Sequential oxidative and reductive bleaching in a multicomponent single liquor system

Abstract

The present invention is drawn to new processes for sequential oxidative and reductive bleaching of fibers (e.g. natural, synthetic, or blends thereof) e.g. in a single bath, which provide superior bleaching with less physical damage. Said processes comprising the steps of: (1) bleaching fibers with hydrogen peroxide; (2) adding either, (a) a material which combines with hydrogen peroxide to form a reductive bleaching agent, or (b) an inactivating material to inactivate unspent hydrogen perioxide with subsequent addition of a reductive bleaching agent, and; (3) reductively bleaching the already oxidatively bleached fibers. Also encompassed by the present invention are novel bleached fibers produced by the aforementioned processes, having highly advantageous and desirable properties e.g. a high degree of whiteness with low degree of damage.

Description

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to processes for oxidative (using hydrogen peroxide) and reductive bleaching of fibers, and fibers bleached by the aforementioned processes.

2. Description of the Prior Art

German Offenlegungsschrift 3,433,926 (3/27/86) to Streit et al, discloses a single bath reductive and oxidative bleaching process, in which the reductive bleaching with thiourea dioxide precedes an oxidative hydrogen peroxide bleaching, whereas in the processes of the present invention the reductive bleaching is subsequent to the oxidative bleaching. Japanese Pat. No. 51-64082 (6/3/76) is drawn to a process in which hydrogen peroxide and thiourea are mixed at the start of the bleaching processes (i.e., bleaching with a single mixture which contains both hydrogen peroxide and thiourea), while by contrast the instant invention utilizes separate steps of oxidative bleaching followed by reductive bleaching. It has unexpectedly and surprisingly been discovered that the process of the present invention provides greatly improved results (including, a higher Whiteness Index, lower Yellowness Index, and lower degree of damage) as compared to the results achieved by either of the aforementioned prior art processes.

SUMMARY

It is a first object of the present invention to provide bleaching greatly superior to that of prior art processes, said bleaching providing fibers of a surprising and unexpectingly high degree of whiteness, low degree of yellowness and low degree of fiber damage.

It is a second object of the present invention to provide processes which may provide oxidative and reductive bleaching in a single bath, and thereby provide the advantages of: (a) avoiding the two or three step treatment processes normally required by conventional processes thereby simplifying the process; (b) reducing the amount of time required to provide effective bleaching, and; (c) reducing the amount of equipment required to perform the bleaching.

Other objects and advantages of this invention will become readily apparent from the ensuing description.

The aforementioned objects and advantages are achieved by:

A first process of the present invention which comprises,

contacting fibers with hydrogen peroxide under conditions which provide oxidative bleaching of the fibers to produce bleached fibers in contact with unspent hydrogen peroxide; adding to the bleached fibers in contact with unspent hydrogen peroxide (from the previous step), a material which combines with hydrogen peroxide to form a reductive bleaching agent (e.g. thiourea, substituted thiourea (e.g. 1,3-dimethyl-2-thiourea, 1,3-diphenyl-2-thiourea, 1,1,3,3-tetramethyl-2-thiourea), compounds containing thiol (for example, 1-dodecanethiol, 1-octadecanethiol, thioglycolic acid, thiophenol)), in an amount sufficient to produce a reductive bleaching media; and maintaining the oxidatively bleached fibers in said reductive bleaching media under conditions providing reductive bleaching of the bleached fibers, and;

A second process of the present invention which comprises,

contacting fibers with hydrogen peroxide under conditions which provide oxidative bleaching of the fibers to produce bleached fibers in contact with unspent hydrogen peroxide; adding to the bleached fibers in contact with unspent hydrogen peroxide (from the previous step), an inactivating material in an amount at least sufficient to inactivate all of the unspent hydrogen peroxide to form an inactivated media; and subsequent to the inactivation of all the unspent hydrogen peroxide, reductively bleaching the bleached fibers by addition of a reductive bleaching agent to the inactivated media.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a line graph of Whiteness Index versus thiourea concentration, for a process of the present invention with in situ formation of a reductive bleaching substance using conditions referred to in example 1 and table I.

FIG. 2 is a line graph of Whiteness Index versus bleaching time after thiourea addition, for a process of the present invention (using conditions as described in example 2 and table II), showing the effect of varying bleaching time.

FIG. 3 is a line graph of Whiteness Index versus hydrogen peroxide bleaching time for conditions as referred to in example 3 and table III.

FIG. 4 is a line graph of Whiteness Index versus bath temperature: showing a comparison between conventional alkaline hydrogen peroxide bleaching and bleaching of the present invention; as referred to in example 4 and table IV.

FIG. 5 is a line graph of Whiteness Index versus Bleachit D concentration for a process of the present invention as referred to in example 6 and table VI.

FIG. 6 is a line graph of Whiteness Index versus thiourea dioxide concentration for a process of the present invention as referred to in example 6 and table VI.

DETAILED DESCRIPTION OF THE INVENTION

Both of the bleaching processes of the present invention may be utilized to great advantage with any of a wide variety of fiber compositions, including animal hair fibers, plant fibers, synthetic fibers, and blends of two or more of the aforementioned, (notably, fibers consisting essentially of wool, fibers consisting of cotton, and blends of wool with either materials). Said fibers may be in any suitable form which permits bleaching, including: loose fibers, yarns (twisted, woven, wrapped, etc.), fabric (e.g. woven, matted, felted), etc. It is also a great advantage of the present invention that the processes may be carried out over a wide range of temperatures e.g. 20.degree. C. to 100.degree. C. Both of the bleaching processes of the present invention permit, either: (1) all steps to be carried out batch-wise in a single bath, or; (2) all steps to be carried out continuously using a continuous pad system ("padding" is a process well known in the art, and is for example defined on page 109 of Textile Terms and Definitions, Fifth Edition, published by Textile Institute, Aug. 1963). Either of the processes of the present invention may produce novel and highly advantageous fibers having unexpectedly superior properties, such as a degree of whiteness as measured by ASTM E-313 of at least about 43 with a degree of damage indicated by an alkali solubility of 30% or less as measured by IWTO-4-60, preferably said degree of whiteness being at least 44 with a said solubility of 25% or less, and more preferably a said degree of whiteness of at least about 46.

When the aforementioned first process of the present invention is carried out employing thiourea as the material which combines with hydrogen peroxide to form a reductive bleaching agent, it is preferred to: add the thiourea in a stoichiometric ratio to the unspent hydrogen peroxide of, at least about 1 to 4 i.e. at least one mole of thiourea for each 4 moles of unspent hydrogen peroxide (more preferably in a said ratio of, at least about 2 to 4 i.e. at least about 2 moles of thiourea for each 4 moles of unspent hydrogen peroxide, and most preferably in a said ratio of about 2 to 4 i.e. about 2 moles of thiourea for each 4 moles of unspent hydrogen peroxide), and; adjust the reductive bleaching media to a pH of about 6 to about 9, more preferably about 7 to 8. Also, in regard to said first process, it is preferred to carry out the bleaching of fibers in the reductive bleaching media for a time period of from about 25 to about 35 minutes.

In carrying out the aforementioned second process of the present invention, it is preferred to: utilize as the inactivating material, a material selected from the group consisting of:

(1) catalysts which catalyze decomposition of hydrogen peroxide, such as transition metals preferably used at a pH of from about 6 to about 10 (e.g. if necessary a suitable chemical is added to the bleached fibers in contact with unspent hydrogen peroxide, in order to bring the pH into the range of from about 6 to about 10). Optionally, after the transition metal(s) have completed deactivation of the unspent hydrogen peroxide, a chelating agent may be added in order to chelate excess transition metal ions (if any) prior to the reductive bleaching;

(2) enzymes which decompose hydrogen peroxide, preferably the pH of the bleached fibers in contact with unspent hydrogen peroxide is adjusted to be from about 3 to about 10 prior to adding the enzyme. For example, suitable enzymes include catalase (which preferably is used at a pH of from about 5 to about 8.5) and enzymes referred to in chapter 8 of Hydrogen Peroxide, W. C. Schumb et al editors, published by Reinhold Pub. Corp., New York, 1955.

(3) materials which react with hydrogen peroxide to render the hydrogen peroxide inactive, such as cerium (which may be provided in chemical combination with other materials, but which upon addition to the bleached fiber and unspent hydrogen peroxide makes cerium available for reaction with hydrogen peroxide) or quinones.

While any suitable reductive bleaching agent may be utilized in said second process, it is preferred to utilize as the reductive bleaching agent either thiourea dioxide or sodium hydroxymethanesulfinate.

EXAMPLES

The following examples are intended only to further illustrate the invention and are not intended to limit the scope of the invention which is defined by the claims.

In the following examples, bleaching of wool fabric was performed using an Ahiba Texomat (Ahiba Inc., Charlotte, N.C.) laboratory dyeing apparatus. Oxidation potential was monitored on a voltmeter using a Corning Platinum Redox Combination electrode (Fisher Scientific Co., Springfield, N.J.); pH was monitored on an E & K pH meter (E & K Scientific product, Saragota, Calif.) using a combination glass electrode (Cole-Palmer International, Chicago, Ill.). All bleaching treatments were carried out at a liquor to wool ratio of 30 milliliters liquor: 1 gram of fabric. Wool samples (10 g) were bleached in various bleach bath compositions and conditions.

Whiteness (ASTM; E-313) and Yellowness (ASTM; D-1925) Indices were measured with a Colorgard System 1000 tristimulus colorimeter (Pacific Scientific Co., Silver Spring, MD). Sample illumination was by a quartz-halogen lamp at color temperature of 2854 degrees Kelvin with 360.degree. circumferential illumination (CIE Source C, 1931 Standard Observer Illuminant) geometry that is 45.degree. from the sample's normal direction, sample viewing being at 0.degree.. The equations used in the Colorgard System for the calculations of Whiteness and Yellowness Indices are:

WI=3.387Z-3Y YI=[100(1.277X-1.06Z)]/Y where; X, Y and Z are the measured tristimulus values; WI is the Whiteness Index, and YI is the Yellowness Index. The extent of degradation of the wool caused by bleaching was determined by measuring the loss in weight of the sample after immersion in 0.1M sodium hydroxide for 1 hour at 65.degree..+-.0.5.degree. C. [I.W.T.O. Technical Committee Report, 1960, IWTO-4-60(E)]. Wet tensile strength measurements of wool flannel, bleached and treated under various conditions, were carried out according to the standard method as set forth in ASTM, 1981 Book of ASTM standards, Am. Soc. for Testing and Materials: Wool flannel fabric was cut into ten equal size strips of length 140 mm and width 13 mm, 5 oriented along the warp axis (18 yarns) and the other 5 along the weft axis (14 yarns). These samples were then soaked for 24 hours in an aqueous solution containing Triton X-100 (0.5 g/L). An Instron tensile testing machine (Instron Corp., Canton, Mass.) of gauge length 90 mm was used for the measurements of breaking load and elongation. The wetted-out samples were secured between the clamps and a constant rate of load was applied along the warp or weft directions until the fabric was broken.

A. Oxidative hydrogen peroxide bleaching followed by thiourea

One aspect of the present invention relates to the formation of a reductive substance in situ when thiourea is added to an oxidative hydrogen peroxide bleach bath. When using thiourea, a strong reductive substance is preferably formed under approximately neutral or slightly alkaline conditions (e.g. pH of about 6 to about 9, preferably a pH of from about 7 to about 8). The optimum stoichiometric ratio of thiourea to hydrogen peroxide was found to be about 2 to 4. An exact amount of thiourea therefore may be calculated based on the amount of unspent hydrogen peroxide remaining after a bleaching process, and that amount of thiourea may be added to the bleach bath for maximum efficiency. In the examples a marked drop in pH (pH=2 to 3) and an increase in temperature (by 5.degree.-7.degree. C.) of solution were observed along with the appearance of incipient turbidity. The pH of the solution was then adjusted to a pH of from about 7 to about 8, at which point the oxidation potential of the solution changed markedly from a positive to a very negative value, indicative of the complete consumption of hydrogen peroxide.

EXAMPLE 1

Bleaching experiments were done in stirred bleaching vessels immersed in a stirred thermostatic bath. The substrate was a wool flannel fabric (20.60-26.39 microns in diameter, 233 g/m.sup.2) with black hair and yellow wool, kindly supplied by Forstmann and Co., Inc., Dublin, Ga. Wool flannel fabric was bleached in the alkaline hydrogen peroxide bleach bath for 1 hour at 60.degree. C. This was then followed by addition of thiourea and the necessary pH adjustment to attain a reductive substance in situ for the reductive bleaching part of the process. The reductive bleaching was carried out for 25 minutes at the same temperature. The bleaching conditions and the results are shown in Table I and depicted graphically in FIG. 1.

TABLE V__________________________________________________________________________The effect of thiourea on the oxidative/reductive bleaching of woolflannel..sup.a Warp.sup.e Weft.sup.eThiourea Total time of Whiteness Yellowness Alkali Breaking Elongation Breaking Elongation(g/L) bleaching (min.) Index.sup.b Index.sup.c Solubility (%).sup.d Load (N) (%) Load (N) (%)__________________________________________________________________________-- 65 29.12 .+-. 0.12 16.24 .+-. 0.30 28.49 .+-. 0.30 37.25 .+-. 2.04 66.15 .+-. 2.48 24.39 .+-. 0.47 59.33 .+-. 2.005.38 65 42.56 .+-. 0.29 10.13 .+-. 0.14 21.72 .+-. 0.84 27.97 .+-. 1.83 56.82 .+-. 3.11 17.99 .+-. 1.26 51.88 .+-. 2.84-- 85 29.26 .+-. 0.33 16.03 .+-. 0.12 -- 34.06 .+-. 0.31 63.11 .+-. 2.32 26.33 .+-. 1.85 63.75 .+-. 4.485.38 85 43.60 .+-. 0.21 9.51 .+-. 0.28 -- 24.53 .+-. 0.83 53.46 .+-. 3.18 19.72 .+-. 0.88 56.22 .+-.__________________________________________________________________________ 1.63 .sup.a Acidic hydrogen peroxide bleaching (as per experimental) for 40 or 60 min at 80.degree. C., followed, when indicated, by thiourea addition, (pH adjustment with NaOH to pH 7.4-7.6), and continued bleaching at 80.degree. C. for 25 min. .sup.b As per Table I. .sup.c As per Table I. .sup.d As per Table I. .sup.e As per Table I. It is seen from the results that the bleaching efficiency are markedly improved with the hydrogen peroxide-thiourea system as compared to an oxidative acidic hydrogen peroxide bleaching alone. The decrease in breaking load and elongation noted in Table V for acidic oxidative/reductive bleaching is not understood, but is inconsistent with the alkali solubility results.

B. Direct addition of reductive substance to a decomposed oxidative hydrogen peroxide bleach bath

It is well known that typically only a small fraction of hydrogen peroxide is consumed or decomposed during an efficient and effective bleaching process. In a typical two step, two-bath oxidative/reductive process, the goods are first bleached oxidatively using hydrogen peroxide (alkaline or acidic). They are then removed from the first bath and bleached in the second bath with a reducing agent. This process is not only costly but also time-consuming, since both baths must be heated up to a suitable temperature.

The principle behind this aspect of the present invention is that the active surplus hydrogen peroxide remaining after an oxidative bleaching treatment may be successfully decomposed with no adverse effect on the fiber or subsequent chemical treatment, thus allowing a reductive substance to be added to the bath directly. This is particularly sound for a single-bath process, since the bath is already in the temperature range suitable for subsequent reductive bleaching. There are many inorganic catalysts (such as, transition metals, e.g. iron, copper, manganese, cobalt, etc.) and enzymes that will decompose hydrogen peroxide. A typical set of conditions would be as follows:

______________________________________Hydrogen peroxide (30% w/w) 20 mL/L of liquorTetrasodium pyrophosphate decahydrate 10 g/L of liquorTriton X-100 1 g/L of liquor______________________________________ Wool fabric (10 g) was bleached with the above solution at a liquor to goods ratio of 30 milliliter liquor: 1 gram of wool for 60 minutes at 60.degree. C. The pH of the bleach liquor was then adjusted to 8.8 and CoSO.sub.4 (25 mg/L) was added to the bleach bath. Rapid evolution of oxygen was observed and the decomposition of hydrogen peroxide was complete within 10-15 minutes as the titration against acidified KMnO.sub.4 showed. At this stage, a chelating agent such as nitrilotriacetic acid trisodium salt could be added to complex with the free Co ions and the pH of the solution could be adjusted to the desired value for the reductive bleaching part of the process.

The above is a specific set of typical conditions, but in general the conditions may be varied. It is found that hydrogen peroxide may be decomposed efficiently in the pH range 7.8-9.0 and temperature range 80.degree.-60.degree. C. with no adverse effect on wool. Reductive bleaching is either carried out under neutral or acidic conditions. Therefore, after the decomposition of hydrogen peroxide and the pH adjustment, the temperature of the bath may be increased to the desired temperature to obtain optimum bleaching yields.

EXAMPLE 6

In this example the effect of reductive bleaching (sodium hydroxymethanesulfinate [Bleachit D (BASF Chemical Division, Charlotte, N.C.)] or thiourea dioxide) is demonstrated under various conditions as an aftertreatment following an oxidative alkaline hydrogen peroxide bleaching. The results of bleaching trials are shown in Table VI and depicted graphically in FIGS. 5 and 6.

TABLE I__________________________________________________________________________The effect of thiourea concentration on the oxidative/reductive bleachingof wool flannel..sup.a Warp.sup.e Weft.sup.e ReductionThiourea Whiteness Yellowness Alkali Breaking Elongation Breaking Elongation potential(g/L) Index.sup.b Index.sup.c Solubility (%).sup.d Load (N) (%) Load (N) (%) (mV).sup.f__________________________________________________________________________Unbleached 11.42 .+-. 0.45 23.71 .+-. 0.20 11.60 .+-. 0.43 35.62 .+-. 1.41 56.64 .+-. 1.92 24.72 .+-. 1.26 60.57 .+-. 2.79 ----.sup.g 35.85 .+-. 0.54 12.38 .+-. 0.17 22.43 .+-. 1.09 35.18 .+-. 2.58 55.32 .+-. 2.44 27.87 .+-. 0.83 55.51 .+-. 1.72 +2013.07 34.24 .+-. 0.48 13.16 .+-. 0.26 24.48 .+-. 0.49 -- -- -- -- +2263.85 38.09 .+-. 0.07 11.49 .+-. 0.03 -- -- -- -- -- -1704.61 43.15 .+-. 0.28 9.55 .+-. 0.03 22.14 .+-. 0.69 -- -- -- -- -6635.38 43.83 .+-. 0.09 9.23 .+-. 0.04 23.53 .+-. 0.37 32.43 .+-. 1.06 55.13 .+-. 1.90 22.99 .+-. 0.63 51.25 .+-. 1.88 -6986.15 43.52 .+-. 0.26 9.17 .+-. 0.16 24.00 .+-. 0.24 -- -- -- -- -6927.69 43.62 .+-. 0.05 9.23 .+-. 0.08 24.44 .+-. 0.22 32.74 .+-. 1.73 53.58 .+-. 2.37 22.39 .+-. 1.59 50.48 .+-. 2.80 -6805.38.sup.h 31.84 .+-. 0.40 14.51 .+-. 0.22 -- 43.30 .+-. 0.78 57.46 .+-. 1.72 27.82 .+-. 0.58 53.26 .+-. 0.99 -145.38.sup.i 37.14 .+-. 0.42 12.11 .+-. 0.14 -- -- -- -- -- -242__________________________________________________________________________ .sup.a Alkaline hydrogen peroxide bleaching, 60.degree. C., 1 hr, followe by thiourea addition, pH adjustment with NaOH to pH 7.4-7.6 unless indicated, and continued bleaching, 60.degree. C., 25 min. .sup.b As per ASTM E313; mean value .+-. standard deviation of 3 samples, each having 8 measurements. .sup.c As per ASTM D1925; mean value .+-. standard deviation of 3 samples each having 8 measurements. .sup.d As per IWTO4-60; mean value .+-. standard deviation of 3 samples. .sup.e As per ASTM D1682-64; mean value .+-. standard deviation of 5 determination. .sup.f Measured immediately after thiourea addition and pH adjustment. .sup.g I.e., alkaline hydrogen peroxide bleaching for 1 hr 25 min with no pH adjustment at 1 hr. .sup.h pH of the solution is not adjusted after the addition of thiourea (pH = 3.6). .sup.i Solution was buffered (pH = 6.8) before thiourea addition so that the reaction is carried out under neutral conditions. Below a certain thiourea concentration (FIG. 1), no improvement in whiteness of wool flannel fabric is observed, this being due to the fact that under these conditions, a reductive substance is not formed since there is not sufficient thiourea to react with all the residual hydrogen peroxide. ______________________________________Alkaline bleach bath composition______________________________________Hydrogen peroxide (30% w/w) 20.0 mL/L of liquorTetrasodium pyrophosphate 10.0 g/L of liquordecahydrateTriton X-100 1.0 g/L of liquorInitial pH of bleach bath 9.4pH after oxidative bleaching for 8.31 hr at 60.degree. C.Weight of wool flannel fabric 10 gLiquor to wool ratio 30 milliliters of liquor : 1 gram of wool______________________________________ Sufficient thiourea should be added to make certain that a reductive bleaching media is produced. Above a certain thiourea concentration, no further improvement of whiteness of wool flannel fabric is observed. It is also apparent from the results in Table I that the pH adjustment to 7-8 may be very advantageous for attaining a high negative oxidation potential and an improvement in the whiteness of wool flannel fabric. The pH may be adjusted to provide a suitable reduction potential so that an improvement in whiteness of the wool flannel fabric is achieved.

EXAMPLE 2

The bleaching solution composition and conditions were the same as those of Example 1 except that bleaching time after thiourea addition following alkaline hydrogen peroxide bleaching was varied. The results are shown in Table II and depicted graphically in FIG. 2.

TABLE II__________________________________________________________________________The effect of thiourea bleaching time on the oxidative/reductivebleaching of wool flannel..sup.aBleaching time Warp.sup.e Weft.sup.eafter thiourea Whiteness Yellowness Alkali Breaking Elongation Breaking Elongationaddition (min.) Index.sup.b Index.sup.c Solubility (%).sup.d Load (N) (%) Load (N) (%)__________________________________________________________________________--.sup.f 34.23 .+-. 0.66 13.15 .+-. 0.31 19.04 .+-. 0.33 35.32 .+-. 1.02 55.88 .+-. 1.70 28.25 .+-. 0.75 56.51 .+-. 1.0315 43.69 .+-. 0.18 9.18 .+-. 0.07 22.05 .+-. 0.26 -- -- -- --25 43.83 .+-. 0.09 9.23 .+-. 0.04 23.53 .+-. 0.37 32.43 .+-. 1.06 55.13 .+-. 1.90 22.99 .+-. 0.63 51.25 .+-. 1.8835 44.75 .+-. 0.07 8.87 .+-. 0.07 -- 31.17 .+-. 1.70 54.68 .+-. 2.82 21.97 .+-. 0.99 52.44 .+-. 1.4745 43.61 .+-. 0.24 9.31 .+-. 0.08 22.54 .+-. 0.72 -- -- -- --25.sup.g 44.42 .+-. 0.05 9.03 .+-. 0.01 20.63 .+-. 0.44 37.36 .+-. 1.56 58.77 .+-. 2.17 26.58 .+-. 1.36 58.04 .+-. 1.8525.sup.h 44.63 .+-. 0.63 8.93 .+-. 0.25 21.45 .+-. 0.67 36.29 .+-. 2.02 57.49 .+-. 3.41 23.57 .+-. 1.44 54.33__________________________________________________________________________ .+-. 3.78 .sup.a As per Table I except 5.38 g/L thiourea was used for various bleaching times. .sup.b As per Table I. .sup.c As per Table I. .sup.d As per Table I. .sup.e As per Table I. .sup.f I.e., alkaline hydrogen peroxide bleaching for 60 min, with neithe subsequent pH adjustment nor addition of thiourea. .sup.g pH was adjusted to 7.1 (6 mL of 30% w/v Na.sub.2 CO.sub.3 solution after thiourea addition. .sup.h pH was adjusted to 7.4 (7.5 g NaHCO.sub.3) after thiourea addition The results in Table II show that the bleaching time after thiourea addition is not critical in the time range studied (15-45 min.). Bleaching times of 25-35 minutes after thiourea addition are preferred. Alkali solubility values are seen to be well below the critical value of 30% as referred to in Ziegler, K. Textil-Praxis, 17, 376(1962). It is also shown in Table II that for the operating conditions of the instant example, that the pH of the bleach solution after thiourea addition may be raised to achieve a high negative oxidation potential; a pH of 7-8, obtained by weak alkalis such as sodium carbonate and bicarbonate, is as sufficient for achieving high bleaching efficiencies as higher values obtained with sodium hydroxide. The pH adjustment may be made with weak alkalis on large scale bleaching trials to avoid unwanted damage to wool that might occur from use of sodium hydroxide and uneven mixing.

EXAMPLE 3

The bleaching solution composition and conditions were the same as those of Example 1 except the initial alkaline hydrogen peroxide bleaching time prior to thiourea addition was varied. The results, as shown in Table III and depicted graphically in FIG. 3, demonstrate that the longer the hydrogen peroxide bleaching part of the process, the whiter the bleached wool flannel fabric.

TABLE III__________________________________________________________________________The effect of varying the hydrogen peroxide bleaching time on theoxidative/reductive bleaching ofwool flannel..sup.aOxidative Warp.sup.e Weft.sup.ebleaching Whiteness Yellowness Alkali Breaking Elongation Breaking Elongationtime (min.) Index.sup.b Index.sup.c Solubility (%).sup.d Load (N) (%) Load (N) (%)__________________________________________________________________________ 0.sup.f 31.84 .+-. 0.19 13.89 .+-. 0.02 -- -- -- -- --20 39.43 .+-. 0.38 10.97 .+-. 0.16 -- -- -- -- --40 42.46 .+-. 0.15 9.69 .+-. 0.06 20.12 .+-. 0.34 -- -- -- --60 43.52 .+-. 0.26 9.38 .+-. 0.04 24.00 .+-. 0.24 32.56 .+-. 1.51 54.90 .+-. 2.05 22.60 .+-. 1.20 50.95 .+-. 1.3080 46.82 .+-. 0.16 8.04 .+-. 0.04 24.29 .+-. 0.13 30.91 .+-. 1.30 56.31 .+-. 1.35 19.20 .+-. 1.28 48.44 .+-. 1.22__________________________________________________________________________ .sup.a As per Table I except 6.15 g/L thiourea is used. .sup.b As per Table I. .sup.c As per Table I. .sup.d As per Table I. .sup.e As per Table I. .sup.f Thiourea mixed with hydrogen peroxide and pH adjusted with no prio time for oxidative bleaching. Here it must be emphasized that in the process of this example, that the wool flannel fabric to be bleached should first be given an oxidative peroxide bleaching prior to thiourea addition. This is simply demonstrated by the results given in Table III where the wool flannel fabric was not given an initial peroxide bleach. Hydrogen peroxide, thiourea and all the other additives were mixed at the start of the bleaching treatment and bleaching was allowed to proceed for 20 minutes. The importance of initial hydrogen peroxide bleaching becomes more apparent when the Whiteness Index values of wool bleached for 60 minutes (with all chemicals mixed at the start i.e. as taught by Japan 51-64082) are compared with those of wool bleached for 65 minutes (40 minutes alkaline peroxide bleach followed by thiourea addition and bleaching for 25 minutes after pH adjustment). Although in both cases a high negative oxidation potential was attained, it seems that the initial oxidative hydrogen peroxide bleaching somehow modifies wool sufficiently so that a followup reductive bleaching further whitens wool effectively.

EXAMPLE 4

The bleaching solution composition was the same as per Example 1. In the present example, a direct comparison of conventional alkaline hydrogen peroxide bleaching to that of the new invention (oxidative/reductive single-bath process) at different bleaching temperatures is made and the results are shown in Table IV and depicted graphically in FIG. 4.

TABLE IV__________________________________________________________________________The effect of bleaching temperature on the oxidative/reductive bleachingof wool flannel..sup.aTreatment Thiourea Total time of Whiteness Yellowness Alkalitemperature (.degree.C.) addition bleaching (min.) Index.sup.b Index.sup.c Solubility (%).sup.d__________________________________________________________________________55 No 65 32.76 .+-. 0.39 13.77 .+-. 0.16 --55 Yes 65 40.11 .+-. 0.33 10.73 .+-. 0.15 --60 No 65 34.23 .+-. 0.66 13.15 .+-. 0.31 19.04 .+-. 0.3360 Yes 65 42.46 .+-. 0.15 9.69 .+-. 0.06 20.12 .+-. 0.34 60.sup.e Yes 60 33.89 .+-. 0.94 13.51 .+-. 0.35 --65 No 65 37.63 .+-. 0.33 11.57 .+-. 0.13 28.23 .+-. 0.6365 Yes 65 44.05 .+-. 0.31 9.00 .+-. 0.18 25.15 .+-. 0.5270 No 65 39.36 .+-. 0.28 10.96 .+-. 0.11 32.61 .+-. 0.9970 Yes 65 45.43 .+-. 0.23 8.46 .+-. 0.14 28.88 .+-. 0.37__________________________________________________________________________ .sup.a Alkaline hydrogen peroxide bleaching at different temperatures, 40 min., followed by thiourea addition (6.15 g/L; pH adjustment with NaOH to pH 7.4-7.6 only in the thiourea cases), and continued bleaching for 25 min. .sup.b As per Table I. .sup.c As per Table I. .sup.d As per Table I. .sup.e Thiourea mixed with hydrogen peroxide and pH adjusted with no prio time for oxidative bleaching. It is noteworthy that the same level of whiteness is reached at a bleaching temperature of 55.degree. C. with the hydrogen peroxide-thiourea bleaching system (oxidative/reductive) as at 70.degree. C. with the hydrogen peroxide system alone. Furthermore the former process is less damaging to the wool, as evidenced by lower alkali solubilities.

EXAMPLE 5

______________________________________Acidic bleach bath composition______________________________________Hydrogen peroxide (30% w/w) 20.0 mL/L of liquorPrestogen NB-W 3.43 g/L of liquorTriton X-100 1.0 g/L of liquorInitial pH of bleach bath 5.7pH after oxidative bleaching for 5.21 hr at 80.degree. C.Weight of wool flannel fabric 10 gLiquor to wool ratio 30 milliliters of liquor : 1 gram of fabric______________________________________ Prestogen NB-W (BASF Chemicals Division, Charlotte, N.C.) is a mixture of organic acid salts in aqueous solution which activates hydrogen peroxide at mildly acid pH values by forming peroxy compounds.

In this example, we demonstrate the effectiveness of the hydrogen peroxide-thiourea system on the bleaching efficiency under acidic oxidative bleaching with hydrogen peroxide followed by thiourea. The results are shown in Table V.

TABLE VI__________________________________________________________________________The effect of reductive agent aftertreatment (Bleachit D, thioureadioxide) on theoxidative/reductive bleaching of wool flannel..sup.aBath Hydrogentemperature peroxide Bleachit D Thiourea dioxide Whiteness Yellowness Alkali(.degree.C.) (mL/L) (g/L) (g/L) Index.sup.b Index.sup.c Solubility (%).sup.d__________________________________________________________________________60 20.sup.e -- -- 35.85 .+-. 0.54 12.38 .+-. 0.17 22.43 .+-. 1.0960 20.sup.f 1.0 -- 39.84 .+-. 0.42 10.66 .+-. 0.21 24.58 .+-. 0.4760 20.sup.f 2.0 -- 39.93 .+-. 0.27 10.58 .+-. 0.07 --60 20.sup.f 4.0 -- 40.80 .+-. 0.07 10.60 .+-. 0.03 24.59 .+-. 0.6970 20.sup.e -- -- 39.33 .+-. 0.36 10.94 .+-. 0.17 30.73 .+-. 0.7870 20.sup.g -- 1.0 35.75 .+-. 0.66 12.51 .+-. 0.24 22.65 .+-. 0.6770 20.sup.g -- 2.0 41.21 .+-. 0.13 10.26 .+-. 0.19 --70 20.sup.g -- 3.0 42.14 .+-. 0.28 9.69 .+-. 0.08 22.51 .+-. 0.3270 20.sup.g -- 5.0 43.26 .+-. 0.52 9.24 .+-. 0.19 --__________________________________________________________________________ .sup.a As per experimental; residual hydrogen peroxide quenched using CoSO.sub.4 prior to reductive bleaching. .sup.b As per Table I. .sup.c As per Table I. .sup.d As per Table I. .sup.e Alkaline hydrogen peroxide bleaching for 1 hour and 25 minutes, as per Table I, note g. .sup.f As per .sup.e, but for 50 minutes, followed by peroxide decomposition with CoSO.sub.4 for the next 10 minutes at pH 8.8 and finally reductive bleaching (Bleachit D, pH adjusted to 2.5) at the same temperature for 25 minutes. .sup.g As per .sup.`f` except for reductive bleaching agent (thiourea dioxide, pH adjusted to 6.5-7.0). In the process of the instant example, the decomposition of residual hydrogen peroxide is essential; preliminary experiments showed that large amounts of reductive agents (thiourea dioxide, sodium hydroxymethanesulfinate) were needed to consume all the residual hydrogen peroxide before a high negative oxidation potential could be attained upon addition of the reductive agent. It should also be noted that thiourea dioxide, unlike sodium hydroxymethanesulfinate, does not produce a high negative oxidation potential under acidic conditions; therefore, with thiourea dioxide it is preferred to utilize a pH of about 6.5-7.0. For reasons of economy it is preferred that all residual hydrogen peroxide after oxidative bleaching be completely decomposed so that an addition of only a relatively small amount of reductive substance creates the reduction potential that is needed for the latter part of the process.

EXAMPLE 7

Comparative Example

The purpose of this example is to show the increased effectiveness of the present invention as compared to the processes of German Patent DE No. 3433926 A1 (3/27/86) and Japanese Patent JP No. 51-64082 (6/3/76). The German patent discloses a single-bath process whereby a reductive bleaching with thiourea dioxide precedes an oxidative hydrogen peroxide bleaching. In that patent, two processes--one with and one without thiourea dioxide--were compared and it was concluded that the process with thiourea dioxide was favorable to the one without. The optimum bleaching conditions were said to be a reductive bleaching with a buffer mixture (pH=7.8, 4 g/L) containing thiourea dioxide (0.36 g/L) for 20 minutes at 80.degree. C. followed by a direct addition of hydrogen peroxide (20 mL/L of 35% w/w solution) and further bleaching for 60 minutes at the same temperature. The Japanese patent mentions a process whereby thiourea and hydrogen peroxide are mixed at the start of the bleaching process (i.e., no prior oxidative bleaching) and there is no prescribed pH adjustment. Optimum bleaching conditions were said to be 2.91 g/L hydrogen peroxide (30% w/w) and 2.0 g/L thiourea at 95.degree. C. for 20 minutes.

All the above processes were repeated in the exact manner outlined in the patents and the results along with those of our invention are shown in Table VII.

TABLE VII__________________________________________________________________________Comparison of different bleaching processes.Process Treatment Hydrogen Thiourea Thiourea Bleachit D Whiteness Yellowness AlkaliType.sup.a temperature (.degree.C.) peroxide (g/L) (g/L) dioxide (g/L) (g/L) Index.sup.b Index .sup.c solubility__________________________________________________________________________ (%).sup.dA 60 20 5.38 -- -- 43.83 .+-. 0.09 9.23 .+-. 0.04 23.53 .+-. 0.37B 80 20 5.38 -- -- 42.56 .+-. 0.29 9.51 .+-. 0.28 21.72 .+-. 0.84C 80 20 -- 0.36 -- 35.31 .+-. 0.07 13.29 .+-. 0.02 27.40 .+-. 0.64C 80 20 -- -- -- 32.59 .+-. 0.21 14.36 .+-. 0.07 --D 95 2.91 2.0 -- -- 20.33 .+-. 0.50 18.87 .+-. 0.15 --E 60 20 -- -- 4.0 40.80 .+-. 0.07 10.60 .+-. 0.03 24.59 .+-. 0.69F 70 20 -- 5.0 -- 43.26 .+-. 0.52 9.24 .+-. 0.19 --__________________________________________________________________________ .sup.a A (Our Process): Alkaline hydrogen peroxide bleaching followed by thiourea, as per Table I, note a; B (Our Process): Acidic hydrogen peroxide bleaching followed by thiourea, as per Table V, note a; C (Germa Patent): Reductive bleaching with thiourea dioxide at pH 7.8 for 25 min, followed by hydrogen peroxide bleaching for 60 min,; D (Japanese Patent): Hydrogen peroxide and thiourea mixed at start of bleaching process with n pH adjustment; E (Our Process): As per Table VI, note f; F (Our Process): As per Table VI, note g. .sup.b As per Table I. .sup.c As per Table I. .sup.d As per Table I. It is clearly seen that the present invention processes (A, B, E, F) give more effective bleaching (i.e. higher Whiteness Index, lower Yellowness Index and lower alkali solubility) than either of the other processes (C or D). Process type C (Table VII; reductive/oxidative) with thiourea dioxide is a near reverse of the present invention processes A, B, E and F (oxidative/reductive). One would therefore expect similar results. The differences that were observed must be a function of the process sequence, since high negative oxidation potentials were observed in all these processes. One may therefore conclude from this that in a single-bath bleaching process, an oxidative hydrogen peroxide bleaching must be carried out first, and only then followed by a reductive bleach.

The foregoing examples and detailed descriptions are given merely for purposes of illustration. Modifications and variations may be made therein without departing from the spirit and scope of the invention.

Claims

1. A process for oxidative and reductive bleaching of fibers comprising:

contacting fibers with hydrogen peroxide under conditions which provide oxidative bleaching of said fibers to produce bleached fibers in contact with unspent hydrogen peroxide;

adding to said bleached fibers in contact with unspent hydrogen peroxide, an inactivating material in an amount at least sufficient to inactivate all of said unspent hydrogen peroxide to form an inactivated media; and

subsequent to said inactivation of all said unspent hydrogen peroxide, reductively bleaching said bleached fibers by addition of a reductive bleaching agent to said inactivated media.

2. The process of claim 1 wherein, said inactivating material is selected from the group consisting of: catalysts which catalyze decomposition of hydrogen peroxide, enzymes which decompose hydrogen peroxide, and materials which react with hydrogen peroxide to render said hydrogen peroxide inactive.

3. The process of claim 2 wherein, said inactivating material is a transition metal and the pH of said bleached fibers in contact with unspent hydrogen peroxide is adjusted to be from about 6 to about 10 prior to adding said transition metal.

4. The process of claim 3 further including the step of chelating excess metal ions by adding a chelating agent to said inactivated media prior to said reductive bleaching.

5. The process of claim 2 wherein said inactivating material is an enzyme and the pH of said bleached fibers in contact with unspent hydrogen peroxide is adjusted to be from about 3 to about 10 prior to adding said enzyme.

6. The process of claim 5 wherein said enzyme is catalase and said pH is adjusted from about 5 to about 8.5.

7. The process of claim 2 wherein said inactivating material is a material which reacts with hydrogen peroxide to render said hydrogen peroxide inactive, selected from the group consisting of cerium and quinone.

8. The process of claim 1 wherein said reductive bleaching agent is selected from the group consisting of thiourea dioxide or sodium hydroxymethanesulfinate.

9. The process of claim 1 wherein all steps are carried out batch-wise in a single bath.

10. The process of claim 1 wherein all steps are carried out continuously using a continuous padding system.

11. The process of claim 1 wherein said fibers are in a form selected from the group consisting of loose fiber, yarn and fabric.

12. The process of claim 1 wherein said fibers are a material selected from the group consisting of animal hair fibers, plant fibers, synthetic fibers, and blends of two or more of said fibers.

13. The process of claim 12 wherein said fibers are a material selected from the group consisting of wool, wool blends, and cotton.

14. The process of claim 1 wherein all steps are carried out at temperatures between about 20.degree. C. and 100.degree. C.

15. A bleached fiber produced by the process of claim 1.

16. The bleached fiber of claim 15 wherein said fiber, is wool, has a degree of whiteness as measured by ASTM E-313 of at least about 43, and a degree of damage indicated by an alkali solubility of 30% or less as measured by IWTO-4-60.

17. The bleached wool fiber of claim 16 wherein said fiber has a said degree of whiteness of at least about 44, and a said degree of damage indicated by an alkali solubility of 25% or less.

18. The bleached wool fiber of claim 17 where said fiber has a said degree of whiteness of at least about 46.