Claims
- 1. A composition for treatment of keratinous materials, consisting essentially of in an aqueous medium, at least one silicone, at least one latex consisting of a colloidal suspension of polymer particles insoluble in said aqueous medium, and at least one suspension agent for the silicone and the latex and/or at least one thickening agent selected from the group consisting of guar gum, gum arabic, scleroglucanes, polyacrylic acids which are crosslinked or non-crosslinked, aqueous dispersions of crosslinked ammonium acrylate/acrylamide copolymers and an emulsion of neutralised acrylamide/2-methylpropane sulfonic acrylamide copolymer.
- 2. Composition according to claim 1 wherein the silicone is selected from the group consisting of polyorganosiloxanes which are soluble or insoluble in the aqueous medium and are in a form selected from the group consisting of an oil, a wax, a gum and a resin.
- 3. Composition according to claim 2 wherein the polyorganosiloxanes are selected from the group consisting of volatile silicones.
- 4. Composition according to claim 3 wherein the volatile silicones are selected from the group consisting of:
- cyclic silicones comprising three to seven silicon atoms;
- dimethylsiloxane/methylalkylsiloxane cyclopolymers;
- mixtures of cyclic silicones with organic silicon derivatives; and
- linear volatile silicones having two to nine silicon atoms and a viscosity less than or equal to 5.10.sup.-6 m.sup.2 /s at 25.degree. C.
- 5. Composition according to claim 1 wherein the silicones are non-volatile silicones selected from the group consisting of:
- (a) polyalkylsiloxanes selected from the group consisting of:
- linear polydimethylsiloxanes having trimethylsilyl terminal groups and a viscosity of between 5.10.sup.-6 and 2.5 m.sup.2 /s at 25.degree. C.
- linear polydimethylsiloxanes with dimethylsilanol terminal groups; and
- poly (C.sub.1 -C.sub.20)alkylsiloxanes;
- (b) polyalkylarylsiloxanes selected from the group consisting of:
- polydimethylmethylphenylsiloxanes, polymethylphenylsiloxanes and linear and branched polydimethyldiphenylsiloxanes having a viscosity of between 1.10.sup.-5 and 5.10.sup.2 m.sup.2 /s at 25.degree. C.;
- (c) silicone gums selected from the group consisting of polydiorganosiloxanes having molecular weights of between 200,000 and 1,000,000 used alone or mixed with a solvent;
- (d) silicone resins containing the following units:
- R'.sub.2 SiO.sub.2/2, R'SiO.sub.3/2, SiO.sub.4/2
- wherein R' represents a hydrocarbon group having one to six carbon atoms or a phenyl group; and
- (e) organomodified silicones selected from the group consisting of silicones comprising one or more organofunctional groups fixed to the siloxane chain directly and via a hydrocarbon radical.
- 6. Composition according to claim 5 wherein the silicone gums used either alone or in a mixture are selected from the group consisting of:
- poly[(dimethylsiloxane)/(methylvinylsiloxane)],
- poly[(dimethylsiloxane)/(diphenylsiloxane)],
- poly[(dimethylsiloxane)/(phenylmethylsiloxane)],
- poly[(dimethylsiloxane)/(diphenylsiloxane)/(methylvinylsiloxane)]
- and the following mixtures:
- mixtures formed from a chain end hydroxylated polydimethylsiloxane and a cyclic polydimethylsiloxane;
- mixtures formed from a polydimethylsiloxane gum and a cyclic silicone; and
- mixtures of polydimethylsiloxane in which the polymethylsiloxanes have different viscosities.
- 7. Composition according to claim 5 wherein the organomodified silicones are selected from the group consisting of the following polyorganosiloxanes:
- a) polyethyleneoxy and polypropyleneoxy groups;
- b) substituted and unsubstituted amine groups;
- c) thiol groups;
- d) carboxylate groups
- e) alkoxyl groups;
- f) hydroxyalkyl groups having the following formula: ##STR5## wherein: radicals R.sub.1, which may be identical or different, are selected from the group consisting of methyl and phenyl radicals, at least 60 mole % of radicals R.sub.1 designating methyl;
- radical R', is a divalent hydrocarbonated C.sub.2 -C.sub.18 alkylene link;
- p is between 1 and 30 inclusive;
- q is between 1 and 150 inclusive;
- g) acyloxyalkyl groups having the following formula: ##STR6## wherein: R.sub.2 represents a methyl, phenyl, --OCOR" or hydroxyl group where only one radical R.sub.2 per silicon atom is OH;
- R'.sub.2 represents methyl or phenyl, at least 60 mole % of the total of radicals R.sub.2 and R'.sub.2 representing methyl;
- R" represents a C.sub.8 -C.sub.20 alkyl or alkenyl group;
- R.sub.3 represents a divalent hydrocarbonated alkylene linear C.sub.2 -C.sub.18 radical or branched C.sub.2 -C.sub.18 radical;
- r is between 1 and 120 inclusive;
- p is between 1 and 30;
- q is zero or less than 0.5 p, p+q being between 1 and 30;
- polyorganosiloxanes of formula (II) optionally containing ##STR7## groups in proportions not exceeding 15% of the sum p+q+r; h) alkylcarboxyl groups;
- i) 2-hydroxyalkylsulfonate groups; and
- j) 2-hydroxyalkylthiosulfate groups.
- 8. Composition according to claim 2 wherein the polyorganosiloxanes are selected from the group consisting of linear polyalkylsiloxanes with trimethylsilyl terminal groups and a viscosity of between 0.2 and 2.5 m.sup.2 /s at 25.degree. C., mixtures of a chain end hydroxylated polydimethylsiloxane and a cyclic polydimethylsiloxane and mixtures of two polydimethylsiloxanes constituted by a gum and an oil wherein the gum and oil have different viscosities.
- 9. Composition according to claim 1 wherein the latex is a colloidal suspension of polymer particles obtained by polymerization or copolymerization of monomers selected from the group consisting of styrene, butadiene, acrylonitrile, chloroprene, vinyl acetate, urethanes, isoprene, isobutylene and acrylic, methacrylic, maleic, crotonic and itacronic acid and their esters or amides.
- 10. composition according to claim 9 wherein the latex which is insoluble in the aqueous medium is selected from the group consisting of homopolymers and copolymers of vinyl acetate, homopolymers and copolymers of acrylic acid, polyurethanes, carboxylated and non-carboxylated butadiene/styrene copolymers, carboxylated and non-carboxylated butadiene/acrylonitrile copolymers and styrene/acrylic ester copolymers.
- 11. Composition according to claim 1 wherein the suspension agent is selected from the group consisting of compounds having the formula:
- a) R.sub.4 X (III)
- wherein R.sub.4 is a long carbon chain aliphatic radical which may optionally include oxygen atoms and X is selected from the group consisting of a carboxylic, sulfuric and phosphoric acid residue and a radical derived from a carboxylic acid and a radical derived from an amide.
- 12. Composition according to claim 1 wherein the suspension agent is an alcohol having 27 to 44 carbon atoms and including one or two ether and/or thioether or sulfoxide groups and has the formula (IV):
- R.sub.8 --X--[C.sub.2 H.sub.3 (OH)]--CH.sub.2 --Y--R.sub.9 (IV)
- wherein:
- R.sub.8 and R.sub.9, which may be identical or different, represent linear C.sub.12 -C.sub.20 alkyl groups;
- X represents an oxygen atom, a sulfur atom or a sulfoxide group;
- Y represents an oxygen atom, a sulfur atom, a sulfoxide group or a methylene group; when Y represents a methylene group the sum of the number of carbon atoms in R.sub.8 and R.sub.9 is from 24 to 40, and when Y does not represent a methylene group the sum of the carbon atoms in R.sub.8 and R.sub.9 is from 24 to 40 inclusive when X or Y represents sulfoxide, Y or X does not designate sulfur.
- 13. Composition according to claim 1 wherein the composition comprises a mixture of a chain end hydroxylated polydimethylsiloxane and a cyclic polydimethylsiloxane, a latex which is a homopolymer or copolymer derived from acrylic acid and a thickening agent which is a crosslinked ammonium acrylate and acrylamide copolymer.
- 14. Composition according to claim 1 wherein the silicone(s) are present in proportions of between 0.1 and 50% by weight with respect to the total composition weight.
- 15. Composition according to claim 1 wherein the latex is present in the composition in proportions of between 0. 1 and 10% by weight with respect to the total composition weight.
- 16. Composition according to claim 1 wherein the thickening agent and/or suspension agent are present in the composition in proportions of between 0.1 and 20% by weight with respect to the total composition weight.
- 17. Composition according to claim 1 wherein it is in the form of a shampoo containing at least one surfactant detergent selected from the group consisting of anionic, non-ionic, amphoteric and zwitterionic surfactants and mixtures thereof.
- 18. Method of treating keratinous material wherein at least one composition as defined in claim 1 the keratinous material.
- 19. A composition as defined in claim 17 as in the form of a shampoo.
- 20. A composition as defined in claim 1 in the form of a mascara.
- 21. A composition for treatment of keratinous materials consisting essentially of, in an aqueous medium, at least one silicone, at least one latex consisting of a colloidal suspension of polymer particles consisting essentially of acrylic acid containing polymers insoluble in said aqueous medium, and at least one suspension agent for the silicone and the latex and/or at least one thickening agent which is an aqueous dispersion of crosslinked ammonium acrylate/acrylamide copolymers.
Priority Claims (1)
Number |
Date |
Country |
Kind |
91 06657 |
Jun 1991 |
FRX |
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Parent Case Info
This application is a continuation of application Ser. No. 08/609,488, filed Mar. 1, 1996, abandoned, which in turn is a continuation of application Ser. No. 08/162,007, filed May 2, 1994, abandoned. This is a 371 of PCT/FR92/00485, filed Jun. 2, 1992.
PCT Information
Filing Document |
Filing Date |
Country |
Kind |
102e Date |
371c Date |
PCT/FR92/00485 |
6/2/1992 |
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5/2/1994 |
5/2/1994 |
Publishing Document |
Publishing Date |
Country |
Kind |
WO92/21316 |
12/10/1992 |
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US Referenced Citations (3)
Foreign Referenced Citations (4)
Number |
Date |
Country |
0214626 |
May 1988 |
EPX |
0266921 |
May 1988 |
EPX |
0424260 |
Apr 1991 |
EPX |
2114580 |
Aug 1983 |
GBX |
Continuations (2)
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Number |
Date |
Country |
Parent |
609488 |
Mar 1996 |
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Parent |
162007 |
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