Separating 3-methyl-1-butanol from 1-pentanol using certain organic compounds as the agent in extractive distillation

Abstract

3-Methyl-1-butanol is difficult to separate from 1-pentanol by conventional distillation or rectification because of the proximity of their boiling points. 2 Methyl-1-butanol can be easily separated from 1-pentanol by extractive distillation. Effective agents are phenol, anisole and methyl salicylate.

Description

FIELD OF THE INVENTION

This invention relates to a method for separating 3-methyl-1-butanol from 1-pentanol using certain organic compounds as the agent in extractive distillation.

DESCRIPTION OF PRIOR ART

Extractive distillation is the method of separating close boiling compounds from each other by carrying out the distillation in a multiplate rectification column in the presence of an added liquid or liquid mixture, said liquid(s) having a boiling point higher than the compounds being separated. The extractive agent is introduced near the top of the column and flows downward until it reaches the stillpot or reboiler. Its presence on each plate of the rectification column alters the relative volatility of the close boiling compounds in a direction to make the separation on each plate greater and thus require either fewer plates to effect the same separation or make possible a greater degree of separation with the same number of plates. The extractive agent should boil higher than any of the close boiling liquids being separated and not form minimum azeotropes with them. Usually the extractive agent is introduced a few plates from the top of the column to insure that none of the extractive agent is carried over with the lowest boiling component. This usually requires that the extractive agent boil about twenty Celcius degrees or more higher than the highest boiling component.

At the bottom of a continuous column, the less volatile components of the close boiling mixtures and the extractive agent are continuously removed from the column. The usual methods of separation of these two components are the use of another rectification column, cooling and phase separation, or solvent extraction.

The usual method of evaluating the effectiveness of extractive distillation agents is the change in relative volatility of the compounds to be separated. Table 1 shows the degree of separation or purity obtainable by theoretical plates at several relative volatilities. Table 1 shows that a relative volatility of at least 1.2 is required to get an effective separation by rectification.

TABLE 1__________________________________________________________________________Effect of Relative Volatility on Theoretical Stage Requirements.Separation Purity, Relative VolatilityBoth Products Theoretical Stages at Total Reflux(Mole Fraction) 1.02 1.1 1.2 1.3 1.4 1.5 2.0 3.0__________________________________________________________________________0.999 697 144 75 52 40 33 19 120.995 534 110 57 39 30 25 14 90.990 463 95 49 34 26 22 12 70.98 392 81 42 29 22 18 10 60.95 296 61 31 21 16 14 8 40.90 221 45 23 16 12 10 5 3__________________________________________________________________________

3-Methyl-1-butanol and 1-pentanol boil eight degrees apart, have a relative volatility of 1.28 and are difficult to separate by conventional rectification. Table 2 shows that with agent giving a relative volatility of 1.4, only 35 actual plates are required.

TABLE 2______________________________________Theoretical And Actual Plates Required vs. RelativeVolatility For 3-Methyl-1-butanol-1-Pentanol SeparationRelative Theoretical Plates Required Actual PlatesVolatility At Total Reflux 99% Purity Required, 75% Eff.______________________________________1.28 37 491.4 26 35______________________________________

OBJECTIVE OF THE INVENTION

The object of this invention is to provide a process or method of extractive distillation that will enhance the relative volatility of 3-methyl-1-butanol from 1-pentanol in their separation in a rectification column. It is a further object of this invention to identify effective extractive distillation agents that are stable and can be recylced.

SUMMARY OF THE INVENTION

The objects of this invention are provided by a process for the separation of 3-methyl-1-butanol from 1-pentanol which entails the use of certain organic compounds when employed as the agent in extractive distillation.

DETAILED DESCRIPTION OF THE INVENTION

I have discovered that certain organic compounds will effectively increase the relative volatilty between 3-methyl-1-butanol and 1-pentanol during rectification when employed as the agent in extractive distillation. They are methyl benzoate, butyl butyrate, methyl salicylate, propiophenone, 1,3-butanediol, anisole and phenol.

TABLE 3______________________________________Effective Extractive Distillation Agents ForSeparating 3-Methyl-1 butanol From 1-Pentanol RelativeCompounds Volatility______________________________________None 1.28Methyl benzoate 1.35Butyl butyrate 1.4*Methyl salicylate 1.35*Propiophenone 1.351,3-Butanediol 1.35Anisole 1.35Phenol 1.4______________________________________ *Reverses the volatility

WORKING EXAMPLE

Example 1

Fifty grams of 3-methyl-1-butanol-1-pentanol mixture and fifty grams of phenol as the extractive agent were charged to a vapor liquid equilibrium still and refluxed for three hours. The vapor composition was 34.9% 3-methyl-1-butanol, 65.1% 1-pentanol; the liquid composition was 27.5% 3-methty-1-butanol, 72.5% 1-pentanol. This is a relative volatility of 1.4,

Claims

1. A method for recovering 3-methyl-1-butanol from 1-pentanol from a mixture of 3-methyl-1-butanol and 1-pentanol which comprises distilling a mixture of 3-methyl-1-butanol and 1-pentanol in the presence of an extractive agent, recovering the 3-methyl-1-butanol as overhead product and obtaining the 1-pentanol and the extractive agent as bottoms product, wherein said extractive agent consists of one material selected from the group consisting of methyl benzoate, propiophenone, 1,3-butanediol, anisole and phenol.

2. A method for recovering 1-pentanol from 3-methyl-1-butanol from a mixture of 1-pentanol and 3-methyl-1-butanol which comprises distilling a mixture of 1-pentanol and 3-methyl-1-butanol in the presence of an extractive agent, recovering the 1-pentanol as overhead product and obtaining the 3-methyl-1-butanol and the extractive agent as bottoms product, wherein said extractive agent consists of methyl salicylate or butyl butyrate.