This Application is based on, and claims priority of TW application Ser. No. 11/211,7260 filed on May 10, 2023, the content of the entirety of which is incorporated by reference herein.
The present disclosure relates to a semiconductor structure and a method of forming the same, and in particular to a semiconductor structure having a support fragment and a method of forming the same.
With the development of optoelectronic technology, the designers of various types of display devices are constantly improving the characteristics and performance of the devices, such as increasing resolution and reducing size and saving energy, and a display device with micro-light-emitting diodes (μLED) is one of the most important types of the development. The advantages of micro-light-emitting diodes include low power consumption, high brightness, high resolution and high color saturation. Thus, the micro-light-emitting diode display devices are regarded as the mainstream of the next generation of display technology.
The micro-light-emitting diode is configured as a traditional standard light emitting diode with a reduced size to an order of magnitude below about 100 microns or even tens of microns. Since the size of a micro-light-emitting diode is very small, the number of light emitting diodes formed in the same area increases dramatically. After micro-light-emitting diodes are fabricated on a growth substrate, support structures (also called weakened structures) that weaken the connection between the micro-light-emitting diodes and the substrate can be formed. Then, the micro-light-emitting diodes are picked up and transferred to another target substrate in large quantities by using a precise pick-up technology (such as using a transfer stamp with electrostatic force). Currently, the weakened structures between the micro-light-emitting diodes and the substrate can be divided into tether-type weakened structures and anchor-type weakened structures. The tether-type weakened structures occupy additional areas of the substrate, thereby affecting the number of micro-light-emitting diodes that can be produced on a single wafer. In addition, the weakened anchor-type structures suffer from poor pick-up during the pick-up step due to the solid support. Thus, although existing micro semiconductor structures and their method have been adequate for their intended purposes, they have not been entirely satisfactory in all respects.
Some embodiments of the present disclosure provide semiconductor structures. An embodiment of a semiconductor structure includes a micro semiconductor device and a support fragment. The micro semiconductor device has a first surface, a second surface opposite the first surface, first electrode on the first surface, and a second electrode on the first surface. The first electrode and the second electrode are separated from each other, and the first electrode has a main portion. The support fragment connects to the micro semiconductor device and corresponds to a region between the main portion of the first electrode and the second electrode in a vertical direction. The support fragment has an annular breaking surface in a plan view of the micro semiconductor device.
Some embodiments of the present disclosure provide a method of forming a semiconductor structure. The method includes providing a micro semiconductor device having a first surface, a second surface opposite the first surface, a first electrode on the first surface, and a second electrode on the first surface. The first electrode and the second electrode are separated from each other, and the first electrode has a main portion. The method includes forming a support fragment connected to the micro semiconductor device. The support fragment corresponds to a region between the main portion of the first electrode and the second electrode in a vertical direction. The support fragment has an annular breaking surface in a plan view of the micro semiconductor device.
A detailed description is given in the following embodiments with reference to the accompanying drawings.
The present disclosure can be more fully understood by reading the subsequent detailed description and examples with references made to the accompanying drawings, wherein:
In order to make the description of the present disclosure more detailed and complete, the following provides an illustrative description for the implementation aspects and specific embodiments of the present disclosure; but this is not the only form of implementing or using the specific embodiments of the present disclosure. The embodiments disclosed below can be combined or substituted with each other under beneficial circumstances, and other embodiments can also be added to one embodiment without further description or explanation. In addition, it will be understood that although the terms like “first”, “second”, “third” may be used herein to describe various elements, components, regions, layers, and/or portions, these elements, components, regions, layers, and/or portions should not be limited by these terms, and these terms are only used to distinguish between different elements, components, regions, layers, and/or portions. Thus, a first element, component, region, layer, and/or portion discussed below could be referred to as a second element, component, region, layer, and/or portion without departing from the teachings of the present disclosure.
Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact.
In addition, spatially relative terms, such as “beneath”, “below”, “lower”, “above”, “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented and the spatially relative descriptors used herein may likewise be interpreted accordingly. In addition, the present disclosure may repeat reference numbers and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
In the embodiments, semiconductor structures and methods of forming the same are provided. In some embodiments, a semiconductor structure includes a semiconductor device such as a micro semiconductor device and a support fragment connected to the semiconductor device. The support fragment has an annular breaking surface in a plan view of the support fragment. In addition, the support fragment of the embodiments is disposed within an area of a substrate occupied by the semiconductor device connected to the support fragment without occupying additional lateral space of the substrate, thereby increasing the number of the semiconductor devices that can be fabricated on the substrate. In addition, according to the method of forming a semiconductor structure in some embodiments, a void is formed between the support structure and a connection assembly, so the support structure can be broken off easily.
The present disclosure is described fully hereinafter with reference to the accompanying drawings, in which embodiments of the present disclosure are shown. It should be noted, however, that the present disclosure is not limited to the following embodiments, and may be implemented in various forms. The drawings as illustrated are only schematic and are non-limiting. For example, for clarity, the relative size, thickness, and position of each layer, each area, and/or each structure may be reduced or enlarged. Some embodiments are described below. Throughout the various views and illustrative embodiments, similar reference numbers are used to designate similar features/components.
In addition, the semiconductor structure in some embodiments may include a micro semiconductor device, such as a micro-light-emitting diode (micro-LED). For the sake of simplicity and clarity,
Method of forming a semiconductor structure and the formed semiconductor structure with the support fragment SB in accordance with some embodiments of the present disclosure are described below. In addition, additional procedures may be provided before, during, and after the method, and some of the recited steps may be replaced or eliminated for different embodiments of the disclosure.
Referring to
In some embodiments, the first semiconductor layer 211 includes one or more group III-V semiconductor materials, such as gallium nitride (GaN), gallium arsenide (GaAs), gallium phosphide (GaP), indium arsenide (InAs), aluminum nitride (AlN), indium nitride (InN), indium phosphide (InP), other binary epitaxial material, or the like. The first semiconductor layer 211 may also include aluminum gallium nitride (AlGaN), aluminum gallium arsenide (AlGaAs), indium gallium phosphide (InGaP), indium gallium nitride (InGaN), aluminum indium gallium nitride (AlInGaN), aluminum indium gallium phosphide (AlInGaP), indium gallium arsenide phosphide (InGaAsP), other ternary or quaternary epitaxial materials, or the like. In addition, in some embodiments, the group III-V semiconductor layer can be doped with group IVA elements (such as silicon) to form an n-type first semiconductor layer 211. In addition, the first semiconductor layer 211 can be a single-layer structure or a multi-layer structure. A single layer of the first semiconductor layer 211 is depicted in the drawings for the sake of simplicity and clarity.
In some embodiments, the light-emitting layer 212 formed on the first semiconductor layer 211 can be referred to as an active layer. When the electric current passes through the active layer, the active layer emits light of a specific color. The light-emitting layer 212 may include multiple quantum wells (MQW), single quantum well (SQW), homojunction, heterojunction, or other similar structure, but the present disclosure is not limited thereto.
In some embodiments, the second semiconductor layer 213 on the light-emitting layer 212 may include the aforementioned binary, ternary or quaternary epitaxial materials of group III-V semiconductors, which is not be repeated here. Moreover, the second semiconductor layer 213 and first semiconductor layer 211 have different conductivity types. In some embodiments, the group III-V semiconductor layer can be doped with group IIA elements (such as beryllium, magnesium, calcium or strontium) to form a p-type second semiconductor layer 213. In one embodiment, the first semiconductor layer 211 includes n-type GaN, and the second semiconductor layer 213 includes p-type GaN. In addition, in some implementations, the width of the second semiconductor layer 213 is substantially equal to the width of the underlying light-emitting layer 212, but the present disclosure is not limited thereto.
In some embodiments, the micro semiconductor device 200 further includes a conductive layer 215 formed on the second semiconductor layer 213, and a passivation layer 216 formed on the conductive layer 215. The conductive layer 215 may include metal oxides, metals, other suitable conductive materials, or the combination thereof. The foregoing metal oxides are, for example, indium tin oxide (ITO), indium zinc oxide (IZO), aluminum zinc oxide (AZO), other suitable metal oxide, or the combination thereof. The foregoing metals are, for example, titanium (Ti), nickel (Ni), aluminum (Al), gold (Au), platinum (Pt), chromium (Cr), silver (Ag), copper (Cu), other suitable metal, the alloy thereof, or the combination thereof. In some other embodiments, the conductive layer 215 may be omitted.
The passivation layer 216 covers the first semiconductor layer 211, the light-emitting layer 212 and the second semiconductor layer 213. In some embodiments, the passivation layer 216 includes an insulating material. In addition to being an insulator, the passivation layer 216 protects and prevents the first semiconductor layer 211, the light-emitting layer 212 and the second semiconductor layer 213 from being damaged by the mechanical strength of the passivation layer 216.
In addition, in this embodiment, the passivation layer 216 has openings to respectively expose a portion of the first semiconductor layer 211 and a portion of the conductive layer 215 on the second semiconductor layer 213. In some embodiments, the passivation layer 216 can be formed by chemical vapor deposition (CVD), printing, coating, or other suitable methods. Besides, the openings that penetrate through the passivation layer 216 may be formed by lithography and etching processes or other suitable processes.
In some other embodiments, a reflective layer (not shown) and a barrier layer (not shown) can be formed on the conductive layer 215. The passivation layer 216 is formed on the barrier layer (not shown). The reflective layer can reflect light, and the barrier layer can protect and fix the reflective layer to prevent the reflective layer from being oxidized and peeled off. The reflective layer may include silver, aluminum, other suitable materials, the alloy thereof, or a combination thereof. The barrier layer may include titanium, platinum, gold, nickel, tungsten, tungsten-titanium alloy, aluminum, silver alloy, other suitable materials, or a combination thereof. In some examples, the reflectivity of the reflective layer is greater than the reflectivity of the barrier layer. In addition, in some examples, the conductive layer 215 (such as transparent indium tin oxide, ITO) disposed between the second semiconductor layer 213 (such as a p-type semiconductor layer) and the reflective layer can improve the uniformity of the current distribution between the second semiconductor layer 213 and the reflective layer.
According to some embodiments, the micro semiconductor device 200 has a first surface 2001 and a second surface 2002 opposite to the first surface 2001. In this embodiment, as shown in
In some embodiments, the micro semiconductor device 200 further includes a first electrode 217 and a second electrode 218 disposed on the first surface 2001. An electrode material layer can be formed on the first surface 2001 by a suitable process such as a sputtering method or electron beam physical deposition, and the electrode material layer fills the opening of the passivation layer 216. After the electrode material layer is formed, an annealing treatment can be performed to increase the ohmic contact between the electrode material layer and the epitaxial stack 210. Then, the first electrode 217 and the second electrode 218 are formed by performing a patterning process, including an etching process. Therefore, in this embodiment, the first electrode 217 and the second electrode 218 are separated from each other, and the first electrode 217 is electrically connected to the first semiconductor layer 211 through the opening of the passivation layer 216. The second electrode 218 is electrically connected to the conductive layer 215 and the second semiconductor layer 213 through another opening of the passivation layer 216. The first electrode 217 and the second electrode 218 may include other suitable electrode material, such as gold (Au), titanium (Ti), nickel (Ni), aluminum (Al), platinum (Pt), chromium (Cr), silver (Ag), copper (Cu), other suitable conductive materials, the alloy thereof, or a combination of the foregoing material.
In some embodiments, the first electrode 217 includes a main portion 217M and an extension portion 217E. The extension portion 217E is connected to the main portion 217M and extends towards the second electrode 218 into a region A1 between the main portion 217M and the second electrode 218. In addition, the main portion 217M of the first electrode 217 is, for example (but not limited to), disposed on the same level as the second electrode 218. In this embodiment, the opening of the passivation layer 216 that exposes a portion of the first semiconductor layer 211 is located in the region A1, and the extension portion 217E fills up the opening, so that the first electrode 217 is electrically connected the first semiconductor layer 211.
The material and shape of each layer of the above-mentioned micro semiconductor device 200 are only provided for illustrative purposes. Other micro semiconductor device that has different configurations (including different materials and shapes of each layer) can also be applied to the embodiments of the present disclosure and is not limited thereto.
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In some embodiments, the first sacrificial layer 220 includes benzocyclobutene (BCB), polyimide (PI), or other suitable sacrificial materials that can be removed easily in subsequent processes. The first sacrificial layer 220 includes one or more sacrificial materials. The first sacrificial layer 220 can be a single-layer structure or a multi-layer structure. In this exemplified embodiment, the first sacrificial layer 220 is depicted as a single-layer structure for the purpose of simplicity and clarity of the drawings.
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Specifically, in some examples, the liner portion 232 includes a bottom portion 2321 and an annular sidewall 2322. The bottom portion 2321 is positioned on the micro semiconductor device 200, for example, disposed on the first electrode 217 and in contact with the extension portion 217E. The annular sidewall 2322 is connected to the bottom portion 2321. In addition, the bottom portion 2321 and the annular sidewall 2322 collectively define the recess 230h.
Specifically, in some embodiments, the suspension portion 231 is connected to the annular sidewall 2322 of the liner portion 232, and the suspension portion 231 extends over the first electrode 217 and the second electrode 218. For example, the suspension portion 231 is integrally formed on the top surface 220a of the first sacrificial layer 220. It should be noted that the suspension portion 231 is not in direct contact with the first electrode 217 and the second electrode 218. As shown in
In some embodiments, the support structure 230 includes an insulating material, a metal material, or other suitable supporting materials. The foregoing insulating material includes silicon oxide, silicon nitride, silicon oxynitride, one or more ceramic material, epoxy resin, other suitable materials, or the combination thereof, but the present disclosure is not limited thereto. The foregoing metal material includes aluminum, titanium, gold, platinum or nickel, but the present disclosure is not limited thereto. In addition, the support structure 230 may be a single-layer structure or a multi-layer structure. The support structure 230 is depicted as a single-layer structure in the drawings for the sake of simplicity and clarity. In some embodiments, the thickness of the material layer of the support structure 230 is, for example, in a range of about 0.5 μm to 5 μm.
In addition, in this embodiment, the support structure 230 and the subsequently formed support fragment SB (
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In some embodiments, the second sacrificial layer 240 includes benzocyclobutene (BCB), polyimide (PI), or other suitable materials. The second sacrificial layer 240 may include one or more materials. The second sacrificial layer 240 and the first sacrificial layer 220 may include different materials or the same material. When the second sacrificial layer 240 and the first sacrificial layer 220 include the same material, they can be removed simultaneously in the same subsequent process.
Next, a connection assembly 250 is formed on the support structure 230 and the second sacrificial layer 240. As shown in
Referring to
In some embodiments, the adhesive layer 260 may include insulating adhesive, conductive adhesive, metal, other suitable material, or a combination thereof. For examples, the insulating adhesive may include epoxy resin, silica gel, other suitable material, or a combination thereof; the conductive adhesive may include epoxy resin mixed with silver powder, other suitable material, or a combination thereof; the metal may include copper, aluminum, tin, silver, other suitable metal, or the combination thereof; but the disclosure is not limited thereto.
In addition, in some embodiments, the adhesive layer 260 may be a single-layer structure or a multi-layer structure, but the disclosure is not limited thereto. The adhesive layer 260 is depicted as a single-layer structure in the drawings for the sake of simplicity and clarity.
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In addition, the first sacrificial layer 220 and the second sacrificial layer 240 can be removed by using any suitable method to form the air gap 223 and the void 243. For example, the first sacrificial layer 220 and the second sacrificial layer 240 may be removed by wet etching using one or more suitable chemical solutions. In addition, in some embodiments, the first sacrificial layer 220 and the second sacrificial layer 240 include the same material, and the first sacrificial layer 220 and the second sacrificial layer 240 can be removed simultaneously in one process (for example, the same wet etching process), thereby forming the foregoing air gap 223 and void 243.
In accordance with some embodiments of the present disclosure, the sacrificial layers (including the first sacrificial layer 220 and the second sacrificial layer 240) and the support structure 230 include different materials. Specifically, the support structure 230 is not substantially removed when the sacrificial layers are removed. In addition, when the sacrificial layers are removed, the other material layers would not be substantially removed or damaged. For example, the first semiconductor layer 211, the light-emitting layer 212, the second semiconductor layer 213, the first electrode 217, the second electrode 218 and the adhesive layer 260 are not removed or damaged when the sacrificial layers are removed. Therefore, in some embodiments, the chemical solvent that is used for removing the first sacrificial layer 220 and the second sacrificial layer 240 has high selectivity between the materials of the sacrificial layers and the materials of other above-mentioned structures/layers. Thus, after the first sacrificial layer 220 and the second sacrificial layer 240 are removed, the other structures/layers are substantially intact without being damaged.
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According to this embodiment, after a small external force is applied to the second substrate S2 (
According to the semiconductor structure provided in the embodiments, the suspension portion 231 of the support structure 230 is supported by the liner portion 232 which has a relatively small area. A contact area between the suspension portion 231 and the liner portion 232 is very small so as to greatly reduce the external force required to break the support structure 230 and facilitate subsequent process to pick up the micro semiconductor device 200 by a pick-up device, even if the size of the micro semiconductor device 200 is further reduced. In addition, the air gap 223 between the suspension portion 231 and the electrodes (i.e., the first electrode 217 and the second electrode 218) and the void 243 between the support structure 230 and the connection assembly 250 provide the spaces for the support structure 230 to be pressed down. Thus, the support structure 230 of the embodiment has the benefit of being easily disconnected for later pick-up and transfer process. Specifically, the support structure 230 of the embodiments can be disposed within a vertical projection area of the first sacrificial layer 220, in other words, the support structure 230 overlaps with the micro semiconductor device 200 in the vertical direction (i.e., the third direction D3). Accordingly, the support structure 230 of the embodiments does not occupy additional space of the substrate, such as the lateral space of the substrate, thereby increasing the number of the semiconductor structures 300 that can be produced on a single wafer and avoiding wasting the wafer area.
According to some embodiments, a pick-up device is used to break the support structures 230 and place the semiconductor structures 300 with support fragments SB (
In addition, in this embodiment, although a part of the support fragment SB protrudes from the first electrode 217 and the second electrode 218, the top surface 232a of the support fragment SB may be slightly higher than the top surface 217a of the first electrode 217 and the top surface 218a of the second electrode 218. When it is electrically bonded to the carrier (such as a printed circuit board) in a subsequent process, the bonding layer of the carrier also has an opening corresponding to the region between the first electrode 217 and the second electrode 218. In addition, the bonding layer of the carrier has a thickness. Therefore, the support fragment SB left on the micro semiconductor device 200 in accordance with some embodiments of the present disclosure does not affect the electrical connection between the first electrode 217, the second electrode 218 and the carrier (such as a printed circuit board) in a subsequent process.
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In some embodiments, the support fragment SB has a U-shaped cross section. As shown in
According to some embodiments, the support fragment SB has a top surface 232a and a bottom surface 232b opposite the top surface 232a, and the bottom surface 232b of the support fragment SB is disposed on the micro semiconductor device 200. As shown in
In addition, as shown in
In addition, in some embodiments, in the semiconductor structure 300 as shown in
In addition to the above-mentioned manufacturing method as proposed in
The features/elements in
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Next, a first connection assembly 410 is formed on the first substrate S1 and the micro semiconductor device 200, as shown in
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Details of the material and manufacturing method of the first adhesive layer 402 in
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In some embodiments, the liner portion 232 includes a bottom portion 2321 and an annular sidewall 2322. The bottom portion 2321 is connected to the micro-semiconductor device 200, for example, be in contact with the portion of the second surface 2002 exposed from the hole 220h. The annular sidewall 2322 is connected to the bottom portion 2321. The bottom portion 2321 and the annular sidewall 2322 collectively define the recess 230h.
In addition, in some embodiments, the suspension portion 231 is connected to the annular sidewall 2322 of the liner portion 232 and the suspension portion 231 extends along the second direction D2 to cover the first sacrificial layer 220. It should be noted that the suspension portion 231 is not in direct contact with the second surface 2002 of the micro semiconductor device 200. As shown in
In addition, in this embodiment, since the support structure 230 is positioned on the second surface 2002 (which is the light exist surface) of the micro semiconductor device 200, it is better to have the support structure 230 with high light transmittance, e.g., at least 80% for the light emits from the micro semiconductor device 200. In some embodiments, the light transmittance of the support structure 230 may be equal to or greater than 80%, equal to or greater than 85%, equal to or greater than 90% or equal to or greater than 95%. In some embodiments, the support structure 230 includes, for example, silicon oxide, silicon nitride, silicon oxynitride, epoxy resin, or other suitable materials, but the present disclosure is not limited thereto. In addition, the support structure 230 may be a single-layer structure or a multi-layer structure. The support structure 230 is depicted as a single-layer structure in the drawings for the sake of simplicity and clarity.
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Next, a connection assembly 450 is formed on the support structure 230 and the second sacrificial layer 240. As shown in
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Details of the material and manufacturing method of the second adhesive layer 460 in
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In addition, the sacrificial layers (including the first sacrificial layer 220 and the second sacrificial layer 240) and the support structure 230 include different materials, in accordance with some embodiments of the present disclosure. The support structure 230 is not substantially removed when the sacrificial layers are removed. In addition, when the sacrificial layers are removed, the other material layers would not be substantially removed or damaged. For example, the first semiconductor layer 211, the light-emitting layer 212, the second semiconductor layer 213, the first electrode 217, the second electrode 218 and the second adhesive layer 460 of the micro semiconductor device 200 are not removed or damaged when the sacrificial layers are removed. Therefore, in some embodiments, the chemical solvent that is used for removing the first sacrificial layer 220 and the second sacrificial layer 240 has high selectivity between the materials of the sacrificial layers and the materials of the above-mentioned other structures/layers. Thus, after the first sacrificial layer 220 and the second sacrificial layer 240 are removed, the other structures/layers are substantially intact without being damaged.
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According to this embodiment, since the void 243 formed between the support structure 230 and the second connection assembly 450, the micro semiconductor device 200 is supported by a hollow cylinder (i.e., 231 the liner portion 232) which can be broken off by a relatively small force comparing to a solid cylinder. When a small external force is applied to the micro semiconductor device 200 to press the support structure 230 downwardly, the support structure 230 is easily broken at the part where the liner portion 232 is connected to the suspension portion 231. As shown in
In addition, similar to the support fragments SB in the examples of
The disclosed semiconductor structures and the methods of forming the same can be not only used in the light emitting diodes (LEDs) and micro-light-emitting diodes (micro-LEDs) whose sizes are down to micron (μm) level, but also widely used in the displays and wearable devices. Those LEDs can be red, green or blue LEDs.
According to the aforementioned descriptions, the semiconductor structures and the methods of forming the same in accordance with some embodiments of the present disclosure have many advantages. The support fragment may be formed over the first surface or the opposite second surface of the micro semiconductor device. For example, the support fragment may be arranged so that it corresponds to the region between the main portion of the first electrode and the second electrode of the micro semiconductor device, so it does not occupy additional lateral space over the substrate, thereby increasing the quantity of micro semiconductor devices that can be produced on a single wafer. In addition, in the methods of forming semiconductor structures proposed in the above-mentioned embodiments, the support structure 230 not only has the benefits of the anchor-type weakened structure such as providing stable support without taking lateral space of the wafer, but also has the benefits of easy disconnection of the tether-type weakened structure. In addition, the methods of forming the semiconductor structure in accordance with some embodiments are simple and compatible with the existing semiconductor manufacturing process. Thus, the embodied methods are suitable for mass production, and can be applied to fabricate the support structures with high precision using suitable photolithography process.
While the disclosure has been described by way of example and in terms of the preferred embodiments, it should be understood that the disclosure is not limited to the disclosed embodiments. On the contrary, it is intended to cover various modifications and similar arrangements (as would be apparent to those skilled in the art). Therefore, the scope of the appended claims should be accorded the broadest interpretation so as to encompass all such modifications and similar arrangements.
Number | Date | Country | Kind |
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112117260 | May 2023 | TW | national |