The present disclosure relates to a separator plate assembly for a fuel cell, and more particularly, to a separator plate assembly for a fuel cell capable of forming a variable flow path pattern to form gas flow paths of various patterns on a base plate by arranging flow path forming blocks on the base plate having coupling protrusions arranged in a grid pattern.
In general, a solid oxide fuel cell (SOFC) operates at the highest temperature (700 to 900° C.) among fuel cells, and since the components are all solid, solid oxide fuel cells have a simple structure compared to other fuel cells, do not have problems with electrolyte loss, replenishment and corrosion, eliminate the need for precious metal catalysts and are easy to supply fuels through direct internal reforming.
Additionally, it is possible to achieve combined heat and power production using waste heat due to high temperature gas emission. Due to this advantage, many studies are now done on solid oxide fuel cells.
A solid oxide fuel cell is an electrochemical energy conversion device, and includes an oxygen ion conducting electrolyte, and an air electrode and a fuel electrode on two surfaces.
Oxygen ions produced by reduction reaction of oxygen at the air electrode move to the fuel electrode through the electrolyte and react with hydrogen supplied to the fuel electrode to produce water, and in this instance, electrons are produced at the fuel electrode and consumed at the air electrode, so when the two electrodes are connected to each other, electricity flows.
However, since a unit cell including the air electrode, the electrolyte and the fuel electrode produces a very small amount of power, a plurality of unit cells may be stacked to form a fuel cell so as to produce considerable power output, and further, may be used in a wide range of power generation system applications.
For the stacking, it is necessary to electrically connect the air electrode of a unit cell to the fuel electrode of another unit cell, and to this end, a separator plate (interconnect) is used.
The present disclosure is directed to providing a separator plate assembly for a fuel cell for improving precision and productivity in flow path shape processing by forming a gas flow path by arranging flow path forming blocks on a base plate rather than forming the gas flow path in the base plate by an etching process.
The present disclosure is further directed to providing a separator plate assembly for a fuel cell capable of variably forming various gas flow paths on a base plate by arranging coupling protrusions on the base plate in a grid pattern and arranging flow path forming blocks of various shapes and various numbers in various patterns.
The objective of the present disclosure is not limited thereto and these and other objectives will be clearly understood by those skilled in the art from the following description.
To achieve the above-described technical objective, an embodiment of the present disclosure provides a separator plate assembly for a solid oxide fuel cell capable of forming a variable flow path, including a base plate having a plurality of coupling protrusions protruding in a direction toward one side and arranged spaced apart from each other; at least one flow path forming block having coupling holes which are coupled to the coupling protrusions, the flow path forming block arranged on the base plate by the coupling of the coupling protrusions and the coupling holes; and a gas flow path formed in varying patterns depending on a shape or arrangement pattern of the flow path forming block, and configured to allow a reactive gas supplied from outside to flow therein.
Additionally, there is provided the separator plate assembly for the fuel cell capable of forming the variable flow path, wherein the plurality of coupling protrusions is arranged in a grid pattern.
Additionally, there is provided the separator plate assembly for the fuel cell capable of forming the variable flow path, wherein the flow path forming block is formed in a quadrilateral prism shape, and has at least two coupling holes in a lengthwise direction.
Additionally, there is provided the separator plate assembly for the fuel cell capable of forming the variable flow path, wherein the flow path forming block is circular in horizontal cross section, and has at least one coupling hole inside.
Additionally, there is provided the separator plate assembly for the fuel cell capable of forming the variable flow path, wherein the flow path forming block is hexagonal in horizontal cross section, and has at least one coupling hole inside.
Additionally, there is provided the separator plate assembly for the fuel cell capable of forming the variable flow path, wherein the base plate is made of a material including a Fe—Cr alloy.
According to an embodiment of the present disclosure, the gas flow path may be formed by arranging the flow path forming blocks on the base plate rather than forming the gas flow path in the base plate by an etching process, thereby improving precision and productivity in flow path shape processing.
Additionally, it may be possible to variably form various gas flow paths on the base plate by arranging the coupling protrusions on the base plate in a grid pattern and arranging the flow path forming blocks of various shapes and numbers in various patterns.
Hereinafter, some embodiments of the present disclosure will be described in detail through the exemplary drawings. In affixing the reference signs to the elements of each drawing, it should be noted that the identical elements have the identical signs as possible although they are shown in different drawings. Additionally, in describing the present disclosure, when it is determined that a certain detailed description of relevant known features or functions may obscure the subject matter of the present disclosure, the detailed description is omitted.
Additionally, in describing the elements of the present disclosure, the terms “first”, “second”, A, B, (a), (b) or the like may be used. These terms are used to distinguish one element from another, and the nature, sequence or order of the corresponding elements are not limited by the terms. When an element is referred to as being “connected to”, “coupled to” or “joined to” another element, the element may be directly connected or joined to the other element, but it should be understood that intervening elements may be “connected”, “coupled” or “joined” between each element.
As shown in the drawings, the separator plate assembly for the fuel cell capable of forming a variable flow path according to an embodiment of the present disclosure is a separator plate assembly for a solid oxide fuel cell and includes the base plate 100 having a plurality of coupling protrusions 110 protruding in a direction toward one side and arranged spaced apart from each other; at least one flow path forming block 200 having coupling holes 210 which are coupled to the coupling protrusions 110, the flow path forming block 200 arranged on the base plate 100 by the coupling of the coupling protrusions 110 and the coupling holes 210; and the gas flow path 300 formed in varying patterns depending on the shape or arrangement pattern of the flow path forming block 200 and configured to allow a reactive gas supplied from outside to flow therein.
Hereinafter, each component of the present disclosure will be described in detail with reference to
A conventional separator plate for a solid oxide fuel cell has a flow path for allowing a flow of reactive gas, for example, oxygen or hydrogen using an etching process by corrosive reaction between a chemical and a material, and flow path shape processing by etching has uneven processed profiles, low processing precision, long processing time and consequential low productivity.
The present disclosure is characterized in that the separator plate assembly for the solid oxide fuel cell includes the base plate 100 and the flow path forming blocks 200 arranged on the base plate 100, wherein the gas flow path 300 in which reactive gas flows is formed by the flow path forming blocks 200 by arranging the flow path forming blocks 200 on the base plate 100.
Further, the present disclosure is characterized by arranging the flow path forming blocks 200 on the base plate 100 in various patterns, to variably form the pattern of the gas flow path 300 depending on the shape or arrangement pattern of the flow path forming blocks 200.
To begin with, the base plate 100 has the plurality of coupling protrusions 110 protruding in a direction toward one side and arranged spaced apart from each other.
The base plate 100 may be, for example, a plate shaped member having a predetermined area and thickness, and the coupling protrusions 110 protruding in a direction toward one side of the base plate 100 are formed on the base plate 100.
As shown in
Specifically, as shown in
Meanwhile, the plurality of coupling protrusions 110 may be arranged on the base plate 100, spaced apart from each other, and in this instance, the plurality of coupling protrusions 110 may be arranged in a grid pattern.
In an embodiment, as shown in
In this instance, the distance between the plurality of coupling protrusions 110 forming the array (a) and the distance between the plurality of arrays (a) may be equal or different.
Meanwhile, in another embodiment, as shown in
Meanwhile, as described above, the coupling protrusion 110 may be formed and raised on the base plate 100 by stamping that is one of plate manufacturing methods, and accordingly a recess 130 recessed in a direction toward one side from the other side may be formed on the base plate 100 at a location corresponding to the coupling protrusion 110.
In this instance, the recess 130 may be formed in a shape (horizontal cross section, height, etc.) corresponding to the coupling protrusion 110.
Subsequently, the base plate 100 according to an embodiment of the present disclosure is made of a material including Fe—Cr alloy.
The conventional separator plate for the solid oxide fuel cell essentially includes expensive rare earth elements (La, Zr, etc.) to improve oxidation resistance and electrical conductivity in a high temperature oxidative environment, but the separator plate assembly according to the present disclosure does not include expensive rare earth elements and is based on Fe—Cr alloy.
Here, the base plate 100 may be based on Fe—Cr alloy, and at least one of Mn, Nb or Mo may be included in the Fe—Cr alloy as an additive.
Meanwhile, as shown in
Here, the protective coating layer 150 may be a Spinel-based coating layer including at least one of La, Mn or Sr, or a Perovskite-based coating layer including at least one of La, Mn or Sr.
The protective coating layer 150 formed on the base plate 100 may prevent the performance degradation of the fuel cell caused by Cr volatilization of the base plate 100, and as shown in
Additionally, in the case of the present disclosure, the flow path forming block 200 as described below is arranged on the base plate 100 by the coupling of the coupling protrusion 110 and the coupling hole 210, and in this instance, a gap may be formed on the interface between the base plate 100 and the flow path forming block 200 and interrupt a normal flow of gas on the gas flow path 300.
Accordingly, the protective coating layer 150 formed on the base plate 100 may improve the interfacial contact between the base plate 100 and the flow path forming block 200, thereby preventing the above-described problem.
Subsequently, the flow path forming block 200 has the coupling hole 210 which is coupled to the coupling protrusion 110, and is arranged on the base plate 100 by the coupling of the coupling protrusion 110 and the coupling hole 210.
The flow path forming block 200 is arranged on the base plate 100 to form the gas flow path 300 on the base plate 100, and the flow path forming block 200 according to an embodiment of the present disclosure is arranged on the base plate 100 by the coupling of the coupling hole 210 and the coupling protrusion 110 of the base plate 100.
The coupling hole 210 may be formed in a shape of a hole passing between one surface and the other surface of the flow path forming block 200 or a groove recessed in a direction toward one side from the other side, and may be formed in a shape corresponding to the shape of the coupling protrusion 110 to allow the coupling protrusion 110 of the base plate 100 to insert and couple.
For example, in case where the coupling protrusion 110a, 110b having the horizontal cross section of a circular or polygonal shape is formed on the base plate 100 and the hole-shaped coupling hole 210 is formed in the flow path forming block 200, the horizontal cross section of the coupling hole 210 may have a shape corresponding to the horizontal cross section of the coupling protrusion 110a, and the length of the coupling hole 210 may be equal to the height of the coupling protrusion 110a.
In this instance, in the case of the hole-shaped coupling hole 210, the height of the flow path forming block 200 is equal to the height of the coupling protrusion 110.
Additionally, in case where the coupling protrusion 110a, 110b having the horizontal cross section of a circular or polygonal shape is formed on the base plate 100 and the groove-shaped coupling hole 210 is formed in the flow path forming block 200, the horizontal cross section of the coupling hole 210 may have a shape corresponding to the horizontal cross section of the coupling protrusion 110a, and the recess depth of the coupling hole 210 may be equal to the height of the coupling protrusion 110a.
Meanwhile, the flow path forming block 200 according to the present disclosure may be arranged on the base plate 100 by press-fitting the coupling protrusion 110 of the base plate 100 into the coupling hole 210 of the flow path forming block 200.
Accordingly, the size of the coupling hole 210 may be smaller than the size of the coupling protrusion 110 by a predetermined amount.
Here, the separator plate assembly for the fuel cell according to the present disclosure may further include the press-fit member 170 which is coupled to the other side of the coupling protrusion 110 and press-fitted into the other side of the flow path forming block 200 when the coupling protrusion 110 is coupled to the coupling hole 210, as shown in
The press-fit member 170 may be formed in a predetermined ring shape and put on the coupling protrusion 110, and in this instance, when the coupling protrusion 110a is formed in a cylindrical shape as described above, the press-fit member 170 may be formed in a circular ring shape, and when the coupling protrusion 110b is formed in a polygonal shape, the press-fit member 170 may be formed in a polygonal ring shape, and in this instance, the cross section of the press-fit member 170 may have a quadrilateral shape.
The press-fit member 170 is coupled to the other side of the coupling protrusion 110, and when the coupling protrusion 110 is press-fit into the coupling hole 210, the press-fit member 170 is press-fit into the other side of the flow path forming block 200, thereby improving the coupling strength of the base plate 100 and the flow path forming block 200.
Meanwhile, the number of flow path forming blocks 200 according to the present disclosure may be one or more to form various flow path patterns on the base plate 100, and as shown in
The flow path forming block 200 according to the present disclosure is formed in various shapes and arranged on the base plate 100, to variably form the gas flow path 300 of various patterns on the base plate 100.
To begin with, as shown in
The flow path forming block 200a according to an embodiment of the present disclosure may be formed in a quadrilateral prism shape having a predetermined length, height and width, and in this instance, the flow path forming block 200a may have at least two coupling holes 210a arranged at a predetermined interval along the lengthwise direction of the flow path forming block 200a.
Here, in addition to the quadrilateral prism shape having the rectangular horizontal cross section, the flow path forming block 200a according to an embodiment of the present disclosure may be formed in a quadrilateral prism shape having a partially bent horizontal cross section such as “┐” or “└”.
In this instance, the coupling hole 210 of the flow path forming block 200a may have the horizontal cross section of a circular or polygonal corresponding to the shape of the coupling protrusion 110 as described above.
Subsequently, as shown in
The flow path forming block 200b according to another embodiment of the present disclosure may be formed in a cylindrical shape having a predetermined diameter and height, wherein the flow path forming block 200b may have at least one coupling hole 210b inside, and in this instance, the horizontal cross section of the coupling hole 210 may have a circular or polygonal shape corresponding to the shape of the coupling protrusion 110 as described above.
Subsequently, as shown in
Here, the horizontal cross section of the flow path forming block 200c may have, especially, a regular hexagon shape.
The flow path forming block 200c according to still another embodiment of the present disclosure may be formed in a hexagonal prism shape having a predetermined height, and in this instance, the flow path forming block 200c may have at least one coupling hole 210c inside.
In this instance, the coupling hole 210 may be formed with the horizontal cross section of a circular or polygonal shape corresponding to the shape of the coupling protrusion 110 as described above, and in particular, the coupling hole 210c of the flow path forming block 200c according to still another embodiment of the present disclosure is characterized by being formed with the horizontal cross section of a polygonal shape so as to be coupled to the coupling protrusion 110b having the horizontal cross section of a polygonal shape.
When the coupling protrusion 110a is circular in horizontal cross section, the flow path forming block 200a according to an embodiment of the present disclosure as described above has at least two coupling holes 210a inside, and thus it is possible to prevent the pattern of the gas flow path 300 from arbitrarily changing by rotation of the flow path forming block 200a on the base plate 100.
Additionally, since the flow path forming block 200b according to another embodiment of the present disclosure is circular in horizontal cross section, the pattern of the gas flow path 300 does not change by the rotation of the flow path forming block 200b.
However, since the flow path forming block 200c according to still another embodiment of the present disclosure is hexagonal in horizontal cross section, when the flow path forming block 200c rotates, the pattern of the gas flow path 300 changes, and in order to prevent the rotation of the flow path forming block 200c, the coupling hole 210c is formed with the horizontal cross section of a polygonal shape to arrange the flow path forming block 200c on the base plate 100 by the coupling protrusion 110b having the horizontal cross section of a polygonal shape.
Meanwhile, the flow path forming block 200 according to the present disclosure may have the horizontal cross section of a pentagonal shape (including a regular pentagon shape), and one coupling hole 210 inside.
Subsequently, for example, the flow path forming block 200 according to the present disclosure may have a larger area of one surface contacting the negative electrode layer 11 or the positive electrode layer 15 than the area of the other surface to increase the contact area of one surface as shown in
More specifically, the flow path forming block 200 may be formed with a gradient such that it is inclined outward as it goes from the other surface to one surface, and the area of the horizontal cross section increases as it goes from the other surface to one surface.
As shown in
Accordingly, it may be possible to prevent the performance degradation of the fuel cell caused by the increased interfacial contact resistance by increasing the area of one surface of the flow path forming block 200 contacting the negative electrode layer 11 or the positive electrode layer 15 to reduce the interfacial contact resistance between one surface of the flow path forming block 200 and the negative electrode layer 11 or the interfacial contact resistance between one surface of the flow path forming block 200 and the positive electrode layer 15.
Meanwhile, in the same way as the base plate 100, the flow path forming block 200 according to an embodiment of the present disclosure may be made of a material including Fe—Cr alloy.
Additionally, in the same way as the base plate 100, the flow path forming block 200 may have a Spinel-based coating layer including at least one of La, Mn or Sr, or a Perovskite-based coating layer including at least one of La, Mn or Sr on the surface, thereby achieving the technical effect as described above.
Subsequently, the gas flow path 300 is formed in varying patterns depending on the shape or arrangement pattern of the flow path forming blocks 200, to allow reactive gas supplied from the outside to flow therein.
As shown in
As described above, in the case of the conventional separator plate for the solid oxide fuel cell, the flow path is formed by etching, but in the case of the separator plate assembly for the fuel cell according to the present disclosure, the gas flow path 300 is formed by the flow path forming blocks 200 arranged on the base plate 100.
In this instance, the gas flow path 300 formed on the base plate 100 may be variably formed in various patterns depending on the shape or arrangement pattern of the flow path forming blocks 200 arranged on the base plate 100.
As described above, the flow path forming block 200 according to the present disclosure may be formed in various shapes including a polygonal or circular shape in horizontal cross section, and various numbers and arrangements of coupling holes 210 may be formed in the flow path forming block 200.
In this instance, since the coupling protrusions 110 are arranged on the base plate 100 in a grid pattern, various numbers of flow path forming blocks 200 formed in various shapes may be arranged on the base plate 100 in various patterns.
Accordingly, it may be possible to variably form the gas flow path 300 of various patterns on the base plate 100, and
As described above, the present disclosure is characterized in that various gas flow paths 300 may be variably formed on the base plate 100 by variously changing the arrangement of the coupling protrusions 110 on the base plate 100 and the shape and the arrangement pattern of the flow path forming blocks 200.
Meanwhile,
As shown in
As described above, according to an embodiment of the present disclosure, the gas flow path may be formed by arranging the flow path forming blocks on the base plate rather than forming the gas flow path in the base plate by an etching process, thereby improving precision and productivity in flow path shape processing.
Additionally, it may be possible to variably form various gas flow paths on the base plate by arranging the coupling protrusions on the base plate in a grid pattern and arranging the flow path forming blocks of various shapes and numbers in various patterns.
While the exemplary embodiments of the present disclosure have been hereinabove illustrated and described, the present disclosure is not limited to the above-described particular exemplary embodiments, and it is obvious to those having ordinary skill in the technical field pertaining to the present disclosure that a variety of modifications and changes may be made thereto without departing from the claimed subject matter of the present disclosure in the appended claims, and such modifications and changes fall in the scope of the appended claims.
Number | Date | Country | Kind |
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10-2021-0051210 | Apr 2021 | KR | national |
This application claims benefit under 35 U.S.C. 119, 120, 121, or 365(c), and is a National Stage entry from International Application No. PCT/KR2021/017487, filed Nov. 25, 2021 which claims priority to the benefit of Korean Patent Application No. 10-2021-0051210 filed in the Korean Intellectual Property Office on Apr. 20, 2021, the entire contents of which are incorporated herein by reference.
Filing Document | Filing Date | Country | Kind |
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PCT/KR2021/017487 | 11/25/2021 | WO |