Silicon compound, liquid cystal composition and liquid crystal display

Abstract

Silicon compounds having a low viscosity and a low threshold voltage and improved mutual solubility, a liquid crystal composition comprising the same and a liquid crystal display using the liquid crystal composition. The silicon compound is represented by formula (1): 1

Description

BACKGROUND OF THE INVENTION

[0001] 1. Field of the Invention

[0002] The present invention relates to a novel liquid crystalline compound and a liquid crystal composition (hereinafter referred to merely as a composition according to circumstances). More specifically, it relates to a liquid crystalline compound having a SiH3 group at an end, a composition comprising the same and a liquid crystal display constituted using this composition. The term “liquid crystalline compound” used in the present invention is a general term for a compound showing a liquid crystal phase and a compound which does not show a liquid crystal phase but is useful as a component for a liquid crystal composition.

[0003] 2. Description of the Related Art

[0004] A liquid crystal display (LCD) making use of characteristics of a nematic liquid crystal phase is widely used for various uses including monitors for personal computers and portable telephones, and demand therefor has been growing large year by year. In accordance with it, improvement items for performances required for LCD have come to extend over many divergences such as an expansion in an operable temperature range, a shift to a high density and coloring of a display picture plane, an acceleration in response and an expansion in a viewing angle. Various display modes using electro-optical effects, such as a DS (Dynamic Scattering) mode, a TN (Twisted Nematic) mode, a GH (Guest Host) mode, an STN (Super Twisted Nematic) mode, an IPS (In-Plane switching) mode, a VA (Vertical Alignment) mode and OCB (Optically Compensated Bend) have been proposed in order as means for solving them.

[0005] In such situation, various characteristics are required to a composition used for LCD according to the respective display modes. First, the physical property values such as a birefringence (Δn), a dielectric anisotropy (Δε), a viscosity (η), a conductivity and an elastic constant ratio K33/K11 (K33: bend elastic constant and K11: spray elastic constant) of a liquid crystal composition are required to have values which are optimum for a display mode and a form of an element. Further, in order to achieve high-speed response in any of the LCD's shown above, a composition having a low viscosity is required, and a liquid crystalline compound has to be indispensably reduced as well in a viscosity. In addition thereto, given as common items of characteristics required to a composition are stability against moisture, light, heat and air which are usually present under an use environment and stability against an electric field and electromagnetic irradiation. Further, it is important that a liquid crystalline compound constituting a composition is chemically stable under use conditions and that they have a good solubility with each other.

[0006] In the existing state, however, it is very difficult to solve these problems only with the existing liquid crystal compounds and compositions, and it is an urgent matter to develop a novel liquid crystalline compound and composition which can meet the various requirements described above.

[0007] In recent years, development of various techniques in a liquid crystal display has been tried for the purpose of an enlargement in a picture plane. Especially, liquid crystal compositions which contribute largely to a reduction in power consumption and high speed response are desired to be developed. It is essential for a reduction in power consumption to further reduce a threshold voltage of a composition (E. Jakeman et al., Phys. Lett., 39A. 69 (1972)). Also, a low viscosity is important as well for high speed response. Various compounds have so far been developed in order to achieve these objects. For example, compounds having a silyl group in a molecule represented by the following formulas (a), (b) and (c) are known respectively according to Japanese Patent Application Laid-Open No. 9653/1994, Japanese Patent Application Laid-Open No. 2878/1995 and Japanese Patent Application Laid-Open No. 2879/1995: 2

[0008] In these compounds, silicon is substituted with three alkyl groups. For example, the present inventors measured the physical property values of a compound having a propyldimethylsilyl group represented by the following formula (d) to find the problem that it had not only a markedly high viscosity but also an unsatisfactory mutual solubility with other components constituting a composition: 3

[0009] Physical property measurement: a nematic phase-isotropic phase transition temperature (NI) and a viscosity (η) at 20° C. of a liquid crystal composition ZLI-1132 manufactured by Merck Co., Ltd. were 72.6° C. and 26.7 mPa.s respectively. Then, 15% by weight of the compound represented by the formula (d) was added to 85% by weight of this composition, and NI and η of the resulting composition were determined to find that they were 15° C. or lower and 39.7 mPa.s respectively. It has been found from this result that a composition prepared using the compound represented by the formula (d) is not only notably increased in a viscosity but also reduced in NI by 50° C. or lower. Further, the compound represented by the formula (d) was inferior in mutual soluboility with the other compositions.

SUMMARY OF THE INVENTION

[0010] An object of the present invention is to solve problems on conventional techniques and provide a novel silicon compound which has a low viscosity and a low threshold voltage and which is improved in mutual solubility, a composition comprising the same and a liquid crystal display using the above composition.

[0011] In order to achieve the objects described above, the following inventions are claimed for the grant of a patent in the present application.

[0012] [1] A silicon compound represented by formula (1):

H3Si—Y1—A1—Z1—A2&Parenopenst;Z2—A3&Parenclosest;p&Parenopenst;Z3—A4&Parenclosest;qY2  (1)

[0013] wherein Y1 is alkylene having 1 to 10 carbon, in which any —CH2— in this alkylene may be replaced by —O—, —S—, —CO—, —CH═CH— or —C—C—, but —O— and —O—, —S—and —S—, —O— and —S—, —O— and SiH3, or —S— and SiH3 are not adjacent, and at least one hydrogen in the alkylene may be replaced by halogen or —CN; Y2 is hydrogen, halogen, —CN, —C≡—C—CN, or alkyl having 1 to 10 carbon, in which any —CH2— in the alkyl may be replaced by —S—,—S—, —CO—, —CH═CH—, or —C≡C—, but —O— and —O—, —S— and —S—, or —O— and —S— are not adjacent, and any hydrogen in the alkyl may be replaced by halogen or —CN; A1, A2, A3, and A4 each are independently 1,4-cyclohexylene, 1,4-cyclohexenylene, 1,4-phenylene, or 1,4-phenylene in which any hydrogen is replaced by halogen; in which any hydrogen in 1,4-cyclohexylene or 1,4-cyclohexenylene may be replaced by halogen, any —CH2— in these rings may be replaced by —O—, but —O— and —O— are not adjacent, and any —CH═ in 1,4-phenylene may be replaced by —N═; Z1, Z2 and Z3 each are independently a single bond, —(CH2)2—, —OCH2—, —CH2O—, —CH═CH—, —C≡C—, —(CH2)4—, —O(CH2)3—, —(CH2)3O—, —COO—, —OCO—, —OCF2—, or —CF2O—; and p and q each are independently 0 or 1.

[0014] [2] The silicon compound defined in the above item [1], wherein in formula (1) described above, p and q are 0; A1 and A2 each are independently 1,4-cyclohexylene, 1,4-cyclohexylene in which one or more non-adjacent —CH2— are replaced by —O—, 1,4-phenylene, 1,4-phenylene in which any hydrogen is replaced by halogen, or pirimidine-2,5-diyl; and Z1 is a single bond, —(CH2) 2-, —CH═CH—, —C≡C—, —(CH2)4—, —COO—, —OCO—, —OCF2—, or —CF2O—.

[0015] [3] The silicon compound defined in the above item [1], wherein in formula (1) described above, p is 1, and q is 0; A1, A2 and A3 each are independently 1,4-cyclohexylene, 1,4-cyclohexylene in which one or more non-adjacent —CH2— are replaced by —O—, 1,4-phenylene, 1,4-phenylene in which any hydrogen is replaced by halogen, or pirimidine-2,5-diyl; and Z1 and Z2 each are independently a single bond, —(CH2)2—, —CH═CH—, —C≡C—, —COO—, —OCO—, —(CH2)4—, —OCF2—, or —CF2O—.

[0016] [4] The silicon compound defined in the above item [1], wherein in formula (1) described above, p and q are 1; A1, A2, A3, and A4 each are independently 1,4-cyclohexylene, 1,4-cyclohexylene in which one or more non-adjacent —CH2— are replaced by —O—, 1,4-phenylene, 1,4-phenylene in which any hydrogen is replaced by halogen, or pirimidine-2,5-diyl; and Z1, Z2 and Z3 each are independently a single bond, —(CH2)2—, —CH═CH—, —C≡C—, —COO—, —OCO—, —(CH2)4—, —OCF2—, or —CF2O—.

[0017] [5] The silicon compound defined in the above item [1], wherein in formula (1) described above, Y1 is alkylene having 1 to 10 carbon, in which any —CH2— in this alkylene may be replaced by —O— or —CH═CH—, but —O— and —O— or —O— and SiH3 are not adjacent; Y2 is alkyl having 1 to 10 carbon, in which any —CH2— in the alkyl may be replaced by —O—, —CH═CH— or —C≡C—, but —O— and —O— are not adjacent; and A1, A2, A3, and A4 each are independently 1,4-cyclohexylene, 1,4-cyclohexylene in which one or more non-adjacent —CH2— are replaced by —O—, 1,4-phenylene, or pirimidine-2,5-diyl.

[0018] [6] The silicon compound defined in the above item [1], wherein in formula (1) described above, Y1 is alkylene having 1 to 10 carbon, in which any —CH2— in the alkylene may be replaced by —O— or —CH═CH—, but —O— and —O— or —O— and SiH3 are not adjacent; Y2 is halogen, —CN, —C≡C—CN or alkyl having 1 to 10 carbon, in which any —CH2— in the alkyl may be replaced by —O—, but —O— and —O— are not adjacent, and at least one hydrogen is replaced by halogen; and A1, A2, A3, and A4 each are independently 1,4-cyclohexylene in which one or more non-adjacent —CH2— are replaced by —O—, 1,4-phenylene, 1,4-phenylene in which at least one hydrogen is replaced by halogen, or pirimidine-2,5-diyl.

[0019] [7] The silicon compound defined in the above item [1], wherein in formula (1) described above, Y1 is alkylene having 1 to 10 carbon, in which any —CH2— in the alkylene may be replaced by —O— or —CH═CH—, but —O— and —O— or —O— and SiH3 are not adjacent; Y2 is alkyl having 1 to 10 carbon, in which any —CH2— in the alkyl may be replaced by —O—, —S— or —CH═CH—, but: —O— and —O—, —S— and —S—, or —O— and —S— are not adjacent; A1, A2, A3, and A4 each are independently 1,4-cyclohexylene, 1,4-cyclohexylene in which one or more non-adjacent —CH2— are replaced by —O—, 1,4-phenylene in which a 2-position is replaced by halogen, 1,4-phenylene in which a 3-position is replaced by halogen, or 1,4-phenylene in which a 2-position and a 3-position are replaced by halogen, and one of A1, A2, A3, and A4 is always 1,4-phenylene in which a 2-position or a 3-position is replaced by halogen or 1,4-phenylene in which a 2-position and a 3-position are replaced by halogen.

[0020] [8] A liquid crystal composition comprising at least one silicon compound defined in any one of the items [1] to [7].

[0021] [9] The liquid crystal composition defined in the above item [8], comprising at least one silicon compound described in any one of the items [1] to [7] as a first component and at least one compound selected from the group of compounds represented by formulas (2), (3) and (4) as a second component: 4

[0022] wherein R1 is alkyl having 1 to 10 carbon, in which any —CH2— in the alkyl may be replaced by —O— or —CH═CH—, but —O— and —O— are not adjacent, and any hydrogen in the group may be replaced by fluorine; X1 is fluorine, Chlorine, —OCF3, —OCF2H, —CF3, —CF2H, —CFH2, —OCF2CF2H, or —OCF2CFHCF3; L1 and L2 each are independently hydrogen or fluorine; Z4 and Z5 each are independently —(CH2)2—, —(CH2)4—, —COO—, —CF2O—, —OCF2—, —CH═CH—, or a single bond; a ring B and a ring C each are independently 1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 1,4-phenylene, or 1,4-phenylene in which at least one hydrogen is replaced by fluorine; and a ring D is 1,4-cyclohexylene, 1,4-phenylene or 1,4-phenylene in which at least one hydrogen is replaced by fluorine.

[0023] [10] The liquid crystal composition defined in the above item [8], comprising at least one silicon compound described in any one of the items [1] to [7] as the first component and at least one compound selected from the group of compounds represented by formulas (5) and (6) as a second component: 5

[0024] wherein R2 and R3 each are independently alkyl having 1 to 10 carbon, in which any —CH2— in the alkyl may be replaced by —O— or —CH═CH—, but —O— and —O— are not adjacent, and any X2 hydrogen in the alkyl may be replaced by fluorine; X2 is —CN or —C≡C—CN; a ring E is 1,4-cyclohexylene, 1,4-phenylene, 1,3-dioxane-2,5-diyl, or pyrimidine-2,5-diyl; a ring F is 1,4-cyclohexylene, 1,4-phenylene, 1,4-phenylene in which hydrogen is replaced by fluorine, or pyrimidine-2,5-diyl; a ring G is 1,4-cyclohexylene or 1,4-phenylene; Z6 is —(CH2)2—, —COO—, —CF2O—, —OCF2—, or a single bond; L3, L4 and L5 each are independently hydrogen or fluorine; and a, b and c each are independently 0 or 1.

[0025] [11] The liquid crystal composition defined in the above item [8], comprising at least one silicon compound described in any one of the items [1] to [7] as the first component and at least one compound selected from the group of compounds represented by formulas (7), (8) and (9) as a second component: 6

[0026] wherein R4 and R5 each are independently alkyl having 1 to 10 carbon, in which any —CH2— in the alkyl may be replaced by —O— or —CH═CH—, but —O— and —O— are not adjacent, and any hydrogen in the alkyl may be replaced by fluorine; a ring I and a ring J each are independently 1,4-cyclohexylene or 1,4-phenylene; L6, L7, L8 and L9 each are independently hydrogen or fluorine, and all of them are not hydrogen simultaneously; and Z7 and Z8 each are independently —(CH2)2—, —COO— or a single bond.

[0027] [12] The liquid crystal composition defined in the above item [8], comprising at least one silicon compound described in any of the items [1] to [7] as the first component, at least one compound selected from the group of the compounds represented by formulas (2), (3) and (4) described in the above item [9] as the second component, and at least one compound selected from the group of compounds represented by formulas (10), (11) and (12) as a third component: 7

[0028] wherein R6 and R7 each are independently alkyl having 1 to 10 carbon, in which any —CH2— in the alkyl may be replaced by —O— or —CH═CH—, but —O— and —O— are not adjacent, and any hydrogen in the alkyl may be replaced by fluorine; a ring K, a ring M and a ring N each are independently 1,4-cyclohexylene, pyrimidine-2,5-diyl, 1,4-phenylene, or 1,4-phenylene in which hydrogen is replaced by fluorine; and Z9 and Z10 each are independently —C≡C—, —COO—, —(CH2)2—, —CH═CH— or a single bond.

[0029] [13] The liquid crystal composition defined in the above item [8], comprising at least one silicon compound described in any one of the items [1] to [7] as the first component, at least one compound selected from the group of the compounds represented by formulas (5) and (6) described in the above item [10] as the second component, and at least one compound selected from the group of the compounds represented by formulas (10), (11) and (12) described in the above item [12] as the third component.

[0030] [14] The liquid crystal composition defined in the above item [8], comprising at least one silicon compound described in any one of the items [1] to [7] as the first component, at least one compound selected from the group of the compounds represented by formulas (7), (8) and (9) described in the above item [11] as the second component and at least one compound selected from the group of the compounds represented by formulas (10), (11) and (12) described in the above item [12] as the third component.

[0031] [15] The liquid crystal composition defined in the above item [8], comprising at least one silicon compound described in any of the items [1] to [7] as the first component, at least one compound selected from the group of the compounds represented by formulas (2), (3) and (4) described in the above item [9] as the second component, at least one compound selected from the group of the compounds represented by formulas (5) and (6) described in the above item [10] as the third component, and at least one compound selected from the group of the compounds represented by formulas (10), (11) and (12) described in the above item [12] as a fourth component.

[0032] [16] A liquid crystal composition comprising at least one liquid crystal composition defined in the items [8] and further comprising at least one optically active compound.

[0033] [17] A liquid crystal display using the liquid crystal composition defined in any of the items [8] to [15].

[0034] The compound (1) of the present invention is a compound having a SiH3 group at an end and 2 to 4 six-membered rings (hereinafter referred to as a bicyclic system to a tetracyclic system), and it is physically and chemically very stable under conditions on which a display is used. Further, six-membered rings, a bonding group and side chains constituting the compound (1) having a good mutual solubility, a low viscosity and a low threshold voltage are suitably selected, whereby the desired physical property values can optionally be controlled. The preferred compounds are shown below. 89101112131415161718192021222324252627282930

[0035] Y1 and Y2 mean the same as those described in the item [1] described above.

[0036] Capable of being given as preferred Y1 is alkylene, alkyleneoxy, alkyleneoxyalkylene, alkenylene, alkenyleneoxy, alkenyleneoxyalkylene or alkyleneoxyalkenylene which has 1 to 10 carbon atoms. Among them, the most preferred group includes methylene, ethylene, propylene, butylene, pentylene, hexylene, heptylene, methyleneoxy, ethyleneoxy, propyleneoxy, butyleneoxy, pentyleneoxy, hexyleneoxy, heptyleneoxy, methyleneoxymethylene, ethyleneoxymethylene, propyleneoxymethylene, methyleneoxyethylene, ethyleneoxyethylene, methyleneoxypropylene, ethyleneoxypropylene, vinylene, 1-propenylene, 2-propenylene, 1-butenylene, 2-butenylene, 3-butenylene, 2-prpenyleneoxy and 2-butenyleneoxy.

[0037] Capable of being given as preferred Y2 is alkyl alkoxy, alkoxyalkyl, alkenyl, alkenyloxy, alkenyloxyalkyl or alkyloxyalkenyl which has 1 to 10 carbon atoms, alkynyl, fluoroalkyl, fluoroalkyloxy, halogen, cyano and cyanoalkynyl. Among them, the particularly preferred groups include methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, methoxy, ethoxy, propoxy, butoxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, methoxymethyl, ethoxymethyl, propoxymethyl, butoxymethyl, methoxyethyl, ethoxyethyl, propoxyethyl, methoxypropyl, ethoxypropyl, propoxypropyl, vinyl, 1-propenyl, 2-propenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-pentenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl, 2-propenyloxy, 2-butenyloxy, 2-poentenyloxy, 4-pentenyloxy, 2-propenyloxymethyl, 2-propenyloxyethyl, 3-butenyloxymethyl, 3-methoxy-1-propenyl, 3-methoxy-1-pentenyl, 3-methoxy-2-pentenyl, ethynyl, 1-propynyl, 2-propynyl, 1-butynyl, 2-butynyl, 3-butynyl, 1-pentynyl, 2-pentynyl, 3-pentynyl, 4-pentynyl, —F, —Cl, —CN, —C≡C—CN, —CF3, —OCF3 and —OCF2H.

[0038] The compound in which one or both of Y1 and Y2 are optically active groups is particularly useful as a chiral dopant. Addition thereof to the composition makes it possible to prevent reverse twist domain from being produced.

[0039] The compound (1) can suitably be used as a component for a composition used for various displays including a TN type, an STN type, a TFT type and so on. Among the compounds (1), the bicyclic and tricyclic compounds show a low viscosity, and the tricyclic and tetracyclic compounds show a high isotropic phase transition temperature.

[0040] The compound (1) having two or more cyclohexane rings in a molecule shows a high isotropic phase transition temperature, a small Δn and a low viscosity. Further, the compound (1) having a dioxane ring or a pyrimidine ring shows a relatively large Δε.

[0041] The compound (1) having at least one benzene ring in a molecule shows a relatively large Δn and a high liquid crystal orientational parameter and therefore is excellent. In particular, the compound (1) having two or more benzene rings in a molecule shows a particularly large Δn, a broad liquid crystal temperature range and a chemically high stability.

[0042] The compound (1) which is substituted with groups such as —F, —CN, —CF3, —OCF3 and —OCF2H so that the dipole moment grows larger in a molecular long axis direction has a large positive Δε, a high isotropic phase transition temperature and a relatively low viscosity. The compound in which these groups are substituted on a benzene ring shows an excellent stability and a particularly large positive Δε. Further, the compound in which plural groups are substituted on a benzene ring shows a larger Δε.

[0043] The compound (1) which is substituted with —F so that the dipole moment grows larger in a molecular short axis direction has a large negative Δε, a high isotropic phase transition temperature and a relatively low viscosity. The compound in which —F is substituted on a lateral side of a benzene ring shows an excellent chemical stability and a large negative Δε. The compound having two or more —F shows a particularly large negative Δε.

[0044] The compound (1) having double bonds on Z1, Z2 or Z3 shows a broad liquid crystal temperature range and a large elastic constant ratio, and therefore it is suitably used as a composition for STN. The compound (1) having a triple bond shows a large Δε.

[0045] These matters make it possible to provide a novel liquid crystalline compound having desired physical properties by suitably selecting rings, side chains and/or bonding groups. Further, the compound (1) in which atoms constituting it are substituted with the isotopes shows the same characteristics and therefore can be used as well.

[0046] The composition of the present invention shall be explained below. This composition preferably contains 0.1 to 99.9% by weight of at least one compound (1) (hereinafter referred to as a first component) in order to allow excellent characteristics to be revealed. The amount is more preferably 1 to 80% by weight and further preferably 1 to 60% by weight.

[0047] The composition may comprise only the first component. It is allowed to be added as the second component, which is at least one compound (hereinafter referred to as a second A component) selected from the compounds (2), (3) and (4) described above or at least one compound (hereinafter referred to as a second B component) selected from the compounds (5) and (6) to the first component. At least one compound selected from the compounds (10), (11) and (12) can also be added as the third component for the purpose of con-trolling a threshold voltage, a liquid crystal phase temperature range, a birefringence, a dielectric anisotropy and a viscosity.

[0048] The compounds which are the respective components for the composition may be the analogues thereof comprising the isotopes of the respective elements since there is no large difference between the physical characteristics thereof.

[0049] In the second A component described above, the suitable examples of the compound (2) are (2-1) to (2-9); the suitable examples of the compound (3) are (3-1) to (3-97); and the suitable examples of the compound (4) are (4-1) to (4-33). 31323334353637383940414243444546

[0050] In the formulas, R1 and X1 mean the same as those described in the item [9] described above.

[0051] These compounds (2), (3) and (4) have a positive dielectric anisotropy and are very excellent in heat stability and chemical stability, so that they are used primarily for a composition for TFT. When preparing a composition for TFT, an amount of the above compound falls in a range of 0.1 to 99.9% by weight, preferably 10 to 97% by weight and more preferably 40 to 95% by weight based on the whole weight of a composition. The compounds (10) to (12) may further be added to the composition for the purpose of controlling a viscosity.

[0052] In the second B component described above, the suitable examples of the compounds (5) to (6) are (5-1) to (5-58) and (6-1) to (6-3) respectively. 474849505152

[0053] In the formulas, R2, R3 and X2 mean the same as those described in the item [10] described above.

[0054] These compounds (5) and (6) have a very large positive dielectric anisotropy, so that they are used mainly for the compositions for STN or TN. These compounds are used particularly for the purpose of reducing a threshold voltage. They are used as well for the purposes of controlling a viscosity and a birefringence and expanding a liquid crystal phase temperature range and also for the purpose of improving steepness. When preparing a composition for STN or TN, a use amount of the compounds (5) and (6) falls in a range of 0.1 to 99.9% by weight, preferably 10 to 97% by weight and more preferably 40 to 95% by weight. A third component described later can further be added for the purpose of controlling a threshold voltage, a liquid crystal phase temperature range, a birefringence, a dielectric anisotropy and a viscosity.

[0055] When preparing a composition having a negative dielectric anisotropy which is suited for a vertical aligning En mode (VA mode), preferably mixed is at least one compound (hereinafter referred to as a second C component) selected from the compounds (7) to (9). The suitable examples of the compounds (7) to (9) in the second C component are (7-1) to (7-3), (8-1) to (8-5) and (9-1) to (9-3) respectively. 5354

[0056] In the formulas, R4 and R5 mean the same as those described in the item [11] described above).

[0057] The compounds (7) to (9) have a negative dielectric anisotropy. The compound (7) having two six-membered rings is used mainly for the purpose of controlling a threshold voltage, a viscosity or a dielectric anisotropy. The compound (8) is used for the purpose of elevating the clearing point to expand a nematic range, reducing a threshold voltage and increasing a dielectric anisotropy.

[0058] The compounds (7) to (9) are used for a composition for a VA mode having a negative value of the dielectric anisotropy. If an amount thereof is increased, a composition is reduced in a threshold voltage but increased in a viscosity. Accordingly, as small amount as possible is preferred as long as a required value of the threshold voltage is satisfied. An amount of the compounds (7) to (9) is preferably 40% by weight or more, more preferably 50 to 90% by weight in the case of uses for a VA mode.

[0059] The compounds (7) to (9) are mixed in a certain case with a composition having a positive dielectric anisotropy for the purpose of controlling an elastic constant and a voltage transmission curve of the composition. An amount thereof is preferably 30% by weight or less.

[0060] In the third component described above, the suitable examples of the compounds (10) to (12) are (10-1) to (10-11), (11-1) to (11-12) and (12-1) to (12-6) respectively. 555657

[0061] In the formulas, R6 and R7 mean the same as those described in the item [12] described above.

[0062] The compounds (10) to (12) have a small absolute value of a dielectric anisotropy and are close to neutrality. The compound (10) is used mainly for the purpose of controlling a viscosity or a dielectric anisotropy. Further, the compounds (11) and (12) are used for the purpose of elevating a clearing point to broaden a nematic range or controlling a dielectric anisotropy. If a use amount of the compounds (10) to (12) is increased, a composition is elevated in a threshold voltage and reduced in a viscosity. Accordingly, they are used preferably in a large amount as long as a required value of the threshold voltage is satisfied. An amount of the compounds (10) to (12) is 40% by weight or less, preferably 35% by weight or less in the case of uses for TFT. An amount in uses for STN or TN is 70% by weight or less, preferably 60% by weight or less.

[0063] A composition of the present invention contains 0.1 to 99% by weight of at least one of the compounds (1), whereby the excellent characteristics are revealed.

[0064] A composition is prepared by a publicly known method, for example, by dissolving various components by heating. Suitable additives are added if necessary, whereby the composition is optimized according to intended uses. Such additives are well known by a person averagely skilled in the art, and described in detail in literatures. A chiral dopant induces a spiral structure of liquid crystal to provide distortion to thereby prevent inverse distortion. The following optically active compounds can be given as the examples of the chiral dopant. 58

[0065] Usually, in the composition of the present invention, these optically active compounds are added to control a pitch in distortion. The pitch in distortion falls preferably in a range of 40 to 200 μm in the case of the compositions for TFT and TN. In the case of the composition for STN, it falls preferably in a range of 6 to 20 μm. Further, in the case of the composition for a bistable TN mode, it falls preferably in a range of 1.5 to 4 μm. Two or more kinds of the optically active compounds may be added for the purpose of controlling a temperature dependency of the pitch.

[0066] The composition of the present invention can also be used as a liquid crystal composition for a G-H mode by adding dichroic dyes such as merocyanines, styryls, azo, azomethines, azoxy, quinophthalones, anthraquinones, tetrazines, or the like. The composition according to the present invention can also be used as a composition for NCAP prepared by micro-capsulizing nematic liquid crystal and Polymer Dispersed Liquid Crystal Display (PDLCD) prepared by forming a three-dimensional network polymer in the liquid crystal, for example, Polymer Network Liquid Crystal Display (PNLCD). It can also be used as a composition for Electrically Controlled Birefringence (ECB) mode and a DS mode The compound (1) is produced by a conventional organic synthetic method. Suitably selected and combined are publicly known and conventional synthetic methods described in publications and magazines such as, for example, Organic Synthesis (John Wiley & Sons), Organic Reactions (John Wiley & Sons), Comprehensive Organic Synthesis (Pergamon Press) and Shin-Zikken Kagaku Koza (Maruzen).

[0067] Suitably selected and combined for introducing an Si part are publicly known and conventional synthetic methods described in publications and magazines such as, for example, Silicon in Organic Synthesis (Butterworths), Silicon Reagents for Organic Synthesis (Springer-Verlag) and Silicon Reagents in Organic Synthesis (Academic Press).

[0068] Routes shown below can be given as the specific examples. 59

[0069] Y1, Y2, A1, A2, A3, A4, Z1, Z2, Z3, p and q each described above are the same as those described in the item [1] described above. Q1 is halogen, and Q2 is halogen or alkoxy. Mt is lithium, potassium, halogenated magnesium or halogenated zinc.

[0070] First, the compound (11) is reacted with metal such as magnesium and various organic metal reagents such as alkyllithium compounds, alkylzinc compounds, alkylpotassium compounds and alkylcadmium compounds, whereby an organic metal reagent (12) is prepared. This is reacted with tretrasubstituted silane such as tetraalkoxysilane and tetrahalosilane to obtain a silicon compound (13). The compound (13) is subjected to reducing treatment with a suitable reducing agent such as lithium aluminum hydride, diisobutylaluminum hydride, sodium borohydride, sodium cyanoborohydride and diborane-THF, whereby it is derived into a compound (1). When other substituents in the compound (13) are reduced with these reducing agents, suitable additives are used or the reaction conditions are controlled to selectively reduce only SiQ23.

EXAMPLES

[0071] The present invention shall be explained below in more details with reference to examples, but the present invention shall not be restricted by these examples. The structures of the compounds were confirmed by means of a nuclear magnetic resonance spectrum and a mass spectrum (hereinafter abbreviated as MS). M+ in MS represents a molecular ion peak. C shows a crystal phase; S shows a smectic phase; N shows a nematic phase; and Iso shows an isotropic liquid phase. A unit of a phase transition temperature is ° C. in all examples.

Example 1

[0072] Production of trans-1-pentyl-4-(trans-4-silylmethylcyclohexyl)cyclohexane (compound (No. 742) in which in Formula (1), Y1 is methylene; Y2 is pentyl; A1 and A2 are trans-1,4-cyclohexylene; Z1 is a single bond; p and q are 0)

[0073] First Step:

[0074] A Grignard reagent was prepared from 100 ml of THF, magnesium (120 mmole) and trans-1-pentyl-4-(trans-4-chloromethylcyclohexyl)cyclohexane (100 mmole) under nitrogen atmosphere. A THF 100 ml solution of tetramethoxysilane (150 mmole) was heated to 65° C., and the Grignard reagent was added dropwise thereto. Further, the solution was stirred at the same temperature for 2 hours, and after left standing for cooling, the reaction mixture was filtered. The solvent was distilled off, and then trans-1-pentyl-4-(trans-4-trimethoxysilylmethyl-cyclohexyl)cyclohexane (65 mmole) was obtained by distillation under reduced pressure.

[0075] Second Step:

[0076] Lithium aluminum hydride (59 mmole) was suspended in 50 ml of THF on an ice bath under nitrogen atmosphere, and a THF 50 ml solution of trans-1-pentyl-4-(trans-4-trimethoxymethylsilylcyclohexyl)cyclohexane (65 mmole), which was obtained in the reaction of the first step, was added dropwise thereto. After stirring for one hour, water was added to the reaction mixture, and insoluble matters were filtered off. The separated organic layer was dried on anhydrous magnesium sulfate, and the solvent was distilled off under reduced pressure. The residue was purified with a silica gel column chromatography (eluent:heptane), and then it was recrystallized from heptane to obtain trans-1-pentyl-4-(trans-4-silylmethylcyclohexyl)cyclohexane (30 mmole). Phase transition temperature: Cr −0.9 S 74.2 Iso

[0077] MS: m/e=280 (M+)

Example 2

[0078] Production of 1-trifluoromethoxy-4-(trans-4-(trans-4-silylethylcyclohexyl)cyclohexyl)benzene (compound (No. 34) in which in Formula (1), Y1 is ethylene; Y2 is —OCF3; A1 and A2 are trans-1,4-cyclohexylene; A3 is 1,4-phenylene; Z1 and Z2 are single bonds; p is 1, and q is 0)

[0079] First Step:

[0080] A Grignard reagent was prepared from 100 ml of THF, magnesium (120 mmole) and 1-trifluoromethoxy-4-(trans-4-(trans-4-chloroethylcyclohexyl)cyclohexyl)benzene (100 mmole) under nitrogen atmosphere. A THF 100 ml solution of tetramethoxysilane (150 mmole) was heated to 65° C., and the Grignard reagent was added dropwise thereto. The solution was stirred at the same temperature for 2 hours, and after left standing for cooling, the reaction mixture was filtered. The solvent was distilled off, and then 1-trifluoromethoxy-4-(trans-4-(trans-4-trimethoxysilylethylcyclohexyl)cyclohexyl)benzene (57 mmole) was obtained by distillation under reduced pressure.

[0081] Second Step:

[0082] Lithium aluminum hydride (51 mmole) was suspended in 50 ml of THF on an ice bath under nitrogen atmosphere, and a THF 50 ml solution of 1-trifluoromethoxy-4-(trans-4-(trans-4-trimethoxysilylethylcyclohexyl)cyclohexyl)-benzene (57 mmole), which was obtained in the reaction of the first step, was added dropwise thereto. After adding dropwise, the solution was stirred for one hour, and water was added to the reaction mixture, followed by filtering off insoluble matters. The separated organic layer was dried on anhydrous magnesium sulfate, and the solvent was distilled off under reduced pressure. The residue was purified with a silica gel column chromatography (eluent: mixed solvent of heptane/toluene), and it was recrystallized from heptane to obtain 1-trifluoromethoxy-4-(trans-4-(trans-4silylethylcyclohexyl)cyclohexyl)benzene (26 mmole).

[0083] MS: m/e=384 (M+)

Example 3

[0084] Production of 1-ethoxy-2,3-difluoro-4-(trans-4-silylbutylcyclohexyl)benzene (compound (No. 676) in which in Formula (1), Y1 is butylene; Y2 is ethoxy; A1 is trans-1,4-cyclohexylene, and A2 is 2,3-difluoro-1,4-phenylene; Z1 is a single bond; p and q are 0)

[0085] First Step:

[0086] A Grignard reagent was prepared from 100 ml of THF, magnesium (120 mmole) and 1-ethoxy-2,3-difluoro-4-(trans-4-chlorobutylcyclohexyl)benzene (100 mmole) under nitrogen atmosphere. A THF 100 ml solution of tetramethoxysilane (150 mmole) was heated to 65° C., and the Grignard reagent was added dropwise thereto. Further, the solution was stirred at the same temperature for 2 hours, and after left standing for cooling, the reaction mixture was filtered. The solvent was distilled off, and then 1-ethoxy-2,3-difluoro-4-(trans-4trimethoxysilyl-butylcyclohexyl)benzene (58 mmole) was obtained by distillation under reduced pressure.

[0087] Second Step:

[0088] Lithium aluminum hydride (52 mmole) was suspended in 50 ml of THF on an ice bath under nitrogen atmosphere, and a THF 50 ml solution of 1-ethoxy-2,3-difluoro-4-(trans-4-trimethoxysilylbutylcyclohexyl)benzene (58 mmole), which was obtained in the reaction of the first step, was added dropwise thereto. After adding dropwise, the solution was stirred for one hour, and water was added to the reaction mixture, followed by filtering off insoluble matters. The separated organic layer was dried on anhydrous magnesium sulfate, and the solvent was distilled off under reduced pressure. The residue was purified with a silica gel column chromatography (eluent: mixed solvent of heptane/toluene), and it was recrystallized from heptane to obtain 1-ethoxy-2,3-difluoro-4-(trans-4-silylbutylcyclohexyl)benzene (25 mmole).

[0089] MS: m/e=326 (M+)

Example 4

[0090] Production of 2-fluoro-1-(4-propylphenyl)-4-(4-silylethylphenyl)benzene (compound (No. 861) in which in Formula (1), Y1 is ethylene; Y2 is propyl; A1 and A3 are 1,4-phenylene; A2 is 2-fluoro-1,4-phenylene; Z1 and Z2 are single bonds; p is 1, and q is 0)

[0091] First Step:

[0092] A Grignard reagent was prepared from 100 ml of THF, magnesium (120 mmole) and 2-fluoro-1-(4-propylphenyl)-4-(4-chloroethylphenyl)benzene (100 mmole) under nitrogen atmosphere. A THF 100 ml solution of tetramethoxysilane (150 mmole) was heated to 65° C., and the Grignard reagent was added dropwise thereto. Further, the solution was stirred at the same temperature for 2 hours, and after left standing for cooling, the reaction mixture was filtered. The solvent was distilled off, and then 2-fluoro-1-(4-propylphenyl)-4-(4-trimethoxysilyl-ethylphenyl)benzene (59 mmole) was obtained by distillation under reduced pressure.

[0093] Second Step:

[0094] Lithium aluminum hydride (53 mmole) was suspended in 50 ml of THF on an ice bath under nitrogen atmosphere, and a THF 50 ml solution of 2-fluoro-(4-propylphenyl)-4-1-(4-trimethoxysilylethylphenyl)benzene (59 mmole), which was obtained in the reaction of the first step, was added dropwise thereto. After adding dropwise, the solution was stirred for one hour, and water was added to the reaction mixture, followed by filtering off insoluble matters. The separated organic layer was dried on anhydrous magnesium sulfate, and the solvent was distilled off under reduced pressure. The residue was purified with a silica gel column chromatography (eluent: heptane), and it was recrystallized from heptane to obtain 2-fluoro-1-(4-propylphenyl)-4-(4-silylethylphenyl)benzene (22 mmole).

[0095] MS: m/e=348 (M+)

[0096] The following compounds were produced according to the methods of Examples 1 to 4.

	Y1	A1	Z1	A2	Z2	A3	Z3	A4	Y2
1	60	61	—	62					—F
2	—CH2O—	63	—	64					—Cl
3	65	66	—	67					—OCF2H
4	—C4H8—	68	—	69					—OCF3
5	—C3H6O—	70	—	71					—F
6	72	73	—	74					—OCF2H
7	75	76	—	77					—CF3
8	78	79	—	80					—F
9	81	82	—	83					—OCF3
10	84	85	—	86					—F
11	87	88	—	89					—CF3
12	90	91	—	92					—OCF3
13	93	94	—	95					—F
14	96	97	—	98					—OCF2H
15	—CH2O—	99	—	100					—F
16	101	102	103	104					—OCF3
17	—CH2O—	105	106	107					—OCF2CF3
18	—C3H6O—	108	109	110					—CF3
19	111	112	113	114					—OCF3
20	115	116	117	118					—F
21	119	120	121	122					—OCF2
22	123	124	125	126					—CF3
23	127	128	129	130					—F
24	131	132	133	134					—OCF3
25	135	136	137	138					—F
26	—C2H4O—	139	140	141	—CF2H
27	142	143	144	145					—OCF3
28	146	147	148	149					—F
29	—CH2—	150	151	152					—OCF2H
30	153	154	155	156					—F
31	157	158	—	159	—	160			—F
32	—CH2O—	161	—	162	—	163			—Cl
33	164	165	—	166	—	167			—OCF3
34	168	169	—	170	—	171			—OCF3
35	172	173	—	174	—	175			—F
36	176	177	—	178	—	179			—OCF3
37	—C2H4O—	180	—	181	—	182			—CF3
38	183	184	—	185	—	186			—OCF3
39	—C3H6—	187	—	188	—	189			—OCF3
40	190	191	—	192	—	193			—F
41	—C2H4—	194	—	195	—	196			—OCF2H
42	197	198	—	199	—	200			—OCF3
43	201	202	—	203	—	204			—F
44	—C3H6—	205	—	206	—	207			—OCF2H
45	208	209	—	210	—	211			—OCF2H
46	212	213	—	214	215	216			—OCF2H
47	217	218	—	219	220	221			—F
48	—CH2O—	222	—	223	224	225			—CF3
49	226	227	—	228	229	230			—OCF3
50	231	232	—	233	234	235			—F
51	236	237	—	238	239	240			—OCF3
52	241	242	—	243	244	245			—CF2H
53	246	247	—	248	249	250			—F
54	—C3H6O—	251	—	252	253	254			—OCF3
55	255	256	—	257	258	259			—F
56	260	261	—	262	263	264			—OCF3
57	265	266	—	267	268	269			—OCF3
58	270	271	—	272	273	274			—F
59	—CH2—	275	—	276	277	278			—OCF2H
60	—C2H4O—	279	—	280	281	282			—F
61	283	284	285	286					—OCF3
62	287	288	289	290					—F
63	291	292	293	294					—OCF3
64	295	296	297	298					—F
65	299	300	301	302					—F
66	303	304	—	305	306	307			—OCF3
67	308	309	—	310	311	312			—Cl
68	313	314	—	315	316	317			—OCF3
69	—C3H6O—	318	—	319	320	321			—F
70	322	323	—	324	325	326			—F
71	327	328	—	329	330	331			—F
72	332	333	—	334	335	336			—OCF3
73	337	338	—	339	340	341			—F
74	—CH2—	342	—	343	344	345			—OCF2H
75	—C2H4O—	346	—	347	348	349			—F
76	350	351	352	353	—	354			—Cl
77	355	356	357	358	—	359			—OCF3
78	360	361	362	363	—	364			—CF2H
79	—CH2O—	365	366	367	—	368			—OCF3
80	369	370	371	372	—	373			—F
81	374	375	376	377	—	378			—OCF3
82	—C3H6O—	379	380	381	—	382			—OCF2H
83	383	384	385	386	—	387			—F
84	388	389	390	391	—	392			—OCF3
85	393	394	395	396	—	397			—F
86	398	399	400	401	—	402			—CF3
87	403	404	405	406	—	407			—OCF3
88	408	409	410	411	—	412			—F
89	—CH2—	413	414	415	—	416			—OCF2H
90	—C2H4O—	417	418	419	—	420			—F
91	421	422	423	424	—	425			—F
92	426	427	428	429	—	430			—OCF3
93	—CH2O—	431	432	433	—	434			—CF2H
94	435	436	437	438	—	439			—OCF3
95	440	441	442	443	—	444			—F
96	445	446	447	448	—	449			—OCF2H
97	—C3H6O—	450	451	452	—	453			—OCF2H
98	454	455	456	457	—	458			—F
99	459	460	461	462	—	463			—OCF3
100	464	465	466	467	—	468			—F
101	469	470	471	472	—	473			—OCF2H
102	474	475	476	477	—	478			—OCF3
103	479	480	481	482	—	483			—F
104	—CH2—	484	485	486	—	487			—CF3
105	488	489	490	491	—	492			—F
106	493	494	—	495	—	496			—F
107	497	498	—	499	—	500			—Cl
108	501	502	—	503	—	504			—OCF3
109	505	506	—	507	—	508			—OCF3
110	509	510	—	511	—	512			—F
111	513	514	—	515	—	516			—OCF3
112	517	518	—	519	—	520			—OCF2H
113	521	522	—	523	—	524			—F
114	—CH2O—	525	—	526	—	527			—OCF3
115	528	529	—	530	—	531			—F
116	—C2H4O—	532	—	533	—	534			—CF3
117	—CH2—	535	—	536	—	537			—OCF3
118	538	539	—	540	—	541			—F
119	542	543	—	544	—	545			—OCF2H
120	—C3H6O—	546	—	547	—	548			—F
121	549	550	551	552	—	553			—OCF3
122	554	555	556	557	—	558			—Cl
123	559	560	561	562	—	563			—F
124	564	565	566	567	—	568			—OCF3
125	569	570	571	572	—	573			—F
126	574	575	576	577	—	578			—OCF3
127	579	580	581	582	—	583			—CF2H
128	584	585	586	587	—	588			—F
129	—CH2O—	589	590	591	—	592			—OCF3
130	593	594	595	596	—	597			—F
131	—C2H4O—	598	599	600	—	601			—OCF3
132	—C2H4—	602	603	604	—	605			—OCF3
133	606	607	608	609	—	610			—F
134	611	612	613	614	—	615			—OCF2H
135	—C3H6O—	616	617	618	—	619			—F
136	620	621	622	623	—	624			—OCF3
137	625	626	627	628	—	629			—F
138	630	631	632	633	—	634			—OCF3
139	635	636	637	638	—	639			—OCF3
140	640	641	642	643	—	644			—F
141	645	646	—	647	648	649			—OCF3
142	650	651	—	652	653	654			—OCF2H
143	655	656	—	657	658	659			—OCF3
144	—CH2O—	660	—	661	662	663			—F
145	664	665	—	666	667	668			—F
146	—C2H4O—	669	670	671	—	672			—F
147	—C4H8—	673	674	675	—	676			—OCF3
148	677	678	679	680	—	681			—F
149	682	683	684	685	—	686			—OCF3
150	687	688	689	690	—	691			—F
151	692	693	—	694	695	696			—OCF3
152	697	698	—	699	700	701			—F
153	—CH2O—	702	—	703	704	705			—CF3
154	706	707	—	708	709	710			—OCF3
155	711	712	—	713	714	715			—F
156	716	717	—	718	719	720			—OCF3
157	721	722	—	723	724	725			—CF3
158	726	727	—	728	729	730			—F
159	—CH2O—	731	—	732	733	734			—OCF3
160	735	736	—	737	738	739			—F
161	740	741	—	742	743	744			—OCF3
162	745	746	—	747	748	749			—OCF3
163	750	751	—	752	753	754			—F
164	—CH2—	755	—	756	757	758			—OCF2H
165	—C2H4O—	759	—	760	761	762			—F
166	763	764	—	765	766	767			—OCF3
167	—CH2O—	768	—	769	770	771			—F
168	772	773	—	774	775	776			—CF3
169	777	778	—	779	780	781			—OCF3
170	782	783	—	784	785	786			—F
171	787	788	—	789	790	791			—OCF3
172	792	793	—	794	795	796			—OCF2H
173	797	798	—	799	800	801			—F
174	802	803	—	804	805	806			—OCF3
175	—C3H6O—	807	—	808	809	810			—F
176	811	812	—	813	814	815			—OCF3
177	816	817	—	818	819	820			—OCF3
178	821	822	—	823	824	825			—F
179	—C2H4O—	826	—	827	828	829			—OCF2H
180	—C4H8—	830	—	831	832	833			—F
181	834	835	—	836	—	837			—OCF3
182	838	839	—	840	—	841			—F
183	842	843	—	844	—	845			—CF3
184	846	847	—	848	—	849			—OCF3
185	850	851	—	852	—	853			—F
186	854	855	—	856	—	857			—OCF3
187	858	859	—	860	—	861			—OCF2H
188	862	863	—	864	—	865			—F
189	—C3H6—	866	—	867	—	868			—F
190	—CH2O—	869	—	870	—	871			—OCF3
191	872	873	—	874	—	875			—F
192	—CH2—	876	—	877	—	878			—OCF3
193	879	880	—	881	—	882			—F
194	883	884	—	885	—	886			—F
195	887	888	—	889	—	890			—F
196	891	892	893	894	—	895			—OCF3
197	896	897	898	899	—	900			—F
198	901	902	903	904	—	905			—F
199	906	907	908	909	—	910			—OCF3
200	911	912	913	914	—	915			—F
201	916	917	918	919	—	920			—OCF3
202	—CH2—	921	922	923	—	924			—CF2H
203	925	926	927	928	—	929			—F
204	930	931	932	933	—	934			—OCF3
205	—CH2O—	935	936	937	—	938			—OCF3
206	939	940	941	942	—	943			—F
207	—CH2—	944	945	946	—	947			—OCF3
208	948	949	950	951	—	952			—F
209	953	954	955	956	—	957			—F
210	958	959	960	961	—	962			—F
211	963	964	—	965	966	967			—OCF3
212	968	969	—	970	971	972			—F
213	—CH2O—	973	—	974	975	976			—CF3
214	977	978	—	979	980	981			—OCF3
215	982	983	—	984	985	986			—F
216	987	988	—	989	990	991			—OCF3
217	992	993	—	994	995	996			—OCF2CFHCF3
218	997	998	—	999	1000	1001			—F
219	1002	1003	—	1004	1005	1006			—OCF3
220	—CH2—	1007	—	1008	1009	1010			—OCF3
221	1011	1012	—	1013	1014	1015			—F
222	1016	1017	—	1018	1019	1020			—OCF3
223	1021	1022	—	1023	1024	1025			—F
224	—C3H6—	1026	—	1027	1028	1029			—OCF3
225	1030	1031	—	1032	1033	1034			—F
226	1035	1036	—	1037	—	1038			—F
227	1039	1040	—	1041	—	1042			—Cl
228	1043	1044	—	1045	—	1046			—OCF3
229	1047	1048	—	1049	—	1050			—F
230	1051	1052	—	1053	—	1054			—OCF3
231	1055	1056	—	1057	—	1058			—OCF2H
232	1059	1060	—	1061	—	1062			—F
233	1063	1064	—	1065	—	1066			—F
234	1067	1068	—	1069	—	1070			—OCF3
235	—CH2O—	1071	—	1072	—	1073			—F
236	1074	1075	—	1076	—	1077			−OCF3
237	1078	1079	—	1080	—	1081			—OCF3
238	1082	1083	—	1084	—	1085			—F
239	1086	1087	—	1088	—	1089			—OCF3
240	1090	1091	—	1092	—	1093			—CF3
241	1094	1095	—	1096	—	1097			—F
242	1098	1099	—	1100	—	1101			—F
243	1102	1103	—	1104	—	1105			—OCF3
244	1106	1107	—	1108	—	1109			—F
245	1110	1111	—	1112	—	1113			—OCF3
246	1114	1115	—	1116	—	1117			—OCF2H
247	1118	1119	—	1120	—	1121			—F
248	1122	1123	—	1124	—	1125			—F
249	1126	1127	—	1128	—	1129			—OCF3
250	—C3H6O—	1130	1131	1132	—	1133			—F
251	1134	1135	1136	1137	—	1138			—OCF3
252	1139	1140	1141	1142	—	1143			—OCF3
253	1144	1145	1146	1147	—	1148			—F
254	1149	1150	1151	1152	—	1153			—OCF3
255	1154	1155	1156	1157	—	1158			—CF3
256	1159	1160	—	1161	1162	1163			—OCF3
257	1164	1165	—	1166	1167	1168			—F
258	1169	1170	—	1171	1172	1173			—CF3
259	1174	1175	—	1176	1177	1178			—OCF3
260	1179	1180	—	1181	1182	1183			—F
261	—C3H6O—	1184	—	1185	1186	1187			—OCF3
262	1188	1189	—	1190	1191	1192			—CF3
263	1193	1194	—	1195	1196	1197			—F
264	—C2H4—	1198	—	1199	1200	1201			—OCF3
265	1202	1203	—	1204	1205	1206			—F
266	1207	1208	—	1209	1210	1211			—OCF3
267	1212	1213	—	1214	1215	1216			—OCF3
268	1217	1218	—	1219	1220	1221			—F
269	—CH2—	1222	—	1223	1224	1225			—OCF2H
270	1226	1227	—	1228	1229	1230			—F
271	1231	1232	—	1233	1234	1235			—OCF3
272	1236	1237	—	1238	1239	1240			—F
273	1241	1242	—	1243	1244	1245			—CF3
274	1246	1247	—	1248	1249	1250			—OCF3
275	1251	1252	—	1253	1254	1255			—F
276	—C3H6O—	1256	—	1257	1258	1259			—Cl
277	—C6H12—	1260	—	1261	1262	1263			—CF3
278	—C2H4—	1264	—	1265	1266	1267			—F
279	1268	1269	—	1270	1271	1272			—OCF3
280	1273	1274	—	1275	1276	1277			—F
281	1278	1279	—	1280	1281	1282			—OCF3
282	1283	1284	—	1285	1286	1287
283	1288	1289	—	1290	1291	1292			—F
284	—CH2O—	1293	—	1294	1295	1296			—OCF2H
285	1297	1298	—	1299	1300	1301			—OCF3
286	1302	1303	—	1304	1305	1306			—OCF3
287	1307	1308	—	1309	1310	1311			—F
288	1312	1313	—	1314	1315	1316			—CF3
289	1317	1318	—	1319	1320	1321			—F
290	1322	1323	—	1324	1325	1326			—F
291	1327	1328	—	1329	1330	1331			—OCF3
292	1332	1333	—	1334	1335	1336			—CF2H
293	—C2H4—	1337	—	1338	1339	1340			—F
294	1341	1342	—	1343	1344	1345			—OCF3
295	1346	1347	—	1348	1349	1350			—Cl
296	1351	1352	—	1353	1354	1355			—OCF3
297	—C3H6O—	1356	—	1357	1358	1359			—F
298	1360	1361	—	1362	1363	1364			—F
299	—CH2O—	1365	—	1366	1367	1368			—OCF2H
300	1369	1370	—	1371	1372	1373			—OCF3
301	1374	1375	—	1376	1377	1378			—OCF3
302	1379	1380	—	1381	1382	1383			—F
303	1384	1385	—	1386	1387	1388			—CF3
304	1389	1390	—	1391	1392	1393			—OCF3
305	1394	1395	—	1396	1397	1398			—F
306	—C3H6O—	1399	—	1400	1401	1402			—Cl
307	1403	1404	—	1405	1406	1407			—CF2H
308	1408	1409	—	1410	1411	1412			—F
309	1413	1414	—	1415	1416	1417			—OCF3
310	1418	1419	—	1420	1421	1422			—F
311	1423	1424	—	1425	1426	1427			—OCF3
312	1428	1429	—	1430	1431	1432			—OCF3
313	1433	1434	—	1435	1436	1437			—F
314	1438	1439	—	1440	1441	1442			—OCF2H
315	—CH2—	1443	—	1444	1445	1446			—F
316	1447	1448	—	1449	—	1450			—F
317	—CH2O—	1451	—	1452	—	1453			—Cl
318	1454	1455	—	1456	—	1457			—OCF3
319	1458	1459	—	1460	—	1461			—OCF3
320	1462	1463	—	1464	—	1465			—F
321	1466	1467	—	1468	—	1469			—OCF3
322	1470	1471	—	1472	—	1473			—CF3
323	1474	1475	—	1476	—	1477			—F
324	1478	1479	—	1480	—	1481			—OCF3
325	1482	1483	—	1484	—	1485			—F
326	—C2H4O—	1486	—	1487	—	1488			—CFH2
327	1489	1490	—	1491	—	1492			—OCF3
328	1493	1494	1495	1496	—	1497			—F
329	—CH2—	1498	1499	1500	—	1501			—OCF2H
330	1502	1503	1504	1505	—	1506			—OCF3
331	1507	1508	1509	1510	—	1511			—F
332	1512	1513	1514	1515	—	1516			—OCF3
333	—C3H6O—	1517	1518	1519	—	1520			—OCF3
334	1521	1522	1523	1524	—	1525			—OCF3
335	1526	1527	1528	1529	—	1530			—F
336	1531	1532	1533	1534	—	1535			—F
337	1536	1537	—	1538	—	1539			—CF3
338	1540	1541	—	1542	—	1543			—F
339	1544	1545	—	1546	—	1547			—OCF3
340	1548	1549	—	1550	—	1551			—F
341	1552	1553	—	1554	—	1555			—OCF3
342	1556	1557	—	1558	—	1559			—CF3
343	1560	1561	—	1562	—	1563			—F
344	—CH2—	1564	—	1565	—	1566			—OCF2H
345	1567	1568	—	1569	—	1570			—F
346	1571	1572	—	1573	—	1574	—	1575	—F
347	1576	1577	—	1578	—	1579	—	1580	—Cl
348	1581	1582	—	1583	—	1584	—	1585	—OCF3
349	1586	1587	—	1588	—	1589	—	1590	—OCF3
350	1591	1592	—	1593	—	1594	—	1595	—F
351	1596	1597	—	1598	—	1599	—	1600	—OCF3
352	1601	1602	—	1603	—	1604	—	1605	—CF3
353	1606	1607	—	1608	—	1609	—	1610	—F
354	—CH2O—	1611	—	1612	—	1613	—	1614	—OCF3
355	—C2H4—	1615	—	1616	—	1617	—	1618	—F
356	—C2H4O—	1619	—	1620	—	1621	—	1622	—CF3
357	1623	1624	—	1625	—	1626	—	1627	—OCF3
358	1628	1629	—	1630	—	1631	—	1632	—F
359	—CH2—	1633	—	1634	—	1635	—	1636	—CF2H
360	1637	1638	—	1639	—	1640	—	1641	—OCF3
361	1642	1643	—	1644	—	1645	—	1646	—F
362	1647	1648	—	1649	—	1650	—	1651	—CFH2
363	1652	1653	—	1654	—	1655	—	1656	—OCF3
364	1657	1658	—	1659	—	1660	—	1661	—OCF3
365	—CH2O—	1662	—	1663	—	1664	—	1665	—F
366	1666	1667	—	1668	—	1669	—	1670	—OCF2H
367	1671	1672	—	1673	—	1674	—	1675	—CF3
368	—C2H4O—	1676	—	1677	—	1678	—	1679	—F
369	1680	1681	—	1682	—	1683	—	1684	—OCF3
370	1685	1686	—	1687	—	1688	—	1689	—F
371	1690	1691	—	1692	—	1693	—	1694	—CF3
372	1695	1696	—	1697	—	1698	—	1699	—OCF3
373	1700	1701	—	1702	—	1703	—	1704	—F
374	—CH2—	1705	—	1706	—	1707	—	1708	—CF2H
375	1709	1710	—	1711	—	1712	—	1713	—OCF3
376	1714	—	1715	—	1716	—	1717	—F
377	1718	1719	—	1720	—	1721	—	1722	—CFH2
378	—CH2O—	1723	—	1724	—	1725	—	1726	—OCF3
379	1727	1728	—	1729	—	1730	—	1731	—OCF3
380	1732	1733	—	1734	—	1735	—	1736	—F
381	1737	1738	—	1739	—	1740	—	1741	—CF3
382	1742	1743	—	1744	1745	1746	—	1747	—CF3
383	—C5H10O—	1748	—	1749	1750	1751	—	1752	—F
384	1753	1754	—	1755	1756	1757	—	1758	—OCF3
385	1759	1760	—	1761	1762	1763	—	1764	—F
386	1765	1766	—	1767	1768	1769	—	1770	—CF3
387	1771	1772	—	1773	1774	1775	—	1776	—OCF3
388	1777	1778	—	1779	1780	1781	—	1782	—F
389	—CH2—	1783	—	1784	1785	1786	—	1787	—CF2H
390	1788	1789	—	1790	1791	1792	—	1793	—OCF3
391	1794	1795	—	1796	—	1797	1798	1799	—F
392	—C3H6—	1800	—	1801	—	1802	1803	1804	—CFH2
393	—C2H4—	1805	—	1806	—	1807	1808	1809	—OCF3
394	1810	1811	—	1812	—	1813	1814	1815	—F
395	1816	1817	—	1818	—	1819	1820	1821	—OCF3
396	—CH2O—	1822	—	1823	—	1824	1825	1826	—OCF2H
397	—C2H4O—	1827	—	1828	—	1829	1830	1831	—CF3
398	1832	1833	—	1834	—	1835	1836	1837	—F
399	1838	1839	—	1840	—	1841	1842	1843	—OCF3
400	1844	1845	—	1846	—	1847	1848	1849	—F
401	1850	1851	—	1852	—	1853	1854	1855	—CF3
402	1856	1857	—	1858	—	1859	1860	1861	—OCF3
403	1862	1863	—	1864	—	1865	1866	1867	—F
404	—CH2—	1868	—	1869	—	1870	1871	1872	—CF2H
405	1873	1874	—	1875	—	1876	1877	1878	—OCF3
406	—C2H4—	1879	—	1880	—	1881	1882	1883	—F
407	—CH2O—	1884	—	1885	—	1886	1887	1888	—CF2H
408	1889	1890	—	1891	—	1892	1893	1894	—OCF3
409	—C2H4—	1895	—	1896	—	1897	1898	1899	—F
410	1900	1901	—	1902	—	1903	1904	1905	—OCF3
411	—C3H6O—	1906	—	1907	—	1908	1909	1910	—OCFH2
412	1911	1912	—	1913	—	1914	1915	1916	—CF3
413	1917	1918	—	1919	—	1920	1921	1922	—F
414	1923	1924	—	1925	—	1926	1927	1928	—OCF3
415	1929	1930	—	1931	—	1932	1933	1934	—F
416	1935	1936	—	1937	—	1938	1939	1940	—CF3
417	1941	1942	—	1943	—	1944	1945	1946	—OCF3
418	1947	1948	—	1949	—	1950	1951	1952	—F
419	—CH2—	1953	—	1954	—	1955	1956	1957	—CF2H
420	1958	1959	—	1960	—	1961	1962	1963	—OCF3
421	1964	1965	—	1966	—	1967	1968	1969	—F
422	1970	1971	—	1972	—	1973	1974	1975	—OCF3
423	—CH2O—	1976	—	1977	—	1978	1979	1980	—OCF2H
424	1981	1982	—	1983	—	1984	1985	1986	—CF3
425	1987	1988	—	1989	—	1990	1991	1992	—F
426	—C2H4O—	1993	—	1994	—	1995	1996	1997	—OCF3
427	1998	1999	—	2000	—	2001	2002	2003	—F
428	2004	2005	—	2006	—	2007	2008	2009	—CF3
429	2010	2011	—	2012	—	2013	2014	2015	—OCF3
430	2016	2017	—	2018	—	2019	2020	2021	—F
431	—CH2—	2022	—	2023	—	2024	2025	2026	—CF2H
432	2027	2028	—	2029	—	2030	2031	2032	—OCF3
433	2033	2034	—	2035	—	2036	2037	2038	—F
434	—C3H6—	2039	—	2040	—	2041	2042	2043	—CFH2
435	—C2H4—	2044	—	2045	—	2046	2047	2048	—OCF3
436	2049	2050	—	2051	—	2052	2053	2054	—F
437	2055	2056	—	2057	—	2058	2059	2060	—OCF3
438	2061	2062	—	2063	—	2064	2065	2066	—CF2H
439	—C2H4O—	2067	—	2068	—	2069	2070	2071	—CF3
440	2072	2073	—	2074	—	2075	2076	2077	—F
441	—CH2—	2078	—	2079	—	2080	2081	2082	—OCF3
442	2083	2084	—	2085	—	2086	2087	2088	—F
443	2089	2090	—	2091	—	2092	2093	2094	—CF3
444	2095	2096	—	2097	—	2098	2099	2100	—OCF3
445	2101	2102	—	2103	—	2104	2105	2106	—F
446	2107	2108	—	2109	—	2110	2111	2112	—OCF2H
447	2113	2114	—	2115	—	2116	2117	2118	—OCF3
448	—CH2O—	2119	—	2120	—	2121	2122	2123	—F
449	—C3H6—	2124	—	2125	—	2126	2127	2128	—OCFH2
450	—C2H4—	2129	—	2130	—	2131	2132	2133	—OCF3
451	—C4H8—	2134	—	2135					—CN
452	—C3H6O—	2136	—	2137					—CN
453	2138	2139	—	2140					—CN
454	—C4H8—	2141	—	2142					—CN
455	—C5H10O—	2143	—	2144					—CN
456	2145	2146	—	2147					—CN
457	—C4H8—	2148	—	2149					2150
458	2151	2152	—	2153					—CN
459	2154	2155	—	2156					—CN
460	2157	2158	—	2159					—CN
461	—C2H4O—	2160	—	2161					2162
462	2163	2164	2165	2166					—CN
463	—CH2O—	2167	2168	2169					—CN
464	2170	2171	2172	2173					—CN
465	2174	2175	2176	2177					—CN
466	—C4H8—	2178	—	2179					—CN
467	—C3H6O—	2180	—	2181					—CN
468	2182	2183	—	2184					—CN
469	—C4H8—	2185	—	2186					2187
470	2188	2189	—	2190					—CN
471	—C2H4O—	2191	—	2192					—CN
472	2193	2194	—	2195					—CN
473	2196	2197	—	2198					2199
474	2200	2201	—	2202					—CN
475	—CH2O—	2203	—	2204					—CN
476	2205	2206	—	2207					—CN
477	2208	2209	—	2210					2211
478	—C4H8—	2212	—	2213					—CN
479	—C5H10O—	2214	—	2215					—CN
480	2216	2217	—	2218					2219

[0097]

	Y1	A1	Z1	A2	Z2	A3	Z3	A4	Y2
481	—C2H4—	2220	2221	2222				—CN
482	—C3H6O—	2223	2224	2225					—CN
483	2226	2227	2228	2229					—CN
484	—C2H4—	2230	2231	2232					2233
485	2234	2235	2236	2237					—CN
486	—C2H4O—	2238	2239	2240					—CN
487	2241	2242	2243	2244					—CN
488	2245	2246	2247	2248					2249
489	—C3H6—	2250	2251	2252					—CN
490	—C3H6—	2253	2254	2255					—CN
491	2256	2257	2258	2259					—CN
492	2260	2261	2262	2263					—CN
493	—CH2O—	2264	2265	2266					—CN
494	2267	2268	2269	2270					—CN
495	2271	2272	2273	2274					2275
496	—C2H4—	2276	2277	2278					—CN
497	—C3H6O—	2279	2280	2281					—CN
498	2282	2283	2284	2285					2286
499	2287	2288	2289	2290					—CN
500	—C2H4O—	2291	2292	2293					—CN
501	2294	2295	2296	2297					—CN
502	2298	2299	2300	2301					—CN
503	—C3H6O—	2302	2303	2304					—CN
504	—C3H6—	2305	2306	2307					2308
505	2309	2310	2311	2312					—CN
506	2313	2314	2315	2316					—CN
507	2317	2318	2319	2320					2321
508	—CH2O—	2322	2323	2324					—CN
509	2325	2326	2327	2328					—CN
510	2329	2330	2331	2332					—CN
511	—C2H4—	2333	2334	2335					—CN
512	—C3H6O—	2336	2337	2338					—CN
513	2339	2340	2341	2342					—CN
514	—C2H4O—	2343	2344	2345					—CN
515	2346	2347	2348	2349					2350
516	2351	2352	2353	2354					—CN
517	2355	2356	2357	2358					—CN
518	—C3H6O—	2359	2360	2361					—CN
519	—C3H6—	2362	2363	2364					—CN
520	2365	2366	2367	2368					2369
521	2370	2371	2372	2373					—CN
522	—CH2O—	2374	2375	2376					—CN
523	2377	2378	2379	2380					2381
524	2382	2383	2384	2385					—CN
525	—C3H6O—	2386	2387	2388					—CN
526	2389	2390	—	2391	—	2392			—CN
527	—CH2O—	2393	—	2394	—	2395			—CN
528	2396	2397	—	2398	—	2399			2400
529	2401	2402	—	2403	—	2404			—CN
530	—C2H4O—	2405	—	2406	—	2407			—CN
531	2408	2409	—	2410	—	2411			2412
532	2413	2414	—	2415	—	2416			—CN
533	—C3H6O—	2417	—	2418	—	2419			—CN
534	2420	2421	—	2422	—	2423			—CN
535	2424	2425	—	2426	—	2427			—CN
536	—C2H4O—	2428	—	2429	—	2430			—CN
537	—CH2—	2431	—	2432	—	2433			2434
538	2435	2436	—	2437	—	2438			—CN
539	—CH2O—	2439	—	2440	—	2441			—CN
540	2442	2443	—	2444	—	2445			2446
541	—C2H4—	2447	—	2448	—	2449			—CN
542	—C3H6O—	2450	—	2451	—	2452			—CN
543	2453	2454	—	2455	—	2456			2457
544	—C4H8—	2458	—	2459	—	2460			—CN
545	—C2H4O—	2461	—	2462	—	2463			—CN
546	—C3H6—	2464	—	2465	—	2466			2467
547	2468	2469	—	2470	—	2471			—CN
548	—C3H6O—	2472	—	2473	—	2474			—CN
549	2475	2476	—	2477	—	2478			2479
550	2480	2481	—	2482	2483	2484			—CN
551	—C2H4O—	2485	—	2486	2487	2488			—CN
552	—CH2—	2489	—	2490	2491	2492			2493
553	2494	2495	—	2496	2497	2498			—CN
554	—CH2O—	2499	—	2500	2501	2502			—CN
555	2503	2504	—	2505	2506	2507			2508
556	—C2H4—	2509	—	2510	2511	2512			—CN
557	—CH2O—	2513	—	2514	2515	2516			—CN
558	2517	2518	—	2519	2520	2521			2522
559	—C7H14—	2523	—	2524	—	2525			—CN
560	—C3H6O—	2526	—	2527	—	2528			—CN
561	—C3H6—	2529	—	2530	—	2531			2532
562	2533	2534	—	2535	—	2536			—CN
563	—C2H4O—	2537	—	2538	—	2539			—CN
564	2540	2541	—	2542	—	2543			2544
565	2545	2546	—	2547	—	2548			—CN
566	—C2H4O—	2549	—	2550	—	2551			—CN
567	—C2H4—	2552	—	2553	—	2554			2555
568	2556	2557	2558	2559	—	2560			—CN
569	2561	2562	2563	2564	—	2565			—CN
570	—CH2O—	2566	2567	2568	—	2569			2570
571	—C2H4—	2571	2572	2573	—	2574			—CN
572	—CH2O—	2575	2576	2577	—	2578			—CN
573	2579	2580	2581	2582	—	2583			2584
574	—C2H4—	2585	2586	2587	—	2588			—CN
575	—C3H6O—	2589	2590	2591	—	2592			—CN
576	—C3H6—	2593	2594	2595	—	2596			—CN
577	2597	2598	—	2599	2600	2601			—CN
578	—C3H6O—	2602	—	2603	2604	2605			—CN
579	2606	2607	—	2608	2609	2610			2611
580	2612	2613	—	2614	2615	2616			—CN
581	—C2H4O—	2617	—	2618	2619	2620			—CN
582	—C2H4—	2621	—	2622	2623	2624			2625
583	2626	2627	—	2628	2629	2630			—CN
584	2631	2632	—	2633	2634	2635			—CN
585	—CH2O—	2636	—	2637	2638	2639			2640
586	—C2H4—	2641	—	2642	2643	2644			—CN
587	—C2H4O—	2645	—	2646	2647	2648			—CN
588	2649	2650	—	2651	2652	2653			2654
589	—C4H8—	2655	—	2656	2657	2658			—CN
590	—C3H6O—	2659	—	2660	2661	2662			—CN
591	—C2H4—	2663	—	2664	2665	2666			2667
592	2668	2669	—	2670	2671	2672			—CN
593	—C3H6O—	2673	—	2674	2675	2676			—CN
594	2677	2678	—	2679	2680	2681			—CN
595	2682	2683	—	2684	2685	2686			—CN
596	2687	2688	—	2689	2690	2691			—CN
597	—CH2O—	2692	—	2693	2694	2695			2696
598	2697	2698	—	2699	2700	2701			—CN
599	—C2H4O—	2702	—	2703	2704	2705			—CN
600	2706	2707	—	2708	2709	2710			2711
601	—C2H4—	2712	—	2713	2714	2715			—CN
602	—C3H6O—	2716	—	2717	2718	2719			—CN
603	2720	2721	—	2722	2723	2724			2725
604	—C4H8—	2726	—	2727	2728	2729			—CN
605	—C2H4O—	2730	—	2731	2732	2733			—CN
606	—C2H4—	2734	—	2735	2736	2737			2738
607	2739	2740	—	2741	2742	2743			—CN
608	—C3H6O—	2744	—	2745	2746	2747			—CN
609	2748	2749	—	2750	2751	2752			2753
610	2754	2755	—	2756	2757	2758			—CN
611	2759	2760	—	2761	2762	2763			—CN
612	—C2H4—	2764	—	2765	2766	2767			2768
613	2769	2770	—	2771	2772	2773			—CN
614	—C2H4O—	2774	—	2775	2776	2777			—CN
615	2778	2779	—	2780	2781	2782			2783
616	—C4H8—	2784	—	2785	2786	2787			—CN
617	—C4H8—	2788	—	2789	2790	2791			—CN
618	2792	2793	—	2794	2795	2796			2797
619	—C2H4—	2798	—	2799	2800	2801			—CN
620	—C2H4O—	2802	—	2803	2804	2805			—CN
621	—C4H8—	2806	—	2807	2808	2809			2810
622	2811	2812	—	2813	2814	2815			—CN
623	—C2H4O—	2816	—	2817	2818	2819			—CN
624	—CH2O—	2820	—	2821	2822	2823			2824
625	2825	2826	—	2827	2828	2829	—	2830	—CN
626	—CH2O—	2831	—	2832	2833	2834	—	2835	—CN
627	—C2H4—	2836	—	2837	2838	2839	—	2840	2841
628	2842	2843	—	2844	2845	2846	—	2847	—CN
629	—C2H4O—	2848	—	2849	2850	2851	—	2852	—CN
630	2853	2854	—	2855	2856	2857	—	2858	2859
631	—C4H8—	2860	2861	2862					—F
632	2863	2864	2865	2866					—OCF3
633	—C4H8—	2867	2868	2869					—CF3
634	—CH2O—	2870	2871	2872					—OCF2H
635	—C2H4—	2873	2874	2875					—CN
636	—C4H8—	2876	2877	2878					2879
637	—C4H8—	2880	2881	2882					—F
638	—C2H4O—	2883	2884	2885					—F
639	2886	2887	2888	2889					—OCF3
640	2890	2891	2892	2893					—CF2H
641	—C2H4—	2894	2895	2896					—CN
642	—C2H4—	2897	2898	2899					2900
643	2901	2902	2903	2904					—F
644	2905	2906	2907	2908					—OCF3
645	2909	2910	2911	2912					—OCF3
646	—C4H8—	2913	2914	2915					—CF3
647	2916	2917	2918	2919					—CN
648	—C3H6O—	2920	2921	2922					2923
649	—CH2O—	2924	—	2925	2926	2927			—CN
650	—C2H4—	2928	—	2929	2930	2931			—CN
651	—C4H8—	2932	—	2933	2934	2935			2936
652	—C2H4—	2937	—	2938	2939	2940			—CN
653	—C2H4O—	2941	—	2942	2943	2944			—CN
654	2945	2946	—	2947	2948	2949			2950
655	2951	2952	—	2953	2954	2955			—CN
656	—C4H8O—	2956	—	2957	2958	2959			—CN
657	—C2H4—	2960	—	2961	2962	2963			2964
658	2965	2966	—	2967	—	2968	2969	2970	—CN
659	2971	2972	—	2973	—	2974	2975	2976	—CN
660	—C2H4—	2977	—	2978	—	2979	2980	2981	2982
661	—C4H8—	2983	—	2984	—	2985	2986	2987	—CN
662	2988	2989	—	2990	—	2991	2992	2993	—CN
663	—C2H4—	2994	—	2995	—	2996	2997	2998	—CN
664	—CH2O—	2999	—	3000	—	3001	3002	3003	—CN
665	—C4H8—	3004	—	3005	—	3006	3007	3008	3009
666	—C2H4—	3010	—	3011	—	3012	3013	3014	—CN
667	—C2H4—	3015	—	3016					—F
668	—C6H12 O—	3017	—	3018					—F
669	3019	3020	—	3021					—F
670	3022	3023	—	3024					—F
671	—C5H10O—	3025	—	3026					—F
672	3027	3028	—	3029					—F
673	3030	3031	—	3032	—	3033			—F
674	3034	3035	—	3036	—	3037			—F
675	3038	3039	—	3040	—	3041			—F
676	3042	3043	—	3044					—OC2H5
677	—C3H6—	3045	—	3046					—CH3
678	3047	3048	—	3049					—OC2H5
679	—C4H8O—	3050	—	3051					—C3H7
680	3052	3053	—	3054					—OC3H7
681	—C4H8—	3055	—	3056					—OC2H5
682	—C3H6O—	3057	—	3058					—C2H5
683	—C7H14—	3059	—	3060					—SCH3
684	3061	3062	—	3063					—OC2H5
685	3064	3065	—	3066					—C49
686	3067	3068	3069	3070					—OC2H5
687	3071	3072	3073	3074					—C3H7
688	—CH2O—	3075	3076	3077					—OC3H7
689	3078	3079	3080	3081					—OCH3
690	3082	3083	3084	3085					—C5H11
691	3086	3087	—	3088	—	3089			—OC2H5
692	—C2H4—	3090	—	3091	—	3092			—CH3
693	—C4H8—	3093	—	3094	—	3095			—OC2H5
694	3096	3097	—	3098	—	3099			—C2H5
695	3100	3101	—	3102	—	3103			—OC3H7
696	—C4H8—	3104	—	3105	3106	3107			—OC2H5
697	—C3H6O—	3108	—	3109	3110	3111			—C2H5
698	—C7H14—	3112	—	3113	3114	3115			—OCH3
699	—C2H4—	3116	—	3117	3118	3119			—OC2H5
700	3120	3121	—	3122	3123	3124			—C4H9
701	3125	3126	—	3127	3128	3129			—OC2H5
702	3130	3131	—	3132	3133	3134			—C3H7
703	—CH2O—	3135	—	3136	3137	3138			—OC3H7
704	3139	3140	—	3141	3142	3143			—OCH3
705	3144	3145	—	3146	3147	3148			—C5H11
706	3149	3150	—	3151	—	3152			—OC2H5
707	—C2H4—	3153	—	3154	—	3155			—C3H7
708	3156	3157	—	3158	—	3159			—OCH3
709	—C3H6O—	3160	—	3161	—	3162			—C6H13
710	3163	3164	—	3165	—	3166			—OC2H5
711	—C2H4—	3167	—	3168	3169	3170			—OC2H5
712	—CH2O—	3171	—	3172	3173	3174			—CH3
713	—C4H8—	3175	—	3176	3177	3178			—OCH3
714	3179	3180	—	3181	3182	3183			—SC2H5
715	3184	3185	—	3186	3187	3188			—C4H9
716	3189	3190	—	3191	3192	3193			—OC2H5
717	3194	3195	—	3196	3197	3198			—C3H7
718	—C2H4—	3199	—	3200	—	3201			—OC2H5
719	3202	3203	—	3204	—	3205			—C3H7
720	3206	3207	—	3208	—	3209			—OC2H5
721	3210	3211	—	3212	—	3213			—OC2H5
722	—C2H8—	3214	—	3215	—	3216			—CH3
723	3217	3218	—	3219	—	3220			—OC3H7
724	—C3H6O—	3221	—	3222	—	3223			—C6H13
725	3224	3225	—	3226	—	3227			—OC2H5
726	—C2H4—	3228	—	3229	—	3230			—OC2H5
727	—CH2O—	3231	—	3232	—	3233			—SCH3
728	—C4H8—	3234	—	3235	—	3236			—C2H5
729	3237	3238	—	3239	—	3240			—OC2H5
730	3241	3242	—	3243	—	3244			—CH3
731	3245	3246	—	3247	3248	3249			—OC2H5
732	3250	3251	—	3252	3253	3254			—CH3
733	—C7H14—	3255	—	3256	3257	3258			—OC2H5
734	—C3H6O—	3259	—	3260	3261	3262			—C3H7
735	3263	3264	—	3265	3266	3267			—OC2H5
736	3268	3269	—	3270					—C4H9
737	—CH2O—	3271	—	3272					—C7H15
738	3273	3274	—	3275					3276
739	3277	3278	—	3279					3280
740	3281	3282	—	3283					—C5H11
741	—C7H14O—	3284	—	3285					—OC8H17
742	—CH2—	3286	—	3287					—C5H11
743	3288	3289	—	3290					—COOCH3
744	—C2H4O—	3291	—	3292					—COOC2H5
745	3293	3294	—	3295					—COOC3H7
746	3296	3297	3298	3299					—C5H11
747	3300	3301	3302	3303					—OC4H9
748	3304	3305	3306	3307					3308
749	3309	3310	3311	3312					—C2H5
750	3313	3314	3315	3316					3317
751	—C3H6—	3318	3319	3320					—C2H5
752	—CH2O—	3321	3322	3323					—C8H17
753	3324	3325	3326	3327					3328
754	3329	3330	3331	3332					3333
755	3334	3335	3336	3337					—C3H7
756	3338	3339	—	3340					—C3H7
757	—C2H4O—	3341	—	3342					—C4H9
758	3343	3344	—	3345					3346
759	3347	3348	—	3349					—OC5H11
760	3350	3351	—	3352					3353
761	3354	3355	—	3356					—C5H11
762	—C6H12—	3357	—	3358					—CH2OCH3
763	3359	3360	—	3361					—C2H5
764	3362	3363	—	3364					3365
765	3366	3367	—	3368					—OC2H5
766	3369	3370	—	3371					—OC6H13
767	3372	3373	—	3374					—C8H17
768	3375	3376	—	3377					3378
769	3379	3380	3381	3382					—C3H7
770	—C2H4O—	3383	3384	3385					—C4H9
771	3386	3387	3388	3389					—C5H11
772	3390	3391	3392	3393					—OC7H15
773	3394	3395	3396	3397					3398
774	3399	3400	3401	3402					3403
775	3404	3405	3406	3407					—C5H11
776	—C4H8O—	3408	3409	3410					—C2H5
777	3411	3412	3413	3414					—C4H9
778	—CH2—	3415	3416	3417					—C2H4OCH3
779	3418	3419	3420	3421					3422
780	3423	3424	3425	3426					3427
781	3428	3429	3430	3431					—C3H7
782	—C2H4O—	3432	3433	3434					—C6H13
783	3435	3436	3437	3438					—OC7H15
784	3439	3440	3441	3442					3443
785	3444	3445	3446	3447					—C3H7
786	3448	3449	3450	3451					—C3H7
787	—CH2—	3452	3453	3454					—OC5H11
788	—C2H4O—	3455	3456	3457					—C6H13
789	3458	3459	3460	3461					3462
790	3463	3464	3465	3466					3467
791	—C4H8—	3468	—	3469					—C3H7
792	3470	3471	—	3472					—OC4H9
793	—C4H8O—	3473	—	3474					3475
794	3476	3477	—	3478					—C3H6OC3H7
795	3479	3480	—	3481					—CH2OC2H5
796	3482	3483	3484	3485					—C3H7
797	—C2H4O—	3486	3487	3488					—C5H11
798	3489	3490	3491	3492					—OC7H15
799	3493	3494	3495	3496					3497
800	3498	3499	3500	3501					—C3H7
801	3502	3503	3504	3505					—C5H11
802	—CH2O—	3506	3507	3508					—OC5H11
803	3509	3510	3511	3512					—C4H9
804	3513	3514	3515	3516					—C2H4OC3H7
805	3517	3518	3519	3520					3521
806	—C3H6—	3522	3523	3524					—C3H7
807	3525	3526	3527	3528					—OC2H5
808	—C4H8O—	3529	3530	3531					3532
809	3533	3534	3535	3536					—CH2OC4H9
810	3537	3538	3539	3540					—CH2OC2H5
811	3541	3542	—	3543	—	3544			—C9H19
812	—CH2O—	3545	—	3546	—	3547			—C5H11
813	—C2H4—	3548	—	3549	—	3550			—OCH3
814	3551	3552	—	3553	—	3554			3555
815	3556	3557	—	3558	—	3559			—C2H5
816	3560	3561	—	3562	—	3563			—C3H7
817	—C4H8—	3564	—	3565	—	3566			—OC5H11
818	—C2H4O—	3567	—	3568	—	3569		—C4H9
819	3570	3571	—	3572	—	3573			3574
820		3575	3576	—	3577			3578
821	—C2H4—	3579	3580	3581	—	3582		—C3H7
822	3583	3584	3585	3586	—	3587		—OC3H7
823	—C4H8O—	3588	3589	3590	—	3591		3592
824	3593	3594	3595	3596	—	3597		—CH2OC3H7
825	3598	3599	3600	3601	—	3602			—CH3
826	3603	3604	—	3605	3606	3607			—C3H7
827	—CH2O—	3608	—	3609	3610	3611			—C2H5
828	—C2H4—	3612	—	3613	3614	3615			—OCH3
829	3616	3617	—	3618	3619	3620			3621
830	3622	3623	—	3624	3625	3626			3627
831	—C2H4—	3628	—	3629	3630	3631			—C3H7
832	3632	3633	—	3634	3635	3636			—OC3H7
833	—C3H8O—	3637	—	3638	3639	3640		3641
834	3642	3643	—	3644	3645	3646			—C3H6OC2H5
835	3647	3648	—	3649	3650	3651			—CH3
836	3652	3653	3654	3655	—	3656			—C3H7
837	—C4H8—	3657	3658	3659	—	3660			—OC3H7
838	—C2H4O—	3661	3662	3663	—	3664			—C2H5
839	3665	3666	3667	3668	—	3669			3670
840	3671	3672	3673	3674	—	3675			3676
841	—CH2—	3677	—	3678	—	3679			—C10H21
842	—C2H4O—	3680	—	3681	—	3682			—C4H9
843	—C2H4—	3683	—	3684	—	3685			—OC2H5
844	3686	3687	—	3688	—	3689			3690
845	3691	3692	—	3693	—	3694			—C2H5
846	3695	3696	—	3697	—	3698			—C3H7
847	—C4H8—	3699	—	3700	—	3701			—OC6H13
848	—C2H4O—	3702	—	3703	—	3704			—C2H5
849	3705	3706	—	3707	—	3708			3709
850	3710	3711	—	3712	—	3713			3714
851	—C2H4—	3715	—	3716	3717	3718			—C3H7
852	3719	3720	—	3721	3722	3723			—OC4H9
853	—C4H8O—	3724	—	3725	3726	3727			3728
854	3729	3730	—	3731	3732	3733			—C3H6OCH3
855	3734	3735	—	3736	3737	3738			3739
856	3740	3741	3742	3743	—	3744			—C3H7
857	—CH2O—	3745	3746	3747	—	3748			—C2H5
858	—C2H4—	3749	3750	3751	—	3752			—OC3H7
859	3753	3754	3755	3756	—	3757			3758
860	3759	3760	3761	3762	—	3763			3764
861	—C2H4—	3765	—	3766	—	3767			—C3H7
862	3768	3769	—	3770	—	3771			—OC7H15
863	—C4H8O—	3772	—	3773	—	3774			3775
864	3776	3777	—	3778	—	3779			—C2H4OC2H5
865	3780	3781	—	3782	—	3783			—CH3
866	3784	3785	—	3786	—	3787	—	3788	—C3H7
867	—C2H4—	3789	—	3790	—	3791	—	3792	—OC3H7
868	—C2H4O—	3793	—	3794	—	3795	—	3796	—C2H5
869	3797	3798	—	3799	—	3800	—	3801	3802
870	3803	3804	—	3805	—	3806	—	3807	3808
871	3809	3810	—	3811	—	3812	—	3813	—C3H7
872	—CH2O—	3814	—	3815	—	3816	—	3817	—C5H11
873	3818	3819	—	3820	—	3821	—	3822	—OC2H5
874	—C4H8—	3823	—	3824	—	3825	—	3826	—C3H7
875	—C3H6—	3827	—	3828	—	3829	—	3830	—OC2H5
876	3831	3832	—	3833	—	3834	—	3835	3836
877	3837	3838	—	3839	—	3840	—	3841	—C2H5
878	—C2H4—	3842	—	3843	—	3844	—	3845	—C3H7
879	—C4H8—	3846	—	3847	—	3848	—	3849	—OCH3
880	3850	3851	—	3852	—	3853	—	3854	3855
881	3856	3857	—	3858	—	3859	—	3860	—CH3
882	—C4H8—	3861	—	3862	—	3863	—	3864	—C3H7
883	—C3H6—	3865	—	3866	—	3867	—	3868	—C2H4OC2H5
884	3869	3870	—	3871	—	3872	—	3873	3874
885	3875	3876	—	3877	—	3878	—	3879	—C6H13
886	—C2H4—	3880	—	3881	—	3882 —	3883	—CH3
887	—CH2—	3884	—	3885	—	3886	—	3887	—OCH3
888	3888	3889	—	3890	—	3891	—	3892	3893
889	3894	3895	—	3896	—	3897	—	3898	—C3H7
890	—C2H4—	3899	—	3900	—	3901	—	3902	—C2H5
891	—CH2—	3903	—	3904	—	3905	—	3906	—OC2H5
892	3907	3908	—	3909 —	3910	—	3911	3912
893	3913	3914	—	3915	—	3916	—	3917	—C3H7
894	3918	3919	—	3920	—	3921	—	3922	—C3H7
895	—CH2O—	3923	—	3924	—	3925	—	3926	—CH3
896	3927	3928	—	3929	—	3930	—	3931	—OC2H5
897	—C3H6—	3932	—	3933	—	3934	—	3935	—C3H7
898	—C4H8—	3936	—	3937	—	3938	—	3939	—OCH3
899	3940	3941	—	3942	—	3943	—	3944	3945
900	3946	3947	—	3948	—	3949	—	3950	—C8H17
901	3951	3952	—	3953					—C3H7
902	—CH2O—	3954	—	3955					—C5H11
903	—C2H4—	3956	—	3957					—OC4H9
904	3958	3959	—	3960	—	3961			—C5H11
905	—C3H6O—	3962	—	3963	—	3964			—C3H7
906	—CH2—	3965	—	3966	—	3967			3968
907	3969	3970	—	3971	—	3972			—C3H7
908	—C2H4O—	3973	—	3974	—	3975			—C5H11
909	—C2H4—	3976	—	3977	—	3978			3979
910	3980	3981	—	3982	—	3983			—C2H5
911	—C3H6O—	3984	—	3985	—	3986			—C3H7
912	—C6H12—	3987	—	3988	—	3989			—OC3H11
913	3990	3991	—	3992	—	3993			—C3H7
914	—C4H8O—	3994	—	3995	—	3996			—C5H11
915	3997	3998	—	3999	—	4000			—OCH3
916	4001	4002	—	4003					—C3H7
917	—C2H4O—	4004	—	4005					—C4H9
918	—C2H4—	4006	—	4007					—OC6H13
919	4008	4009	—	4010	—	4011			—C5H11
920	4012	4013	—	4014	—	4015			—OC3H7
921	4016	4017	—	4018	—	4019			—CH3
922	4020	4021	—	4022	—	4023			—C3H7
923	4024	4025	—	4026	—	4027			—OC3H7
924	4028	4029	—	4030	—	4031			—CH3
925	4032	4033	—	4034	—	4035			—C2H5
926	4036	4037	—	4038	—	4039			—OC3H7
927	4040	4041	—	4042	—	4043			—C6H13
928	4044	4045	—	4046	—	4047			—C3H7
929	4048	4049	—	4050	—	4051			—OC5H11
930	—C4H8O—	4052	—	4053	—	4054			4055
931	—C2H4—	4056	—	4057	4058	4059			—CH3
932	—CH2—	4060	—	4061	4062	4063			—OC2H5
933	4064	4065	—	4066	4067	4068			4069
934	4070	4071	—	4072	4073	4074			—C3H7
935	—C3H6—	4075	4076	4077	—	4078			—C3H7
936	—CH2—	4079	4080	4081	—	4082			—OC4H9
937	4083	4084	4085	4086	—	4087			4088
938	4089	4090	4091	4092	—	4093			—C3H7
939	4094	4095	—	4096	4097	4098			—C2H5
940	—C3H6O—	4099	—	4100	4101	4102			—CH3
941	4103	4104	—	4105	4106	4107			—OC3H7
942	—C2H4—	4108	4109	4110	—	4111			—C3H7
943	—C4H8—	4112	4113	4114	—	4115			—OC2H5
944	4116	4117	4118	4119	—	4120			4121
945	4122	4123	4124	4125	—	4126			—C8H17
946	—C4H8—	4127	4128	4129	4130	4131			—CH3
947	—CH2—	4132	4133	4134	4135	4136			—OC2H5
948	4137	4138	4139	4140	4141	4142			4143
949	4144	4145	4146	4147	4148	4149			—C3H7
950	—C3H6—	4150	4151	4152	4153	4154			—C4H9
951	—CH2—	4155	4156	4157	4158	4159			—OC2H5
952	—C2H4O—	4160	4161	4162	4163	4164			4165
953	4166	4167	4168	4169	4170	4171			—C3H7
954	4172	4173	—	4174	4175	4176	—	4177	—C2H5
955	—C2H4O—	4178	—	4179	4180	4181	—	4182	—C2H5
956	4183	4184	—	4185	4186	4187	—	4188	—OC4H9
957	4189	4190	4191	4192	—	4193	—	4194	—C3H7
958	—C4H8—	4195	4196	4197	—	4198	—	4199	—OC2H5
959	—C2H4—	4200	4201	4202	—	4203	—	4204	4205
960	4206	4207	4208	4209	—	4210	—	4211	—C5H11
961	—C48—	4212	—	4213					4214
962	—C5H10—	4215	4216	4217					4218
963	4219	4220	—	4221	—	4222			4223
964	4224	4225	4226	4227					4228
965	—CH2—	4229	—	4230	—	4231			4232
966	—CH3H6—	4233	4234	4235					4236
967	—C2H4O—	4237	—	4238	4239	—	4240	4241
968	—C4H8—	4242	4243	—	4244			4245
969	—C3H6O—	4246	4247	4248					4249
970	4250	4251	4252	4253					4254
971	4255	4256	—	4257	—	4258	4259	4260	4261
972	—C2H4—	4262	4263	4264	4265	4266			4267
973	—C4H8—	4268	4269	4270					4271
974	—C2H4—	4272	4273	4274	4275	4276	4277	4278	4279
975	4280	4281	4282	4283					4284
976	—CH2—	4285	—	4286	—	4287	—	4288	—F
977	—C3H6—	4289	—	4290	—	4291	—	4292	—Cl
978	—C2H4—	4293	—	4294	—	4295	—	4296	—OCF3
979	—CH2O—	4297	—	4298	—	4299	—	4300	—CF3
980	—C2H4—	4301	—	4302	—	4303	—	4304	—OCHF2
981	—C3H6—	4305	—	4306	—	4307	—	4308	—OCH2CF3
982	—C2H4—	4309	—	4310	—	4311	—	4312	—F
983	—C3H6—	4313	—	4314	—	4315	—	4316	—OCHF2
984	—C2H4—	4317	—	4318	—	4319	—	4320	—F
985	—C3H6—	4321	—	4322	—	4323	—	4324	—OCF3
986	—C2H4—	4325	—	4326	—	4327	—	4328	—F
987	—C3H6—	4329	—	4330	—	4331	—	4332	—Cl
988	—C2H4—	4333	—	4334	—	4335	—	4336	—F
989	—C3H6—	4337	—	4338	—	4339	—	4340	—OCHF2
990	—C2H4—	4341	—	4342	—	4343	—	4344	—OCF3
991	—C2H4—	4345	—	4346	—	4347	—	4348	—F

[0098] Examples in which the compounds of the present invention were used as the components for the compositions shall be shown below. The compounds used in the composition examples and the examples described later were represented by codes exhibited by definitions which were shown in the following Table 1.

TABLE 1
Method for Description of Compounds Using Symbols
R—(SiH3-Y1-)A1—Z1— . . . —Zn-An-X(—Y2)
1)Left Terminal Group R—, SiH3-Y1-	Symbol	3)Bonding Group —Zn—	Symbol
CnH2n+1—	n-	—C2H4—	2
CnH2n+1O—	nO—	—C4H8—	4
CnH2n+1OCmH2m+1—	nOm-	—COO—	E
CH2═CH—	V—	—C≡C—	T
CH2═CHCnH2n—	Vn-	—CH═CH—	V
CnH2n+1CH═CHCmH2m—	nVm-	—CF2O—	CF2O
CnH2n+1CH═CHCmH2mCH═CHCkH2k—	nVmVk-	—OCF2—	OCF2
CF2═CH—	VFF—
CF2═CHCnH2n—	VFFn-
SiH3CnH2n—	Sin-
2) Ring Structure -An-	Symbol	4) Right Terminal Group —X, —Y2	Symbol
4349	B	—F —Cl —CN	—F —Cl —C
4350	B(F)	—CF3—OCF3—OCF2H	—CF3—OCF3 OCF2H
4351	B(F, F)	—CnH2n+1—OCnH2n+1—CnH2nCH═CH2	-n —On —EMe -nV
4352	H	—CmH2mCH═CHCnH2n+1—CH═CF2—CnH2nCH═CF2	-mVn —VFF -nVFF
4353	Ch	—C≡C—CN	—TC
4354	G
4355	Py
4356	B(2F, 3F)
4357	B(2CN, 3CN)
5) Examples of Description
Example 1 3-H2B(F, F)B(F)-F	Example 3 Si2-HB(F, F)-C
4358	4359
Example 2 Si1-HH-5
4360

[0099] In the examples, “%” represents “weight %”, and “part” represents “part by weight” unless otherwise described. When a cis-trans isomer is present in the compound, it means a trans type. When a left terminal group is not described, the group represents a hydrogen atom.

Example 5

[0100]

	Si2—HB(F, F)—C	(No. 459)	15.0%
	Si1—HH-5	(No. 742)	8.0%
	1V2—BEB(F, F)—C		5.0%
	3-HB—C		10.0%
	1-BTB-3		5.0%
	2-BTB-1		10.0%
	3-HH-4		3.0%
	3-HHB-1		11.0%
	3-HHB-3		9.0%
	3-H2BTB-2		4.0%
	3-H2BTB-3		4.0%
	3-H2BTB-4		4.0%
	3-HB(F)TB-2		6.0%
	3-HB(F)TB-3		6.0%
	NI = 74.1 (° C.)
	η = 15.5 (mPa · s)
	Δn = 0.150
	Δε = 9.6
	Vth = 1.81 (V)

[0101] When adding 0.8 part of CM33 to 100 parts of the composition described above, the pitch was 11.3 μm.

Example 6

[0102]

	Si2—HB(F, F)—C	(No. 459)	13.0%
	2O1—BEB(F)—C		5.0%
	3O1—BEB(F)—C		15.0%
	4O1—BEB(F)—C		13.0%
	2-HHB(F)—C		15.0%
	3-HHB(F)—C		15.0%
	3-HB(F)TB-2		4.0%
	3-HB(F)TB-3		4.0%
	3-HB(F)TB-4		4.0%
	3-HHB-1		8.0%
	3-HHB—O1		4.0%
	NI = 85.4 (° C.)
	η = 80.2 (mPa · s)
	Δn = 0.143
	Δε = 31.1
	Vth = 0.86 (V)

Example 7

[0103]

	Si3—HB(F, F)B(F)—F	(No. 189)	4.0%
	5-PyB—F		4.0%
	3-PyB(F)—F		4.0%
	2-BB—C		5.0%
	5-BB—C		5.0%
	2-PyB-2		2.0%
	3-PyB-2		2.0%
	4-PyB-2		2.0%
	6-PyB—O5		3.0%
	6-PyB—O6		3.0%
	6-PyB—O7		3.0%
	6-PyB—O8		3.0%
	3-PyBB—F		6.0%
	4-PyBB—F		6.0%
	5-PyBB—F		6.0%
	3-HHB-1		6.0%
	3-HHB-3		8.0%
	2-H2BTB-2		4.0%
	2-H2BTB-3		4.0%
	2-H2BTB-4		5.0%
	3-H2BTB-2		5.0%
	3-H2BTB-3		5.0%
	3-H2BTB-4		5.0%
	NI = 93.2 (° C.)
	η = 33.4 (mPa · s)
	Δn = 0.198
	Δε = 6.5
	Vth = 2.26 (V)

Example 8

[0104]

	Si2—HHB(F)—OCF3	(No. 36)	5.0%
	Si3—HHB(F)—OCF3	(No. 39)	5.0%
	3-GB—C		10.0%
	2-BEB—C		12.0%
	3-BEB—C		4.0%
	3-PyB(F)—F		6.0%
	3-HEB—O4		8.0%
	4-HEB—O2		6.0%
	5-HEB—O1		6.0%
	3-HEB—O2		5.0%
	5-HEB—O2		4.0%
	5-HEB-5		5.0%
	4-HEB-5		5.0%
	1O—BEB-2		4.0%
	3-HHB-1		6.0%
	3-HHEBB—C		3.0%
	3-HBEBB—C		3.0%
	5-HBEBB—C		3.0%
	NI = 74.0 (° C.)
	η = 39.5 (mPa · s)
	Δn = 0.117
	Δε = 10.7
	Vth = 1.36 (V)

Example 9

[0105]

	Si4—HB(F)EB—OCF3	(No. 219)	3.0%
	3-HB—C		18.0%
	1O1—HB—C		10.0%
	3-HB(F)—C		10.0%
	2-PyB-2		2.0%
	3-PyB-2		2.0%
	4-PyB-2		2.0%
	1O1—HH-3		7.0%
	2-BTB—O1		7.0%
	3-HHB-1		7.0%
	3-HHB—F		4.0%
	3-HHB—O1		4.0%
	3-HHB-3		8.0%
	3-H2BTB-2		3.0%
	3-H2BTB-3		3.0%
	2-PyBH-3		4.0%
	3-PyBH-3		3.0%
	3-PyBB-2		3.0%
	NI = 80.2 (° C.)
	η = 18.3 (mPa · s)
	Δn = 0.140
	Δε = 8.3
	Vth = 1.73 (V)

Example 10

[0106]

	Si2—HB(F, F)—C	(No. 459)	12.0%
	2-BEB(F)—C		5.0%
	3-BEB(F)—C		4.0%
	1V2—BEB(F, F)—C		10.0%
	3-HH—EMe		10.0%
	3-HB—O2		18.0%
	7-HEB—F		2.0%
	3-HHEB—F		2.0%
	5-HHEB—F		2.0%
	3-HBEB—F		4.0%
	2O1—HBEB(F)—C		2.0%
	3-HB(F)EB(F)—C		2.0%
	3-HBEB(F, F)—C		2.0%
	3-HHB—F		4.0%
	3-HHB—O1		4.0%
	3-HHB-3		13.0%
	3-HEBEB—F		2.0%
	3-HEBEB-1		2.0%
	NI = 69.6 (° C.)
	η = 31.6 (mPa · s)
	Δn = 0.109
	Δε = 24.1
	Vth = 0.90 (V)

Example 11

[0107]

	Si2—HB(F, F)—C	(No. 459)	10.0%
	2-BEB(F)—C		5.0%
	3-BEB(F)—C		4.0%
	4-BEB(F)—C		12.0%
	1V2—BEB(F, F)—C		6.0%
	3-HB—O2		10.0%
	3-HH-4		3.0%
	3-HHB—F		3.0%
	3-HHB-1		8.0%
	3-HHB—O1		4.0%
	3-HBEB—F		4.0%
	3-HHEB—F		7.0%
	5-HHEB—F		7.0%
	3-H2BTB-2		4.0%
	3-H2BTB-3		4.0%
	3-H2BTB-4		4.0%
	3-HB(F)TB-2		5.0%
	NI = 81.3 (° C.)
	η = 36.2 (mPa · s)
	Δn = 0.133
	Δε = 24.5
	Vth = 1.12 (V)

Example 12

[0108]

	Si2—HB(2F3F)—O2	(No. 678)	6.0%
	Si4—HB(2F3F)—O2	(No. 676)	6.0%
	2-BEB—C		12.0%
	3-BEB—C		4.0%
	4-BEB—C		6.0%
	3-HB—C		28.0%
	4-HEB—O2		8.0%
	5-HEB—O1		8.0%
	3-HEB—O2		6.0%
	5-HEB—O2		5.0%
	3-HHB-1		7.0%
	3-HHB—O1		4.0%
	NI = 55.4 (° C.)
	η = 27.6 (mPa · s)
	Δn = 0.114
	Δε = 9.3
	Vth = 1.41 (V)

Example 13

[0109]

	Si2—HB(F)B(F, F)—F	(No. 193)	7.0%
	2-BEB—C		10.0%
	5-BB—C		12.0%
	1-BTB-3		7.0%
	2-BTB-1		10.0%
	1O—BEB-2		10.0%
	1O—BEB-5		12.0%
	2-HHB-1		4.0%
	3-HHB—F		4.0%
	3-HHB-1		7.0%
	3-HHB—O1		4.0%
	3-HHB-3		13.0%
	NI = 65.2 (° C.)
	η = 20.6 (mPa · s)
	Δn = 0.155
	Δε = 6.9
	Vth = 1.71 (V)

Example 14

[0110]

	Si2—HB(F, F)—C	(No. 459)	12.0%
	Si2—HHB(F, F)—OCF2H	(No. 41)	7.0%
	Si3—HHB(F, F)—OCF2H	(No. 44)	7.0%
	Si4—HHB(F, F)—OCF2H	(No. 45)	7.0%
	2-HB—C		5.0%
	3-HB—O2		15.0%
	2-BTB-1		3.0%
	3-HHB-1		8.0%
	3-HHB—F		4.0%
	3-HHB—O1		5.0%
	3-HHB-3		14.0%
	3-HHEB—F		4.0%
	5-HHEB—F		4.0%
	3-HHB(F, F)—F		5.0%
	NI = 81.4 (° C.)
	η = 24.9 (mPa · s)
	Δn = 0.091
	Δε = 7.3
	Vth = 2.00 (V)

Example 15

[0111]

	Si2—HB(F)EB—OCF3	(No. 211)	4.0%
	Si3—HB(F)EB—OCF3	(No. 224)	4.0%
	Si2—HH—2V	(No. 738)	7.0%
	3-BEB(F)—C		8.0%
	3-HB—C		8.0%
	V—HB—C		8.0%
	3-HB—O2		3.0%
	3-HH—2V		14.0%
	V2—HHB-1		15.0%
	3-HHB-1		5.0%
	3-HHEB—F		7.0%
	3-H2BTB-2		6.0%
	3-H2BTB-3		6.0%
	3-H2BTB-4		5.0%
	NI = 101.0 (° C.)
	η = 17.1 (mPa · s)
	Δn = 0.130
	Δε = 8.6
	Vth = 2.18 (V)

Example 16

[0112]

	Si2—HB(F, F)—C	(No. 459)	24.0%
	V2—HB—C		12.0%
	1V2—HB—C		12.0%
	3-HB(F)—C		5.0%
	2-BTB-1		2.0%
	3-HH-4		8.0%
	3-HH—VFF		6.0%
	2-HHB—C		3.0%
	3-HHB—C		6.0%
	3-HB(F)TB-2		8.0%
	3-H2BTB-2		5.0%
	3-H2BTB-3		5.0%
	3-H2BTB-4		4.0%
	NI = 60.6 (° C.)
	η = 19.3 (mPa · s)
	Δn = 0.135
	Δε = 12.8
	Vth = 1.67 (V)

Example 17

[0113]

	Si2—HHB(2F, 3F)—O2	(No. 691)	7.0%
	5-BEB(F)—C		5.0%
	V—HB—C		11.0%
	5-PyB—C		6.0%
	4-BB-3		11.0%
	3-HH—2V		10.0%
	5-HH—V		11.0%
	V2—HHB-1		15.0%
	3-HHB-1		9.0%
	1V2—HBB-2		10.0%
	3-HHEBH-3		5.0%
	NI = 91.1 (° C.)
	η = 17.8 (mPa · s)
	Δn = 0.116
	Δε = 4.2
	Vth = 2.53 (V)

Example 18

[0114]

	Si2—HB(F, F)—C	(No. 459)	10.0%
	1V2—BEB(F, F)—C		8.0%
	3-HB—C		10.0%
	V2V—HB—C		4.0%
	V2V—HH-3		19.0%
	3-HB—O2		4.0%
	3-HHB-1		10.0%
	3-HHB-3		15.0%
	3-HB(F)TB-2		4.0%
	3-HB(F)TB-3		4.0%
	3-H2BTB-2		4.0%
	3-H2BTB-3		4.0%
	3-H2BTB-4		4.0%
	NI = 87.6 (° C.)
	η = 17.6 (mPa · s)
	Δn = 0.121
	Δε = 9.7
	Vth = 1.91 (V)

Example 19

[0115]

	Si2—HB(F, F)—C	(No. 459)	10.0%
	V2—HB—TC		10.0%
	3-HB—TC		10.0%
	5-HB—C		7.0%
	5-BB—C		3.0%
	2-BTB-1		10.0%
	2-BTB—O1		5.0%
	3-HH-4		5.0%
	3-HHB-1		10.0%
	3-HHB-3		11.0%
	3-H2BTB-2		3.0%
	3-H2BTB-3		3.0%
	3-HB(F)TB-2		3.0%
	5-BTB(F)TB-3		10.0%
	NI = 89.6 (° C.)
	η = 14.5 (mPa · s)
	Δn = 0.197
	Δε = 8.5
	Vth = 1.87 (V)

Example 20

[0116]

	Si2—HB(F, F)—C	(No. 459)	12.0%
	Si1—HH-5	(No. 742)	10.0%
	Si2—HH—2V	(No. 738)	10.0%
	1V2—BEB(F, F)—C		6.0%
	3-HB—C		6.0%
	2-BTB-1		10.0%
	5-HH—VFF		10.0%
	1-BHH—VFF		8.0%
	1-BHH—2VFF		11.0%
	3-H2BTB-2		5.0%
	3-H2BTB-3		4.0%
	3-H2BTB-4		4.0%
	3-HHB-1		4.0%
	NI = 67.8 (° C.)
	η = 12.7 (mPa · s)
	Δn = 0.121
	Δε = 8.5
	Vth = 1.79 (V)

Example 21

[0117]

	Si2—HB(F, F)—C	(No. 459)	15.0%
	5-HBCF2OB(F, F)—C		3.0%
	3-HB(F, F)CF2OB(F, F)—C		3.0%
	3-HB—C		3.0%
	2-BTB-1		10.0%
	5-HH—VFF		30.0%
	1-BHH—VFF		8.0%
	1-BHH—2VFF		11.0%
	3-H2BTB-2		5.0%
	3-H2BTB-3		4.0%
	3-H2BTB-4		4.0%
	3-HHB-1		4.0%
	NI = 66.8 (° C.)
	η = 13.0 (mPa · s)
	Δn = 0.116
	Δε = 7.0
	Vth = 2.03 (V)

Example 22

[0118]

	Si3—HHB(F)—OCF3	(No. 39)	8.0%
	Si4—HHB(F)—OCF3	(No. 38)	8.0%
	Si2—HB(F, F)B(F)—F	(No. 188)	6.0%
	Si3—HB(F, F)B(F)—F	(No. 189)	6.0%
	2-HHB(F)—F		17.0%
	3-HHB(F)—F		17.0%
	2-H2HB(F)—F		10.0%
	3-H2HB(F)—F		5.0%
	5-H2HB(F)—F		10.0%
	5-HBB(F)—F		13.0%
	NI = 86.7 (° C.)
	η = 29.8 (mPa · s)
	Δn = 0.089
	Δε = 6.6
	Vth = 1.90 (V)

[0119] When adding 0.3 part of CN to 100 parts of the composition described above, the pitch was 78.7 μm.

Example 23

[0120]

	Si2—HHB(F, F)—OCF2H	(No. 41)	10.0%
	Si3—HHB(F, F)—OCF2H	(No. 44)	10.0%
	Si2—HB(F)B(F, F)—F	(No. 193)	9.0%
	Si3—HB(F)B(F, F)—F	(No. 194)	9.0%
	7-HB(F, F)—F		3.0%
	3-HB—O2		7.0%
	5-HHB(F)—F		10.0%
	5-HBB(F)—F		16.0%
	2-HBB—F		4.0%
	3-HBB—F		4.0%
	5-HBB—F		3.0%
	3-HBB(F, F)—F		5.0%
	5-HBB(F, F)—F		10.0%
	NI = 71.1 (° C.)
	η = 31.5 (mPa · s)
	Δn = 0.111
	Δε = 7.7
	Vth = 1.69 (V)

Example 24

[0121]

	Si2—HB(F, F)—C	(No. 459)	8.0%
	Si1—HH-5	(No. 742)	6.0%
	5-HB—CL		16.0%
	3-HH-4		6.0%
	3-HH-5		4.0%
	3-HHB—F		4.0%
	3-HHB—CL		3.0%
	4-HHB—CL		4.0%
	3-HHB(F)—F		10.0%
	4-HHB(F)—F		9.0%
	5-HHB(F)—F		9.0%
	5-HBB(F)—F		4.0%
	5-HBBH—1O1		3.0%
	3-HHBB(F, F)—F		2.0%
	4-HHBB(F, F)—F		3.0%
	5-HHBB(F, F)—F		3.0%
	3-HH2BB(F, F)—F		3.0%
	4-HH2BB(F, F)—F		3.0%
	NI = 100.8 (° C.)
	η = 18.7 (mPa · s)
	Δn = 0.089
	Δε = 5.7
	Vth = 2.25 (V)

Example 25

[0122]

	Si2-HHB (F)-OCF3	(No. 36)	8.0%
	Si3-HHB (F)-OCF3	(No. 39)	8.0%
	Si2-HB (F) EB-OCF3	(No. 211)	10.0%
	Si4-HB (F, F) B (F)-F	(No. 182)	10.0%
	Si4-HB (F) B (F, F)-F	(No. 191)	10.0%
	3-HHB (F, F)-F		9.0%
	5-H2HB (F, F)-F		8.0%
	3-HBB (F, F)-F		11.0%
	3-H2BB (F, F)-F		10.0%
	5-HHBB (F, F)-F		3.0%
	5-HHEBB-F		2.0%
	3-HH2BB (F, F)-F		3.0%
	4-HBBH-101		4.0%
	5-HBBH-101		4.0%
	NI = 83.7 (° C.)
	η = 38.0 (mPa · s)
	Δn = 0.118
	Δε = 11.1
	Vth = 1.58 (V)

[0123] When adding 0.25 part of CM-43L to 100 parts of the composition described above, the pitch was 63.7 μm.

Example 26

[0124]

	Si2-HB (F, F)-C	(No. 459)	12.0%
	Si4-HHB (F)-OCF3	(No. 38)	5.0%
	Si4-HB (F) EB-OCF3	(No. 219)	10.0%
	6-HB-F		9.0%
	7-HB-F		7.0%
	2-HHB-OCF3		7.0%
	3-HHB-OCF3		7.0%
	4-HHB-OCF3		7.0%
	3-HH2B-OCF3		4.0%
	5-HH2B-OCF3		4.0%
	3-HHB (F, F)-OCF3		5.0%
	3-HBB (F)-F		10.0%
	3-HH2B (F)-F		3.0%
	3-HB (F) BH-3		3.0%
	5-HBBH-3		3.0%
	3-HHB (F, F)-OCF2H		4.0%
	NI = 79.4 (° C.)
	η = 22.3 (mPa · s)
	Δn = 0.094
	Δε = 8.8
	Vth = 1.65 (V)

Example 27

[0125]

	Si2-HB (F, F) B (F)-F	(No. 188)	7.0%
	Si3-HB (F, F) B (F)-F	(No. 189)	7.0%
	Si4-HB (F, F) B (F)-F	(No. 182)	15.0%
	Si2-HB (F) B (F, F)-F	(No. 193)	10.0%
	Si3-HB (F) B (F, F)-F	(No. 194)	11.0%
	Si4-HB (F) B (F, F)-F	(No. 191)	11.0%
	2-HHB (F)-F		3.0%
	4-HBB (F)-F		2.0%
	3-H2BB (F)-F		10.0%
	5-HBB (F, F)-F		6.0%
	2-HHB (F, F)-F		5.0%
	3-HHB (F, F)-F		5.0%
	4-HHB (F, F)-F		5.0%
	3-HHB-F		3.0%
	NI = 64.0 (° C.)
	η = 41.6 (mPa · s)
	Δn = 0.125
	Δε = 11.1
	Vth = 1.53 (V)

Example 28

[0126]

	Si2-HHB (F, F)-OCF2H	(No. 41)	10.0%
	Si4-HHB (F, F)-OCF2H	(No. 45)	10.0%
	Si2-HB (F) EB-OCF3	(No. 211)	3.0%
	Si3-HB (F) EB-OCF3	(No. 224)	3.0%
	Si4-HB (F) EB-OCF3	(No. 219)	3.0%
	5-HB-CL		11.0%
	3-HH-4		8.0%
	5-HBB (F, F)-F		15.0%
	3-HHB (F, F)-F		8.0%
	3-HHEB (F, F)-F		10.0%
	3-HBEB (F, F)-F		5.0%
	5-HBEB (F, F)-F		3.0%
	3-HHBB (F, F)-F		6.0%
	3-HHB-1		5.0%
	NI = 85.7 (° C.)
	η = 25.5 (mPa · s)
	Δn = 0.100
	Δε = 8.6
	Vth = 1.70 (V)

Example 29

[0127]

	Si4-HB (F) B (F, F)-F	(No. 191)	4.0%
	Si2-HH-2V	(No. 738)	6.0%
	7-HB (F)-F		6.0%
	5-H2B (F)-F		6.0%
	3-HB-O2		4.0%
	3-HH-4		6.0%
	2-HHB (F)-F		11.0%
	3-HHB (F)-F		11.0%
	5-HHB (F)-F		11.0%
	2-HBB (F)-F		2.0%
	3-HBB (F)-F		2.0%
	3-HBB (F, F)-F		3.0%
	2-HHBB (F, F)-F		4.0%
	3-HHBB (F, F)-F		5.0%
	3-HHEB-F		4.0%
	5-HHEB-F		4.0%
	3-HHB-1		7.0%
	3-HHB-F		4.0%
	NI = 97.3 (° C.)
	η = 20.4 (mPa · s)
	Δn = 0.086
	Δε = 4.8
	Vth = 2.34 (V)

Example 30

[0128]

	Si2-HHB (F)-OCF3	(No. 36)	10.0%
	Si3-HHB (F)-OCF3	(No. 39)	10.0%
	Si2-HB (F, F) B (F)-F	(No. 188)	15.0%
	Si4-HB (F, F) B (F)-F	(No. 182)	15.0%
	Si2-HB (F) B (F, F)-F	(No. 193)	16.0%
	Si4-HB (F) B (F, F)-F	(No. 191)	16.0%
	3-HH-4		4.0%
	5-H2HB (F, F)-F		8.0%
	3-HBB (F, F)-F		3.0%
	3-HHBB (F, F)-F		3.0%
	NI = 41.8 (° C.)
	η = 34.8 (mPa · s)
	Δn = 0.102
	Δε = 12.2
	Vth = 1.18 (V)

Example 31

[0129]

	Si2-HHB (F, F)-OCF2H	(No. 41)	10.0%
	Si4-HHB (F, F)-OCF2H	(No. 45)	10.0%
	Si2-HHB (F)-OCF3	(No. 36)	10.0%
	Si2-HB (F) EB-OCF3	(No. 211)	10.0%
	7-HB (F, F)-F		5.0%
	3-H2HB (F, F)-F		2.0%
	4-HHB (F, F)-F		5.0%
	3-HBB (F, F)-F		10.0%
	4-HHEB (F, F)-F		3.0%
	5-HHEB (F, F)-F		3.0%
	2-HBEB (F, F)-F		3.0%
	3-HBEB (F, F)-F		5.0%
	5-HBEB (F, F)-F		3.0%
	3-HGB (F, F)-F		15.0%
	3-HHBB (F, F)-F		6.0%
	NI = 76.9 (° C.)
	η = 39.0 (mPa · s)
	Δn = 0.094
	Δε = 14.5
	Vth = 1.32 (V)

Example 32

[0130]

	Si2-HB (F, F) B (F)-F	(No. 188)	5.0%
	Si3-HB (F, F) B (F)-F	(No. 189)	5.0%
	Si4-HHB (F)-OCF3	(No. 38)	5.0%
	5-H4HB (F, F)-F		7.0%
	5-H4HB-OCF3		15.0%
	3-H4HB (F, F)-CF3		8.0%
	5-H4HB (F, F)-CF3		10.0%
	3-HB-CL		6.0%
	5-HB-CL		4.0%
	2-H2BB (F)-F		5.0%
	5-H2HB (F, F)-F		5.0%
	3-HHB-OCF3		5.0%
	3-H2HB-OCF3		5.0%
	V-HHB (F)-F		5.0%
	3-HHB (F)-F		5.0%
	3-HBEB (F, F)-F		5.0%
	NI = 60.5 (° C.)
	η = 28.6 (mPa · s)
	Δn = 0.093
	Δε = 9.3
	Vth = 1.64 (V)

Example 33

[0131]

	Si4-HHB (2F, 3F)-O2	(No. 693)	3.0%
	Si1-HH-5	(No. 742)	5.0%
	Si2-HH-2V	(No. 738)	5.0%
	5-HB-CL		17.0%
	7-HB (F, F)-F		3.0%
	3-HH-5		5.0%
	3-HB-O2		15.0%
	3-H2HB (F, F)-F		5.0%
	4-H2HB (F, F)-F		5.0%
	3-HHB (F, F)-F		6.0%
	2-HHB (F)-F		7.0%
	3-HHB (F)-F		7.0%
	5-HHB (F)-F		7.0%
	3-HHB-1		5.0%
	3-HHB-O1		5.0%
	NI = 70.6 (° C.)
	η = 14.0 (mPa · s)
	Δn = 0.074
	Δε = 2.5
	Vth = 2.45 (V)

Example 34

[0132]

	Si3-HHB (F)-OCF3	(No. 39)	10.0%
	Si4-HHB (F)-OCF3	(No. 38)	9.0%
	Si2-HHB (F, F)-OCF2H	(No. 41)	8.0%
	Si2-HB (F, F) B (F)-F	(No. 188)	10.0%
	Si4-HB (F) B (F, F)-F	(No. 191)	10.0%
	5-HB-CL		4.0%
	7-HHB (F)-F		9.0%
	4-HHB (F, F)-F		3.0%
	3-H2HB (F, F)-F		12.0%
	3-HBB (F, F)-F		2.0%
	2-HHBB (F, F)-F		6.0%
	3-GHB (F, F)-F		3.0%
	4-GHB (F, F)-F		8.0%
	5-GHB (F, F)-F		6.0%
	NI = 66.8 (° C.)
	η = 39.4 (mPa · s)
	Δn = 0.089
	Δε = 10.6
	Vth = 1.18 (V)

Example 35

[0133]

	Si2—HHB(F)—OCF3	(No. 36)	7.0%
	Si4—HHB(F)—OCF3	(No. 38)	7.0%
	Si3—HB(F)EB—OCF3	(No. 224)	10.0%
	Si3—HB(F, F)B(F)—F	(No. 189)	7.0%
	Si3—HB(F)B(F, F)—F	(No. 194)	7.0%
	3-HHB(F)—F		8.0%
	3-HHB(F, F)—F		8.0%
	3-HBB(F, F)—F		7.0%
	3-H2HB(F, F)—F		10.0%
	4-HHEB(F, F)—F		3.0%
	2-HBEB(F, F)—F		2.0%
	3-HBEB(F, F)—F		3.0%
	3-GHB(F, F)—F		3.0%
	4-GHB(F, F)—F		7.0%
	5-GHB(F, F)—F		7.0%
	3-HHBB(F, F)—F		4.0%
	NI = 70.5 (° C.)
	η = 41.0 (mPa · s)
	Δn = 0.092
	Δε = 12.3
	Vth = 1.16 (V)

Example 36

[0134]

	Si2—HB(F, F)—C	(No. 459)	4.0%
	Si3—HB(F)EB—OCF3	(No. 224)	5.0%
	Si4—HHB(F, F)—OCF2H	(No. 45)	6.0%
	Si2—HHB(F)—OCF3	(No. 36)	4.0%
	7-HB(F)—F		3.0%
	5-HB—CL		3.0%
	3-HH-4		9.0%
	3-HH—EMe		23.0%
	3-HHEB(F, F)—F		10.0%
	3-HHEB—F		8.0%
	5-HHEB—F		8.0%
	4-HGB(F, F)—F		5.0%
	3-H2GB(F, F)—F		5.0%
	5-GHB(F, F)—F		7.0%
	NI = 81.0 (° C.)
	η = 22.5 (mPa · s)
	Δn = 0.069
	Δε = 6.7
	Vth = 1.41 (V)

Example 37

[0135]

	Si2—HB(F)B(F, F)—F	(No. 193)	10.0%
	Si3—HB(F)B(F, F)—F	(No. 194)	10.0%
	Si4—HB(F)B(F, F)—F	(No. 191)	10.0%
	3-H2HB(F, F)—F		5.0%
	5-H2HB(F, F)—F		5.0%
	5-HBB(F, F)—F		30.0%
	5-HBB(F)B-2		10.0%
	5-HBB(F)B-3		10.0%
	3-BB(F)B(F, F)—F		5.0%
	5-B2B(F, F)B(F)—F		5.0%
	NI = 94.0 (° C.)
	η = 52.1 (mPa · s)
	Δn = 0.148
	Δε = 11.3
	Vth = 1.66 (V)

Example 38

[0136]

	Si2—HHB(F, F)—OCF2H	(No. 41)	6.0%
	Si2—HB(F)EB—OCF3	(No. 211)	8.0%
	Si2—HH—2V	(No. 738)	10.0%
	3-HB(F, F)CF2OB(F, F)—F		11.0%
	5-HB(F, F)CF2OB(F, F)—F		11.0%
	5-HB—CL		7.0%
	3-HH-4		4.0%
	2-HH-5		4.0%
	3-HHB-1		4.0%
	3-HHEB—F		6.0%
	5-HHEB—F		6.0%
	4-HHB(F, F)—F		3.0%
	4-HHEB(F, F)—F		3.0%
	5-HHEB(F, F)—F		2.0%
	2-HBEB(F, F)—F		3.0%
	3-HBEB(F, F)—F		3.0%
	5-HBEB(F, F)—F		3.0%
	2-HHBB(F, F)—F		3.0%
	3-HHBB(F, F)—F		3.0%
	NI = 81.0 (° C.)
	η = 22.1 (mPa · s)
	Δn = 0.083
	Δε = 9.0
	Vth = 1.38 (V)

Example 39

[0137]

	Si2—HHB(F)—OCF3	(No. 36)	5.0%
	Si2—HB(F, F)B(F)—F	(No. 188)	5.0%
	Si2—HB(F)B(F, F)—F	(No. 193)	5.0%
	3-BB(F, F)CF2OB(F, F)—F		35.0%
	3-HH-4		8.0%
	3-HHB(F, F)—F		5.0%
	3-H2HB(F, F)—F		9.0%
	3-HBB(F, F)—F		5.0%
	2-HHBB(F, F)—F		3.0%
	3-HHBB(F, F)—F		3.0%
	3-HH2BB(F, F)—F		4.0%
	3-HHB-1		6.0%
	5-HBBH—1O1		7.0%
	NI = 76.7 (° C.)
	η = 29.8 (mPa · s)
	Δn = 0.114
	Δε = 12.8
	Vth = 1.36 (V)

Example 40

[0138]

	Si2—HB(2F, 3F)—O2	(No. 678)	7.0%
	Si4—HB(2F, 3F)—O2	(No. 676)	7.0%
	3-HEB—O4		28.0%
	4-HEB—O2		20.0%
	5-HEB—O1		20.0%
	3-HEB—O2		18.0%
	NI = 64.7 (° C.)
	η = 19.8 (mPa · s)
	Δn = 0.089

Example 41

[0139]

	Si2—HB(2F, 3F)—O2	(No. 678)	12.0%
	Si4—HB(2F, 3F)—O2	(No. 676)	11.0%
	Si2—HHB(2F, 3F)—O2	(No. 691)	14.0%
	Si4—HHB(2F, 3F)—O2	(No. 693)	15.0%
	Si2—HHB(2F, 3F)-2	(No. 694)	14.0%
	3-HH-2		5.0%
	3-HH-4		6.0%
	3-HH—O1		4.0%
	3-HH—O3		5.0%
	5-HH—O1		4.0%
	3-HHB(2F, 3F)-2		10.0%
	NI = 74.0 (° C.)
	Δn = 0.080
	Δε = −4.0

Example 42

[0140]

	Si2—HB(2F, 3F)—O2	(No. 678)	10.0%
	Si4—HB(2F, 3F)—O2	(No. 676)	10.0%
	Si2—HHB(2F, 3F)—O2	(No. 691)	12.0%
	Si4—HHB(2F, 3F)—O2	(No. 693)	13.0%
	Si2—HHB(2F, 3F)-2	(No. 694)	4.0%
	3-HH-5		5.0%
	3-HH-4		5.0%
	3-HH—O1		6.0%
	3-HH—O3		6.0%
	3-HB—O1		5.0%
	3-HB—O2		5.0%
	2-HHB(2F, 3F)-1		4.0%
	3-HHEH-3		5.0%
	3-HHEH-5		5.0%
	4-HHEH-3		5.0%
	NI = 78.5 (° C.)
	Δn = 0.077
	Δε = −3.3

Example 43

[0141]

	Si2—HB(F, F)—C	(No. 459)	5.0%
	3-BB(2F, 3F)—O2		12.0%
	3-BB(2F, 3F)—O4		10.0%
	5-BB(2F, 3F)—O4		10.0%
	2-BB(2F, 3F)B-3		20.0%
	3-BB(2F, 3F)B-5		13.0%
	5-BB(2F, 3F)B-5		14.0%
	5-BB(2F, 3F)B-7		16.0%
	NI = 66.4 (° C.)
	Δn = 0.190
	Δε = −1.9

Example 44

[0142]

	Si2—HB(F, F)B(F)—F	(No. 188)	3.0%
	Si2—HB(F)B(F, F)—F	(No. 193)	3.0%
	3-HB—O1		15.0%
	3-HB—O2		6.0%
	3-HEB(2F, 3F)—O2		9.0%
	4-HEB(2F, 3F)—O2		9.0%
	5-HEB(2F, 3F)—O2		9.0%
	2-BB2B—O2		6.0%
	3-BB2B—O2		6.0%
	5-BB2B—O1		6.0%
	1-B2BB(2F)-5		7.0%
	3-B2BB(2F)-5		7.0%
	5-B(F)BB—O2		7.0%
	3-BB(2F, 3F)B-3		7.0%
	NI = 75.4 (° C.)
	η = 24.2 (mPa · s)
	Δn = 0.155

Example 45

[0143]

	Si4-HHB (F)-OCF3	(No. 38)	5.0%
	3-HH-O1		8.0%
	5-HH-O1		4.0%
	3-HH-4		5.0%
	3-HB (2F, 3F)-O2		16.0%
	5-HB (2F, 3F)-O2		21.0%
	3-HHB (2F, 3F)-1		7.0%
	3-HHB (2F, 3F)-O2		14.0%
	5-HHB (2F, 3F)-O2		20.0%
	NI =	61.0 (° C.)
	η =	23.8 (mPa · s)
	Δn =	0.076
	Δε =	−3.5

Example 46

[0144]

	Si2-HB (2F, 3F)-O2	(No. 678)	12.0%
	Si4-HB (2F, 3F)-O2	(No. 676)	12.0%
	Si2-HHB (2F, 3F)-1	(No. 692)	12.0%
	Si2-HHB (2F, 3F)-2	(No. 694)	12.0%
	Si2-HHB (2F, 3F)-O2	(No. 691)	13.0%
	Si4-HHB (2F, 3F)-O2	(No. 693)	13.0%
	3-HB-O1		15.0%
	3-HH-4		5.0%
	3-HHB-1		6.0%
	NI =	74.5 (° C.)
	η =	38.3 (mPa · s)
	Δn =	0.090
	Δε =	−3.4

Example 47

[0145]

	Si2-HB (2F, 3F)-O2	(No. 678)	12.0%
	Si4-HB (2F, 3F)-O2	(No. 676)	12.0%
	Si2-HHB (2F, 3F)-1	(No. 692)	12.0%
	Si2-HHB (2F, 3F)-2	(No. 694)	12.0%
	3-HB-O1		15.0%
	3-HH-4		5.0%
	3-HHB (2F, 3F)-O2		13.0%
	5-HHB (2F, 3F)-O2		13.0%
	6-HEB (2F, 3F)-O2		6.0%
	NI =	74.2 (° C.)
	η =	36.2 (mPa · s)
	Δn =	0.087
	Δε =	−3.7

Example 48

[0146]

	Si2-HB (2F, 3F)-O2	(No. 678)	3.0%
	Si4-HHB (2F, 3F)-O2	(No. 693)	3.0%
	3-HB-O2		20.0%
	1O1-HH-3		6.0%
	1O1-HH-5		5.0%
	3-HH-EMe		12.0%
	4-HEB-O1		9.0%
	4-HEB-O2		7.0%
	5-HEB-O1		8.0%
	3-HHB-1		6.0%
	3-HHB-3		6.0%
	3-HEB (2 CN, 3CN)-O5		4.0%
	4-HEB (2 CN, 3CN)-O5		3.0%
	5-HEB (2 CN, 3CN)-O5		2.0%
	2-HBEB (2CN, 3CN)-O2		2.0%
	4-HBEB (2CN, 3CN)-O4		4.0%
	NI =	70.4 (° C.)
	η =	30.7 (mPa · s)
	Δn =	0.080
	Δε =	−5. 4
	Vth =	1.60 (V)

[0147] Effects of the Invention

[0148] The compounds of the present invention, that is, the di- to tetracyclic compounds having SiH3 at a terminal are sufficiently stable physically and chemically under the condition where the a liquid crystal display device is usually used. It is characterized by having a good mutual solubility, a low viscosity and a low threshold voltage. Further, addition of the compound of the present invention makes it possible, as shown in the examples, to provide a liquid crystal composition and a liquid crystal display which have good characteristics and are novel.

Claims

1. A silicon compound represented by formula (1):

2. The silicon compound defined in claim 1, wherein in formula (1) described in claim 1, p and q are 0; A1 and A2 each are independently 1,4-cyclohexylene, 1,4-cyclohexylene in which one or more non-adjacent —CH2— are replaced by —O—, 1,4-phenylene, 1,4-phenylene in which any hydrogen is replaced by halogen, or pirimidine-2,5-diyl; and Z1 is a single bond, —(CH2)2—, —CH═CH—, —C≡C—, —(CH2)4—, —COO—, —OCO—, —OCF2—, or —CF2O—.

3. The silicon compound defined in claim 1, wherein in formula (1) described in claim 1, p is 1; q is 0; A1, A2 and A3 each are independently 1,4-cyclohexylene, 1,4-cyclohexylene in which one or more non-adjacent —CH2— are replaced by —S—,1,4-phenylene, 1,4-phenylene in which any hydrogen is replaced by halogen, or pirimidine-2,5-diyl; and Z1 and Z2 each are independently a single bond, —(CH2)2—, —CH═CH—, —C≡C—, —COO—, —OCO—, —(CH2)4—, —OCF2—, or —CF2O—.

4. The silicon compound defined in claim 1, wherein in formula (1) described in claim 1, p and q are 1; A1, A2, A3, and A4 each are independently 1,4-cyclohexylene, 1,4-cyclohexylene in which one or more non-adjacent —CH2— are replaced by —S—,1,4-phenylene, 1,4-phenylene in which any hydrogen is replaced by halogen, or pirimidine-2,5-diyl; and Z1, Z2 and Z3 each are independently a single bond, —(CH2)2—, —CH═CH—, —C≡C—, —COO—, —OCO—, —(CH2)4—, —OCF2—, or —CF2O—.

5. The silicon compound defined in claim 1, wherein in formula (1) described in claim 1, Y1 is alkylene having 1 to 10 carbon, in which any —CH2— in the alkylene may be replaced by —O— or —CH═CH—, but —O— and —O— or —O— and SiH3 are not adjacent; Y2 is alkyl having 1 to 10 carbon, in which any —CH2— in the alkyl may be replaced by —O—, —CH═CH— or —C≡C—, but —O— and —O— are not adjacent; and A1, A2, A3, and A4 each are independently 1,4-cyclohexylene, 1,4-cyclohexylene in which one or more non-adjacent —CH2— are replaced by —O—, 1,4-phenylene, or pirimidine-2,5-diyl.

6. The silicon compound defined in claim 1, wherein in formula (1) described in claim 1, Y1 is alkylene having 1 to 10 carbon, in which any —CH2— in the alkylene may be replaced by —O— or —CH═CH—, but —O— and —O— or —O— and SiH3 are not adjacent; Y2 is halogen, —CN, —C≡C—CN, or alkyl having 1 to 10 carbon, in which any —CH2— in the alkyl may be replaced by —O—, but —O— and —O— are not adjacent, and at least one hydrogen is replaced by halogen; and A1, A2, A3, and A4 each are independently 1,4-cyclohexylene in which one or more non-adjacent —CH2— are replaced by —S—,1,4-phenylene, 1,4-phenylene in which at least one hydrogen is replaced by halogen, or pirimidine-2,5-diyl.

7. The silicon compound defined in claim 1, wherein in formula (1) described in claim 1, Y1 is alkylene having 1 to 10 carbon, in which any —CH2— in the alkylene may be replaced by —O— or —CH═CH—, but —O— and —O— or —O— and SiH3 are not adjacent; Y2 is alkyl having 1 to 10 carbon, in which any —CH2— in the alkyl may be replaced by —O—, —S— or —CH═CH—, but —O— and —O—, —S— and —S— or —O— and —S— are not adjacent; A1, A2, A3 and A4 each are independently 1,4-cyclohexylene, 1,4-cyclohexylene in which one or more non-adjacent —CH2— are replaced by —O—, 1,4-phenylene in which a 2-position is replaced by halogen, 1,4-phenylene in which a 3-position is replaced by halogen, or 1,4-phenylene in which a 2-position and a 3-position are replaced by halogen, and one of A1, A2 A3, and A4 is always 1,4-phenylene in which a 2-position or a 3-position is replaced by halogen or 1,4-phenylene in which a 2-position and a 3-position are replaced by halogen.

8. A liquid crystal composition comprising at least one silicon compound defined in any one of claims 1 to 7.

9. The liquid crystal composition defined in claim 8, comprising at least one silicon compound described in any one of claims 1 to 7 as a first component and at least one compound selected from the group of compounds represented by formulas (2), (3) and (4) as a second component:

10. The liquid crystal composition defined in claim 8, comprising at least one silicon compound described in any one of claims 1 to 7 as the first component and at least one compound selected from the group of compounds represented by formulas (5) and (6) as a second component:

11. The liquid crystal composition defined in claim 8, comprising at least one silicon compound described in any one of claims 1 to 7 as the first component and at least one compound selected from the group of compounds represented by formulas (7), (8) and (9) as a second component:

12. The liquid crystal composition defined in claim 8, comprising at least one silicon compound described in any one of claims 1 to 7 as the first component, at least one compound selected from the group of the compounds represented by formulas (2), (3) and (4) described in claim 9 as the second component, and at least one compound selected from the group of compounds represented by formulas (10), (11) and (12) as a third component:

13. The liquid crystal composition defined in claim 8, comprising at least one silicon compound described in any one of claims 1 to 7 as the first component, at least one compound selected from the group of the compounds represented by formulas (5) and (6) described in claim 10 as the second component, and at least one compound selected from the group of the compounds represented by formulas (10), (11) and (12) described in claim 12 as the third component.

14. The liquid crystal composition defined in claim 8, comprising at least one silicon compound described in any one of claims 1 to 7 as the first component, at least one compound selected from the group of the compounds represented by formulas (7), (8) and (9) described in claim 11 as the second component and at least one compound selected from the group of the compounds represented by formulas (10), (11) and (12) described in claim 12 as the third component.

15. The liquid crystal composition defined in claim 8, comprising at least one silicon compound described in any one of claims 1 to 7 as the first component, at least one compound selected from the group of the compounds represented by formulas (2), (3) and (4) described in claim 9 as the second component, at least one compound selected from the group of the compounds represented by formulas (5) and (6) described in claim 10 as the third component, and at least one compound selected from the group of the compounds represented by formulas (10), (11) and (12) described in claim 12 as a fourth component.

16. A liquid crystal composition comprising at least one liquid crystal composition defined in claims 8 and further comprising at least one optically active compound.

17. A liquid crystal display using the liquid crystal composition defined in any of claims 8 to 15.