The present invention relates to an apparatus for acquiring information on a sheet material.
In recent years, apparatuses for obtaining information on sheet materials are attracting attention. For instance, U.S. Pat. No. 6,291,829 discloses a device for identifying the type of recording paper sheet provided in an image-forming apparatus.
The sheet materials to be detected include anisotropic materials. U.S. Pat. No. 5,475,233 discloses a method for measuring orientation of fiber in anisotropic materials.
In identification of an anisotropic sheet material with a sheet material information-detecting apparatus by application of an external force, the detection result depends on the relative position of the sensor to the sheet material. Therefore, for detection of information on the sheet material fed successively to an image-forming apparatus, so-called oblique feed of the sheet should be prevented to obtain precise information. This is explained below specifically.
Paper sheets produced from wood pulp as the main source material, for instance, are widely used as recording sheets. The paper sheets have anisotropic characters owing to orientation of the fiber in a specific direction (machine direction) in the paper making process.
Such paper sheets, which are generally cut in machine direction and cross direction, are anisotropic in characteristics according to the sheet cutting directions as called “crosswise orientation” or “lengthwise orientation” based on the cutting ends, and the properties thereof differ depending on the orientation directions: the properties such as rigidity, distortion by force, elongation at break, Young's modulus, swelling and curling by water absorption, light reflectivity, surface roughness, and periodic structure.
The inventors of the present invention have studied on detection of information on sheet materials by application of external force onto sheet materials fed successively to an image-forming apparatus or the like. As the results, the inventors have found newly that, when a paper sheet having the aforementioned orientation comes to be fed with its orientation direction oblique to the sheet feed direction, the information on the sheet material is affected by the anisotropy. Such a problem arises also in coated paper sheets and resin films having orientation caused by the production process.
The present invention provides a sheet material information-detecting apparatus excellent in information detecting accuracy.
The present invention is made to solve the above problem.
According to an aspect of the present invention, there is provided a sheet material information-detecting apparatus comprising:
a sheet feeding means for feeding a sheet material;
a correcting means for correcting the position of the fed sheet material to bring the orientation direction of the constituting material of the sheet material to be in a prescribed direction relative to the feed direction of the sheet material;
an external force applying means for applying an external force to the sheet material in the corrected position; and
an information-acquiring means for acquiring information corresponding to the stress caused by the applied external force in the sheet material.
According to another aspect of the present invention, there is provided a sheet material information-detecting apparatus comprising:
a sheet feeding means for feeding a sheet material;
a correcting means for correcting the position of the fed sheet material to bring the orientation direction of the constituting material of the sheet material to be in a prescribed direction relative to the feed direction of the sheet material;
an external force applying means for applying an external force to the sheet material in the corrected position;
a signal-detecting means for detecting signal from the sheet material; and
an information-acquiring means for acquiring information on the stress caused by the applied external force corresponding to the sheet material.
According to still another aspect of the present invention, there is provided a sheet-material treating apparatus, comprising the aforementioned sheet material information-detecting apparatus, and a sheet material-treating assembly for treating the sheet material by utilizing the information obtained by the sheet information-detecting apparatus.
According to a further aspect of the present invention, there is provided a sheet material feeding unit comprising the aforementioned sheet material information-detecting apparatus, and a driving assembly for the sheet material feeding means.
According to a still further aspect of the present invention, there is provided a process for acquiring information on a sheet material, comprising the steps of:
correcting the position of a fed sheet material to bring the orientation direction of the constituting material of the sheet material to be in a prescribed direction relative to the feed direction of the sheet material;
applying an external force to the sheet material placed in the corrected position; and
acquiring information corresponding to the stress caused by the applied external force in the sheet material.
The sheet material information-detecting apparatus comprises a sheet material sensor for sensing interaction of an external force-applying means and a signal detecting means with the sheet material.
The sheet material sensor can sense the state or position of the sheet material.
The sheet material information-acquiring means can acquire the information on the sheet material by comparison of the detection results of the signal detecting means with a data.
The sheet material information-acquiring means can acquire the information on the sheet material by comparison of the results of detection of the signal detecting means with a data for directions of sheet material.
The external force includes a mechanical force. This mechanical force may be plural times of impacts at different collision velocity.
The external force includes vibrations having different frequency components.
The external force includes a wave.
The external force includes a light beam.
The sheet material information detection apparatus comprises a restricting member which restricts the region of displacement of the sheet material on application of the external force.
The embodiment of the present invention is explained by reference to
As shown in
The orientation of the sheet-constituting material, in the present invention, signifies fiber orientation caused in the paper making process for paper sheets, and molecule orientation caused by stretching for resin films.
The sheet material information-detecting apparatus of the present invention comprises an oblique feed correcting means for correcting the oblique introduction of the sheet material P through the sheet feed path (correction of the sheet feed direction), and applies an external force by the external force applying means after the correction of the oblique sheet introduction.
With the sheet material information-detecting apparatus of the present invention, sheet feeding means 1a and 1b feed a sheet material P, the oblique feed correcting means corrects the oblique introduction of sheet P (step S1 in
An oblique feed correcting means, as an example, takes selectively either a first position to project into sheet feed path A or a second position to withdraw from sheet feed path A. The correcting means corrects the oblique sheet introduction by taking the first position by pushing the front edge of sheet material P, and then allows the feed of sheet material P by taking the second position. Such an oblique feed correcting means is provided as a single-functional member for oblique feed correction, like a so-called shuttering member.
In another example, the oblique feed correcting member employs feeding rollers 1a and 1b, as shown in
Sheet material P can be corrected not only for the oblique feed within the plane of sheet material P by the oblique feed correcting means, but also for the position in the thickness direction of sheet material P by a sheet material displacing means (reference number 4 in
The sheet material information can be acquired manually based on the detection result derived by signal detecting means 3, or automatically by inputting the detection result by the signal detecting means 3 to the sheet material information-acquiring means (reference number 5 in
<Detection of Frequency Components of Detected Signals>
Naturally, the obtained one output waveform may be subjected to extraction of plural characters, and combination of the extracted characters may be utilized for the identification. Otherwise, one output signal may be branched into plural fractions and the respective branched signal fractions may be processed separately in different manners. For instance, the branched signal fractions are respectively subjected to filtering with different cutoff frequencies to extract different frequency components and obtain the intensity ratio.
The sheet material information-acquiring means 5 may be used to comparing the detected results obtained by signal-detecting means 3 with known data for acquiring the sheet material information. That is, the sheet material information-acquiring means 5 may be used by comparing the acquired character data with a memorized data table and to output information on the kind, type, state change, printed state, multiple sheet feed, and so forth of the sheet material. In the case where the signal from the sheet material varies depending on the environmental conditions, the sheet feeding state and so forth, plural data tables are prepared correspondingly as the reference standard for the judgment. When plural signal detecting means 3 are employed or plural times of signal detection is conducted by changing the external force application conditions, the data tables are provided correspondingly.
For discriminating an anisotropic sheet material, sheet material information-acquiring means may be made to acquire the sheet material information by comparing the detection results of the aforementioned signal-detecting means 3 with memorized data (data for orientation-directions of the sheet material). For example, data tables are provided for feeding a regular-sized sheet material (e.g., A4 size) in a longitudinal direction and in a cross direction (breadth direction). Since most of commercial sheet materials are classified into lengthwise oriented ones and crosswise oriented ones, the data tables are preferably prepared for the orientation directions. Further, the sheet material may be identified by utilizing combinedly other procedures (e.g., input of paper sheet type-numbers set artificially, and signals from a separately provided sensor). Furthermore, a logic circuit is preferably provided for judging from combination of plural detection results or plural judgment results.
The detected signal may be processed for subtracting the output signal in no sheet feeding state. The circuit for this signal processing can process signals by utilizing a first signal detected by the sensor on external force application without the pinched sheet material and a second signal detected by the sensor on external force application with the sheet pinched.
The “sheet material” in this Specification includes recording mediums such as plain paper sheets, glossy paper sheets, coated paper sheets, regenerated paper sheets, and OHP; and recorded document sheet materials.
The “sheet material information” in this Specification includes kind or type-numbers, densities, thicknesses, surface roughnesses, state changes, and printed states of the sheet materials; occurrence of overlapping sheet feeding, overlapping sheet numbers, unused remaining sheet numbers, presence of the sheet material, and overlapping position of the sheet materials.
The application of the external force by external force-applying means 2 should be conducted after correction of the oblique feed. The setting position of external force-applying means 2 is not limited to a downstream side of the oblique feed correcting means (downstream side along the sheet feed direction), but may be an upstream side of the oblique feed-correcting means. With external force-applying means 2 set at the downstream side of the oblique feed-correcting means, the external force may be applied to sheet material P being in contact with the oblique feed-correcting means, or to sheet material P having passed through the oblique feed-correcting means. On the other hand, with external force-applying means 2 placed at the upstream side of the oblique feed-correcting means, the external force may be applied to sheet material P having been corrected for oblique feed by contact with the oblique feed-correcting means. Since the detected information (sheet material information) is used in a later step for controlling the sheet material-treating assembly (symbol C in
This external force-applying means 2 may be the ones which apply external force by bringing an external force-applying member (reference number 20 in
The external force in the present invention includes electricity, magnetism, heat, thermal expansion/contraction of a gas or the like, optical beams such as laser beams, electromagnetic waves, sonic waves, vibration, and mechanical force, but is not limited thereto. The external force may be applied as impact, or as vibration.
The driving source for application of the impact includes the ones which hold external force applying member 20 above sheet material P and allow the member 20 to fall onto sheet material P, and the ones which allow external force applying means 20 to collide against sheet P by a mechanical or electromagnetic energy (e.g., mechanical means like a spring, electromagnetic means like a solenoid or a voice coil). In preferred examples, a rotational force of a motor or a roller of sheet feeding system is changed in direction or strength by a conversion mechanism such as gear and cam. Such mechanisms are preferred in view of the stability.
The driving source for application of vibration includes vibrating means for vibrating external force applying member 20 (e.g., piezoelectric actuators, electrostatic actuators, and electromagnetic sound generators).
For applying the impact force, external force applying member 20 may be allowed to collide against sheet material P. Otherwise, external force applying member 20 kept in contact with sheet material P may be impacted. In this case, the application of external force is conducted with the member 20 kept in contact with sheet material P. External force applying member 20 may be brought into contact with sheet material P only at the time of external force application, or may be kept in contact with sheet material P before the external-force application. In the former case, when the external force applying means and the signal detecting means are placed in opposition, the distance between the external force applying means and the signal detecting means comes to be changed (shortened). Since application of external force by the external force applying means can deform the sheet material slightly (formation of a hollow or the like), the external force is applied preferably at the edge or end of the sheet material.
The external force may be applied to sheet material P in a feeding state, or may be applied to sheet material P in a temporarily stopping state. The external force application to sheet material P in a feeding state has an advantage of ease of detection of the surface state of the face of the sheet material (at the external force application side), whereas the external force application to sheet material P in a stopping state has an advantage of preciseness of detection owing to the absence of noise caused by sheet feeding. The state of the sheet material in the detection may be selected as necessary.
The external force includes several kinds of forces as mentioned above. Only one kind of external force may be employed, or plural kinds of external forces may be employed. When one kind of external force is employed, one external force application may be conducted for obtaining the information, or plural times of external force application may be conducted for obtaining the information. By the plural times of external force application (one kind of external force plural times, or plural kinds of external forces), plural data can be obtained, improving the judgment accuracy. The plural times of external force application may be conducted with one external force applying member, or with plural external force applying members. In the plural times of external force application, the strength of the external force (impact strength, or vibration intensity) may be kept constant, or may be varied. In the plural times of external force application, a subsequent external force is preferably applied after the shake of the sheet material by the preceding external force has come to attenuate sufficiently or become lower than a prescribed level.
Further, preferred mode of plural times of external force application includes plural times of impacting at different collision velocity, and vibration in different frequency components. By such external force application, the viscoelasticities of polymeric sheet materials can be reflected efficiently on the output signal, which enables output of more detailed information of the sheet materials. Furthermore, by plural times of external force application, plural pieces of information can be outputted from signal detection means 3.
In order to detect the information with high precision, a member is provided in opposition to external force applying member 20 with interposition of sheet material P to stop the external force (the member hereinafter referred to as an “external force stopping member”). With sheet displacing means 4 placed in opposition to external force applying member 20, the sheet displacing means 4 is allowed to function as the external force stopping member (to stop the external force by this displacing means without providing additional external force stopping member). When displacing means 4 is not opposed to external force applying member 20, an external force stopping member is provided in opposition to external force applying member 20. The sheet contact face of such an external force stopping member may be a flat plane or a curved plane. On the external force stopping member, a recess may be formed at the position opposing through the sheet material to the tip of external force applying member 20 to avoid concentration of the external force to one point for lengthening the life of the element. The recess is preferably formed since the absorption of the external force by the sheet material by being deformed toward the recess by the external force can be detected.
The aforementioned sheet displacing means 4 may be of any construction, provided that it is capable of displacing the sheet material, being exemplified by the ones which displace the sheet material with interposition of a cushioning layer like air, and the ones which a displacing member is allowed to protrude into the sheet material feed path to come into contact with the sheet material and to displace it. When the sheet displacing means is employed as the external force stopping member, the sheet displacing means should be of the latter type.
This sheet displacing means may be utilized for defining the position of the sheet materials: the position relative to signal detecting means 3 (interval between sheet material P and signal detecting means 3); the position relative to external force applying member 20 (interval between sheet material P and external force applying member 20); or the position relative to the external force stopping member (interval between sheet material P and external force stopping member). Incidentally, by defining the position of the sheet material relative to the external force stopping member, the bending of the sheet material caused by the external force application can be made constant to enable stable detection independently of the applied external force. More preferably, this sheet displacing means brings sheet material P into contact with the external force stopping member. For such control, the external force stopping member is placed to push the sheet material, or the sheet displacing means is constituted to displace the sheet material in the direction to push the external force stopping member.
<Restricting Member>
A restricting member is preferably provided which restricts the region of displacement of the sheet material on application of the external force.
In
<Anisotropy Impartment>
In
In
The dimensions of d, W1, and W2 are roughly in the ranges: 0.1 mm<d<2.0 mm, 5 mm<W1<20 mm, and 5 mm<W2<40 mm. Within these ranges, the information can be suitably detected on a recording medium such as plain paper, gloss paper, coated paper, regenerated paper and OHP paper.
A sheet sensor is preferably provided additionally to detect the state or position of the sheet material P (interaction of the sheet with external force applying means 2 or signal detecting means 3). The words “the state or position of the sheet material P (interaction of the sheet with external force applying means 2 or signal detecting means 3)” signifies a contacting state of the sheet material with the external force applying means 2 or signal detecting means 3; the position of the front edge of the sheet material; the state of passage of the sheet material; the pressure given by the sheet material to external force applying means 2 or signal detecting means 3; deformation of the sheet material; and so forth. The sheet sensor includes mechanical sensors and optical sensors for detecting contact or deformation, pressure sensors for detecting a pressure, and acceleration sensors for detecting vibration. Such a sheet sensor may be joined directly to external force applying means 2 or signal detecting means 3, or may be installed near external force applying means 2 or signal detecting means 3, and may be suitably designed for the sensor employed.
The feedback of the signal from the sheet sensor can optimize the control of external force applying means 2 or signal detecting means 3 for higher precision of sheet information detection. Further, the conditions such as the timing of beginning and stop of external force application, the strength of external force, and so forth can also be decided according to the signal from the sheet sensor. More information can be derived by utilizing the detection of the interaction of the sheet material with external force applying means 2 or signal detecting means 3 (pressure given by the sheet material, deformation of the sheet material, and so forth) in combination with the signal of impact application.
The aforementioned signal detecting means 3 can be comprised of an inorganic or organic material having a piezoelectric property, including specifically piezoelectric inorganic materials and piezoelectric organic materials such as PZT (lead titanate zirconate), PLZT, BaTiO3, and PMN—PT(Pb(Mg1/3Nb2/3)O3—PbTiO3). With such a piezoelectric material, the external force is detected as a voltage signal.
The arrangement position of signal detecting means 3 is not limited insofar as the signal caused by the external force application can be detected. For instance, the signal detecting means may be placed in opposition to external force applying means 2 with interposition of sheet material P as shown in
The external force in the present invention includes waves. The wave includes ultrasonic waves, high-frequency waves, and optical waves.
Since the information detection is conducted after correction of oblique feed of the sheet material in the present invention, the information on the sheet material can be detected precisely even if the sheet material is anisotropic in the light reflectivity, surface roughness, or periodic structure thereof.
In detection of an image as the sheet material information, an interference phenomenon like moiré may occur depending on the periodic structure (e.g., fiber orientation structure of a paper sheet) of an observation object (sheet material) and arrangement of arrayed light-receiving elements, or the extent of the interference is varied by the oblique feed of the sheet material, causing an error in the information detection. The present invention lessens such adverse effect of the interference, enabling precise detection of the sheet material information.
The signal detecting means may be of one-dimensional arrangement or two-dimensional arrangement. With the latter two-dimensional arrangement, the breadth of the sheet material can be detected by employing a sensor assembly having a length equal to the breadth of the sheet material (e.g., a recording medium) or longer. Naturally, the breadth of the recording medium can be detected by plural sensor assemblies.
<Sheet Material Feeding Unit>
The embodiment of the present invention includes a sheet feeding unit incorporating the aforementioned sheet material information detecting-apparatus and a sheet feed driving assembly.
In another embodiment, the sheet material-treating apparatus of the present invention, as shown in
Sheet material-treating assembly C is exemplified by an image-forming assembly for image formation, a scanner assembly for reading an image, or like assemblies. The sheet material-treating apparatus includes copying machines, printers, facsimiles, scanners for image reading, and automatic document feeder.
In such an apparatus, CPU may be employed for conducting change of printing mode (e.g., adjustment of image formation conditions, adjustment of the feeding conditions such as a pressure given to a feeding rollers, stop of printing, stop of feed of a recording medium, generation of alarm signal, and so forth) based on the detection results of sheet material information-detecting apparatus B. The CPU may be installed in the inside of the sheet material-treating apparatus, or at the outside thereof. The CPU installed inside need not transmit or receive data signals to or from the outside.
The signal outputting apparatus may be comprised of external force applying means 2 for applying an external force to sheet material P; sheet displacing means 4 placed in opposition to the external force applying means 2 (with interposition of the sheet material) for controlling the position of sheet material P; and signal detecting means 3 for detecting a signal generated by the applied external force. The signal outputting apparatus of such a constitution is preferably connected to an external instrument which serves to acquire the sheet material information according to the output signal from the signal outputting assembly.
Next, the effects of embodiments of the present invention are explained below.
According to embodiment of the present invention, information on the sheet material can be obtained precisely even if the sheet material is anisotropic.
The present invention is explained in more detail by reference to an example.
In this Example, a paper type-detecting apparatus (a sheet material information-detecting apparatus) as shown in
In this apparatus, sheet feeding path A is formed by a pair of feed guide 10a and 10b, and feeding rollers (sheet feeding means) 1a, 1b, 1c and 1d are arranged along sheet feeding path A for feeding a recording paper sheet (sheet material). Of the rollers, upstream-side feeding rollers 1a and 1b serves also as oblique-feed correcting means. For oblique feed correction, the rotation of the rollers is stopped, and the nip between the rollers is narrowed to stop recording sheet P once for correction of oblique sheet feed. Then the nip is widened and feed of recording sheet is started by rotation of the rollers. The reference numeral 11 denotes a sheet material sensor placed near the roller 1a. This sensor detects the passage of the sheet material and displacement in the oblique feed correction.
External force applying means 2 and signal detecting means 3 are placed between rollers 1a and 1b and the rollers 1c and 1d.
At a portion of feed guide 10a, an aperture is formed, and bracket 12 is placed to cap the aperture. To bracket 12, are attached cushioning material 13, detecting sensor (signal detecting means) 3, and displacing member (sheet displacing means) 4 as shown in the drawing: cushioning material 13 supports detecting sensor 3, and the detecting sensor 3 supports displacing member 4 to allow displacing member 4 to protrude into the feed path. The dimension of the protrusion of displacing member 4 is one-fourth the breadth of feed path A (breadth at the position of displacing member 4) so that the recording sheet fed in the apparatus of this Example necessarily comes into contact with the displacing member 4 regardless of the type of the sheet (paper sheet or OHP sheet). Displacing member 4 is formed from a metal in a partial-cylindrical shape as shown in the drawing. The face of the displacing member for contact with recording paper sheet P is recessed at the upstream-side end and the downstream-side end from level of the aperture face of feed guide 10a on feed path A, and is allowed to protrude toward feed guide 10b at the middle portion thereof. The reference number 14 denotes a pushing-pressure controller.
As another embodiment, the contact face of the sheet displacing member is entirely recessed from the aperture face of feed guide 10a for feed guide A. In this embodiment, the sheet material is bent by application of an external force to allow the sheet material to come into contact with the contact face of the sheet displacing member, only when applying the external force thereto.
Detecting sensor 3 is comprised of PZT (lead titanate zirconate) as a piezoelectric material held between silver electrodes. The piezoelectric material has a length of 20 mm, a breadth of 5 mm, and thickness of 0.3 mm. Cushioning material 13 made of rubber is placed between bracket 12 and detecting sensor 3, whereby propagation of mechanical vibration from feed guide 10a to detecting sensor 3 is reduced to improve the detection accuracy. In
In this Example, paper presser 15 is provided to assist the contact of sheet material P with displacing member 4. Paper presser 15 is comprised of an elastic plate and a fixing member, and applies force by elasticity of the plate to the sheet material to push it to displacing member 4. Paper presser 15 has a mechanism (not shown in
External force applying means 2 for applying an external force to recording paper sheet P is placed in opposition to displacing member 4. An aperture is provided in feed guide 10b and bracket 211 is placed in that portion. Roughly cylindrical guiding member 215 is attached to bracket 211, and rod 217 is placed to be movable horizontally in the guiding member 215. Pressing member (external force applying means) 20 is attached to the tip (tip at the recording sheet side) of rod 217. Stopper member 214 in a brim shape is provided at rod 217. Coil spring 210 in a compressed state is provided in the space between stopper member 214 and guide member 215. To bracket 211, motor 213 is attached, and to the output shaft of the motor, cam 212 is attached for pushing protrusion 218 attached to the end of rod 217. Incidentally, the reference numeral 216 denotes a pressure relief hole for mitigating damping by air in the guide member.
The aforementioned pressing member 20 applies external force to recording paper sheet P by collision at prescribed velocity with the aid of coil spring 210 and cam 212. When pressing member 20 is in a free state, the strength of the external force is decided by the product “mν” of the mass m of pressing member 20 and collision velocity ν and interaction among pressing member 20, recording paper sheet P and the external force stopping member. For instance, for identification of the type of usual paper sheets, the strength of the external force ranges preferably from about 0.1 gm/s to about 10 gm/s. For one signal output, the external force is applied plural times preferably by changing the strength, whereby the information regarding the recording paper sheet can be detected with high precision.
In this Example, cam 212 is of two-step type having different steps for applying two different strengths of external forces by one rotation of motor 213. That is, higher cam 212 pushes projection 217 to move pressing member 20 upward, and releases pressing member 20 instantaneously to cause collision of pressing member 20 against recording paper sheet P by the spring force of coil spring 210, and thereafter lower cam 212 pushes projection 217 to move pressing member 20 upward, and releases pressing member 20 instantaneously to cause collision of pressing member 20 against recording paper sheet P by the spring force of coil spring 210. In this external force application, the strength of the external force applied to recording paper sheet is changed by using higher cam 212 and lower cam 212 by the difference of the compression distance of coil spring 210.
Another cam is attached also preferably to the driving shaft of cam 212 (i.e., rotation shaft of the motor) to displace the displacing member or an auxiliary displacing member by linking with external force application.
In this Example, displacing member 4 is placed in opposition to pressing member 20 to receive the external force.
In this Example, the data in the initial state without the sheet material is read by a processing apparatus before feed of the sheet material from the tray. This step of reading of the initial state may be omitted.
The operation in this Example is explained below.
Recording paper sheet P is fed by downstream-side feeding rollers 1c and 1d with the nip of upstream-side rollers 1a and 1b kept narrow. The recording paper sheet P is pushed against upstream-side rollers 1a and 1b to correct oblique feeding. Then, external force is applied by pressing member 20 to recording paper sheet P. The external force is transmitted through displacing member 4 to detecting sensor 3. Thereby, a signal as shown in
According to this Example, information regarding a sheet material can be obtained even if the sheet material is anisotropic.
Number | Date | Country | Kind |
---|---|---|---|
2003-043271 | Feb 2003 | JP | national |
2004-041999 | Feb 2004 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
---|---|---|---|---|
PCT/JP2004/002015 | 2/20/2004 | WO | 00 | 6/10/2005 |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2004/073990 | 9/2/2004 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
3470734 | Agdur et al. | Oct 1969 | A |
5104488 | Chase | Apr 1992 | A |
5123284 | Edinburgh et al. | Jun 1992 | A |
5475233 | Fukuoka et al. | Dec 1995 | A |
5774146 | Mizutani | Jun 1998 | A |
5852499 | Tomita et al. | Dec 1998 | A |
6291829 | Allen et al. | Sep 2001 | B1 |
20020039495 | Metzler | Apr 2002 | A1 |
20020181963 | Takeda | Dec 2002 | A1 |
Number | Date | Country | |
---|---|---|---|
20060022400 A1 | Feb 2006 | US |