Claims
- 1. A compound represented by the formula: ##STR26## wherein at least one X is ##STR27## and each remaining X is independently selected from the group consisting of hydrogen, halogen, hydroxyl, amino which may be substituted by a linear or branched alkyl group of 1 to 6 carbon atoms, carboxyl, alkyl having 1 to 6 carbon atoms, and alkoxy having 1 to 6 carbon atoms;
- each R, which may be the same or different, represents hydrogen or a linear, branched-chain or cyclic hydrocarbon group of 1 to 8 carbon atoms; m, n and h each represents integers from 1 to 6; "a" represents an integer from 1 to 400; and
- wherein B is R or ##STR28## wherein two of the Ys are a nitrogen atom and the remaining Y is a carbon atom.
- 2. A compound according to claim 1, represented by the general formula: ##STR29## wherein R, m, n, h, and "a" have the same meaning as given previously; p represents an integer from 1 to 3; and, when p is 1 or 2, a hydroxyl group, an amino group which may be substituted by a linear or branched alkyl group of 1 to 6 carbon atoms, a halogen atom, a carboxyl group, a linear or branched alkyl group of 1 to 6 carbon atoms, or a linear or branched alkoxyl group of 1 to 6 carbon atoms, or as well a hydrogen atom, is bound to a residual carbon atom of the ring.
- 3. A compound represented by general formula (3): ##STR30## wherein each R, which may be the same or different, represents hydrogen or a linear, branched-chain or cyclic hydrocarbon group of 1 to 8 carbon atoms; m, n and h each represent integers from 1 to 6; "a" represents an integer from 1 to 400; two of the Ys are a nitrogen atom and the remaining Y is a carbon atom; q represents an integer from 0 to 10; p represents an integer from 1 to 3; and, when p is 1 or 2, a hydroxyl group, an amino group which may be substituted by a linear or branched alkyl group of 1 to 6 carbon atoms, a halogen atom, a carboxyl group, a linear or branched alkyl group of 1 to 6 carbon atoms, or a linear or branched alkoxyl group of 1 to 6 carbon atoms, or as well a hydrogen atom, is bound to a residual carbon atom of the ring; and
- (i) when q is from 1 to 10, A1 and A2 are each represented by general formula (4): ##STR31## wherein R, m, n, h, "a" and Y have the same meanings as given above, and A1' and A2' each represents hydrogen atoms, hydroxyl groups, amino groups which may be substituted by linear or branched alkyl groups each having 1 to 6 carbon atoms, halogen atoms, carboxyl groups, linear or branched alkyl groups each having 1 to 6 carbon atoms, or linear or branched alkoxyl groups each having 1 to 6 carbon atoms;
- or A1 and A2 are each represented by general formula (5): ##STR32## wherein R, m, n, h and "a" have the same meanings as given above; or A1 and A2 each represent hydrogen atoms, hydroxyl groups, amino groups which may be substituted by linear or branched alkyl groups each having 1 to 6 carbon atoms, halogen atoms, carboxyl groups, linear or branched alkyl groups each having 1 to 6 carbon atoms, or linear or branched alkoxyl groups each having 1 to 6 carbon atoms; and
- (ii) when q is 0, general formula (3) is represented by general formula (6): ##STR33##
- 4. A compound represented by the following general formula which is obtained by allowing a side-chain amino silicone to react with a reactive group-containing pyrimidinyl compound: ##STR34## wherein each R, which may be the same or different, represents hydrogen or a linear, branched-chain or cyclic hydrocarbon group of 1 to 8 carbon atoms; m, n and h each represent integers from 1 to 6; "a" and "b" each represent integers of 1 or more, "d" represents an integer of 0 or more, and "a+b+d" represents an integer of 400 or less; and "a", "b" and "d" each show the relative number but do not specify the order of arrangement; two of the Ys are a nitrogen atom and the remaining Y is a carbon atom; and wherein each X is independently selected from the group consisting of hydrogen, halogen, hydroxyl, amino which may be substituted by a linear or branched alkyl group of 1 to 6 carbon atoms, carboxyl, alkyl having 1 to 6 carbon atoms, alkoxy having 1 to 6 carbon atoms, and ##STR35## wherein B is R or ##STR36## wherein two of the Ys are a nitrogen atom and the remaining Y is a carbon atom.
- 5. A method for producing a compound according to claim 1, the method comprising reacting with a reactive group-containing pyrimidine compound an amino silicone oil represented by the following general formula (8): ##STR37## wherein each R, which may be the same or different, represents hydrogen or a linear, branched-chain or cyclic hydrocarbon group of 1 to 8 carbon atoms; "a" and "b" each represent integers of 1 or more, and the sum of "a" and "b" represents an integer of 400 or less; "a" and "b" each show the relative number but do not specify the order of arrangement; and at least one of B, B' and B" is a group represented by general formula (9): ##STR38## wherein each R', which may be the same or different, represents hydrogen or a linear, branched or cyclic hydrocarbon group of 1 to 8 carbon atoms; m, n and h each represent integers from 1 to 6; and
- the reactive group-containing pyrimidine compound is a compound represented by the following general formula: ##STR39## wherein at least one of X represents a halogen atom, and each remaining X represents a hydrogen atom, a hydroxyl group, an amino group which may be substituted by linear or branched alkyl groups each having 1 to 6 carbon atoms, a carboxyl group, a linear or branched alkyl group having 1 to 6 carbon atoms, or a linear or branched alkoxyl group having 1 to carbon atoms.
- 6. A composition comprising an admixture of (i) a compound and (ii) a liquid oil or silicone oil, said compound represented by the formula: ##STR40## wherein at least one X is ##STR41## and each remaining X is independently selected from the group consisting of hydrogen, halogen, hydroxyl, amino which may be substituted by linear or branched alkyl groups each having 1 to 6 carbon atoms, carboxyl, alkyl having 1 to 6 carbon atoms, and alkoxy having 1 to 6 carbon atoms;
- each R, which may be the same or different, represents hydrogen or a linear, branched-chain or cyclic hydrocarbon group of 1 to 8 carbon atoms; m and n each represents integers from 1 to 6; h represents integers from 0 to 6; "a" represents an integer from 1 to 400; and
- wherein B is R or ##STR42## wherein two of the Ys are a nitrogen atom and the remaining Y is a carbon atom.
- 7. The composition according to claim 6, wherein said compound is represented by the general formula: ##STR43## wherein R, m, n, h, and "a" have the same meaning as given previously; p represents an integer from 1 to 3; and, when p is 1 or 2, a hydroxyl group, an amino group which may be substituted by a linear or branched alkyl group of 1 to 6 carbon atoms, a halogen atom, a carboxyl group, a linear or branched alkoxyl group of 1 to 6 carbon atoms, or a linear or branched alkoxyl group of 1 to 6 carbon atoms, or as well a hydrogen atom, is bound to a residual carbon atom of the ring.
- 8. The composition according to claim 6, wherein said compound represented by general formula (3): ##STR44## wherein each R, which may be the same or different, represents hydrogen or a linear, branched-chain or cyclic hydrocarbon group of 1 to 8 carbon atoms; m and n each represent integers from 1 to 6; h represent integers from 0 to 6; "a" represents an integer from 1 to 400; two of the Ys are a nitrogen atom and the remaining Y is a carbon atom; q represents an integer from 0 to 10; p represents an integer from 1 to 3; and, when p is 1 or 2, a hydroxyl group, an amino group which may be substituted by a linear or branched alkyl group of 1 to 6 carbon atoms, a halogen atom, a carboxyl group, a linear or branched alkyl group of 1 to 6 carbon atoms, or a linear or branched alkoxyl group of 1 to 6 carbon atoms, or as well a hydrogen atom, is bound to a residual carbon atom of the ring; and
- (i) when q is from 1 to 10, A1 and A2 are each represented by general formula (4): ##STR45## wherein R, m, n, h, "a" and Y have the same meanings as given above, and A1' and A2' each represents hydrogen atoms, hydroxyl groups, amino groups which may be substituted by linear or branched alkyl groups each having 1 to 6 carbon atoms, halogen atoms, carboxyl groups, linear or branched alkyl groups each having 1 to 6 carbon atoms, or linear or branched alkoxyl groups each having 1 to 6 carbon atoms;
- or A1 and A2 are each represented by general formula (5): ##STR46## wherein R, m, n, h and "a" have the same meanings as given above; or A1 and A2 each represent hydrogen atoms, hydroxyl groups, amino groups which may be substituted by linear or branched alkyl groups each having 1 to 6 carbon atoms, halogen atoms, carboxyl groups, linear or branched alkyl groups each having 1 to 6 carbon atoms, or linear or branched alkoxyl groups each having 1 to 6 carbon atoms; and
- (ii) when q is 0, general formula (3) is represented by general formula (6): ##STR47##
- 9. The composition according to claim 6, wherein said compound is represented by the following formula which is obtained by allowing a side-chain amino silicone to react with a reactive group-containing pyrimidinyl compound: ##STR48## wherein each R, which may be the same or different, represents hydrogen or a linear, branched-chain or cyclic hydrocarbon group of 1 to 8 carbon atoms; m and n each represent integers from 1 to 6; h represent integers from 0 to 6; "a" and "b" each represent integers of 1 or more, "d" represents an integer of 0 or more, and "a+b+d" represents an integer of 400 or less; and "a", "b" and "d" each show the relative number but do not specify the order of arrangement; two of the Ys are a nitrogen atom and the remaining Y is a carbon atom; and wherein each X is independently selected from the group consisting of hydrogen, halogen, hydroxyl, amino which may be substituted by a linear or branched alkyl group of 1 to 6 carbon atoms, carboxyl, alkyl having 1 to 6 carbon atoms, alkoxy having 1 to 6 carbon atoms, and ##STR49## wherein B is R or ##STR50## wherein two of the Ys are a nitrogen atom and the remaining Y is a carbon atom.
- 10. A gel comprising an admixture of (i) a compound and (ii) a liquid oil or silicone oil, said compound represented by the formula: ##STR51## wherein at least one X is ##STR52## and each remaining X is independently selected from the group consisting of hydrogen, halogen, hydroxyl, amino which may be substituted by a linear or branched alkyl group of 1 to 6 carbon atoms, carboxyl, alkyl having 1 to 6 carbon atoms, and alkoxy having 1 to 6 carbon atoms;
- each R, which may be the same or different, represents hydrogen or a linear, branched-chain or cyclic hydrocarbon group of 1 to 8 carbon atoms; m and n each represents integers from 1 to 6; h represents integers from 0 to 6; "a" represents an integer from 1 to 400; and
- wherein B is hydrogen, R or ##STR53## wherein two of the Ys are a nitrogen atom and the remaining Y is a carbon atom.
- 11. The gel according to claim 10, wherein said compound is represented by the general formula: ##STR54## wherein R, m, n, h, and "a" have the same meaning as given previously; p represents an integer from 1 to 3; and, when p is 1 or 2, a hydroxyl group, an amino group which may be substituted by a linear or branched alkyl group of 1 to 6 carbon atoms, a halogen atom, a carboxyl group, a linear or branched alkoxyl group of 1 to 6 carbon atoms, or a linear or branched alkoxyl group of 1 to 6 carbon atoms, or as well a hydrogen atom, is bound to a residual carbon atom of the triazine ring.
- 12. The gel according to claim 10, wherein said compound represented by general formula (3): ##STR55## wherein each R, which may be the same or different, represents hydrogen or a linear, branched-chain or cyclic hydrocarbon group of 1 to 8 carbon atoms; m and n each represent integers from 1 to 6; h represent integers from 0 to 6; "a" represents an integer from 1 to 400; two of the Ys are a nitrogen atom and the remaining Y is a carbon atom; q represents an integer from 0 to 10; p represents an integer from 1 to 3; and, when p is 1 or 2, a hydroxyl group, an amino group which may be substituted by a linear or branched alkyl group of 1 to 6 carbon atoms, a halogen atom, a carboxyl group, a linear or branched alkyl group of 1 to 6 carbon atoms, or a linear or branched alkoxyl group of 1 to 6 carbon atoms, or as well a hydrogen atom, is bound to a residual carbon atom of the ring; and
- (i) when q is from 1 to 10, A1 and A2 are each represented by general formula (4): ##STR56## wherein R, m, n, h "a" and Y have the same meanings as given above, and A1' and A2' each represents hydrogen atoms, hydroxyl groups, amino groups which may be substituted by linear or branched alkyl groups each having 1 to 6 carbon atoms, halogen atoms, carboxyl groups, linear or branched alkyl groups each having 1 to 6 carbon atoms, or linear or branched alkoxyl groups each having 1 to 6 carbon atoms;
- or A1 and A2 are each represented by general formula (5): ##STR57## wherein R, m, n, h and "a" have the same meanings as given above; or A1 and A2 each represent hydrogen atoms, hydroxyl groups, amino groups which may be substituted by linear or branched alkyl groups each having 1 to 6 carbon atoms, halogen atoms, carboxyl groups, linear or branched alkyl groups each having 1 to 6 carbon atoms, or linear or branched alkoxyl groups each having 1 to 6 carbon atoms; and
- (ii) when q is 0, general formula (3) is represented by general formula (6): ##STR58##
- 13. The gel according to claim 10, wherein said compound is represented by the following formula, which is obtained by allowing a side-chain amino silicone to react with a reactive group-containing pyrimidinyl compound: ##STR59## wherein each R, which may be the same or different, represents hydrogen or a linear, branched-chain or cyclic hydrocarbon group of 1 to 8 carbon atoms; m and n each represent integers from 1 to 6; h represent integers from 0 to 6; "a" and "b" each represent integers of 1 or more, "d" represents an integer of 0 or more, and "a+b+d" represents an integer of 400 or less; and "a", "b" and "d" each show the relative number but do not specify the order of arrangement; two of the Ys are a nitrogen atom and the remaining Y is a carbon atom; and wherein each X is independently selected from the group consisting of hydrogen, halogen, hydroxyl, amino which may be substituted by a linear or branched alkyl group of 1 to 6 carbon atoms, carboxyl, alkyl having 1 to 6 carbon atoms, alkoxy having 1 to 6 carbon atoms, and ##STR60## wherein B is R or ##STR61## wherein two of the Ys are a nitrogen atom and the remaining Y is a carbon atom.
- 14. A base for a cosmetic or a pharmaceutical preparation, the base comprising an admixture of (i) a compound and (ii) a liquid oil or silicone oil, said compound represented by the formula: ##STR62## wherein at least one X is ##STR63## and each remaining X is independently selected from the group consisting of hydrogen, halogen, hydroxyl, amino which may be substituted by a linear or branched alkyl group of 1 to 6 carbon atoms, carboxyl, alkyl having 1 to 6 carbon atoms, and alkoxy having 1 to 6 carbon atoms;
- each R, which may be the same or different, represents hydrogen or a linear, branched-chain or cyclic hydrocarbon group of 1 to 8 carbon atoms; m and n each represents integers from 1 to 6; h represents integers from 0 to 6; "a" represents an integer from 1 to 400; and
- wherein B is R or ##STR64## wherein two of the Ys are a nitrogen atom and the remaining Y is a carbon atom.
- 15. The base according to claim 14, wherein said compound is represented by the general formula: ##STR65## wherein R, m, n, h, and "a" have the same meaning as given previously; p represents an integer from 1 to 3; and, when p is 1 or 2, a hydroxyl group, an amino group which may be substituted by a linear or branched alkyl group of 1 to 6 carbon atoms, a halogen atom, a carboxyl group, a linear or branched alkoxyl group of 1 to 6 carbon atoms, or a linear or branched alkoxyl group of 1 to 6 carbon atoms, or as well a hydrogen atom, is bound to a residual carbon atom of the ring.
- 16. The base according to claim 14, wherein said compound represented by general formula (3): ##STR66## wherein each R, which may be the same or different, represents hydrogen or a linear, branched-chain or cyclic hydrocarbon group of 1 to 8 carbon atoms; m and n each represent integers from 1 to 6; h represent integers from 0 to 6; "a" represents an integer from 1 to 400; two of the Ys are a nitrogen atom and the remaining Y is a carbon atom; q represents an integer from 0 to 10; p represents an integer from 1 to 3; and, when p is 1 or 2, a hydroxyl group, an amino group which may be substituted by a linear or branched alkyl group of 1 to 6 carbon atoms, a halogen atom, a carboxyl group, a linear or branched alkyl group of 1 to 6 carbon atoms, or a linear or branched alkoxyl group of 1 to 6 carbon atoms, or as well a hydrogen atom, is bound to a residual carbon atom of the ring; and
- (i) when q is from 1 to 10, A1 and A2 are each represented by general formula (4): ##STR67## wherein R, m, n, h, "a" and Y have the same meanings as given above, and A1' and A2' each represents hydrogen atoms, hydroxyl groups, amino groups which may be substituted by linear or branched alkyl groups each having 1 to 6 carbon atoms, halogen atoms, carboxyl groups, linear or branched alkyl groups each having 1 to 6 carbon atoms, or linear or branched alkoxyl groups each having 1 to 6 carbon atoms;
- or A1 and A2 are each represented by general formula (5): ##STR68## wherein R, m, n, h and "a" have the same meanings as given above; or A1 and A2 each represent hydrogen atoms, hydroxyl groups, amino groups which may be substituted by linear or branched alkyl groups each having 1 to 6 carbon atoms, halogen atoms, carboxyl groups, linear or branched alkyl groups each having 1 to 6 carbon atoms, or linear or branched alkoxyl groups each having 1 to 6 carbon atoms; and
- (ii) when q is 0, general formula (3) is represented by general formula (6): ##STR69##
- 17. The base according to claim 14, wherein said compound is represented by the following formula, which is obtained by allowing a side-chain amino silicone to react with a reactive group-containing pyrimidinyl compound: ##STR70## wherein each R, which may be the same or different, represents hydrogen or a linear, branched-chain or cyclic hydrocarbon group of 1 to 8 carbon atoms; m and n each represent integers from 1 to 6; h represent integers from 0 to 6; "a" and "b" each represent integers of 1 or more, "d" represents an integer of 0 or more, and "a+b+d" represents an integer of 400 or less; and "a", "b" and "d" each show the relative number but do not specify the order of arrangement; two of the Ys are a nitrogen atom and the remaining Y is a carbon atom; and wherein each X is independently selected from the group consisting of hydrogen, halogen, hydroxyl, amino which may be substituted by a linear or branched alkyl group of 1 to 6 carbon atoms, carboxyl, alkyl having 1 to 6 carbon atoms, alkoxy having 1 to 6 carbon atoms, and ##STR71## wherein B is R or ##STR72## wherein two of the Ys are a nitrogen atom and the remaining Y is a carbon atom.
Parent Case Info
This is a divisional of application Ser. No. 08/671,001 filed on Jun. 28, 1996 now U.S. Pat. No. 5,712,391.
Foreign Referenced Citations (6)
Number |
Date |
Country |
638065 |
Mar 1962 |
CAX |
0 461 071 A1 |
Dec 1991 |
EPX |
0 502 821 A1 |
Sep 1992 |
EPX |
2-43263 |
Feb 1990 |
JPX |
5-140320 |
Jun 1993 |
JPX |
WO 9414822 |
Jul 1994 |
WOX |
Non-Patent Literature Citations (1)
Entry |
Andrianov et al., Organosilicon oligomers containing symmetric triazine rings, Vysokomolekuliarnye Sodineniya serii A., vol. 16, issue 10, pp. 2255-9 (1974). |
Divisions (1)
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Number |
Date |
Country |
Parent |
671001 |
Jun 1996 |
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