The present application is related to the field of heat shrinkable bags and specifically those designed to tear open in a manner that provides for easy access to the contents.
Shrink bag packaging is commonly used for food, such as meat or cheese, and other items. Bags are typically pre-manufactured with a top seal and header area incorporating various features including handles, tear initiators and tack seals to prevent curling. Depending on the application, the multilayer bags are manufactured using highly engineered polymer formulas and controlled processing conditions to provide specific properties such as oxygen barrier, sealing through contamination, abuse resistance, low temperature shrink, directional tear, etc. For many applications, it is desired to have bags that can be manually tom open for removal of the product.
Current tear-open shrink bags suffer from inconsistent performance when the tear propagates through the seal area and follows either the leading or trailing bead of the main seal to the edge of the bag. As a result either the bag is not open at all (tears above the seal), or it is not open enough to empty the contents. This is especially evident in cook-in applications where material selection is limited and machine direction tear properties suffer.
A heat shrinkable bag has been developed with superior tear open performance. By modifying the main seal of a heat shrinkable bag with extension areas that may be placed both external and internal to the main seal, manual tearing of the bags consistently results in a propagation path straight into the body of the bag.
One embodiment of the shrink bag has a first wall and a second wall opposing each other. The walls may contain multilayer heat shrink films. The bag has a first edge, a second edge opposing the first edge, a third edge substantially perpendicular to the first edge and the second edge, and a fourth edge opposing the third edge. A first seal connects the first and second walls. The first seal has a first part extending from the first edge to the second edge, a second part extending into the header and a third part extending into the product space. A header is located between the first part of the first seal and the fourth edge and a product space is located between the first part of the first seal and the third edge. A tear initiator starts at a point within the header and extends to a point within the first seal. Some embodiments of the shrink bag may include a first assistor and a second assistor in the header.
In some embodiments the second part of the first seal has a sealed section and a heated section, wherein the first and second walls are not sealed together in the heated section. Additionally, the second part of the first seal may have more than one sealed section. One embodiment of the shrink bag has the second part of the first seal, the third part of the first seal and the tear initiator located at an approximate center of the first part of the first seal.
Embodiments of the shrink bag may have the tear initiator extending from a location on the fourth edge. Other embodiments may have the tear initiator extending from a location spaced from the fourth edge to a location within the first seal. In any embodiment, the tear initiator may extend through the entire thickness of each of the first wall and the second wall.
Embodiments of the shrink bag may have various shapes. The third and fourth edges may be arcuate. In addition, the first part of the first seal may be arcuate.
Further embodiments of the shrink bag have a first seal connecting a first wall of a multilayer film to a second wall of the multilayer film. The first seal has a first part, separating the bag into a header and a product space, a second part extending into the header, and a third part extending into the product space. The bag also includes a tear initiator. The tear initiator may extend from a first point within the header to a second point within the header, and may be positioned with linear continuity to the second part of the first seal and the third part of the first seal. Alternatively, the tear initiator may extend from a first point within the header to a point within the first part of the first seal. Alternatively, the tear initiator may extend from a first point within the header to a point within the second part of the first seal. When the bag is filled with a product, sealed, and subjected to heat to shrink the bag, the bag may be torn open using the tear initiator, the tear continuing into the product space of the bag.
One embodiment of the shrink bag includes a first wall and a second wall. The bag has a first edge, a second edge opposing the first edge, an arcuate shaped third edge extending relatively perpendicular to the first edge, and an arcuate shaped fourth edge opposing the third edge. A first seal connects the first and second walls. The first seal has an arcuate shape first part, a second part and a third part, wherein the arcuate shape first part extends from the first edge to the second edge and the second and third parts are located at an approximate center of the arcuate shape first part. The shrink bag also has a header located between the arcuate shape first part of the first seal and the fourth edge and the second part of the first seal extends into the header. The shrink bag has a product space located between the arcuate shape first part of the first seal and the third edge, and the third part of the first seal extends into the product space. A tear initiator may be located at an approximate center of the arcuate shape first part of the first seal, extending from a point between the fourth edge and the second part of the first seal to a point within the second part of the first seal. A first assistor and a second assistor, formed as holes through the entire thicknesses of the first and second wall, may be located in the header on either side of the tear initiator. A second seal may be adjacent the first assistor and a third seal may be adjacent the second assistor.
In some embodiments the second part of the first seal and the third part of the first seal are rectangular. The tear initiator may be a continuous slit extending through both the first and second walls. The shrink bag may have the arcuate shape first part of the first seal, the second part of the first seal, the third part of the first seal and the tear initiator positioned with linear continuity. Upon filling the bag with a product, sealing the bag along the third edge, subjecting the bag to heat to shrink the bag, and tearing open the bag using the tear initiator, the bag may tear into the center portion of the product space in at least one of the first or second wall.
There are several aspects of the present subject matter which may be embodied separately or together. These aspects may be employed alone or in combination with other aspects of the subject matter described herein, and the description of these aspects together is not intended to preclude the use of these aspects separately or the claiming of such aspects separately or in different combinations.
The disclosure may be more completely understood in consideration of the following detailed description of various embodiments of the disclosure in connection with the accompanying drawings, in which:
The figures are not necessarily to scale. Like numbers used in the figures refer to like components. It will be understood, however, that the use of a number to refer to a component in a given figure is not intended to limit the component in another figure labeled with the same number.
The present application describes a shrink bag having a first seal with a first part, a second part, and a third part. The shrink bag of the present application also includes a header with a tear initiator present. The tear initiator may extend into the first seal. The first seal (with the first part, the second part, and the third part) and the tear initiator combine to provide easy access to the contents of the bag when an end-user opens the bag, as the bag will tear down the center of each wall of the bag. This is in contrast to current shrink bags with tear openings, which often improperly tear along the seal on one or both walls of the bag and, therefore, create difficulties in opening and require additional effort to remove the contents of the bag.
Bag 10 further includes a first seal 30. First seal 30 includes a first part 32 that extends from first edge 16 to second edge 18, a second part 34 that extends into header 40, and a third part 36 that extends into product space 24 (as depicted in
Header 40 includes tear initiator 42 overlapping and partially in second part 34 of first seal 30. Tear initiator 42 may be a continuous or non-continuous series of holes, slits, slots, perforations, notches, punctures, orifices, openings, gaps, scores, knurls, or otherwise as known in the art. In various embodiments, tear initiator 42 may be formed by mechanical means (e.g., using a cutting blade), by chemical means (e.g., using solvents), by thermal means (e.g., by optical ablation including but not limited to laser) or by other means known in the art. In various embodiments, tear initiator 42 has varying depth and, in some embodiments, extends through the entire thicknesses of each of first wall 12 and second wall 14. Additionally, in various embodiments, tear initiator 42 has various length. As a non-limiting example, tear initiator 42 may extend from a point of fourth edge 22 through second part 34 to a point at the intersection of second part 34 and first part 32 (but not into first part 32). As a further non-limiting example, tear initiator 42 may extend from a point between fourth edge 22 and second part 34, through second part 34 to a point before the intersection of second part 34 and first part 32 (as depicted in
Header 40 also includes first assistor 44 and second assistor 46. First assistor 44 and second assistor 46 are areas of header 40 that an end-user may grip or grasp or otherwise hold to assist in opening bag 10. In some embodiments, first assistor 44 and second assistor 46 are holes through the entire thicknesses of each of first wall 12 and second wall 14. In other embodiments, first assistor 44 and second assistor 46 are slits. In yet other embodiments, first assistor 44 and second assistor 46 are knurled areas of header 40. And, in yet further embodiments, first assistor 44 and second assistor 46 are unaltered areas of header 40 which an end-user simply holds in opening bag 10.
As depicted in
In linear embodiments, the first part is a straight line substantially throughout, traced by a point traversing in a constant direction and having an equation that may be written in slope intercept form, y=mx+b, where “m” is the slope and “b” is the y-intercept.
In non-linear embodiments, the first part of the first seal has a shape or geometry that is not a straight line substantially throughout, such that it has at least two dimensions and is traced by a point traversing in at least two directions.
Returning to
Again returning to
In some embodiments the second part 34′ may be subjected to varying degrees of heat in sealing the first wall and the second wall and includes a heated section 54′ separate from a sealed section 56. Such varying degrees of heat may create a temperature gradient.
In yet further embodiments, the tear initiator may be present in a zone of the second part of the first seal.
Returning to
As depicted in
The various embodiments of each of the tear initiator, the first part of the first seal, the second part of the first seal, and the third part of the first seal are described above. The bag of the present application may include any combination of each of these embodiments. As a non-limiting example, the bag may be torpedo shape and may have a first seal that has a first part that is arcuate shape, a second part that is trapezoid shape, and a third part that is inverted bell curve shape, where the tear initiator is present in the second part of the first seal. As a further non-limiting example, the bag may be rectangle shape and may have a first seal that has a first part that is linear zero-slope shape, a second part that is rectangle shape (with a first edge to second edge dimension smaller than a third edge to fourth edge dimension), and a third part that is half-circle shape (with the diameter adjacent the first part), where the heated section of the second part is separate from the sealed section of the second part and the tear initiator is present in the heated section but not the sealed section.
Returning to
First wall 12 and second wall 14 may each comprise a monolayer or multilayer heat-shrinkable film and may have the same or different composition, provided the composition of first wall 12 and second wall 14 allow first wall 12 and second wall 14 to seal at the various seals or sealed sections of bag 10. The compositions of first wall 12 and second wall 14 may be such that each of first wall 12 and second wall 14 has (1) a machine direction shrinkage value of greater than 5% shrink at 90° C. or from greater than 5% to 70% shrink at 90° C. or at least 10% shrink at 90° C. or at least 20% shrink at 90° C. or from 10% to 50% shrink at 90° C. and (2) a transverse direction shrinkage value of greater than 5% shrink at 90° C. or from greater than 5% to 70% shrink at 90° C. or at least 10% shrink at 90° C. or at least 20% shrink at 90° C. or from 10% to 50% shrink at 90° C.
First wall 12 and second wall 14 may each comprise polypropylene, polyethylene, polyamide, polyester, polystyrene, cyclic olefin copolymer, ethylene vinyl-alcohol copolymer, polyvinylidene chloride, ionomer, or blends of such.
As used throughout this application, the term “polypropylene” or “PP” refers to a plastomer, homopolymer or copolymer having at least one propylene monomer linkage within the repeating backbone of the polymer. The propylene linkage may be represented by the general formula: [CH2—CH(CH3)]n. Such polypropylene may be a polypropylene impact copolymer, a polypropylene random copolymer, or a polypropylene homopolymer, may be syndiotactic or isotactic, or may or may not be clarified.
As used throughout this application, the term “polyethylene” or “PE” refers (unless indicated otherwise) to ethylene homopolymers or copolymers. Such copolymers of ethylene include copolymers of ethylene with at least one alpha-olefin and copolymers of ethylene with other units or groups such as vinyl acetate, acid groups, acrylate groups, or otherwise. The term “polyethylene” or “PE” is used without regard to the presence or absence of substituent branch groups. PE includes, for example, medium density polyethylene, high density polyethylene, low density polyethylene, ethylene alpha-olefin copolymer, ethylene vinyl acetate, ethylene acid copolymers, ethylene acrylate copolymers, or blends of such. Various PE's may be recycled as reclaimed PE.
As used throughout this application, the term “high density polyethylene” or “HDPE” refers to both (a) homopolymers of ethylene which have densities from 0.960 g/cm3 to 0.970 g/cm3 and (b) copolymers of ethylene and an alpha-olefin (usually 1-butene or 1-hexene) which have densities from 0.940 g/cm3 to 0.958 g/cm3. HDPE includes polymers made with Ziegler or Phillips type catalysts and polymers made with single-site metallocene catalysts. HDPE also includes high molecular weight “polyethylenes.”
As used throughout this application, the term “low density polyethylene” or “LDPE” refers to branched homopolymers having densities from 0.915 g/cm3 to 0.930 g/cm3, as well as copolymers containing polar groups resulting from copolymerization (such as with vinyl acetate or ethyl acrylate). LDPE may contain long branches off the main chain (often termed “backbone”) with alkyl substituents of two to eight carbon atoms.
As used throughout this application, the terms “copolymer of ethylene and at least one alpha-olefin” or “ethylene alpha-olefin copolymer” refer to a modified or unmodified copolymer produced by the co-polymerization of ethylene and any one or more alpha-olefins. Suitable alpha-olefins include, for example, C3 to C20 alpha-olefins such as 1-propene, 1-butene, 1-pentene, 1-hexene, 1-octene, 1-decene and blends of such. The co-polymerization of ethylene and an alpha-olefin may be produced by heterogeneous catalysis, such as co-polymerization reactions with Ziegler-Natta catalysis systems, including, for example, metal halides activated by an organometallic catalyst (e.g., titanium chloride) and optionally containing magnesium chloride complexed to trialkyl aluminum. Alternatively, the co-polymerization of ethylene and an alpha-olefin may be produced by homogeneous catalysis, such as co-polymerization reactions with metallocene catalysis systems which include constrained geometry catalysts, (e.g., monocyclopentadienyl transition-metal complexes). Homogeneous catalyzed copolymers of ethylene and alpha-olefin may include modified or unmodified ethylene alpha-olefin copolymers having a long-chain branched (i.e., 8-20 pendant carbons atoms) alpha-olefin co-monomer (commercially available as, for example, Affinity™ from The Dow Chemical Company (Midland, Mich.)), linear copolymers (commercially available as, for example, Tafmer™ from the Mitsui Petrochemical Corporation (Tokyo, Japan)), and modified or unmodified ethylene alpha-olefin copolymers having a short-chain branched (i.e., 3-6 pendant carbons atoms) alpha-olefin co-monomer (commercially available as, for example, Exact™ from ExxonMobil Chemical Company (Houston, Tex.)). Ethylene alpha-olefin copolymers may include, for example, linear low density polyethylene (LLDPE), metallocene-catalyzed LLDPE (mLLDPE), very low density polyethylene (VLDPE), metallocene-catalyzed VLDPE (mVLDPE), and ultra low density polyethylene (ULDPE).
As used throughout this application, the term “ethylene vinyl acetate” or “EVA” refers to copolymers comprised of repeating units of ethylene and vinyl acetate. Ethylene vinyl acetate copolymers may be represented by the general formula: [(CH2—CH2)n—(CH2—CH(COO)(CH3)]n. The vinyl acetate content may vary from less than 10% to greater than 95% by weight (of total EVA composition). The vinyl acetate content of EVA for packaging applications may vary from 5% to 40% by weight.
As used throughout this application, the term “ethylene acid copolymers” refers to copolymers comprised of repeating units of ethylene and acid groups. The acid group content may vary from 2% to 25% by weight. Non-limiting examples of ethylene acid copolymers include ethylene methacrylic acid (EMAA) and ethylene acrylic acid (EAA).
As used throughout this application, the term “ethylene acrylate copolymers” refers to copolymers comprised of repeating units of ethylene and acrylate groups. The acrylate group may be butyl-, ethyl-, methyl-, or otherwise. Non-limiting examples of ethylene acrylate copolymers include ethylene methyl acrylate (EMA) and ethylene methyl methacrylate (EMMA).
As used throughout this application, the term “polyamide” or “PA” or “nylon” refers to a homopolymer or copolymer having an amide linkage between monomer units and formed by any method known in the art. The amide linkage may be represented by the general formula: [C(O)—R—C(O)—NH—R′—NH]n where R and R′ are the same or different alkyl (or aryl) group. Nylon polymers may be high-temperature, low-temperature or amorphous, as described in, for example, International Publication Number WO 2006/063283. Examples of nylon polymers include but are not limited to nylon 6 (polycaprolactam), nylon 11 (polyundecanolactam), nylon 12 (polyauryllactam), nylon 4,2 (polytetramethylene ethylenediamide), nylon 4,6 (polytetramethylene adipamide), nylon 6,6 (polyhexamethylene adipamide), nylon 6.9 (polyhexamethylene azelamide), nylon 6,10 (polyhexamethylene sebacamide), nylon 6,12 (polyhexamethylene dodecanediamide), nylon 7,7 (polyheptamethylene pimelamide), nylon 8,8 (polyoctamethylene suberamide), nylon 9,9 (polynonamethylene azelamide), nylon 10,9 (polydecamethylene azelamide), and nylon 12,12 (polydodecamethylene dodecanediamide). Examples of nylon copolymers include but are not limited to nylon 6,6/6 copolymer (polyhexamethylene adipamide/caprolactam copolymer), nylon 6,6/9 copolymer (polyhexamethylene adipamide/azelamide copolymer), nylon 6/6,6 copolymer (polycaprolactam/hexamethylene adipamide copolymer), nylon 6,2/6,2 copolymer (polyhexamethylene ethylenediamide/hexamethylene ethylenediamide copolymer), and nylon 6,6/6,9/6 copolymer (polyhexamethylene adipamide/hexamethylene azelamide/caprolactam copolymer). Examples of aromatic nylon polymers (also sometimes referred to as “amorphous polyamide” or “amorphous nylon”) include but are not limited to nylon 4,I, nylon 6,I, nylon 6,6/6I copolymer, nylon 6,6/6T copolymer, nylon MXD6 (poly-m-xylylene adipamide), poly-p-xylylene adipamide, nylon 6I/6T copolymer, nylon 6T/6I copolymer, nylon MXDI, nylon 6/MXDT/I copolymer, nylon 6T (polyhexamethylene terephthalamide), nylon 12T (polydodecamethylene terephthalamide), nylon 66T, and nylon 6-3-T (poly(trimethyl hexamethylene terephthalamide).
As used throughout this application, the term “polyester” refers to a homopolymer or copolymer having an ester linkage between monomer units. The ester linkage may be represented by the general formula [O—R—OC(O)—R′—C(O)]n where R and R′ are the same or different alkyl (or aryl) group and may generally be formed from the polymerization of dicarboxylic acid and diol monomers. The dicarboxylic acid (including the carboxylic acid moieties) may be linear or aliphatic (e.g., oxalic acid, maleic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, and the like) or may be aromatic or alkyl substituted aromatic (e.g., various isomers of phthalic acid, such as paraphthalic acid (or terephthalic acid), isophthalic acid and naphthalic acid). Specific examples of a useful diol include but are not limited to ethylene glycol, propylene glycol, trimethylene glycol, 1,4-butane diol, neopentyl glycol, cyclohexane diol, 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and the like. Polyesters may include a homopolymer or copolymer of alkyl-aromatic esters, including but not limited to polyethylene terephthalate (PET), oriented polyethylene terephthalate (OPET), amorphous polyethylene terephthalate (APET), glycol-modified polyethylene terephthalate (PETG), and polybutylene terephthalate (PBT); a copolymer of terephthalate and isophthalate including but not limited to polyethylene terephthalate/isophthalate copolymer, such as isophthalic acid (IPA) (modified polyethylene terephthalate (PETI)); a homopolymer or copolymer of aliphatic esters including but not limited to polylactic acid (PLA); polyhydroxyalkonates including but not limited to polyhydroxypropionate, poly(3-hydroxybutyrate) (PH3B), poly(3-hydroxyvalerate) (PH3V), poly(4-hydroxybutyrate) (PH4B), poly(4-hydroxyvalerate) (PH4V), poly(5-hydroxyvalerate) (PH5V), poly(6-hydroxydodecanoate) (PH6D); and blends of any of these materials.
As used throughout this application, the term “polystyrene” or “PS” or “styrenic polymer” refers to a homopolymer or copolymer having at least one styrene monomer linkage (such as benzene (i.e., C6H6) having an ethylene substituent) within the repeating backbone of the polymer. The styrene linkage may be represented by the general formula: [CH2—CH2(C6H5)]n. Examples of styrenic polymers include but are not limited to high impact polystyrene (HIPS), general purpose polystyrene (GPPS) and styrene butadiene copolymer (SBC).
As used throughout this application the term “cyclic olefin copolymer” or “COC” refers to a class of polymeric materials based on cyclic olefin monomers and ethane, with one or more different cyclic olefin units randomly or alternately attached to an ethylene polymer backbone. Ethylene/norbomene copolymers are a non-limiting example of cyclic olefin copolymers.
As used throughout this application, the term “ethylene vinyl alcohol copolymer” or “EVOH” refers to copolymers comprised of repeating units of ethylene and vinyl alcohol. Ethylene vinyl alcohol copolymers may be represented by the general formula: [(CH2—CH2)n—(CH2—CH(OH))]n. Ethylene vinyl alcohol copolymers may include saponified or hydrolyzed ethylene vinyl acetate copolymers. EVOH refers to a vinyl alcohol copolymer having an ethylene co-monomer and prepared by, for example, hydrolysis of vinyl acetate copolymers or by chemical reactions with vinyl alcohol. Ethylene vinyl alcohol copolymers may comprise from 28 mole percent (or less) to 48 mole percent (or greater) ethylene.
As used throughout this application, the term “polyvinylidene chloride” or “PVdC” refers to a homopolymer or copolymer having at least one vinylidene chloride monomer linkage within the repeating backbone of the polymer. The vinylidene chloride linkage may be represented by the general formula [CH2—CCl2]n. As a copolymer, PVdC may have a major amount of vinylidene chloride and a minor amount of one or more monomers such as vinyl chloride or alkyl acrylates (such as methyl acrylates).
As used throughout this application, “ionomer” refers to ionic copolymers formed from an olefin and an ethylenically unsaturated monocarboxylic acid having the carboxylic acid moieties partially or completely neutralized by a metal ion. Suitable metal ions may include, but are not limited to, sodium, potassium, lithium cesium, nickel, and zinc. Suitable carboxylic acid comonomers may include, but are not limited to, ethylene acid copolymers, such as, ethylene methacrylic acid, methylene succinic acid, maleic anhydride, vinyl acetate methacrylic acid, methyl methacrylate methacrylic acid, styrene methacrylic acid, and blends of such. Useful ionomer ethylene/acid copolymer resins may include an olefinic content of at least 50 mole percent based upon the copolymer and a carboxylic acid content of from 5 to 25 mole percent based upon the copolymer.
As used throughout this application, the term “copolymer” refers to a polymer product obtained by the polymerization reaction or copolymerization of at least two monomer species. Copolymers may also be referred to as bipolymers. The term “copolymer” is also inclusive of the polymerization reaction of three, four or more monomer species having reaction products referred to terpolymers, quaterpolymers, etc.
As used throughout this application, the term “modified” refers to a chemical derivative, such as one having any form of anhydride functionality (e.g., anhydride of maleic acid, crotonic acid, citraconic acid, itaconic acid, fumaric acid, etc.), whether grafted onto a polymer, copolymerized with a polymer or blended with one or more polymers. The term is also inclusive of derivatives of such functionalities, such as acids, esters and metal salts derived from such.
Each of first wall 12 and second wall 14 comprises a sealant film or sealant layer. As used throughout this application, the term “sealant film” refers to a film included in a package or film and involved in the sealing of the package or film to itself or to another layer of another film, sheet, etc. The term “sealant layer” or “sealant layers” refers to the specific layer or layers of the film or the sealant film involved in the sealing to itself or to another layer. A sealant film may be monolayer or multilayer. If the sealant film is monolayer, the term “sealant film” is synonymous with the term “sealant layer.” A sealant film may be a blown film sealant, an extrusion coated sealant, or a heat seal lacquer. Specific non-limiting examples of sealant layers included in each of first wall 12 and second wall 14 include but are not limited to layers comprising polyethylene (such as LLDPE, a blend of LLDPE and LDPE, mLLDPE), polypropylene (such as a blend of random copolymer PP and PP plastomer), ionomer, or blends of any of the above.
Considering the above, each of first wall 12 and second wall 14 comprises a heat-shrinkable film comprising a sealant film (or sealant layer). In some embodiments, each of first wall and second wall 14 comprises materials providing a ratio of TD tear to MD tear pre shrink of greater than 2.7, a ratio of TD tear to MD tear post shrink of greater than 1.0, a ratio of MD tear post shrink to MD tear pre shrink of less than 36, or a ratio of TD tear post shrink to TD pre shrink of less than 13 (as further described below).
A specific non-limiting method of making the bag described in the present application includes producing materials for the first wall and the second wall (such as by blown co-extrusion with appropriate draw ratios to produce desired shrink properties and with optional irradiation via electron beam or otherwise) and producing bags with such materials (such as via bag-making equipment known in the art). In some embodiments where the first wall has the same composition as the second wall, a bag may be formed from a tube of such material by creating first seal 30 and then cutting the tube at third edge 20 and fourth edge 22. Third edge 20 remains open until an item to be packaged is inserted in the partially sealed bag. Once the item is inserted, third edge 20 is sealed to fully seal the bag.
The bags produced may be used in a variety of applications, including packaging food and non-food items. Non-limiting examples of food items that may be packaged in the shrink bag described in the present application include meats and cheeses, including but not limited to large cuts of meat and large blocks of cheese. A further non-limiting example of a food item is meat (such as ham) that is cooked in the package prior to sale to the end-user.
To further exemplify the various embodiments of the present application, several example and comparative example shrink bags were produced and evaluated for various properties.
TABLE 1 provides information regarding the composition of various films used to make the shrink bags. In each instance, the first wall of the bag had the same composition as the second wall, so a tube was initially produced.
The only substantive differences in the compositions of Tubes 1-7 were the compositions of Layer 1 (the exterior layer) and the compositions of Layer 7 (the interior layer). For each tube, the compositions of Layers 2-6 were substantively similar and had no impact on the performance of the tube in general or as used in a shrink bag as described in the present application. For the tubes of TABLE 1, the “interior layer” was the same as the “sealant layer.” As used throughout this application, including but not limited to in TABLE 1, the term “exterior layer” refers to a layer comprising the outermost surface of a film, sheet, web, package or other article. The term “interior layer” refers to a layer comprising the innermost surface of a film, sheet, web, package or other article. Additionally, the exterior layer and the interior layer each have an inner surface and an outer surface. The term “inner surface” refers to a surface touching another layer, and the term “outer surface” refers to a surface not touching another layer.
Each tube was produced on a shrink co-extrusion line and irradiated with electron beam. In addition to the materials listed in TABLE 1, various layers included various processing aids as known to a person of ordinary skill in the packaging arts.
Example bags 1-7 and comparative examples bags 1-7 were produced from Tubes 1-7.
Header 140 included second seal 145 as an “eyebrow” to first assistor 144 and third seal 147 as an “eyebrow” to second assistor 146. First assistor 144 and second assistor 146 were formed as holes through the entire thicknesses of each of first wall 112 and the second wall and provided areas for the end-user to grip or grasp in opening bag 110.
Header 140 further included tear initiator 142. Tear initiator 142 overlapped and was partially in second part 134 of first seal 130. In other words, tear initiator 142 extended from a point between fourth edge 122 and second part 134 through second part 134 to a point before the intersection of second part 134 and first part 132.
Second part 134 and third part 136 of first seal 130 and tear initiator 142 were placed in the approximate center of first part 132 and such that there was some continuity (and continuous and linear positioning) between tear initiator 142, second part 134, first part 132, and third part 136.
Comparative examples bags 1-7 were produced from tubes 1-7 to be similar to Examples 1-7. However, Comparative Examples 1-7 did not include second part 134 or third part 136. In Comparative Examples 1-7, the first seal included only an arcuate shape first part extending from the first edge to the second edge.
A half-ham or larger was then packaged in various samples of each of Examples 1-7 and Comparative Examples 1-7. The respective packages were sealed at the third edge and subjected to heat, such that the bag “shrink around” the ham. The packaged hams were then subjected to various tests to determine fitness for use in cook-in applications and ability to tear.
Various samples of packaged hams of each of Examples 1-7 and Comparative Examples 1-7 were subjected to a hot water test in which the sample was placed in a boiling water (100° C.) tank for 10 minutes and then placed in a refrigerator for at least two hours to cool. After cooling, the tear and opening of each sample was qualitatively assessed.
A sample failed if it tore along the first seal on each of the first wall and the second wall, if it tore in the TD in the header or in the product space, or if it had a header that ripped at an assistor such that the bag could not be opened.
Various samples of packaged hams of each of Examples 4-6 and Comparative Examples 2-6 were also subjected to a cook test in which the sample was placed in a Vulcan® steam oven (79-88° C., 80% relative humidity) for 2-3 hours and then placed in a refrigerator for at least 12 hours to cool. After cooling, the tear and opening of each sample was qualitatively assessed. TABLE 3 reports the results of this assessment.
Tubes 1-7 (specifically, the films of Tubes 1-7) were also evaluated for Elmendorf Tear pre-shrink and post-shrink (i.e., after being immersed in at least 90° water for at least five seconds and cooled). As used throughout this application, the term “Elmendorf Tear” refers to the force to propagate tearing through a length of material after the tear has been initiated, using an Elmendorf-type (pendulum) tearing tester. It is an index of a material's tearing resistance. For the present application, Elmendorf Tear was determined in accordance with ASTM D1922-15 (“Standard Test Method for Propagation Tear Resistance of Plastic Film and Thin Sheeting by Pendulum Method”). Elmendorf Tear values are reported as tearing force, such as, in gram-force. A high Elmendorf Tear value generally reflects a material that is more difficult to tear. TABLE 4 reports tear properties and ratios of tear properties for Tubes 1-7. (A 200-gram pendulum was used to determine MD tear pre-shrink, an 800-gram pendulum was used to determine TD tear pre-shrink, a 1600-gram pendulum was used to determine MD tear post-shrink, and a 6400-gram pendulum was used to determine TD tear post-shrink. At least six measurements were recorded for each tube at each point and averaged.)
Considering such Elmendorf Tear properties, it is believed, without being bound by belief, that Example 3 had 0% passing in the hot water test (as reported in TABLE 1) not because of the configuration of first seal 130 (with first part 132, second part 134, and third part 136) but because of the composition of Layer 7 (the sealant layer). Again, it is believed, without being bound by belief, that the polypropylene composition of the sealant layer of Example 3 contributed to the tear properties of Tube 3 such that Tube 3 had a ratio of TD tear to MD tear pre shrink of 2.7 or less, a ratio of TD tear to MD tear post shrink of 1.0 or less, a ratio of MD tear post shrink to MD tear pre shrink of 36 or greater, or a ratio of TD tear post shrink to TD pre shrink of 13 or greater. As described above, in some embodiments, such materials are not preferred.
In some embodiments, certain optical properties of the shrink bag described in the present application may be desired. As such, Tubes 4-7 were evaluated for clarity, haze, and gloss. TABLE 5 reports these additional properties. (At least five measurements were recorded for each tube at each point and averaged.)
As used throughout this application, the term “clarity” refers to the see-through quality of a material. It refers to the specific light transmitting and narrow-angle-light scattering properties of a material and is determined in an angle range less than 2.5 degrees. Clarity may be determined in accordance with ASTM D1003-13 (“Standard Test Method for Haze and Luminous Transmittance of Transparent Plastics”). Clarity values are reported in percent. A high clarity value generally reflects a material that is more transparent and less cloudy.
As used throughout this application, the term “haze” refers to the scattering of light as it passes through a material. It refers to the specific light-transmitting and wide-angle-light scattering properties of planar sections of a material. Haze may be determined in accordance with ASTM D1003-13 (“Standard Test Method for Haze and Luminous Transmittance of Transparent Plastics”). Haze values are reported in percent. A high haze value generally reflects a material that is more cloudy and less transparent.
As used throughout this application, the term “gloss” refers to the shiny appearance of a material. It is a measure of the light reflected by the surface of a material and is measured at a specific angle of reflection (20, 45, 60, 75, or 85 degrees) against a specific backing. Gloss may be determined in accordance with ASTM D2457-13 (“Standard Test Method for Specular Gloss of Plastic Films and Solid Plastics”). Gloss values are reported in Gloss Units. A high gloss value generally reflects a material that is more shiny.
Each and every document cited in this present application, including any cross referenced or related patent or application, is incorporated in this present application in its entirety by this reference, unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any embodiment disclosed in this present application or that it alone, or in any combination with any other reference or references, teaches, suggests, or discloses any such embodiment. Further, to the extent that any meaning or definition of a term in this present application conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this present application governs.
Unless otherwise indicated, all numbers expressing sizes, amounts, ranges, limits, and physical and other properties used in the present application are to be understood as being preceded in all instances by the term “about”. Accordingly, unless expressly indicated to the contrary, the numerical parameters set forth in the present application are approximations that can vary depending on the desired properties sought to be obtained by a person of ordinary skill in the art without undue experimentation using the teachings disclosed in the present application.
As used in the present application, the singular forms “a,” “an,” and “the” encompass embodiments having plural referents, unless the context clearly dictates otherwise. As used in the present application, the term “or” is generally employed in its sense including “and/or,” unless the context clearly dictates otherwise.
Spatially related terms, including but not limited to, “lower,” “upper,” “beneath,” “below,” “above,” “bottom” and “top,” if used in the present application, are used for ease of description to describe spatial relationships of an element(s) to another. Such spatially related terms encompass different orientations of the device in use or operation, in addition to the particular orientations depicted in the figures and described in the present application. For example, if an object depicted in the drawings is turned over or flipped over, elements previously described as below or beneath other elements would then be above those other elements.
The drawings show some but not all embodiments. The elements depicted in the drawings are illustrative and not necessarily to scale, and the same (or similar) reference numbers denote the same (or similar) features throughout the drawings.
The description, examples, embodiments, and drawings disclosed are illustrative only and should not be interpreted as limiting. The present invention includes the description, examples, embodiments, and drawings disclosed; but it is not limited to such description, examples, embodiments, or drawings. As briefly described above, the reader should assume that features of one disclosed embodiment can also be applied to all other disclosed embodiments, unless expressly indicated to the contrary. Modifications and other embodiments will be apparent to a person of ordinary skill in the packaging arts, and all such modifications and other embodiments are intended and deemed to be within the scope of the present invention.
Filing Document | Filing Date | Country | Kind |
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PCT/US2017/053671 | 9/27/2017 | WO | 00 |
Number | Date | Country | |
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62471665 | Mar 2017 | US |