Claims
- 1. A siloxane ester having an acid number of from about 5 to 65, a hydroxyl number from about 5 to 225, and a tack-temperature of from about 150.degree. F. to 220.degree. F. comprising the reaction product, totaling 100% of:
- (a) 10 to 40 weight percent hindered glycol comprising a mixture of
- (1) a sterically protected glycol selected from the group consisting of 1,4-cyclohexane dimethanol and a glycol having the structure ##STR17## wherein R is selected from hydrogen, lower alkyl, mthylol or ethylol radicals; and R' is lower alkyl, methylol or ethylol radical; and
- (2) a multifunctional glycol acid having the structure ##STR18## wherein R" is hydrogen, lower alkyl, methylol or carboxylic acid radicals; and wherein said glycol acid comprises 5-45 weight percent of said hindered glycol; and
- (b) 60 to 90 weight percent hydroxy functional silicone having at least two ester precursor silanol groups adapted to react with said hindered glycol to provide a storage stable siloxane ester powder coating having a tack-temperature of at least 150.degree. F., said siloxane having the structure: ##STR19## wherein n is an integer from 1 to 10 and R independently represents lower alyl or phenyl groups.
- 2. The siloxane-ester of claim 1 wherein the sterically protected glycol is neopentyl glycol; and the glycol acid is dimethylol propionic acid.
- 3. The siloxane-ester of claim 1 wherein the sterically protected glycol comprises 8 to 24 weight percent neopentyl glycol and said glycol acid comprises 3 to 14 weight percent dimethylol propionic acid; and said siloxane-ester has an acid number of from about 5 to 40, a hydroxyl number of about 5 to about 200; and a tack temperature of at least 150.degree. F.
- 4. A powder coating which comprises the siloxane ester of claims 1, 2, or 3.
- 5. A coating which comprises a blend comprising a major weight portion of the siloxane-ester of claim 1 with a minor weight portion of a hydroxy functional resin having a number average molecular weight from about 1,000 to about 20,000; and a crosslinking agent adapted to crosslink with the blend of resin and siloxane ester; wherein said hydroxy functional resin is selected from the group consisting of a polyester and acrylic resin.
- 6. The coating of claim 5 wherein the resin is a hydroxy functional polyester and the crosslinking agent is a blocked isocyanate.
- 7. The coating of claim 5 wherein the resin is a hydroxy functional acrylate resin and the crosslinking agent is a glycoluril crosslinker.
Parent Case Info
This application is a continuation-in-part application based on copending and commonly assigned application Ser. No. 745,443 filed June 17, 1985, now U.S. Pat. No. 4,608,421, which is incorporated herein by reference.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
4525535 |
Craun et al. |
Jun 1985 |
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4608421 |
Lin |
Aug 1986 |
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Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
745443 |
Jun 1985 |
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