Patent Application
20130333675
The subject matter disclosed herein relates to sensor assemblies with protective coatings for use in high temperature and highly corrosive environments.
As environmental regulations become increasingly stringent, new technology is being utilized to permit compliance by combustion engines. For example, within the automotive industry, Exhaust Gas Recycling (EGR) systems have been developed that recycle at least a portion of the exhaust gases back into the engine's combustion chamber. While EGR systems reduce emission of certain pollutants, including NOx, when the exhaust gases are recycled within the engine, the engine components are exposed to higher concentrations of these gases for long periods of time. This results in elevated acid levels within the EGR system, including nitric and sulfuric acid. The high temperature and highly corrosive environment can negatively affect the functioning of engine components and sensors, including thermistors, that are disposed in the EGR system.
While conventional thermistors are typically protected by a coating of an epoxy, silicone, or other polymeric resin, the highly corrosive environments of EGR systems impose special requirements which these conventional resins used to coat sensors do not satisfy. It would be desirable to provide a coated sensor that was able to function within highly corrosive environments despite the elevated levels of corrosive compounds necessitated by new environmental regulations.
The discussion above is merely provided for general background information and is not intended to be used as an aid in determining the scope of the claimed subject matter.
A sensor assembly with a protective coating and a method of applying the coating is disclosed. The sensor assembly includes a sensor, a first conductive lead extending from the sensor, a second conductive lead extending from the sensor, and a protective coating encapsulating the sensor and portions of the first conductive lead and the second conductive lead proximate to the sensor, wherein the protective coating comprises a fluoroelastomeric polymer. The coating is applied by immersing the sensor assembly into a cooled fluoroelastomeric polymer and then withdrawing the sensor assembly. An advantage that may be realized by the practice of some of the disclosed embodiments is that the fluoroelastomeric polymer protects the sensor without being electrically conductive.
In one exemplary embodiment, a device is disclosed, the device comprising a sensor assembly comprising a sensor, first and second conductive leads, and a protective coating encapsulating the sensor and portions of the first and second conductive leads. The protective coating comprises a fluoroelastomeric polymer that is free of carbon black.
In another exemplary embodiment, a method of coating a sensor assembly is disclosed, the method comprising the steps of dissolving a fluoroelastomeric polymer in an organic carrier solvent, adjusting the viscosity of the organic carrier solvent, cooling the dissolved fluoroelastomeric polymer, immersing a sensor assembly into the cooled fluoroelastomeric polymer, withdrawing the sensor assembly, permitting at least some of the organic carrier solvent to evaporate and curing the conformal layer to produce a coated sensor assembly.
In another exemplary embodiment, a system is disclosed, the system comprising an exhaust gas recycling system comprising, an engine with at least one cylinder chamber, an air intake manifold and an exhaust manifold, both connected to the cylinder chamber, an exhaust gas recycling line connected to the exhaust manifold and the cylinder chamber for recycling a portion of exhaust gases, a cooler for cooling exhaust gases as they pass through the exhaust gas recycling line, a coated thermistor assembly for sensing the temperature of a first location along the exhaust gas recycling line, the first coated thermistor assembly comprising a thermistor, a first conductive lead extending from the thermistor, a second conductive lead extending from the thermistor; and a protective coating encapsulating the thermistor and portions of the first conductive lead and the second conductive lead proximate to the thermistor, wherein the protective coating comprises a fluoroelastomeric polymer that is free of carbon black.
This brief description of the invention is intended only to provide a brief overview of subject matter disclosed herein according to one or more illustrative embodiments, and does not serve as a guide to interpreting the claims or to define or limit the scope of the invention, which is defined only by the appended claims. This brief description is provided to introduce an illustrative selection of concepts in a simplified form that are further described below in the detailed description. This brief description is not intended to identify key features or essential features of the claimed subject matter, nor is it intended to be used as an aid in determining the scope of the claimed subject matter. The claimed subject matter is not limited to implementations that solve any or all disadvantages noted in the background.
So that the manner in which the features of the invention can be understood, a detailed description of the invention may be had by reference to certain embodiments, some of which are illustrated in the accompanying drawings. It is to be noted, however, that the drawings illustrate only certain embodiments of this invention and are therefore not to be considered limiting of its scope, for the scope of the invention encompasses other equally effective embodiments. The drawings are not necessarily to scale, emphasis generally being placed upon illustrating the features of certain embodiments of the invention. In the drawings, like numerals are used to indicate like parts throughout the various views. Thus, for further understanding of the invention, reference can be made to the following detailed description, read in connection with the drawings in which:
In the exemplary embodiment of
The fluoroelastomeric polymer used for the protective coating 108 is selected to provide an acceptable level of chemical durability to resist the acidic environment of a EGR system, including resistance to nitric acid, sulphuric acid and biodiesel combustion products at elevated temperatures without including electrically conductive additives. The fluoroelastomeric polymer is designed to function as an electrically insulating coating with dielectric strengths of about 50 kV per millimeter or greater. In some embodiments, the resistance value is greater than 100 Mega ohms at 500 volts. The fluoroelastomeric polymer should also have sufficient hardness to safeguard the sensor assembly 100 against physical damage, for example, a Shore A hardness of sixty or greater. Sufficient flexibility to permit first and second conductive leads 104, 106 to bend is also desirable. The fluoroelastomeric polymer is also selected to exhibit acceptable water immersion resistance (e.g., minimal change of resistance of the thermistor after 1000 hours of water immersion at 85° C. under 5V of power with a 6.81 kilo ohm series resistor) and mechanical properties (e.g., able to endure over 3000 cycles of thermal shock between −40° C. and 155° C.). The fluoroelastomeric polymer should also be capable of surviving curing temperature of about 200° C. without negatively impacting performance. One or more of these properties are present in the harsh environment of the EGR system, which includes high concentrations of acids at high temperatures (about 250° C. for high melting point lead solder or 200° C. for lead-free solder). To permit proper coating of the sensor assembly 100, the fluoroelastomeric polymer is capable of being applied by dip coating.
The fluoroelastomeric polymer is the polymerization product of a reaction mixture that includes a fluorinated or perfluorinated monomer with one or more co-monomers. Examples of suitable monomers include vinylidene fluoride and tetrafluoroethylene. Examples of suitable co-monomers include fluorinated propylenes, such as hexafluoropropylene. Further examples of suitable monomers include tetrafluoroethylene and perfluoromethylvinylether. The resulting fluoroelastomeric polymer is typically 60% fluorine or more by weight and is saturated. One suitable fluoroelastomeric polymer is sold by Du Pont under the trade name VITON®. Care must be taken to select a fluoroelastomeric polymer formulation where conductive processing aids, such as carbon black, are omitted (e.g. Non-Black VITON®).
In step 204, the viscosity of the dissolved fluoroelastic polymer is adjusted. In one embodiment, the viscosity is adjusted by adding a sufficient amount of the organic carrier solvent to achieve a desired viscosity. The viscosity is adjusted to, for example, a value of between 1000 centipoise and 5000 centipoise. In some embodiments, the viscosity is adjusted by permitting a portion of the organic carrier solvent to evaporate.
In step 206, the liquid is cooled to a temperature below ambient temperature to reduce the rate of evaporation of the organic carrier solvent. The liquid may be cooled to a temperature that is about 10° C. cooler than the ambient temperature. In one exemplary embodiment, the ambient temperature is about 25° C. and the liquid may be cooled to a temperature of about 15° C.
In step 208, the entire sensor of the sensor assembly is immersed in the cooled fluoroelastomeric polymer after the fluoroelastomeric polymer has dissolved. The sensor assembly is immersed such that a portion of the conductive leads of the sensor assembly, which are proximate to the sensor, are also immersed. This helps protect the connection between the sensor and the conductive leads.
In step 210, the sensor assembly is withdrawn from the cooled fluoroelastomeric polymer. The rate with which step 210 is performed controls the thickness of the resulting layer. When a thick layer is desired, the sensor assembly is withdrawn relatively rapidly. The cooled organic carrier solvent contacts the comparatively warm ambient environment and rapidly evaporates to deposit a relatively thick layer of the fluoroelastomeric polymer. When a thin layer is desired, the sensor assembly is withdrawn relatively slowly. The cooled organic carrier solvent is given time to flow off of the sensor assembly before it contacts the comparatively warm ambient environment. This deposits a relatively thin layer of the fluoroelastomeric polymer. By adjusting the rapidity with which the sensor assembly is withdrawn, a layer with a predetermined thickness is produced. In some embodiments, multiple layers are deposited, one atop another, and provide a conformal layer of a predetermined thickness.
In step 212, at least a portion of the organic carrier solvent is permitted to evaporate to form a semisolid conformal layer of the newly deposited fluoroelastomeric polymer. In one embodiment, step 212 further comprises an ambient drying step that lasts for at least two minutes. For example, the newly deposited fluoroelastomeric polymer may be exposed to the ambient environment for about two minutes to permit the organic carrier solvent to evaporate. Since the ambient environment is warm relative to the temperature of the organic carrier solvent, evaporation is facilitated.
In step 214, a determination is made concerning whether or not an additional layer of fluoroelastomeric polymer should be deposited. If another layer is desired, the method 200 returns to step 208 and the sensor assembly is immersed in the cooled fluoroelastomeric polymer again. This deposits an additional layer of fluoroelastomeric polymer atop the previously deposited layer(s). If another layer is not desired, step 216 may be executed wherein a portion of the coated sensor assembly (e.g. the tip) is dipped in a colorant to provide a coating of a predetermined color for color coding. A variety of compatible colorants are known in the art. In one embodiment, two layers of fluoroelastomeric polymer are provided. In another embodiment, three layers of fluoroelastomeric polymer are provided. Advantageously, since the conformal layer(s) are applied using a dip coating technique, the thickness of the resulting coating is easily controlled. The coating length (i.e. immersion depth) of 30 mm or greater can be achieved using this technique.
In step 218, the layer(s) of fluoroelastomeric polymer are cured to encapsulate the sensor. In one embodiment, the curing step includes heating the coated sensor assembly to a predetermined temperature for a predetermined time that is selected to remove the organic carrier solvent and cross-link (vulcanize) the fluoroelastic polymer. For example, the coated sensor assembly may be heated to a temperature of about 100° C. for about thirty minutes. The coated sensor assembly may also be subjected to a stepwise heating process that both drives off any residual organic carrier solvent as well as cures the layers of fluoroelastomeric polymer to seal the sensor within the fluoroelastomeric polymer. An exemplary stepwise heating process heats the cured, coated sensor assembly to a temperature of about 90° C. for a predetermined period of time. Thereafter, the temperature is increased to about 160° C. for a predetermined period of time. Two additional stepwise heating processes are likewise performed at temperatures of 180° C. and 200° C.
Thermistors coated in accordance with the teachings of this specification show less than a 3% shift in resistance after operating at 85° C. for 2000 hours immersed in water. The thermistors likewise showed less than a 0.4% shift in resistance after aging at temperatures of up to 170° C. for 1000 hours. In comparison, conventional thermistors showed a significantly larger shift in resistance when subjected to the same conditions.
The EGR system 300 of
This written description uses examples to disclose the invention, including the best mode, and also to enable any person skilled in the art to practice the invention, including making and using any devices or systems and performing any incorporated methods. The patentable scope of the invention is defined by the claims, and may include other examples that occur to those skilled in the art. Such other examples are intended to be within the scope of the claims if they have structural elements that do not differ from the literal language of the claims, or if they include equivalent structural elements with insubstantial differences from the literal language of the claims.
