Patent Application
20210170339
The present invention relates to a separation membrane module that is used to separate a component part from a fluid such as a solution or mixed gas.
A known apparatus for separating a component in a solution or mixed gas is a separation membrane module. A tubular separation membrane that is used in the separation membrane module includes a tubular porous support and a porous separation membrane that is disposed on the outer circumferential surface of the support and that is composed of, for example, zeolite. Known methods of separating a specific component from a fluid such as a solution or mixed gas include a method of vaporizing and separating the specific component by bringing the fluid of the solution into a side (an outer surface) of a separation membrane element and decreasing the pressure of the other side (an inner surface), a method of separating the specific component by vaporizing the solution into gas, bringing the gas into the separation membrane, and decreasing the pressure of a non-contact surface, and a method of separating the specific component by bringing the pressurized mixed gas into the separation membrane.
PTL 1 (particularly in
Gas that has permeated through the tubular separation membranes flows into an outflow chamber below the support plate and is retrieved from the outlet chamber via an outlet.
PTL 1: JP2016-155093A
In a structure in PTL 1 in which the end tubes that are connected to the lower ends of the tubular separation membranes are inserted into the insertion holes of the support plate, and the end tubes are supported by a support box, pressure in the outlet chamber below the support plate is lower than pressure in a fluid-processing chamber above the support plate, and a large bending load is applied to the support plate.
The structure in PTL 1 needs sufficient sealing between the outer circumferential surface of the support plate and the inner circumferential surface of the housing in order to prevent gas in a fluid-processing chamber above the support plate from passing through a space between the outer circumferential surface of the support plate and the inner circumferential surface of the housing and leaking to the outlet chamber.
In the case where the modules are installed in series, the structure in PTL 1 also needs a pipe that is interposed between the modules.
It is an object of the present invention to provide a separation membrane module that enables a bending load that is applied to a support member that supports ends of tubular separation membranes to be decreased, that enables a seal member between the outer circumferential surface of the support member and the inner circumferential surface of a housing to be omitted, and that enables a bundle of the membranes to be installed in series in the single module without using a pipe.
The separation membrane module of the present invention comprises: a tubular housing; and tubular separation membranes that are arranged in the housing in a longitudinal direction of the housing, a fluid to be processed flowing through a fluid-processing chamber inside the housing in a direction from one end toward another end of the chamber, the fluid that has permeated through the tubular separation membranes being retrieved via the tubular separation membranes, and an end portion of each tubular separation membrane being supported by a support member that is installed in the housing such that the support member extends to cross the housing, wherein the separation membrane module further comprises: a collection chamber that is defined in the support member and that is in communication with an inside of each of the tubular separation membranes; a retrieving member that retrieves the fluid in the collection chamber to outside of the housing; a backpressure chamber that is defined between the support member and an end portion of the housing; and a communication portion that communicates an inside of the backpressure chamber to the fluid-processing chamber.
In one aspect of the present invention, the communication portion is a gap between an outer circumferential surface of the support member and an inner circumferential surface of the housing.
In one aspect of the present invention, a plurality of tubular separation membrane units are disposed in the housing, each unit including the support member and the tubular separation membranes connected thereto; and the collection chamber of the tubular separation membrane unit nearest to the backpressure chamber is communicated to the collection chamber of the other tubular separation membrane unit via a connection member.
In one aspect of the present invention, the connection member is a nozzle that extends from the support member.
In one aspect of the present invention, the nozzle extends from each support member, and the nozzle of the tubular separation membrane unit and the nozzle of the tubular separation membrane unit adjacent thereto are coupled with each other.
In one aspect of the present invention, the separation membrane module further comprises a bearing member that bears the nozzle on the inner circumferential surface of the housing.
In one aspect of the present invention, the bearing member includes a rolling member that is in contact with the inner circumferential surface of the housing and that is capable of rolling.
In one aspect of the present invention, the rolling member is pressed against the inner circumferential surface of the housing by using an elastic member.
In one aspect of the present invention, a deformation-preventing member that prevents the support member from deforming is disposed in the collection chamber.
In one aspect of the present invention, the collection chamber is defined by two or more members.
In a separation membrane module according to the present invention, the backpressure chamber is defined between the support member and an end portion of the housing, the backpressure chamber is in communication with the fluid-processing chamber, and pressure in the backpressure chamber and pressure in the fluid-processing chamber are substantially the same. For this reason, a bending load that is applied to the support member due to the pressure of a fluid to be processed is eliminated or very small. According to the present invention, it is not necessary to dispose a seal member between the outer circumferential surface of the support member and the inner circumferential surface of the backpressure chamber. The separation membrane module according to the present invention has the collection chamber in which a component part in the fluid to be processed that has permeated through the tubular separation membranes is collected. Accordingly, bundles can be installed in series in the single module, and there is no need for a pipe that is needed for an existing module. Accordingly, costs can be reduced, installation can be facilitated, and maintenance can be facilitated.
A separation membrane module according to an embodiment of the present invention will be described with reference to
A separation membrane module 1 includes a housing 2 that has a cylindrical tube shape a cylinder axis direction of which coincides with the vertical direction, tubular separation membranes 3 that are arranged parallel to the axis of the housing 2, a support box 5 that is disposed in a lower portion in the housing 2 and that serves as a support member, a bottom cover 6A that is mounted on the lower end of the housing 2, a top cover 6B that is mounted on the upper end, a first baffle (a baffle plate) 7 and a second baffle (a baffle plate) 8 that are parallel to the support box 5 and that are disposed in the lower portion and an upper portion in the housing 2, and so on. The first baffle 7 is disposed above the support box 5.
According to the embodiment, flanges 2a, 2b, 6b, and 6c that extend outward are disposed on the lower end and the upper end of the housing 2 and the outer edges of the bottom cover 6A and the top cover 6B, and these are secured with bolts (not illustrated).
A gap through which gas can flow is formed between the outer circumferential surface of the support box 5 and the inner circumferential surface of the housing 2. The support box 5 is placed on support 2t that project from the inner circumferential surface of the housing 2. A backpressure chamber 16 is between the support box 5 and the bottom cover 6A. The backpressure chamber 16 is in communication with a chamber 11 above the support box 5 via the gap between the outer circumferential surface of the support box 5 and the inner circumferential surface of the housing 2.
According to the embodiment, end tubes 4 are coupled with the lower ends of the tubular separation membranes 3. End plugs 20 are coupled with the upper ends of the tubular separation membranes 3. In
In
An inlet 9 for a fluid to be processed is formed through the outer circumferential surface of a lower portion of the housing 2, and an outlet 10 for the fluid to be processed is formed through the outer circumferential surface of the upper portion. The inlet 9 is formed so as to face the chamber 11 between the support box 5 and the first baffle 7. The outlet 10 is formed so as to face a chamber 12 above the second baffle 8. A fluid-processing chamber 13 is defined between the baffles 7 and 8. The fluid-processing chamber is also referred to below as a main chamber.
Rods 14 extend upward from the support box 5 in a bottom portion, and the baffles 7 and 8 are supported by the rods 14. in
Seal members such as O-rings, V-packings, or C-rings may be interposed between the outer circumferential surfaces of the baffles 7 and 8 and the inner circumferential surface of the housing 2 such that gas does not preferentially flow along an outer circumferential portion of the housing 2.
The baffles 7 and 8 have circular through-holes 7a and 8a into which the tubular separation membranes 3 are inserted, and coupling bodies of the tubular separation membranes 3, the end tubes 4, and the end plugs 20 are inserted in the through-holes 7a and 8a. The inner diameters of the through-holes 7a and 8a are larger than the diameters (the outer diameters) of the tubular separation membranes 3, the end tubes 4, and the end plugs 20, and gaps are formed between the inner circumferential surfaces of the through-holes 7a and 8a and the end tubes 4 and between the inner circumferential surfaces of the through-holes 7a and 8a and the outer circumferential surfaces of the end plugs 20 over the entire circumference.
As illustrated in
In the collection chamber 5v, a deformation-preventing member that prevents the support box 5 from deforming may be disposed. When differences in pressure between the main chamber 13 and the collection chamber 5v, between the chamber 11 and the collection chamber 5v, and between the backpressure chamber 16 and the collection chamber 5v are large, the deformation-preventing member can prevent the support box 5 from deforming. When the differences in pressure are 10 times or more although this depends on the size and throughput of the module, and the deformation-preventing member is provided, the support box 5 can be effectively prevented from deforming.
The shape of the deformation-preventing member may be any shape provided that the support box 5 can be prevented from deforming but is preferably a shape that connects the top 5t and the bottom 5s to each other such that the top 5t and the bottom 5s can be prevented from deforming. The deformation-preventing member may be an elastic member such as a columnar member or a spring. The deformation-preventing member is preferably a columnar member because the columnar member is typically easy to obtain. A section of the columnar member may be a solid section or a hollow section. A hollow deformation-preventing member is lightweight and can effectively prevent compressive deformation. A solid deformation-preventing member is easy to obtain. A sectional shape of the columnar member may be circular or rectangular. A circular shape is preferable because of ease of obtaining.
The deformation-preventing member may be provided such that holes are formed on the lower surface of the top 5t and the upper surface of the bottom 5s, the upper end of the deformation-preventing member is engaged with the hole of the top 5t, and the lower end of the deformation-preventing member is engaged with the hole of the bottom 5s. An internal thread may be formed on an inner circumferential surface around a hole, an external thread may be formed on the outer circumferential surface of an end portion of a rod-like or tubular deformation-preventing member, and the deformation-preventing member may be screwed in the hole.
The support box 5 may include two or more members in order to readily install the deformation-preventing member. For example, the top 5t or the bottom 5s may be removable, or a portion near the top 5t and a portion near the bottom 5s may be equally divided. The two or more members may be integrally formed by welding, may be integrally formed by fastening from the outside with flanges provided, or may be screwed together with an internal thread formed on the side surface in a direction from the top 5t toward the bottom 5s. In the case where the two or more members are not welded, a gasket or an O-ring is preferably provided to ensure airtightness.
The projections 2t on which the support box 5 is disposed as described above may be omitted. For example, a support (not illustrated) may extend upward from the bottom cover 6A, the support box 5 may be supported by the support in order to increase the strength of the support box 5. The support is preferably between the top 5t and the bottom 5s so as not to completely cover large holes 5c, and the single support or multiple supports may be provided.
Insertion holes 5a in which the lower ends of the end tubes 4 that are coupled with the tubular separation membranes 3 are inserted are formed on the top 5t of the support box 5. Each insertion hole 5a has a columnar shape and extends from the upper surface of the support box 5 to an intermediate position in a thickness direction. The bottoms of the insertion holes 5a face the collection chamber 5v with small holes 5b and large holes 5c interposed therebetween (or there may be only the small holes 5b without the large holes 5c).
Gaskets (not illustrated) are interposed between the lower end surfaces of the end tubes 4 and the bottoms of the insertion holes 5a. Alternatively, O-rings (not illustrated) are interposed between the side surfaces of the end tubes 4 and side surfaces around the insertion holes 5a.
As illustrated in
The end plugs 20 are coupled with the upper ends of the tubular separation membranes 3. The end plugs 20 have a columnar shape or a shape obtained by cutting the columnar shape and seal the upper ends of the tubular separation membranes 3. Small-diameter portions that are inserted in the tubular separation membranes 3 are disposed at the lower ends of the end plugs 20. Spaces between the end plugs 20 and the tubular separation membranes 3 are sealed by gaskets or O-rings. The spaces between the end plugs 20 and the tubular separation membranes 3 may be sealed by using thermal shrink tubes although an illustration thereof is omitted.
According to the present invention, the end tubes 4 and the support box 5 may be disposed near the upper ends of the tubular separation membranes 3, and the end plugs 20 may be disposed near the lower ends of the tubular separation membranes 3.
In the separation membrane module 1, the fluid to be processed is introduced into the chamber 11 of the housing 2 via the inlet 9, passes through gaps between inner circumferential surfaces around through-holes 7a of the baffle 7 and the outer circumferential surfaces of the end tubes 4, flows into the main chamber 13, passes through the main chamber 13, subsequently passes through gaps between the through-holes 8a of the baffle 8 and the end plugs 20, and flows out to the chamber 12. While the fluid to be processed flows through the main chamber 13, a component part therein permeates through the tubular separation membranes 3 and is extracted from inside of the tubular separation membranes 3 via the collection chamber 5v and the nozzles 5n and 6n. The fluid that has not permeated flows out of the outlet 10 to outside the separation membrane module 1.
According to the embodiment, the backpressure chamber 16 and the chamber 11 are in communication with each other via the gap between the outer circumferential surface of the support box 5 and the inner circumferential surface of the housing 2, and there is no difference in pressure between the chambers, or the difference is very small. Accordingly, a bending load that is applied to the support box 5 is very small. In addition, there is no need for a member that seals the space between the outer circumferential surface of the support box 5 and the inner circumferential surface of the housing 2.
The direction of flow in the main chamber 13 and the direction of flow in the tubular separation membranes 3 may be the same or may be opposite, and the inlet 9 and the outlet 10 for the fluid to be processed may be replaced with each other.
As illustrated in
According to the embodiment, a large number of the tubular separation membranes 3 are installed so as to be parallel to each other, and a membrane area is large. Accordingly, membrane separation is efficiently performed.
According to the embodiment, the end tubes 4 and the end plugs 20 that are coupled with the upper and lower ends of the tubular separation membranes 3 are inserted in the through-holes 7a and 8a of the baffles 7 and 8. For this reason, even when the tubular separation membranes 3 vibrate or swing, and the end tubes 4 and the end plugs 20 come into contact with the inner circumferential surfaces of the through-holes 7a and 8a, zeolite membranes are not damaged, and operation can stably continue for a long period of time.
Another embodiment of the present invention will be described with reference to
As for a separation membrane module 1A according to the embodiment, tubular separation membrane units 30 and 31 are disposed in the housing 2. The tubular separation membrane unit 30 includes the support box 5, the end tubes 4, the tubular separation membranes 3, the end plugs 20, the baffles 7 and 8, and the rods 14 in
The tubular separation membrane unit 31 is almost the same as the tubular separation membrane unit 30 but differs in that a communication nozzle 5i that serves as a connection member extends upward from the center of the top 5t of the support box 5. The upper end of the communication nozzle 5i extends to a position higher than that of the baffle 8 of the tubular separation membrane unit 31, and the upper end thereof is coupled with the lower end of the nozzle 5n of the tubular separation membrane unit 30 by using, for example, a screw joint or a flange joint.
Gaps through which an upper chamber and a lower chamber are in communication with each other and gas can flow are formed between the outer circumferential surfaces of the support boxes 5 of the tubular separation membrane units 30 and 31 and the inner circumferential surface of the housing 2.
The other components of the separation membrane module 1A are the same as those of the separation membrane module 1, and like reference signs represent like components. Also, in the separation membrane module 1A, the fluid to be processed flows into the housing 2 via the inlet 9, a specific component permeates through the tubular separation membranes 3, and a non-permeated fluid flows out via the outlet 10. Gas that has permeated through the tubular separation membranes 3 of the lower tubular separation membrane unit 31 flows into the collection chamber 5v in the support box 5 of the tubular separation membrane unit 31 and is extracted via the nozzles 5n and 5i. Gas that has permeated through the tubular separation membranes 3 of the upper tubular separation membrane unit 30 flows into the collection chamber 5v of the support box 5 of the tubular separation membrane unit 30, flows into the collection chamber 5v in the support box 5 of the lower tubular separation membrane unit 31 via the nozzles 5n and 5i, and is extracted via the nozzles 5n and 6n.
As for the separation membrane module 1A, the length of the housing 2 can be increased, and the tubular separation membrane units can be disposed in the housing 2. In
In the case where the tubular separation membrane units are installed in the vertical direction, the upper tubular separation membrane unit is supported by the lower tubular separation membrane unit. In this case, however, a bearing member that prevents the tubular separation membrane units from inclining or swinging from side to side may be provided.
In
In
In the case where the separation membrane module 1 is installed sideways such that the direction in which the bottom cover 6A and the top cover 6B are connected to each other is substantially horizontal, a dispersion plate or the support box 5 of a bundle (a combination of, for example, the separation membranes, the end tubes, and the support box) that is inserted in the housing 2 comes into contact with the inner wall of the housing 2 in some cases. The heavier the bundle, the more the frictional force of the contact. This makes it difficult to push the bundle therein in some cases.
In view of this, as illustrated in
According to the present invention, a tubular body 50 that surrounds the tubular separation membrane unit 31 may be disposed so as to be along the inner circumferential surface of the housing 2, a baffle 51 may be supported on the upper end of the tubular body 50, the nozzle 5i may be inserted in a center hole 51a of the baffle 51, and the upper portion of the nozzle 5i may be supported by the baffle 51 as in a separation membrane module 1B in
The other components in
According to the embodiment described above, the chambers 11 and 16 are in communication with each other via the gap between the outer circumferential surface of the support member and the inner circumferential surface of the housing. A communication portion such as a pipe via which the chambers 11 and 16 are in communication with each other may be disposed in the housing 2. Alternatively, the top 5t and the bottom 5s may be coupled with each other by using a single pipe or pipes.
Preferred materials of the end tubes 4, the end plugs 20, and the tubular separation membranes 3 that are included in a separation membrane module according to the present invention will now be described.
Examples of the materials of the end tubes 4 and the end plugs 20 include a material through which the fluid does not permeate such as metal or ceramics, but are not limited thereto. The materials of the baffles 7, 8, and 51, and a joint tube 17 are typically a metal material such as stainless steel but are not particularly limited provided that the material has resistance against a supply or permeation component and heat resistance in separation conditions and can be replaced with another material such as a resin material depending on use.
Each tubular separation membrane 3 preferably includes a tubular porous support and a zeolite membrane that serves as an inorganic separation membrane that is formed on the outer circumferential surface of the porous support. As for the material of the tubular porous support, an inorganic porous support composed of a sintered metal body or a sintered ceramic body containing silica, α-alumina, γ-alumina, mullite, zirconia, titania, yttria, silicon nitride, or silicon carbide is taken as an example. Among these, an inorganic porous support containing at least one selected from alumina, silica, and mullite. The average diameter of narrow holes on the surface of the porous support is not particularly limited but is preferably controlled and is in the range of typically 0.02 μm or more, preferably 0.05 μm or more, more preferably 0.1 μm or more, and typically 20 μm or less, preferably 10 μm or less, more preferably 5 μm or less.
Zeolite is crystalized on the surface of the porous support and the zeolite membrane is formed.
The main zeolite of which the zeolite membrane is composed includes zeolite that typically has an oxygen 6-to-10-membered ring structure and preferably includes zeolite that has an oxygen 6-to-8-membered ring structure.
The value of n of the zeolite that has an oxygen re-membered rings described herein represents the maximum number of oxygen atoms in the narrow holes composed of T elements and oxygen for forming a zeolite framework. For example, in the case where there are narrow holes of oxygen 12-membered rings and oxygen 8-membered rings as in NOR zeolite, this is regarded as zeolite of oxygen 12-membered rings.
Examples of the zeolite that has an oxygen 6-to-10-membered ring structure include AEI, AEL, AFG, ANA, BRE, CAS, CDO, CHA, DAC, DDR, DOH, EAB, EPI, ESV, EUO, FAR, FRA, FER, GIS, GIU, GOO, HEU, IMF, ITE, ITH, KFI, LEV, LIO, LOS, LTN, MAR, MEP, PIER, MEL, MFI, MFS, MON, MSO, MTF, MTN, MTT, MWW, NAT, NES, NON, PAU, PHI, RHO, RRO, RTE, RTH, RUT, SGT, SOD, STF, STI, SIT, TER, TOL, TON, TSC, TUN, UFI, VNI, VSV, WEI, and YUG.
The zeolite membrane may be a membrane composed of zeolite alone, a membrane that is formed by dispersing powder of the zeolite in a binder such as a polymer, or a zeolite membrane composite obtained by bonding zeolite to various kinds of supports in a membrane form. A part of the zeolite membrane may contain an amorphous component.
The thickness of the zeolite membrane is not particularly limited but is typically 0.1 μm or more, preferably 0.6 μm or more, more preferably 1.0 μm or more, and is typically 100 μm or less, preferably 60 μm or less, more preferably 20 μm or less.
According to the present invention, however, a tubular separation membrane that includes a separation membrane other than the zeolite membrane may be used.
The outer diameter of each tubular separation membrane 3 is preferably 3 mm or more, more preferably 6 mm or more, further preferably 10 mm or more, and is preferably 20 mm or less, more preferably 18 mm or less, further preferably 16 mm or less. In some cases where the outer diameter is too small, the tubular separation membrane has insufficient strength and is easy to break. If the outer diameter is too large, then the membrane area per module decreases.
The length of a portion of each tubular separation membrane 3 that is covered by the zeolite membrane is preferably 20 cm or more and is preferably 200 cm or less.
In a separation membrane module according to the present invention, the tubular separation membranes may be single-tube membranes or multi-tube membranes, 1 to 3000 tubular separation membranes, particularly, 50 to 2000 tubular separation membranes are typically provided, and the tubular separation membranes are preferably arranged such that the minimum distance therebetween is 1 mm to 10 mm. The size of the housing and the number of the tubular separation membranes are appropriately changed depending on the amount of the fluid to be processed. The tubular separation membranes may not be coupled by using the joint tube 17. In the description with reference to the drawings, the separation membrane module 1 is vertically installed but may be used with the separation membrane module 1 installed sideways or diagonally.
The fluid to be processed that is a target for separation or concentration in a separation membrane module according to the present invention is not particularly limited provided that the fluid is a gas or liquid mixture that contains components that can be separated or concentrated by using the separation membranes and may be any mixture. The separation membrane module, however, is preferably used for a gas mixture.
A separation or concentration method called a pervaporation method, or a vapor permeation method can be used for the separation or the concentration. The pervaporation method is a separation or concentration method in which a liquid mixture is introduced into each separation membrane as it is and can facilitate a process including the separation or the concentration.
In the case where the mixture to be separated or concentrated according to the present invention is a gas mixture containing components, examples of the gas mixture include a mixture that contains at least one component selected from the group consisting of carbon dioxide, oxygen, nitrogen, hydrogen, methane, ethane, ethylene, propane, propylene, normal butane, isobutane, 1-butene, 2-butene, isobutene, aromatic compounds such as toluene, sulfur hexafluoride, helium, carbon monoxide, nitrogen monoxide, and water. A gas component that has high permeance in mixtures containing these gas components permeates through each separation membrane and is separated. A gas component that has low permeance is concentrated toward a supply gas.
Separation membrane modules according to the present invention can be coupled with each other and used depending on the amount of the fluid, the target degree of the separation or the target degree of the concentration. In the case where the amount of the fluid is large, or in the case where the target degree of the separation or the target degree of the concentration is high, and the process cannot be performed by a single module, a pipe is preferably connected and used such that the fluid that exits the outlet enters the entrance of another module. The target degree of the separation or the target degree of the concentration can be achieved by additional coupling of module depending on the degree of the separation or the degree of the concentration.
Separation membrane modules according to the present invention may be installed in parallel, the fluid may be split, and the gas may be supplied. In this case, modules can be installed in series with the respective modules that are installed in parallel. In the case where the modules are installed in parallel and in series, the amount of the supply gas decreases in the series direction, and linear velocity decreases. Accordingly, the number of the modules that are installed in parallel is preferably decreased to ensure appropriate linear velocity.
In the case where the modules are arranged in series, the component that has permeated through the modules may be discharged from the respective modules or may be discharged after the component is collected with the modules coupled.
The present invention is described in detail by using a specific aspect. However, it is clear for a person skilled in the art that various modifications can be made without departing from the intention and scope of the present invention.
This application Claims the benefit of Japanese Patent Application No. 2018-121043, filed Jun. 26, 2018, hereby incorporated by reference herein in its entirety.
1, 1A, 1B separation membrane module
2 housing
2
a, 2b flange
2
t support
3 tubular separation membrane
4 end tube
4
a tube hole
5, 5R support box (support member)
5J upper half body
5L lower half body
5
a insertion hole
5
b small hole
5
c large hole
5
i, 5n nozzle
5
r deformation-preventing member
5
s bottom
5
t top
5
u side surface
5
v collection chamber
6A bottom cover
6B top cover
6
b, 6c flange
6
n nozzle
7, 8 baffle
7
a, 8a through-hole
9 inlet
10 outlet
11, 12 chamber
13 main chamber (fluid-processing chamber)
14 rod
14A, 14B sheath tube
16 backpressure chamber
20 end plug
30, 31 tubular separation membrane unit
40 bearing member
41 rod
42 ball holder
43 ball
45 base plate
17 coupling rod
50 tubular body
51 baffle
51
a center hole
51
b opening
| Number | Date | Country | Kind |
|---|---|---|---|
| 2018-121043 | Jun 2018 | JP | national |
| Number | Date | Country | |
|---|---|---|---|
| Parent | PCT/JP2019/025129 | Jun 2019 | US |
| Child | 17128585 | US |
