Claims
- 1. A sensor element comprising:
- an optical fiber having a distal portion coated with a matrix made from a hydrophobic material that is permeable to at least one analyte;
- a first plurality of vesicles disposed in said matrix containing a first aqueous sensing solution with a first fluorescent dye indicator that is responsive to a particular analyte; and
- a second plurality of vesicles disposed in said matrix containing a second aqueous sensing solution with a second fluorescent dye indicator that is responsive to a second analyte, said vesicles being dispersed throughout said matrix, said matrix being only slightly thicker than the size of one of said vesicles.
- 2. A sensor element as defined in claim 1 wherein each said sensing solution and the matrix material are mutually immiscible.
- 3. A sensor element as defined in claim 1 wherein each of said first and second sensing solutions contains an emulsifier that forms an emulsion of said first and second sensing solutions with said matrix, and that renders each of said sensory solutions immiscible with said matrix and stabilizes the resulting emulsion.
- 4. A sensor element as defined in claim 3 wherein the emulsifier is a water soluble or water swellable polymer.
- 5. A sensor element as defined in claim 3 wherein the emulsifier is selected from a group consisting of polyvinylpyrrolidone, polytheylene glycol and polyethylene oxide.
- 6. A method for making a sensor element comprising the steps of:
- combining a first sensing solution including an indicator substance that is responsive to an analyte with an emulsifier solution to form a first emulsified solution;
- mixing a liquified matrix that is immiscible with the first sensing solution, and that is permeable to at least one analyte with the first emulsified solution;
- combining a second sensing solution that is immiscible with the liquified matrix and the first sensing solution, and having an indicator that is receptive to a second analyte with an emulsifier to form a second emulsified solution;
- mixing the second emulsified solution with the liquified matrix and the first emulsified solution;
- dispersing the first and second emulsified solutions as a plurality of vesicles in the liquified matrix material; and
- causing the liquified matrix to solidify in a thickness only slightly greater than the size of one of said vesicles.
- 7. The method of claim 6 wherein the first and second emulsified solutions are homogeneously dispersed throughout the matrix.
- 8. The method of claim 6 further comprising, before the dispersing step, the step of:
- mixing a catalyst to the emulsified solutions and liquified matrix.
Parent Case Info
This application is a continuation of application Ser. No. 07/394,638, filed Aug. 16, 1989 and now abandoned.
US Referenced Citations (19)
Foreign Referenced Citations (5)
Number |
Date |
Country |
0105870A2 |
Apr 1984 |
EPX |
0283206A2 |
Sep 1988 |
EPX |
0336986A1 |
Oct 1989 |
EPX |
8805533 |
Jul 1988 |
WOX |
2132348A |
Jul 1984 |
GBX |
Non-Patent Literature Citations (2)
Entry |
The Condensed Chemical Dictionary, 10th Ed., Van Nostrand Reinhold Co, N.Y., pp. 408, 842. |
G. G. Vurek; Fiber-Optic Carbon Dioxide Partial Pressure Sensor; Mar. 1983; PB83-189738. |
Continuations (1)
|
Number |
Date |
Country |
Parent |
394638 |
Aug 1989 |
|