Ceramic sensor elements for lambda sensors are described, for example, in German Patent Application No. DE 10 2018 206 966 A1, which sought to increase the loadability of the sensor element in relation to mechanical stresses.
The present invention also aims to increase the loadability of the sensor element in relation to mechanical stresses.
In this context, the inventors found, firstly, that in a ceramic sensor element, a certain mechanical weakening in the end region of the sensor element facing away from the exhaust gas already results in principle from the provision of the first, second and third via.
Moreover, the inventors found that the mechanical weakening also occurs when the vias are close together. In this case, the individual weakening caused by each of the vias is further increased in total.
Moreover, the inventors found that the mechanical weakening also occurs when one or more vias in the transverse direction are close to an outer edge of the sensor element. In this case, the sensor element offers only limited resistance to a mechanical stress originating from the outer edge of the sensor element.
Moreover, the inventors found that the mechanical weakening also occurs when a via is spaced relatively far from the axial end of the sensor element facing away from the exhaust gas.
Specifically, in this case, forces acting in the layer direction on the axial end of the sensor element facing away from the exhaust gas give rise to a sizeable lever effect in the region of the via, resulting in high mechanical stresses at that point.
The inventors also found that a further general mechanical weaking may originate from insulating layers arranged between the solid electrolyte layers, partly because these layers already fundamentally disrupt the homogeneous layer structure formed by solid electrolyte layers. In addition, by reason of the differing sintering behavior of the insulating layers and the solid electrolyte layers, the incorporation of the insulating layers leads to mechanical stresses.
The inventors found that this is particularly the case when the insulating layers extend to close to the outer edges of the sensor element in the transverse direction or in the axial direction.
The inventors then found various possibilities for reducing or minimizing this mechanical weakening overall. These possibilities are each effective in themselves and especially so when combined.
According to an example embodiment of the present invention, it is provided a that in a sensor element, the second via and the third via are both arranged on the exhaust gas side of the first via in the axial direction and that the first via is arranged between the second via and the third via in the transverse direction. In comparison to the arrangement described in the related art, it is possible in this way to increase the distance between the vias without having to position the vias excessively far from the axial end of the sensor element facing away from the exhaust gas. Furthermore, the distance between the first via and the outer edge of the sensor element in the transverse direction is increased.
This is all the more the case if the second via and the third via are positioned at the same axial level and if the first via is positioned centrally between the second via and the third via in the transverse direction, such that the first, second and third vias are located at the corners of an isosceles triangle, especially if in the isosceles triangle the angle opposite the base is not greater than 90° and not less than 30°. The triangle may preferably be an equilateral triangle, for example.
In the context of the present invention, the position of a via and, consequently, relative positions of vias in respect of one another, may be specified starting from the position of the centroid of the via in plan view of a large face of the sensor element. In the case of vias that in plan view of a large face of the sensor element are circular, this position would thus be the center point of the respective circle.
In addition or alternatively, it may be provided in the case of a sensor element according to the present invention that the first via, the second via and the third via are positioned entirely in the end region of the sensor element facing away from the exhaust gas, the extent of the end region of the sensor element facing away from the exhaust gas in the axial direction being less than one-fifth of the extent of the sensor element in the axial direction. By reason of the reduced lever effect, forces acting in the layer direction on the axial end of the sensor element facing away from the exhaust gas then bring about only reduced stresses in the region of the via.
It may be provided that the first via is designed as a first hole in the first solid electrolyte layer with a first conductive material arranged in the first hole, and that the second via is designed as a second hole in the second solid electrolyte layer with a second conductive material arranged in the second hole, and that the third via is designed as a third hole in the second solid electrolyte layer with a third conductive material arranged in the third hole, and that the first hole has a first diameter and the second hole has a second diameter and the third hole has a third diameter.
In plan view of a large face of the sensor element, the holes may be circular, for example, such that the diameters of the holes are the diameters of the respective circles. The three diameters in question may be the same size, for example.
It may be provided that, in plan view of the large faces of the sensor element, the centroid of the second hole is spaced a distance a from the centroid of the third hole.
If in a sensor element having the features of the present invention, it is provided that the distance a is less than the sum of the second diameter and the third diameter, and/or if it is provided that the half-distance is less than the distance from the centroid of the second hole to a closest outer edge of the sensor element in the transverse direction, and/or if it is provided that the half-distance is less than the distance from the centroid of the third hole to the closest outer edge of the sensor element in the transverse direction, then the distance between the second and the third via and relative to a distance from the vias to an outer edge of the sensor element and relative to the hole diameters overall is in a balanced and in that sense mechanically optimized range.
If, in a sensor element according to the present invention, it is provided that the distance from the centroid of the first hole in the axial direction to the first, second, third and/or fourth contact surface is no greater than half the diameter of the first hole, this means that the first hole is arranged very close to the contact surfaces in the axial direction and hence close to the end of the sensor facing away from the exhaust gas. By reason of the reduced lever effect, forces acting in the layer direction on the axial end of the sensor element facing away from the exhaust gas then bring about only reduced stresses in the region of the first via.
In addition or alternatively, it may be provided that, in plan view of the large face of the sensor element, the first contact surface has a concave outer contour facing the first via. The first via may then be moved especially close to the end of the sensor element facing away from the exhaust gas without coming into contact with the first contact surface, especially if it is provided that the concave outer contour has a radius that is equal to half the diameter of the first hole or differs from half the diameter of the first hole by no more than 50%. In addition or alternatively, the first via and the concave outer contour of the first contact surface may also be concentric with each other.
In addition or alternatively, in a sensor element according to an example embodiment of the present invention, it may be provided that, between the first and the second solid electrolyte layer, an insulating layer is arranged or a plurality of insulating layers are arranged in such a way that a first electrical network, comprising the second electrode, the second trace and the first via, is electrically isolated by the insulating layer/insulating layers from a second electrical network, comprising the resistive heater trace, the third trace, the fourth trace, the second via and the third via.
It may be provided in this case that, in plan view of the large faces of the sensor element, the extent of the insulating layer/insulating layers is only as large as is necessary in order to electrically isolate the first electrical network from the second electrical network and, in addition, the insulating layer/insulating layers is/are surrounded by a sealing frame/by respective sealing frames made of solid electrolyte material. “Only” in this context may assume in particular that, for manufacturing reasons, the insulating layer/insulating layers extend in the transverse direction and/or in the axial direction beyond the entirety of the structure to be insulated, for example by up to 250 μm and/or by up to 5% of the extent of the sensor element in the transverse direction—but no more—beyond the structure to be isolated. The mechanical weakening of the sensor element is then reduced to a minimum that is unavoidable for the desired electrical isolation.
A comparable technical effect results from the measure whereby the extent of the sealing frame/of all sealing frames in the transverse direction, measured from the associated insulating layer to the outer edge of the sensor element in the end region of the sensor element facing away from the exhaust gas, is always greater than 1/10 of the extent of the sensor element in the transverse direction.
The solid electrolyte material, like the material of the solid electrolyte layers, may be YSZ or the like.
According to an example embodiment of the present invention, advantageously, both a first insulating layer and a second insulating layer may be provided, the first insulating layer being arranged on the side facing the first solid electrolyte layer and the first electrical network, viewed from the second insulating layer in the layer direction, and the second insulating layer being arranged on the side facing the second solid electrolyte layer and the second electrical network, viewed from the first insulating layer in the layer direction.
It may be provided in this case that the first insulating layer, in plan view of the large face of the sensor element, covers the second trace and the first, second and third via, the first insulating layer widening in the transverse direction at the axial level of the second and third via for this purpose, and/or that the second insulating layer, in plan view of the large face of the sensor element, encloses the second electrical network and additionally covers the first via, in that the second insulating layer narrows in the transverse direction at the axial level of the first via. The desired electrical isolation effect occurs in these cases with just a minimal mechanical weakening of the sensor element, in other words with retention of an optimized mechanical stability of the sensor element.
On the upper side of first solid electrolyte layer 21, first contact surface 31 is connected by way of a first trace 51 to a first electrode 61, which is arranged in end region 101 of sensor element 10 facing the exhaust gas.
Second contact surface 32 is electrically conductively connected to a first via 41, which is arranged centrally in transverse direction 203 with respect to sensor element 10, a short axial distance from first and second contact surface 31, 32. First via 41 is, for example, a cylindrical first hole 41′ which passes through first solid electrolyte layer 21 and which contains in its interior—optionally electrically isolated from first solid electrolyte layer 21—a first conductive material 41″. The diameter D of the first hole is 1 mm, for example.
In axial direction 201, first via 41 is, for example, 5 mm away from the end of sensor element 10 facing away from the exhaust gas.
A corner of first contact surface 31 facing first via 41 is designed as a circular recess, such that first contact surface 31 has a concave outer contour 31k here. Concave outer contour 31k is designed as a circular arc, in the example an arc with a radius of curvature of 0.5 mm about 90°. Thus, even in the event of manufacturing-related variations in the precise arrangement of the components, the possibility of an electrical short circuit between first via 41 and first contact surface 31 is excluded.
First electrode 61, which is exposed to the exhaust gas, together with first solid electrolyte layer 21 and second electrode 62, which is not exposed to the exhaust gas, forms an electrochemical Nernst cell with which—assuming appropriate heating, see below—on the basis of a Nernst voltage developing at said cell and measurable between first and second contact surface 31, 32, it may be determined whether the exhaust gas is the result of a combustion with excess oxygen (“lean”) or of a combustion with excess fuel (“rich”) or of a combustion in which oxygen and fuel are in stoichiometric equilibrium.
Third contact surface 33 is electrically conductively connected to a second via 42, which is arranged, for example, at an axial distance of 7.2 mm from the end of sensor element 10 facing away from the exhaust gas. Second via 42 is arranged 0.95 mm off center, for example, in the transverse direction (to the right in
Symmetrically thereto once again, fourth contact surface 34 is electrically conductively connected to a third via 43, which is arranged at the same axial level and is equally off-centered in the transverse direction (albeit to the left rather than the right) as second via 42.
Second and third via 42, 43 are, for example, cylindrical second and third holes 42′, 43′ which pass through second solid Substitute Specification electrolyte layer 22 and which contain in their interior—optionally electrically isolated from second solid electrolyte layer 22—a second and a third conductive material 42″, 43″. The diameter D of these holes is in both cases 1 mm, for example.
By applying an electrical voltage between third and the fourth contact surface 33, 34, resistive trace 63 heats up in such a way that the Nernst cell assumes the operating temperature necessary for the measuring function of sensor element 10.
To prevent undesirable electrical crosstalk between the heating function and the measuring function of sensor element 10, a first insulating layer 23 and a second insulating layer 24 are arranged between first solid electrolyte layer 21 and second solid electrolyte layer 22. First insulating layer 23 is positioned on the underside of first solid electrolyte layer 21 and second solid electrolyte layer [sic] is positioned on the upper side of second solid electrolyte layer 22.
Insulating layers 23, 24 consist, for example, of Al2O3 and in layer direction 202, for example, have a smaller extent than solid electrolyte layers 21, 22. For example, insulating layers 23, 24 may be screen-printed layers, while solid electrolyte layers 21, 22 may be formed from green ceramic films, for example.
First insulating layer 23 is shown in
Second insulating layer 24 is shown in
Number | Date | Country | Kind |
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10 2020 207 877.7 | Jun 2020 | DE | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2021/065892 | 6/14/2021 | WO |