through the second conductive semiconductor layer and the active layer, a trench extending along an edge of the light emitting stack, and passing through the second conductive semiconductor layer and the active layer, and a reflective metal layer disposed within the plurality of holes and within the trench.
According to an embodiment, a semiconductor light emitting device may include a light emitting stack including a first conductive semiconductor layer, an active layer, and a second conductive semiconductor layer, a plurality of conductive vias passing through the second conductive semiconductor layer and the active layer to be connected to the first conductive semiconductor layer, and a conductive line extending along an edge of the light emitting stack, and passing through the second conductive semiconductor layer and the active layer, in which the plurality of conductive vias and the conductive line are formed of metallic materials reflecting light emitted from the active layer in a horizontal direction.
According to an embodiment, a semiconductor light emitting device may include a light emitting stack including a first conductive semiconductor layer, an active layer, and a second conductive semiconductor layer, a plurality of conductive vias passing through the second conductive semiconductor layer and the active layer to be connected to the first conductive semiconductor layer, and a reflective structure disposed adjacent to an edge of the light emitting stack.
Features will become apparent to those of skill in the art by describing in detail exemplary embodiments with reference to the attached drawings in, which:
Detailed example embodiments will be hereinafter described in detail with reference to the attached drawings.
Referring to
The buffer layer 120 may be a layer provided as a stress compensation layer for growing a nitride semiconductor layer with satisfactory quality, e.g., with reduced cracks and defects, and may have a plurality of layers alternately disposed therein to receive tensile stress and compressive stress when grown. That is, when the buffer layer 120 is formed on the substrate 110 (e.g., a silicon substrate), a nitride semiconductor layer may be grown on the buffer layer 120, e.g., rather than directly on the substrate 110, thereby minimizing cracks in the resultant nitride semiconductor layer, e.g., as the buffer layer 120 minimizes tensile stress caused by lattice mismatch between the substrate 110 and the nitride semiconductor layer.
For this purpose, the buffer layer 120 may include a plurality of layers having a composition of AlxInyGa1-x-yN (0≤x≤1, 0≤y≤1, 0≤x+y≤1), and a composition ratio may be determined to implement a lattice constant for obtaining stress required in each layer. The term “lattice constant” may hereinafter refer to a constant value or a lattice constant distribution, and further, when the term “lattice constant” is used for a constituent element including a plurality of layers, or a constituent element having a lattice constant distribution rather than a constant value, the term “lattice constant” may refer to a lattice constant average of the constituent element.
In the example embodiment, the buffer layer 120 may include a first layer 121, a second layer 122, and a third layer 123. The first layer 121 may have a composition of AlxInyGa1-x-yN (0≤x≤1, 0≤y≤1, 0≤x+y≤1), a lattice constant LP1 of the first layer 121 may be smaller than a lattice constant LP0 of the substrate 110, and the first layer 121 may receive tensile stress from the substrate 110 disposed therebelow when grown. The second layer 122 may be formed on the first layer 121, may have a composition of AlxInyGa1-x-yN (0≤x<1, 0≤y<1, 0≤x+y<1), a lattice constant LP2 of the second layer 122 may be greater than the lattice constant LP1 and smaller than LPc, and the second layer 122 may receive compressive stress from the first layer 121 disposed therebelow when grown. Here, LPc refers to a lattice constant having a composition of AlxInyGa1-x-yN (0≤x≤1, 0≤y<1, 0≤x+y<1) that corresponds to a light emitting wavelength λa of an active layer. The third layer 123 may be formed on the second layer 122, may have a composition of AlxInyGa1-x-yN (0≤x<1, 0≤y<1, 0≤x+y<1), a lattice constant LP3 of the third layer 123 may be lower than the lattice constant LP2, and the third layer 123 may receive tensile stress from the second layer 122 disposed therebelow when grown.
For example, the first layer 121 may be a layer directly contacting the silicon substrate 110, and may be formed of AlN. In another example, the first layer 121 may be formed of a nitride of a metal other than the Group III metal, e.g., the first layer 121 may be formed of at least one of HfNx, ZrNx, TaNx, TiN, and WNx.
In the above manner, the buffer layer 120 may include three or more layers including at least one a constituent layer receiving tensile stress and at least one constituent layer receiving compressive stress, and the layers may be alternately formed. The layer receiving tensile stress may be disposed in a position of an odd-numbered layer on the substrate 110, e.g., a first layer directly on the substrate 110, and may be adjusted to have a proper thickness and composition, so as to prevent cracking from occurring therein due to an excessive tensile stress when grown. The layer receiving compressive stress may be disposed in a position of an even-numbered layer on the substrate 110, e.g., a second layer on the substrate 110, and may have a sufficient thickness such that the sum of stresses of the layers forming the buffer layer 120 may be compressive stress. Thus, an occurrence of cracks within a nitride semiconductor layer grown subsequently on the buffer layer 120 may be reduced.
The superlattice structure layer SLS of
The superlattice structure layer SLS' of
As illustrated in
The first layer 131 may have a composition of AlxInyGa1-x-yN (0≤x≤1, 0≤y≤1, 0≤x+y≤1), a lattice constant LP1 of the first layer 131 may be smaller than a lattice constant LP0 of a substrate 110, and the first layer 131 may receive tensile stress from the substrate 110 disposed therebelow when grown. The second layer 132 may be formed on the first layer 131, may have a composition of AlxInyGa1-x-yN (0≤x<1, 0≤y<1, 0≤x+y<1), a lattice constant LP2 of the second layer 132 may be greater than the lattice constant LP1, and the second layer 132 may receive compressive stress from the first layer 131 disposed therebelow when grown.
The third layer 133 may have a composition of AlxInyGa1-x-yN (0≤x≤1, 0≤y≤1, 0≤x+y≤1), a lattice constant LP3 of the third layer 133 may be smaller than the lattice constant LP2 of the second layer 132, and the third layer 133 may receive tensile stress from the second layer 132 disposed therebelow when grown. The fourth layer 134 may be formed on the third layer 133, may have a composition of AlxInyGa1-x-yN (0≤x<1, 0≤y<1, 0≤x+y<1), a lattice constant LP4 of the fourth layer 134 may be greater than the lattice constant LP3, and the fourth layer 134 may receive compressive stress from the third layer 133 disposed therebelow when grown.
The fifth layer 135 may have a composition of AlxInyGa1-x-yN (0≤x≤1, 0≤y≤1, 0≤x+y≤1), a lattice constant LP5 of the fifth layer 135 may be smaller than the lattice constant LP4 of the fourth layer 134, and the fifth layer 135 may receive tensile stress from the fourth layer 134 disposed therebelow when grown. The sixth layer 136 may be formed on the fifth layer 135, may have a composition of AlxInyGa1-x-yN (0≤x≤1, 0≤y≤1, 0≤x+y≤1), a lattice constant LP6 of the sixth layer 136 may be greater than the lattice constant LP5 and smaller than LPc, and the sixth layer 136 may receive compressive stress from the fifth layer 135 disposed therebelow when grown. Here, LPc refers to a lattice constant having a composition of AlxInyGa1-x-yN (0≤x<1, 0≤y<1, 0≤x+y<1) that corresponds to a light emitting wavelength λa of an active layer.
For example, the first layer 131 may be a layer directly contacting the substrate 110, and may be formed of AlN. In another example, the first layer 131 may be formed of a nitride of a metal other than the Group III metal, e.g., the first layer 131 may be formed of at least one of HfNx, ZrNx, TaNx, TiN, and WNx.
For example, the buffer layer 130 may include 6 constituent layers, but example embodiments are not limited thereto. The buffer layer 130 may also include three or more constituent layers. The buffer layer 130 may be designed such that the sum of stresses of all the constituent layers may be a compressive stress. Thus, an occurrence of cracks within a nitride semiconductor layer grown on the buffer layer 130 may be reduced.
Referring to
As further illustrated in
The first conductive semiconductor layer 232 may be a semiconductor layer doped with first conductivity type impurities, and may be formed of a Group III-V nitride semiconductor material, e.g., a semiconductor material having a composition of AlxGayInzN (0≤x≤1, 0≤y≤1, 0≤z≤1, x+y+z=1) doped with n-type impurities. The n-type impurities may be, e.g., Si, Ge, Se, or Te.
The second conductive semiconductor layer 236 may be a semiconductor layer doped with second conductivity type impurities, and may be formed of a Group III-V nitride semiconductor material. e.g., a semiconductor material having a composition of AlxGayInzN (0≤x≤1, 0≤y≤1, 0≤z≤1, x+y+z=1) doped with p-type impurities. The p-type impurities may be, e.g., Mg, Zn, or Be.
The active layer 234 may be a layer emitting light by the combination of electrons and holes, and a level of energy, corresponding to a band gap of the active layer 234, may be emitted in the form of light. The active layer 234 may have a single quantum well or a multiple quantum well structure formed by adjusting the band gap by periodically changing x, y, and z values of AlxGayInzN. For example, a quantum well structure may include at least one quantum well layer and at least one quantum barrier layer of AlGaN/AlGaN, AlGaN/AlN, InGaN/GaN, InGaN/InGaN, InGaN/AlGaN, or InGaN/InAlGaN. Each of the first conductive semiconductor layer 232 and the second conductive semiconductor layer 236 may include a single layer structure, but may also include a multilayer structure. For example, when emitting UV-C light, i.e., a wavelength range of about 200 nm to 280 nm, the quantum well layers and the barrier layers may be formed of a composition of AlxGa1-xN (0.42≤x≤1) having a high aluminum (Al) composition, e.g., Al composition of about 42% or higher.
Referring to
The conductive support substrate 570 may be, e.g., a Si or a SiAl substrate. A bonding metal layer 572 may be disposed on a first surface of the conductive support substrate 570, i.e., between the conductive support substrate 570 and the reflective metal layer 553. Selectively, a rear metal layer 574 may be disposed on a second surface of the conductive support substrate 570, i.e., on a surface of the conductive support substrate 570 facing away from the reflective metal layer 553.
To form the first electrode 551 contacting the first conductive semiconductor layer 232, a plurality of via holes VH and a trench TC may be formed through the second conductive semiconductor layer 536 and the active layer 534. The via holes VH may be arranged to have various shapes in rows and columns, as illustrated in
A first passivation layer 541, i.e., an insulating layer, may cover lateral surfaces of the via holes VH and a portion of a surface of the second conductive semiconductor layer 536 facing away from the active layer 534. The first electrode 551 may pass through the first passivation layer 541 formed within the via holes VH and the trench TC to be in contact with the first conductive semiconductor layer 532. For example, as illustrated in
The second electrode 552 may pass through the first passivation layer 541 to be in contact with the second conductive semiconductor layer 536. For example, as illustrated in
The reflective metal layer 553 may connect to the first electrode 551, and may, e.g., completely, fill the via holes VH and the trench TC. That is, the reflective metal layer 553 may include conductive vias 553V filling the via holes VH, a conductive line 553T filling the trench TC, and a horizontal conductive layer 553H covering the conductive vias 553V and the conductive line 553T (a dashed line in
In detail, when the active layer 534 emits ultraviolet light, i.e., light having a wavelength range of about 200 to 400 nm, the amount of light components emitted in the horizontal direction may be great. Thus, the conductive line 553T, which reflects light emitted horizontally from the active layer 534, contribute considerably to improving light extraction efficiency of the semiconductor light emitting device 500.
The semiconductor light emitting device 500 may have a structure in which a Si substrate used as a substrate for growth, as well as a buffer layer thereon, may be removed, and the conductive support substrate 570 may be bonded to a side of the second conductive semiconductor layer 536. An upper surface of the first conductive semiconductor layer 532, i.e., a surface facing away from the conductive support substrate 570, may be texturized to increase light extraction efficiency, thereby forming an uneven pattern 532a. Further, while in the drawings, all of the Si substrate and the buffer layer are removed, a portion of the buffer layer may remain on the first conductive semiconductor layer 532 and may also be texturized together with the first conductive semiconductor layer 532.
The connecting metal layer 554, covering the second electrode 552, may extend externally of the light emitting stack 530, as illustrated in
Referring to
Referring to
Referring to
For example, the wavelength conversion layer 590 may, e.g., only, be formed on an upper surface of the first conductive semiconductor layer 532. In another example, the wavelength conversion layer 590 may cover, e.g., overlap, all of upper and lateral surfaces of the light emitting stack 530 including the first conductive semiconductor layer 532, the active layer 534, and a second conductive semiconductor layer 536.
Referring to
For example, as illustrated in
Referring to
Referring to
Referring to
Referring to
The buffer layer 520, the first conductive semiconductor layer 532, the active layer 534, and the second conductive semiconductor layer 536 may be formed on the substrate 510 by any suitable semiconductor growth method, e.g., metal organic chemical vapor deposition (MOCVD), molecular beam epitaxy (MBE), or hydride vapor phase epitaxy (HVPE).
When the first conductive semiconductor layer 532 and the second conductive semiconductor layer 536 are formed, impurity gases may be supplied to dope the first conductive semiconductor layer 532 and the second conductive semiconductor layer 536 with n- or p-type impurities. The n-type impurities may be, e.g., Si, Ge, Se, or Te, and the p-type impurities may be, e.g., Zn, Cd, Be, Mg, Ca, or Ba. The via holes VH and the trench TC may be simultaneously formed by a single dry etching process.
Referring to
Subsequently, a portion of the first passivation layer 541 disposed on the second conductive semiconductor layer 536 may be etched, and the second electrode 552 may be formed on the exposed portion of the second conductive semiconductor layer 536. The second electrode 552 may be formed by depositing or plating, e.g., silver (Ag).
Subsequently, a portion of the first passivation layer 541, disposed on the first conductive semiconductor layer 532 within the via holes VH and the trench TC, may be etched, and the first electrode 551 may be formed on the exposed portion of the first conductive semiconductor layer 532. The first electrode 551 may be formed by depositing or plating, e.g., chromium (Cr).
Referring to
Subsequently, the second passivation layer 543 may be formed to cover the connecting metal layer 554. The second passivation layer 543 may be formed by depositing an insulating material, e.g., a silicon oxide (SiO2) or an aluminum oxide (Al2O3).
Referring to
Subsequently, the conductive support substrate 570 may be attached to the reflective metal layer 553. The conductive support substrate 570 may be a Si or SiAl substrate. The bonding metal layer 572 may be disposed between the conductive support substrate 570 and the reflective metal layer 553. Selectively, the rear metal layer 574 may be disposed on the upper surface of the conductive support substrate 570.
Referring to
Subsequently, an upper surface of the first conductive semiconductor layer 532 may be texturized to form the uneven pattern 532a on the upper surface. When a portion of the buffer layer 520 remains on the first conductive semiconductor layer 532, the portion may be texturized together with the upper surface of the first conductive semiconductor layer 532 to form the uneven pattern 532a. The texturing may be formed by dry or wet etching.
Subsequently, portions of the first conductive semiconductor layer 532, the active layer 534, and the second conductive semiconductor layer 536 may be etched to expose the connecting metal layer 554.
Referring again to
Referring to
To form the first electrode 551 contacting the first conductive semiconductor layer 532, the plurality of via holes VH may be formed through the second conductive semiconductor layer 536 and the active layer 534. However, the trench TC may not be formed in the semiconductor light emitting device 600, unlike in the above-mentioned semiconductor light emitting devices 500, 500A, 500B, 500C, 500D, 500E, 500F, and 500G.
Alternatively, as illustrated in
Referring to
Referring to
As set forth above, according to example embodiments, a semiconductor light emitting device having improved light extraction efficiency may be provided. In particular, the semiconductor light emitting device may include a semiconductor buffer structure capable of reducing the occurrence of cracks in a nitride-based semiconductor thin film, and a light emitting stack including the nitride-based semiconductor thin film formed on the buffer structure. Further, conductive structures including reflective metal, e.g., in vias and trench having sloped sidewalls, may be formed in the light emitting stack to efficiently reflect light emitted horizontally from the active layer of the light emitting stack.
Example embodiments have been disclosed herein, and although specific terms are employed, they are used and are to be interpreted in a generic and descriptive sense only and not for purpose of limitation. In some instances, as would be apparent to one of ordinary skill in the art as of the filing of the present application, features, characteristics, and/or elements described in connection with a particular embodiment may be used singly or in combination with features, characteristics, and/or elements described in connection with other embodiments unless otherwise specifically indicated. Accordingly, it will be understood by those of skill in the art that various changes in form and details may be made without departing from the spirit and scope of the present invention as set forth in the following claims.
Number | Date | Country | Kind |
---|---|---|---|
10-2017-0175434 | Dec 2017 | KR | national |
Number | Name | Date | Kind |
---|---|---|---|
6372608 | Shimoda et al. | Apr 2002 | B1 |
6645830 | Shimoda et al. | Nov 2003 | B2 |
RE38466 | Inoue et al. | Mar 2004 | E |
6818465 | Biwa et al. | Nov 2004 | B2 |
6818530 | Shimoda et al. | Nov 2004 | B2 |
6858081 | Biwa et al. | Feb 2005 | B2 |
6967353 | Suzuki et al. | Nov 2005 | B2 |
7002182 | Okuyama et al. | Feb 2006 | B2 |
7084420 | Kim et al. | Aug 2006 | B2 |
7087932 | Okuyama et al. | Aug 2006 | B2 |
7154124 | Han et al. | Dec 2006 | B2 |
7208725 | Sherrer et al. | Apr 2007 | B2 |
7288758 | Sherrer et al. | Oct 2007 | B2 |
7319044 | Han et al. | Jan 2008 | B2 |
7501656 | Han et al. | Mar 2009 | B2 |
7709857 | Kim et al. | May 2010 | B2 |
7759140 | Lee et al. | Jul 2010 | B2 |
7781727 | Sherrer et al. | Aug 2010 | B2 |
7790482 | Han et al. | Sep 2010 | B2 |
7940350 | Jeong | May 2011 | B2 |
7959312 | Yoo et al. | Jun 2011 | B2 |
7964881 | Choi et al. | Jun 2011 | B2 |
7985976 | Choi et al. | Jul 2011 | B2 |
7994525 | Lee et al. | Aug 2011 | B2 |
8008683 | Choi et al. | Aug 2011 | B2 |
8013352 | Lee et al. | Sep 2011 | B2 |
8049161 | Sherrer et al. | Nov 2011 | B2 |
8129711 | Kang et al. | Mar 2012 | B2 |
8179938 | Kim | May 2012 | B2 |
8263987 | Choi et al. | Sep 2012 | B2 |
8324646 | Lee | Dec 2012 | B2 |
8399944 | Kwak et al. | Mar 2013 | B2 |
8432511 | Jeong | Apr 2013 | B2 |
8459832 | Kim | Jun 2013 | B2 |
8502242 | Kim | Aug 2013 | B2 |
8536604 | Kwak et al. | Sep 2013 | B2 |
8564009 | Min | Oct 2013 | B2 |
8735931 | Han et al. | May 2014 | B2 |
8766295 | Kim | Jul 2014 | B2 |
9117986 | Choi et al. | Aug 2015 | B2 |
9680050 | Choi et al. | Jun 2017 | B2 |
20140045284 | Tak et al. | Feb 2014 | A1 |
20160240759 | Chae | Aug 2016 | A1 |
20170222107 | Chen et al. | Aug 2017 | A1 |
20180219133 | Park | Aug 2018 | A1 |
Number | Date | Country |
---|---|---|
10-2012-0031340 | Apr 2012 | KR |
10-2012-0055332 | May 2012 | KR |
Number | Date | Country | |
---|---|---|---|
20190189848 A1 | Jun 2019 | US |