Claims
- 1. Phospholipid compositions represented by the following general formula: wherein:A is selected from H, M, or R—Y—; A1 is selected from H, OH, OM or R—Y—O—; x is 0 or an integer from 1 to 5; M is a cation; Y is alkylene or substitued alkylene; and R is a mixture of quaternized organosilicone amine moieties selected from the group consisting of: a) a quaternized organosilicone amidoamine moiety of the formula: wherein: R1 is a silicone backbone chain to which amidoamine or amine functional group(s) can be attached; R2 is hydrogen or alkyl, hydroxyalkyl or alkenyl of up to 6 carbon atoms each, or cycloalkyl of up to 6 carbon atoms, or polyoxyalkylene of up to 10 carbon atoms within the oxyalkylene unit; R3 and R4, which may be the same or different, are selected from alkyl, hydroxyalkyl, carboxyalkyl of up to 6 carbon atoms in each alkyl, or polyoxyalkylene of up to 10 carbon atoms; in addition R3 and R4 taken together with the nitrogen to which they are attached represent a N-heterocycle; X− is an anion; n is an integer from 2 to 12; n1 is zero or an integer from 1 to 12; n2 is 0 or 1; n3 is an integer from 1 to 5; B is sulfur (S) or oxygen (O); with the proviso that when n2 is 0, n1 or n3 is at least 1 and when n2 is 1, n1 and n3 each is at least 1; and d is one or greater; and b) a quaternized organosilicone tertiary amine moiety of the formula: wherein: R1 is a silicone backbone claim to which amidoamine or amine functional groups can be attached; R6 is alkylene, hydroxyalkylene, arylene, alkarylene, aralkylene, heteroalkylene wherein the heteroatom can be N, S or O and there can be more than one of such hetero atoms in the chain; X− is an anion; d1 is an integer of one or greater; R3 and R4, which may be the same or different, are selected from alkyle, hydroxyalkyl, carboxyalkyl of up to 6 carbon atoms in each alkyl, or polyoxyalkylene of up to 10 carbon atoms; in addition R3 and R4 taken together with the nitrogen to which they are attached represent a N-heterocycle; and a quaternized organic amine moiety selected from the group consisting of:c) a quaternized organic amidoamine moiety of the formula: wherein: R5 is alkyl, alkenyl, alkoxyalkyl or hydroxyalkyl of from 5 to 21 carbon atoms each, alkaryl or aryl of up to 20 carbon atoms; R2 is hydrogen or alkyl, hydroxyalkyl or alkenyl of up to 6 carbon atoms each, cycloalkyl of up to 6 carbon atoms, or polyoxyalkylene of up to 10 carbon atoms within the oxyalkylene unit; R3 and R4 which may be the same or different, are selected from alkyl, hydroxyalkyl, carboxyalkyl of up to 6 carbon atoms in each alkyl moiety, and polyoxyalkylene of up to 10 carbon atoms; in addition R3 and R4 taken together with the nitrogen to which they are attached represent an N-heterocycle; X− is an anion; g is 0 or 1; n is integer from 2 to 12; and n4 is 1 or greater; and d) an organic quaternized tertiary amine moiety of the formula: wherein: R13, R14 and R15 are the same or different and are alkyl, substituted alkyl, alkyl aryl or alkenyl groups of up to 16 carbon atoms with the proviso that the total carbon atoms in R13+R14+R15 is between 10 and 24; with the proviso that wherein R is a mixture of organosilicone amine and organic amine moieties, at least 5 equivalent weight percent to about 60 equivalent weight percent of the total equivalent weight of amine moieties of the phospholipid composition is a quaternized organosilicone amidoamine moiety, a quaternized organosilicone tertiary amine moiety or mixtures of the same.
- 2. The phospholipid compositions according to claim 1, wherein the silicone backbone chain R1 to which amine functional group can be attached is of the formula: wherein:R7 and R8, which may be the same or different are selected from alkyl, aryl, capped or uncapped polyoxyalkylene, alkaryl, aralkylene or alkenyl (vinyl); R10 can be the same or different and are selected from alkyl, aryl or olefinic (vinyl); R11, which can be the same or different, can be selected from R10, —(CH2)n1—Bn2—(CH2)n3—CO—NR2—(CH2)n—NR3R4, —R6—NR3R4— and mixtures thereof, wherein R2, R3, R4, R6, B, n, n1, n2 and n3 are as defined above; with the proviso that at least one of R11 is an amidoamine or tertiary amine; e can be an integer of O to 50,000; f can be an integer of 0 to 100.
- 3. The phospholipid composition according to claim 2, wherein f is 0.
- 4. The phospholipid composition according to claim 2 wherein the terminal groups R11 are R10 and f is greater than 0.
- 5. The phospholipid compositions according to claim 1, wherein g in the quaternized organic amidoamine moiety c) is 1.
- 6. The phospholipid compositions according to claim 1, wherein R is a mixture of:a) quaternized organosilicone amidoamine moieties of the formula: wherein: R1 is a silicone backbone chain to which amidoamine and/or amine functional group(s) can be attached; R2 is hydrogen or alkyl, hydroxyalkyl or alkenyl of up to 6 carbon atoms each, or cycloalkyl of up to 6 carbon atoms, or polyoxyalkylene of up to 10 carbon atoms within the oxyalkylene unit; R3 and R4, which may be the same or different, are selected from alkyl, hydroxyalkyl, carboxyalkyl of up to 6 carbon atoms in each alkyl, or polyoxyalkylene of up to 10 carbon atoms; X− is an anion; n is an integer from 2 to 12; n1 is zero or an integer from 1 to 12; n2 is 0 or 1; n3 is an integer from 1 to 5; B is sulfur (S) or oxygen (O); with the provision that when n2 is 0, n1 or n3 is at least 1 and when n2 is 1, n1 and n3 each is at least 1; and d is one or greater; and c) quaternized organic amidoamine moieties of the formula: wherein: R5 is alkyl, alkenyl, alkoxy, alkyl or hydroxyalkyl of from 5 to 21 carbon atoms each, alkaryl or aryl of up to 20 carbon atoms; R2 is hydrogen or alkyl, hydroxyalkyl or alkenyl of up to 6 carbon atoms each, cycloalkyl of up to 6 carbon atoms, or polyoxyalkylene of up to 10 carbon atoms within the oxyalkylene unit; R3 and R4 which may be the same or different, are selected from alkyl, hydroxyalkyl, carboxyalkyl of up to 6 carbon atoms in each alkyl moiety, or polyoxyalkylene of up to 10 carbon atoms; in addition R3 and R4 taken together with the nitrogen to which they are attached represent an N-heterocycle; X− is an anion; g is 0 or 1; n is integer from 2 to 12; n4 is 1 or greater. with the proviso that at least 5 equivalent weight percent to about 60 equivalent weight percent of the total equivalent weight of amine moieties of the phospholipid composition is a quaternized organosilicone amidoamine moiety or mixtures of the same.
- 7. The phospholipid compositions according to claim 6, wherein the silicone backbone chain R1 to which amine functional group can be attached is of the formula: wherein:R7 and R8, which may be the same or different are selected from alkyl, aryl, capped or uncapped polyoxyalkylene, alkaryl, aralkylene or alkenyl (vinyl); R10 can be the same or different and is selected from alkyl, aryl or olefinic (vinyl); R11, which can be the same or different, is selected from R10, —(CH2)n1—Bn2—(CH2)n3—CO—NR2—(CH2)n—NR3R4, —R6—NR3R4— or mixtures thereof, wherein R2, R3, R4, R6, B, n, n1, n2 and n3 are as defined above; with the proviso that at least one of R11 is an amidoamine; e can be an integer of O to 50,000; f can be an integer of 0 to 100.
- 8. The phospholipid compositions according to claim 6, wherein g in the quaternized organic amidoamine moiety c) is 1.
- 9. The phospholipid composition according to claim 7, wherein f is 0.
- 10. The phospholipid composition according to claim 7, wherein the terminal groups R11 are R10 and f is greater than 0.
- 11. The phospholipid composition according to claim 1, wherein Y is —CH2—CHOH—CH2—.
- 12. A method of preparing novel phospholipid compositions according to claim 1 represented by the general formula: wherein:A is selected from H, M, or R—Y—; A1 is selected from H, OH, OM or R—Y—O—; x is 0 or the intefer from 1 to 5; M is a cation; Y is alkylene or substituted alkylene; and R is a mixture of quaternized amidoamine and/or tertiary amine moieties as hereinabove defined; which comprises reacting the combination of an organic amidoamine organic tertiary amine reactant or mixture of the same and a silicone modified amidoamine silicone modified tertiary amine reactant or mixtures of the same with a polyphosphate, phosphite or phosphate ester halide reactant in the equivalent weight ratios of from about 0.7 to 3.3, of total amidoamine or tertiary amine reactants to 1 of polyphosphate, phosphite or phosphate ester halide reactant until the amine reactant is completely reacted, with the proviso that at least 5 equivalent weight percent to about 60 equivalent weight percent of the total equivalent weight of amine reactants will be silicone containing, said polyphosphate, phosphite or phosphate ester halide reactant being of the general formula: wherein:A2 is selected from H, M and X—Y—; A3 is selected from H, OH, OM and X—Y—O—; x is 0 or the integer from 1 to 5; M is a cation; Y is alkylene or substituted alkylene; and X is halogen.
RELATED APPLICATIONS
This application is a continuation in part of application Ser. No. 08/174,934 filed Dec. 28, 1993 now U.S. Pat. No. 5,405,983 and application Ser. No. 08/265,011 filed Jun. 23, 1994 now abandoned.
US Referenced Citations (42)
Continuation in Parts (2)
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Number |
Date |
Country |
Parent |
08/174934 |
Dec 1993 |
US |
Child |
08/358207 |
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US |
Parent |
08/265011 |
Jun 1994 |
US |
Child |
08/174934 |
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US |