This application claims priority to German Patent Application No. 102023205187.7 filed on Jun. 2, 2023, the content of which is incorporated by reference herein in its entirety.
The present disclosure relates to a sensor device for measuring a gas concentration and to a method for determining a gas concentration, in particular a concentration of hydrogen.
Gas concentration sensors, e.g., thermal conductivity sensors, can be used for example in the automotive sector or in a wide range of industrial applications. Here, such sensors can provide measured values that indicate a thermal conductivity of an analytical gas. However, these measured values may be tainted with deviations or offset effects that are affected by other properties of the gas to be measured. For example, the measurement of thermal conductivity can be highly dependent on the ambient pressure of the gas to be measured. Inaccurate measured values can pose a significant safety risk, especially in the case of applications in the automotive sector. Manufacturers and designers of gas concentration sensors are therefore constantly striving to improve their products. In particular, it may be desirable to provide thermal conductivity sensors that take into account the offset effects mentioned in order to provide reliable and accurate measurement results. In addition, it may be desirable to provide suitable methods for operating such thermal conductivity sensors.
There is a need for a gas sensor that can be used to determine a gas concentration, in particular a hydrogen content, with higher operational reliability.
Based on this, a sensor device according to the main claim is proposed. Advantageous refinements are specified in the subclaims.
A first aspect of the present disclosure relates to a sensor device for measuring a gas concentration, which includes a sensor element with a cavity, an opening of the cavity for receiving a gas, and a resistor element arranged in the cavity. The sensor device further includes a power supply unit, which is configured to apply a voltage to the sensor element, and a control unit. The control unit is configured to set a first voltage of the power supply unit and detect a first output signal of the sensor element at the applied first voltage, and to set a second voltage of the power supply unit and detect a second output signal of the sensor element at the applied second voltage. The second voltage is different here from the first voltage. The sensor device further includes an evaluation unit, which is configured to determine the gas concentration based on the first output signal and the second output signal.
A second aspect of the present disclosure relates to a method for determining a gas concentration. The method includes surrounding a resistor element of a sensor element with a gas, applying a first voltage to the sensor element, detecting a first output signal of the sensor element with the first voltage applied, applying a second voltage to the sensor element, which is different from the first voltage, detecting a second output signal of the sensor element with the second voltage applied, and determining the gas concentration based on the first output signal and the second output signal.
A person skilled in the art will recognize further features and advantages of the disclosure when reading the detailed description that follows and when looking at the accompanying drawings.
The present disclosure is described by way of illustration and in nonlimiting fashion in the figures of the accompanying drawings, in which identical reference numerals refer to similar or identical elements. The elements in the drawings are not necessarily depicted to scale with respect to one another. The features of the various examples shown can be combined, unless they are mutually exclusive.
The implementations described below give a detailed description of thermal conductivity sensors (or thermal conductivity gas sensors) and methods for operating such sensors according to this disclosure. Thermal conductivity sensors, as described here, can be used in particular as hydrogen sensors for the detection of hydrogen and/or hydrogen concentrations. Hydrogen sensors can be used in a variety of applications, such as in the automotive sector or in industrial applications. For example, hydrogen sensors can be used to detect hydrogen exhaust gases, to monitor exhaust gases, to monitor batteries, to detect hydrogen leaks, to detect hydrogen in industrial plants, etc.
With regard to the climate goals, the automotive industry is promoting and developing the production of hydrogen-powered vehicles. Fuel cell cars can be seen as a breakthrough for electromobility and can contribute significantly to reducing the CO2 emissions. The thermal conductivity sensors described here improve the hydrogen technology and can thus at least partially contribute to achieving the set climate goals. The thermal conductivity sensors described here provide a simple and efficient way to compensate for offset effects. By comparison, the manufacture and design of traditional sensors can be more complex and require a higher number of components, resulting in increased resource consumption. The thermal conductivity sensors described here save resources and can contribute to energy savings. Overall, improved thermal conductivity sensors according to the disclosure and methods for operating such sensors can contribute to green technology and green energy solutions, e.g., to climate-friendly solutions with reduced energy consumption.
The sensor device 100 in this example further comprises a power supply 110 configured to apply the supply voltage Vi to the resistor element 104. The power supply 110 can output different supply voltages Vi, in particular a first supply voltage V1 and a second supply voltage V2 different therefrom. The sensor device 100 further comprises a control unit 120, which is electronically coupled to the power supply 110. The control unit 120, for example a control circuit, may be configured to supply the power supply 110 with a trigger signal, based on which the power supply 110 applies a supply voltage Vi to the resistor element 104. For example, the control unit 120 may be configured to output a first and a second trigger signal in order to trigger application of the first supply voltage V1 and the second supply voltage V2, respectively. The second supply voltage V2 may be greater than the first supply voltage V1, so that the associated stable characteristic second temperature T2 of the resistor element 104 at the second supply voltage V2 is higher than the stable characteristic first temperature T1, or vice versa. The control unit 120 is also configured to acquire a sensor value from the sensor element 101. For example, the control unit 120 acquires a first output value O1 of the sensor element 101 after a predefined period t1 with the first supply voltage V1 applied and a second output value O2 after a further predefined period t2 with the second supply voltage V2 applied. The predefined periods t1, t2 may be defined in such a way that a constant temperature, e.g., the stable characteristic first temperature T1, T2, has arisen after the respective supply voltage V1, V2 has been applied. The first and second output signals O1, O2 can be an electrical current through the resistor element 104 when the characteristic stable first and second temperatures T1, T2 of the resistor element 104 have arisen.
The sensor device 100 further comprises an evaluation unit 130, for example an evaluation circuit, which is electronically coupled to the control unit 120 and is configured to receive the first output signal O1 and the second output signal O2 from the control unit 120 and to determine a concentration of a gas in the cavity 102 of the sensor element 101 therefrom. For example, the evaluation unit 130 is configured to compensate the first output signal O1 or a signal formed based on the first output signal O1 using the second output signal O2 or a further signal formed based on the second output signal O2, or vice versa. For example, the second output signal O2 corresponds to a sensor measured value at a high applied supply voltage V2, e.g., 5 V, that is to say a high temperature T2 of the resistor element 104, and depends primarily on the thermal conductivity of the surrounding gas, while the first output signal O1 corresponds to a sensor measured value at a low applied supply voltage V1, e.g., 1 V, that is to say a lower temperature T1 of the resistor element 104, and depends primarily on the ambient pressure of the analytical gas in the cavity 102. This is due to the fact that the gas pressure surrounding the resistor element 104 produces a mechanical tension on the surfaces thereof, which in turn is reflected in a mechanical tension on the piezo resistors, ultimately leading to a pressure-dependent measurement signal. Thus, the evaluation unit 130 may be configured to determine the gas pressure from the first output signal O1, and to correct or compensate the second output signal O2 using the determined gas pressure, for example using a calibration table. The evaluation unit 130 may also be configured to output the corrected output signal or to determine the gas concentration from the corrected first output signal and to output a measurement signal based on the determined gas concentration.
The bridge circuit 400 may further contain a coupling (not shown) to the control unit 120 for providing an output signal Oi that indicates the thermal conductivity and/or the gas pressure of an analytical gas. In particular, the bridge circuit 400 may be configured so that it measures and outputs a voltage difference between a third node 403 and a fourth node 404 as the output signal Oi, as shown in
During operation of the bridge circuit 400, a supply voltage can be applied, as shown in
The bridge circuit 400 may be referred to as a sensor element hereinbelow. It should be noted that the bridge circuit 400 is example and can be replaced by any other half-bridge circuit or bridge circuit configured to provide a measured value indicating the gas pressure or the thermal conductivity of an analytical gas. Accordingly, the sensor elements described here may correspond to or contain a bridge circuit or a half-bridge circuit. The thermal conductivity sensors described here are not limited to the example Wheatstone bridge circuit 400 of
It should be noted that the thermal conductivity sensors described here may contain further circuit components, such as a switch, a signal amplifier, an analog-to-digital converter, etc. However, these components do not necessarily have to be considered as part of a sensor element 101. The operation of these additional components does not necessarily have to depend on the prevailing temperature. In contrast, the operation of the bridge circuit 400 and the value of the output signal Oi, e.g., the output voltage, may depend on the temperature T1 of the bridge circuit.
A further measurement can be repeated in an analogous manner at a further time t3 or t4, for example in order to verify the first measurement and/or to monitor a possible change in the thermal conductivity and thus the gas concentration. A multiplicity of first output signals O1 can also be determined for every second output signal O2, for example in order to improve the signal-to-noise ratio and to determine a reliable pressure value. In this case, the evaluation unit 130 is configured to correct the second output signal O2 with the multiplicity of first output signals O1 or a signal determined from the multiplicity of first output signals O1. For example, the evaluation unit 130 determines a mean gas pressure from the multiplicity of first output signals O1 and corrects the second output signal O2 or a signal determined from the second output signal O2, e.g., a thermal conductivity of the analytical gas, using the mean gas pressure, in order to obtain a corrected thermal conductivity. The evaluation unit 130 is further configured to determine the gas concentration, for example a hydrogen concentration, of the analytical gas from the corrected thermal conductivity. If necessary, the evaluation unit 130 may be configured to output an alarm signal if the determined gas concentration falls below and/or exceeds a threshold value.
As an alternative to the timing diagram shown in
In step 81, a resistor element 104 of a sensor element 101 is surrounded by a gas whose concentration is to be determined. At 82, a first supply voltage V1 can be applied to the resistor element 104. At 83, the control unit 120 can perform a first measurement at the first supply voltage V1 for the analytical gas and can detect a first output signal O1. At 84, a second supply voltage V2 can be applied to the resistor element 104, the second supply voltage V2 being able to be higher than the first supply voltage V1. At 85, the control unit 120 can perform a second measurement at the second supply voltage V2 for the analytical gas. In this context, a second output signal O2 can be determined. At 86, the evaluation unit 130 can determine a compensated output signal or measurement signal, e.g., by compensating for an offset of the second output signal O2 due to an ambient pressure of the analytical gas based on the first output signal O1. At 87, the evaluation unit 130 can determine the concentration of the analytical gas based on the compensated output signal.
It should be pointed out that the description and the drawings illustrate only the principles of the proposed devices and methods. A person skilled in the art will be able to implement various arrangements which, although not expressly described or shown here, embody, and are included in the extent of, the principles of the implementation. In addition, all examples and implementations outlined in the present document are fundamentally and expressly intended only for explanatory purposes to help the reader understand the principles of the proposed methods and devices. In addition, all statements in this document that describe principles, aspects and implementations of the implementation, and specific examples thereof, are also intended to include their equivalents.
Devices and methods according to the disclosure are explained hereinbelow using aspects.
Aspect 1 is a sensor device for measuring a gas concentration, comprising:
Aspect 2 is a sensor device according to Aspect 1, wherein the first output signal and/or the second output signal depends on the gas concentration and the thermal conductivity of the gas.
Aspect 3 is a sensor device according to one of the preceding aspects, wherein the control unit is configured to reach a first temperature of the resistor element using the first voltage and determine the first output signal at the first temperature, and to reach a second temperature of the resistor element using the second voltage and determine the second output signal at the second temperature, the first temperature being different from the second temperature.
Aspect 4 is a sensor device according to Aspect 3, wherein the first and/or the second temperature are greater than an ambient temperature of the sensor device.
Aspect 5 is a sensor device according to Aspect 3 or 4, wherein the first and/or the second temperature depends on the gas concentration and the thermal conductivity of the gas.
Aspect 6 is a sensor device according to one of the preceding aspects, wherein the control unit is configured to determine a first resistance signal of the sensor element as the first output signal and a second resistance signal of the sensor element as the second output signal.
Aspect 7 is a sensor device according to one of the preceding aspects, wherein the resistor element is in the form of a micro-electromechanical systems structure, in particular in the form of a MEMS wire element.
Aspect 8 is a sensor device according to one of the preceding aspects, wherein the resistor element has piezoresistive properties.
Aspect 9 is a sensor device according to one of the preceding aspects, wherein the sensor element further comprises a sealed reference cavity and a reference resistor element arranged in the reference cavity, and wherein the power supply unit is further configured to apply the voltage to the resistor element and to the reference resistor element of the sensor element.
Aspect 10 is a sensor device according to Aspect 9, wherein the resistor element and the reference resistor element are arranged in a parallel switching configuration.
Aspect 11 is a sensor device according to one of the preceding aspects, wherein the sensor element further comprises a further resistor element arranged in the cavity, a sealed reference cavity and two reference resistor elements arranged in the reference cavity, wherein the resistor element, the further resistor element and the two reference resistor elements are arranged in a Wheatstone bridge, and wherein the power supply unit is further configured to apply the voltage to the Wheatstone bridge.
Aspect 12 is a sensor device according to Aspect 11, wherein a respective one of the resistor elements and one of the reference resistor elements form a voltage divider of the Wheatstone bridge.
Aspect 13 is a sensor device according to one of the preceding aspects, wherein the evaluation unit for determining the gas concentration is configured to compensate the first output signal using the second output signal.
Aspect 14 is a sensor device according to one of the preceding aspects, wherein the evaluation unit for determining the gas concentration is configured to apply a filter operation to the first and/or the second output signal, in particular a Kalman filter operation or a sliding average operation.
Aspect 15 is a sensor device according to one of the preceding aspects, wherein the evaluation unit for determining the gas concentration is configured to apply a correction factor to the first and/or the second output signal, in particular a temperature-dependent correction factor.
Aspect 16 is a sensor device according to one of the preceding aspects, wherein the control unit is configured to detect a multiplicity of first output signals at the applied first voltage, and wherein the evaluation unit is configured to determine the gas concentration based on the multiplicity of the first output signals and the second output signal.
Aspect 17 is a sensor device according to one of the preceding aspects, wherein the control unit is configured to set the first voltage and the second voltage such that the first output signal essentially depends on an ambient pressure of the gas and the second output signal essentially depends on the thermal conductivity of the gas.
Aspect 18 is a sensor device according to one of the preceding aspects, wherein the gas concentration is a hydrogen concentration.
Aspect 19 is a sensor device according to one of the preceding aspects, wherein the sensor element is a thermal conductivity sensor.
Aspect 20 is a method for determining a gas concentration comprising:
Number | Date | Country | Kind |
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102023205187.7 | Jun 2023 | DE | national |