Patent Application
20190127403
The present invention relates to a silicon-containing sulfuric acid ester salt.
In recent years, along with rapid proliferation of mobile electronic devices such as digital cameras, smartphones, and tablets, increasing are the demand for power storage devices such as secondary batteries which are used as power sources of these devices and can be repeatedly used by charging, and the demand for the increase of their capacity and energy density.
These power storage devices commonly include a solution of an electrolytic salt in an aprotic organic solvent as an electrolytic solution. Various combination of these electrolyte salts and aprotic organic solvents have been studied up to date. Examples of the widely used electrolytic salts include quaternary ammonium salts (Patent Documents 1 to 3) and quaternary phosphonium salts (Patent Document 4), owing to their high solubility in organic solvents and degree of dissociation, and wide electrochemical stable ranges.
However, these electrolytic salts contain halogen atoms such as fluorine atoms in anions, and thus still have problems in terms of environment load, so that these problems are expected to be solved. Additionally, the electrolytic salts for the above-described uses are demanded to have electrochemical properties such as high ion electrical conductivity and wide electric potential windows.
Patent Document 1: JP-A S61-32509
Patent Document 2: JP-A S63-173312
Patent Document 3: JP-A H10-55717
Patent Document 4: JP-A S62-252927
The present invention has been made in view of the above-described circumstances, and is intended to provide a novel silicon-containing sulfuric acid ester salt which is free of halogen atom, and is suitable as an electrolyte and an electrolytic solution for power storage devices.
As a result of dedicated research for achieving the above-described purpose, the inventor has found that a silicon-containing sulfuric acid ester salt composed of a silicon atom-containing sulfate anion and a certain monovalent cation has marked electrochemical properties, and thus completed the present invention.
That is, the present invention provides the silicon-containing sulfuric acid ester salt.
wherein R1 to R3 each independently represent an alkyl group having 1 to 4 carbon atoms, and n represents an integer of 2 to 4,
wherein R4 to R7 each independently represent an alkyl group having 1 to 4 carbon atoms, or an alkoxyalkyl group represented by —(CH2)k—OR, any two of R4 to R7 may be bonded to each other to form a ring together with a nitrogen atom to which they bond, and the remaining two may be bonded to each other to form a spiro ring wherein a spiro atom is a nitrogen atom, R8 represents an alkyl group having 1 to 12 carbon atoms, R9 represents an alkyl group having 1 to 20 carbon atoms, R10 and R11 each independently represent an alkyl group having 1 to 12 carbon atoms, or an alkoxyalkyl group represented by —(CH2)k—OR, R12 represents an alkyl group having 1 to 12 carbon atoms, or an alkoxyalkyl group represented by —(CH2)k—OR, the symbol k represents 1 or 2, and R represents a methyl group or an ethyl group.
wherein R and k are the same as the above-described ones, R21 to R24 each independently represent an alkyl group having 1 to 4 carbon atoms, R25 and R26 each independently represent an alkyl group having 1 to 4 carbon atoms, and R25 and R26 may be bonded to each other to form a ring together with the nitrogen atom to which they bond.
The silicon-containing sulfuric acid ester salt of the present invention is halogen-free, and thus gives a small environment load. Additionally, the silicon-containing sulfuric acid ester salt of the present invention has a wider electric potential window than prior art halogen-free salts, and is electrochemically stable.
An anion composing a silicon-containing sulfuric acid ester salt of the present invention is represented by the following formula (1).
In the formula (1), R1 to R3 each independently represent an alkyl group having 1 to 4 carbon atoms. The alkyl group may be linear, branched, or cyclic, and its examples include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, a cyclopropyl group, an n-butyl group, a sec-butyl group, an isobutyl group, a tert-butyl group, and a cyclobutyl group. Among them, R1 to R3 are preferably alkyl groups having 1 to 3 carbon atoms, more preferably linear alkyl groups having 1 to 3 carbon atoms, and even more preferably methyl groups or ethyl groups, and yet even more preferably methyl groups.
In the formula (1), n represents an integer of 2 to 4, and is preferably 2 or 3.
The cation composing the silicon-containing sulfuric acid ester salt of the present invention is any one selected from those represented by the following formulae (2) to (5).
In the formula (2), R4 to R7 each independently an alkyl group having 1 to 4 carbon atoms, or an alkoxyalkyl group represented by —(CH2)k—OR. The symbol k represents 1 or 2. R represents a methyl group or an ethyl group.
Examples of the alkyl group having 1 to 4 carbon atoms include those listed as the examples of R1 to R3. Examples of the alkoxyalkyl group include a methoxymethyl group, an ethoxy methyl group, a methoxyethyl group, and an ethoxyethyl group. Among the alkoxyalkyl groups, a methoxyethyl group or an ethoxyethyl group is preferred.
Any two of R4 to R7 may be bonded to each other to form a ring together with the nitrogen atom to which they bond, and the remaining two may be bonded to each other to form a spiro ring wherein the spiro atom is a nitrogen atom. In this case, examples of the to ring include an aziridine ring, an azetidine ring, a pyrrolidine ring, a piperidine ring, an azepane ring, an imidazolidine ring, a pyridine ring, pyrrole ring, an imidazole ring, and a quinol ring. Among them, a pyrrolidine ring, a piperidine ring, an imidazolidine ring, a pyridine ring, a pyrrole ring, an imidazole ring, and a quinol ring are preferred, and a pyrrolidine ring and an imidazolidine ring are more preferred. The spiro ring is particularly preferably a 1,1′-spirobipyrrolidine ring.
Specific examples of the quaternary ammonium ion represented by the formula (2) include those represented by the formulae (2-1) to (2-4).
In the formulae (2-1) to (2-4), R and k represent the same ones as described above. R21 to R24 each independently represents an alkyl group having 1 to 4 carbon atoms. R25 and R26 each independently represent an alkyl group having 1 to 4 carbon atoms. The R25 and R26 may be bonded to each other to form a ring together with the nitrogen atom to which they bond.
Specific examples of the quaternary ammonium ion represented by the formula (2) are shown below, but not limited thereto.
In the formula (3), R8 represents an alkyl group having 1 to 12 carbon atoms. The alkyl group having 1 to 12 carbon atoms may be linear, branched, or cyclic, and its examples include the alkyl group having 1 to 4 carbon atoms described above, and an n-pentyl group, a cyclopentyl group, an n-hexyl group, a cyclohexyl group, an n-heptyl group, an n-octyl group, an n-nonyl group, an n-decyl group, an n-undecyl group, and an n-dodecyl group.
In the formula (3), R9 represents an alkyl group having 1 to 20 carbon atoms. The alkyl group having 1 to 20 carbon atoms may be linear, branched, or cyclic, and its examples include the alkyl group having 1 to 12 carbon atoms described above, an n-tridecyl group, an n-tetradecyl group, an n-pentadecyl group, an n-hexadecyl group, an n-heptadecyl group, an n-octadecyl group, an n-nonadecyl group, and an n-eicosyl group.
Of the quaternary phosphonium ions represented by the formula (3), those having a structure including different R8 and R9 tend to form an ionic liquid. In this case, R8 is preferably an alkyl group having 2 to 8 carbon atoms, more preferably an alkyl group having 3 to 8 carbon atoms, and even more preferably an alkyl group having 4 to 8 carbon atoms. Specifically, R8 is preferably an n-butyl group or an n-hexyl group. R9 is preferably an alkyl group having 10 to 20 carbon atoms, and more preferably an alkyl group having 12 to 20 carbon atoms.
Examples of the quaternary phosphonium ion represented by the formula (3) are shown below, but not limited thereto.
In the formula (4), R10 and R11 each independently represent an alkyl group having 1 to 12 carbon atoms, or an alkoxyalkyl group represented by —(CH2)k—OR. R and k are the same as those described above. Examples of the alkyl group having 1 to 12 carbon atoms include those listed as the examples of R8. The alkyl group preferably has 1 to 8 carbon atoms, and more preferably has 1 to 4 carbon atoms in terms of cost. Examples of the alkoxyalkyl group include those listed as the examples of R4 to R7.
In the formula (5), R12 represents an alkyl group having 1 to 12 carbon atoms, or an alkoxyalkyl group represented by —(CH2)k—OR. R and k are the same as those described above. Examples of the alkyl group having 1 to 12 carbon atoms include the same ones listed as the examples of R8. The alkyl group preferably has 1 to 8 carbon atoms, and more preferably has 1 to 4 carbon atoms in terms of cost. Examples of the alkoxyalkyl group include those listed as the examples of R4 to R7.
The silicon-containing sulfuric acid ester salt of the present invention may be an ionic liquid depending on the type of the cation. For example, those including a cation represented by the formula (2-4) is an ionic liquid, and those represented by the formula (3) tend to be an ionic liquid when R8 and R9 have different structures. The ionic liquid is a salt composed solely of an ion, and generally refers to that having a melting point of 100° C. or lower. The ionic liquid including the silicon-containing sulfuric acid ester salt of the present invention is preferably in a liquid state at room temperature (25° C.).
The silicon-containing sulfuric acid ester salt of the present invention can be produced by, for example, a neutralization method with an ion exchange resin using the silicon-containing sulfuric acid ester salt represented by the formula (6) and the salt represented by the formula (7).
In the formula, R1 to R3 and n are the same as the above-described ones. M+ represents an ammonium ion or a monovalent metal ion. Examples of the monovalent metal ion include Li+, Na+, and K+. A+ represents any one selected from the cations represented by the formulae (2) to (5). X− represents a halide ion. Examples of the halide ion include a fluoride ion, a chloride ion, a bromide ion, and an iodide ion. Among them, a chloride ion, a bromide ion, and an iodide ion are preferred.
The silicon-containing sulfuric acid ester salt represented by the formula (6) may be synthesized by a known method, such as the method described in Al-Horani, R. A., and Desai, U. R., Tetrahedron, 66 (2010), 2907-2918. For example, it can be readily obtained by heating a silicon-containing alcohol and amidosulfuric acid (sulfamic acid) to about 130 to 150° C. in the presence of urea. The salt represented by the formula (7) may be synthesized according to any known method, or may use any commercial product.
When the neutralization method is used, firstly, the silicon-containing sulfuric acid ester salt represented by the formula (6) and the salt represented by the formula (7) are converted to the silicon-containing sulfate and hydroxide represented by the formula (6′) using a cation exchange resin and an anionic exchange resin, respectively, and they are mixed.
(In the formula, R1 to R3 and n are the same as those described above.)
When the neutralization method is used in the present invention, the counter ion is not particularly limited as long as it allows ion exchange of the silicon-containing sulfuric acid ester salt represented by the formula (6) and the salt represented by the formula (7). However, in terms of cost, the silicon-containing sulfuric acid ester salt represented by the formula (6) is preferably an ammonium salt, a sodium salt, or a potassium salt. The counter ion the salt represented by the formula (7) is preferably a halide ion, and particularly preferably a chloride ion or a bromide ion in terms of cost.
The molar ratio between the silicon-containing sulfate and the hydroxide in the neutralization reaction is not particularly limited, and may be about 5:1 to 1:5. In consideration of cost, the molar ratio is preferably close to 1:1, and it is particularly preferred that the point of reaction completion is the neutralization point of the aqueous layer.
After the completion of the reaction, ordinary aftertreatment is carried out to obtain the target object.
Examples of the other method for producing the silicon-containing sulfuric acid ester salt include ion exchange with an ion exchange resin using the silicon-containing sulfuric acid ester salt represented by the formula (6) and the salt represented by the formula (7).
Specifically, the ion exchange method is carried out as follows: firstly, an aqueous solution of the salt represented by the formula (7) is passed through a column filled with a cation exchange resin, thereby allowing the cation exchange resin to carry the cation of the salt, and the column is washed with water. Subsequently, the silicon-containing sulfuric acid ester salt represented by the formula (6) is passed through the column, the eluate is collected, and purified to obtain the desired silicon-containing sulfuric acid ester salt.
The cation exchange resin may be a commonly used cation exchange resin, but is preferably a strongly acidic cation exchange resin. They are commercially available.
The silicon-containing sulfuric acid ester salt of the present invention is useful as an electrolyte or an additive for electrolytes for power storage devices such as electric double layer capacitors, lithium ion capacitors, redox capacitors, lithium secondary batteries, lithium ion secondary batteries, lithium air batteries, and proton polymer batteries. The silicon-containing sulfuric acid ester salt of the present invention is also useful as an antistatic agent, a plasticizer, or a lubricant added to polymer materials such as rubber and plastic.
The ionic liquid including the silicon-containing sulfuric acid ester salt of the present invention is a halogen-free ionic liquid, so that is useful as a green solvent having a low impact on the environment. In particular, the ionic liquid including the silicon-containing sulfuric acid ester salt of the present invention has a wider electric potential window and is more electrochemically stable than prior art ionic liquids as well as prior art solid electrolyte salts, and thus are suitable as electrolytes and electrolytic solutions of electric storage devices.
The present invention is more specifically described below with reference to Examples, but the present invention will not be limited to the following Examples. The reagents, analyzers, and conditions used in Examples are as follows.
1.0 equivalent of trimethylsilyl propanol (Sigma-Aldrich), 1.1 equivalent of amidosulfuric acid (Wako Pure Chemical Industries, Ltd.), and 0.2 equivalent of urea (Wako Pure Chemical Industries, Ltd.) were mixed in a nitrogen atmosphere, and heated to 150° C. under stirring. After the temperature reached to 150° C., heating was continued for 6 hours under stirring, and then the temperature was allowed to decrease to room temperature. To the mixture, ethyl acetate (Wako Pure Chemical Industries, Ltd.) was added until the solid thus obtained was completely immersed therein, the solid was broken with a spatula, stirring was continued for about one hour, and then the solid was isolated by filtration under reduced pressure, and dried. In this manner, the target compound A containing some urea was obtained (yield 79%).
To 1.0 equivalent of the compound A thus obtained, HISHICOLIN PX-412C (Nippon Chemical Industries Co., Ltd., 50% aqueous solution of dodecyl tributyl phosphonium chloride) was added to make the amount of dodecyl tributyl phosphonium chloride 1.0 equivalent, and the mixture was stirred for 30 minutes. To the reaction liquid in two layers, ethyl acetate (Wako Pure Chemical Industries, Ltd.) was added in the same volume with HISHICOLIN PX-412C, and further stirred for 3 hours. After standing, the aqueous layer in the lower layer was removed, and deionized water (half volume of HISHICOLIN PX-412C) and 0.15 equivalent of the compound A were added to the organic layer. After stirring for 3 hours, the liquid was separated again, and the organic layer was washed with water four times. The solvent and water were removed from the organic layer using an evaporator, and then a vacuum pump, thereby obtaining the silicon-containing sulfuric acid ester salt 1 in the form of a colorless transparent liquid (yield: 92%). The 1H-NMR chart (solvent: chloroform-d), DSC chart, and TG-DTA chart of the silicon-containing sulfuric acid ester salt 1 are given in
A silicon-containing sulfuric acid ester salt 2 in the form of a colorless transparent liquid was obtained in the same manner as in Example 1 (yield 91%), except that HISHICOLIN PX-412C was replaced with HISHICOLIN PX-416C (50% aqueous solution of hexadecyl tributyl phosphonium chloride, Nippon Chemical Industries Co., Ltd.,). The 1H-NMR chart (solvent: chloroform-d), DSC chart, and TG-DTA chart of the silicon-containing sulfuric acid ester salt 2 are given in
The melting point and decomposition point (10% weight decrease, in atmosphere) of the silicon-containing sulfuric acid ester salts 1 and 2 obtained from the DSC and TG-DTA measurements are given in Table 1.
The silicon-containing sulfuric acid ester salt 1 (Example 3) and the silicon-containing sulfuric acid ester salt 2 (Example 4) were subjected to cyclic voltammetry measurement. The results are given in
| Number | Date | Country | Kind |
|---|---|---|---|
| 2016-085077 | Apr 2016 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2017/009018 | 3/7/2017 | WO | 00 |
