Single-longitudinal-mode solid laser

Information

  • Patent Grant
  • 6584129
  • Patent Number
    6,584,129
  • Date Filed
    Tuesday, November 13, 2001
    23 years ago
  • Date Issued
    Tuesday, June 24, 2003
    21 years ago
Abstract
A solid laser produces a laser beam of a 1 μm wavelength band with an Nd-doped solid laser medium. An oscillation mode is brought to a single longitudinal mode with a Fabry-Pérot etalon located within a resonator. An etalon thickness, an etalon reflectivity, an etalon inclination, and a resonator longitudinal mode interval satisfy the relationships, 1.2%≦RN≦15% and 0.5°≦θ≦2.0°, in which RN represents an effective reflectivity of the etalon with respect to wavelengths λ=λ0±Δλc deviating by a resonator longitudinal mode interval Δλc from a resonance wavelength λ0 of the etalon, and θ represents an inclination of an etalon optical axis with respect to a resonator optical axis.
Description




BACKGROUND OF THE INVENTION




1. Field of the Invention




This invention relates to a solid laser. This invention particularly relates to a solid laser, wherein an etalon is located in a resonator in order to bring an oscillation mode to a single longitudinal mode.




2. Description of the Related Art




Various solid lasers, which utilize a solid laser medium doped with neodymium (Nd) and produce a laser beam having a wavelength of a 1 μm band (ranging from approximately 1.0 μm to 1.1 μm), have heretofore been proposed. Examples of the solid laser media doped with neodymium (Nd) include Nd:YVO


4


, Nd:YAG (Y


3


Al


5


O


12


), Nd:YLF (YLiF


4


), Nd:GdVO


4


, Nd:YAlO (YAlO


3


), and Nd:glass. In the solid lasers of such types, a technique is utilized broadly, wherein a Fabry-Pérot type of etalon is located within a resonator in order to bring an oscillation mode to a single longitudinal mode. The solid lasers utilizing the technique described above are described in, for example, Japanese Unexamined Patent Publication Nos. 5(1993)-218556 and 6(1994)-130328, and 7(1995)-263785. (In this specification, the term “etalon” means the Fabry-Pérot type of etalon.)




However, in the conventional single-longitudinal-mode solid lasers, wherein the oscillation mode is brought to the single longitudinal mode by the utilization of the etalon, conditions of the etalon (i.e., the thickness of the etalon, the reflectivity of the etalon, and the inclination of the etalon) and conditions of the resonator (i.e., resonator longitudinal mode intervals), under which good single longitudinal mode characteristics are capable of being obtained, were not clear. Therefore, the problems occur in that, in cases where an etalon, which yields good single longitudinal mode characteristics when being located within a certain resonator, is utilized directly in a different resonator, good single longitudinal mode characteristics cannot be obtained.




Also, the problems occur in that, though good single longitudinal mode characteristics are capable of being obtained, a beam profile becomes bad, and the output becomes low. Thus the conditions of the etalon and the resonator, which simultaneously satisfy the requirements for the single longitudinal mode characteristics, the beam profile, and the output, were not clear.




The inventors conducted extensive research and found that, in cases where each of the thickness of the etalon, the reflectivity of the etalon, and the inclination of the etalon is set at a large value, the single longitudinal mode characteristics become good, but the beam profile becomes bad, and the output becomes low. Also, it was found that, in cases where each of the thickness of the etalon, the reflectivity of the etalon, and the inclination of the etalon is set at a small value, the beam profile becomes good, the output becomes high, but the single longitudinal mode characteristics become bad.




Further, it was found that, in cases where a resonator length is set at a large value (i.e., the resonator longitudinal mode intervals are set to be small), the single longitudinal mode characteristics become bad. Furthermore, it was found that, in cases where the resonator length is set at a small value, the single longitudinal mode characteristics become good, and the beam profile and the output are not much affected by the resonator length.




As for a solid laser, which utilizes Nd:YAG as a solid laser medium and produces a laser beam having a wavelength of a 0.9 μm band, the inventors have already found the conditions of the etalon, under which good, reliable single longitudinal mode characteristics, a good beam profile, and a high output are capable of being obtained simultaneously. The conditions of the etalon are disclosed in Japanese Unexamined Patent Publication No. 8(1996)-186316. However, as for the solid laser, which produces a laser beam having a wavelength of the 1 μm band, appropriate conditions of the etalon have not yet been clarified.




SUMMARY OF THE INVENTION




The primary object of the present invention is to provide a single-longitudinal-mode solid laser, which produces a laser beam having a wavelength of a 1 μm band and which exhibits good, reliable single longitudinal mode characteristics, a good beam profile, and a high output.




The present invention provides a single-longitudinal-mode solid laser capable of producing a laser beam having a wavelength of a 1 μm band, the solid laser comprising:




i) a solid laser medium doped with neodymium,




ii) a resonator, and




iii) a Fabry-Pérot type of etalon, which is located within the resonator and brings an oscillation mode to a single longitudinal mode,




wherein a thickness of the etalon, a reflectivity of the etalon, an inclination of the etalon, and a resonator longitudinal mode interval are adjusted so as to satisfy the relationships represented by the formulas:






1.2%≦R


N


≦15% and 0.5°≦θ≦2.0°






in which R


N


represents an effective reflectivity of the etalon with respect to wavelengths λ=λ


0


±Δλc deviating by a resonator longitudinal mode interval Δλc from a resonance wavelength λ


0


of the etalon, and θ represents an inclination of an optical axis of the etalon with respect to an optical axis of the resonator.




The single-longitudinal-mode solid laser in accordance with the present invention should preferably be modified such that the thickness of the etalon, the reflectivity of the etalon, the inclination of the etalon, and the resonator longitudinal mode interval are adjusted so as to satisfy the relationships represented by the formulas:






3.0%≦R


N


≦10% and 0.80°≦θ≦1.5°






in which R


N


represents the effective reflectivity of the etalon, and θ represents the inclination of the optical axis of the etalon with respect to the optical axis of the resonator.




Effects of the single-longitudinal-mode solid laser in accordance with the present invention will be described hereinbelow.




The Fabry-Pérot type of etalon is a wavelength selecting device utilizing multiple interference of light.

FIG. 3

is a graph showing relationships among an effective reflectivity of an etalon, an etalon longitudinal mode, and a resonator longitudinal mode. In

FIG. 3

, a curve “a” indicates the wavelength characteristics of an effective reflectivity R


eff


of the etalon. As illustrated in

FIG. 3

, the effective reflectivity R


eff


of the etalon changes periodically, and the etalon longitudinal mode occurs at points, at which the effective reflectivity R


eff


becomes equal to 0 at a wavelength interval Δλe (FSR: free spectral range).




In

FIG. 3

, a curve “b” indicates a gain spectrum of a solid laser medium. Ordinarily, the resonator longitudinal mode occurs at a plurality of points falling within an oscillation wavelength width W in the gain spectrum. Therefore, in cases where the etalon is not utilized, the laser undergoes oscillation in a multiple longitudinal mode. In cases where the etalon is inserted into the resonator, the loss, to which each of the longitudinal modes of the resonator is subjected, is modulated in accordance with the effective reflectivity R


eff


of the etalon. Also, oscillation occurs only in the mode, which is subjected to the smallest loss among the plurality of the resonator longitudinal modes falling within the wavelength width W.




In the manner described above, with the etalon, the oscillation mode is brought to the single longitudinal mode. However, heretofore, it was not clear how the loss modulation with the effective reflectivity R


eff


of the etalon and the inclination of the etalon are to be set in order for all of the three requirements with respect to good, reliable single longitudinal mode characteristics, a good beam profile, and a high output to be satisfied.




The inventors conducted extensive research in order to clarify how the loss modulation with the effective reflectivity R


eff


of the etalon and the inclination of the etalon are to be set in order for all of the three requirements with respect to good, reliable single longitudinal mode characteristics, a good beam profile, and a high output to be satisfied. It was thus found that all of the three requirements described above are capable of being satisfied in cases where appropriate loss modulation is given by setting the effective reflectivity R


N


of the etalon with respect to the wavelengths λ=λ


0


±Δλc deviating by the resonator longitudinal mode interval Δλc from the resonance wavelength λ


0


of the etalon (as illustrated in

FIG. 3

) so as to fall within a specific range, and in cases where the inclination θ of the optical axis of the etalon is also set so as to fall within a specific range. As described above, the specific range of the effective reflectivity R


N


of the etalon is represented by the formula 1.2%≦R


N


≦15%, and should preferably be represented by the formula 3.0%≦R


N


≦10%. Also, the specific range of the inclination θ of the optical axis of the etalon is represented by the formula 0.5°≦θ≦2.0°, and should preferably be represented by the formula 0.8°≦θ≦1.5°.




How the effective reflectivity R


N


of the etalon is calculated will be described hereinbelow. Firstly, ordinarily, in accordance with Airy's Formulae, the effective reflectivity Reff of the etalon may be represented by Formula (1) shown below.













R
eff

=






F







sin
2



(

δ
/
2

)




1
+

F







sin
2



(

δ
/
2

)
















F
=


4

R



(

1
-
R

)

2














δ
=


4

π






n
e



l
e


λ









(
1
)













wherein R represents the coating reflectivity of the etalon, n


e


represents the refractive index of the etalon, l


e


represents the thickness of the etalon, and represents the wavelength of light.




Also, the longitudinal mode interval Δλe of the etalon may be represented by Formula (2) shown below.






Δλ


e=λ




0




2


/(2


n




e




l




e


)  (2)






wherein λ


0


represents the oscillation wavelength of the etalon.




Thereafter, the resonator longitudinal mode interval Δλc is calculated in the manner described below. In cases where media (including air) respectively having refractive indexes of n


1


, n


2


, n


3


, n


4


, . . . stand side by side within the resonator, and the thicknesses of the media are respectively l


1


, l


2


, l


3


, l


4


, . . . , a resonator optical path length Lopt may be represented by Formula (3) shown below.










L

o





p





t


=



i




n
i



l
i







(
3
)













Therefore, the resonator longitudinal mode interval Δλc may be represented by Formula (4) shown below.






Δλ


c=λ




0




2


/2


Lopt


  (4)






From Formulas (1), (2), and (4) shown above, the effective reflectivity R


N


of the etalon with respect to the wavelengths λ=λ


0


±Δλc deviating by the resonator longitudinal mode interval Δλc from the resonance wavelength λ


0


of the etalon may be approximately represented by Formula (5) shown below.













R
N

=






F







sin
2



(


δ
N

/
2

)




1
+

F







sin
2



(


δ
N

/
2

)

















δ
N

=



Δ





λ





c


Δ





λ





e


×
2





π









(
5
)













Bases for the value ranges of the effective reflectivity R


N


of the etalon and the inclination θ of the optical axis of the etalon described above will hereinbelow be described in detail.




(a) Single Longitudinal Mode Characteristics




In the solid laser, in which the oscillation mode is brought to the single longitudinal mode by the utilization of the Fabry-Pérot type of etalon, the resonator temperature is successively changed by 10° C., and the rate of the temperature region, in which the oscillation occurs in the single longitudinal mode, is calculated in units of %. The thus calculated rate of the temperature region is taken as an index for the single longitudinal mode characteristics. Basically, the index for the single longitudinal mode characteristics changes as illustrated in

FIG. 4

in accordance with the effective reflectivity R


N


of the etalon and the inclination θ of the optical axis of the etalon.




(b) Output




The laser output, which is obtained when an etalon provided with an anti-reflection (AR) coating layer (R


N


=0) is inserted into the resonator at an etalon inclination θ approximately equal to 0°, is taken as 100%. Also, the effective reflectivity R


N


of the etalon and the inclination θ of the optical axis of the etalon are set at various values, and the laser outputs are measured. The ratios of the thus measured laser outputs to the aforesaid laser output taken as 100% were calculated.

FIG. 5

shows how the ratio of the measured laser output changes in accordance with the effective reflectivity R


N


of the etalon and the inclination θ of the optical axis of the etalon. In the determination of the characteristics, the resonator length was kept at a predetermined value.




(c) Beam Quality




Basically, the beam quality, expressed in terms of the M


2


value, changes as illustrated in

FIG. 6

in accordance with the effective reflectivity R


N


of the etalon and the inclination θ of the optical axis of the etalon. In the determination of the characteristics, the resonator length was kept at a predetermined value.




From the characteristics shown in

FIGS. 4

,


5


, and


6


, it is capable of being known in what ranges the effective reflectivity R


N


of the etalon and the inclination θ of the optical axis of the etalon are to be set with respect to arbitrary specifications concerning the single longitudinal mode characteristics, the output, and the beam quality. For example, comparatively loose specifications as shown below:




Single longitudinal mode characteristics≧80%




Output≧30%




M


2


≦1.2




are capable of being accomplished in cases where the effective reflectivity R


N


of the etalon and the inclination θ of the optical axis of the etalon are set so as to fall within the range hatched in FIG.


7


. In such cases, 1.2%≦R


N


≦15% and 0.5°≦θ≦2.0°.




Also, for example, comparatively strict specifications as shown below:




Single longitudinal mode characteristics≧100%




Output≧50%




M


2


≦1.05




are capable of being accomplished in cases where the effective reflectivity R


N


of the etalon and the inclination θ of the optical axis of the etalon are set so as to fall within the range hatched in FIG.


8


. In such cases, 3.0%≦R


N


≦10% and 0.8°≦θ≦1.5°.











BRIEF DESCRIPTION OF THE DRAWINGS





FIG. 1

is a partially broken side view showing an embodiment of the single-longitudinal-mode solid laser in accordance with the present invention,





FIG. 2

is an enlarged side view showing a major part of the single-longitudinal-mode solid laser of

FIG. 1

,





FIG. 3

is a graph showing relationships among an effective reflectivity of an etalon, an etalon longitudinal mode, and a resonator longitudinal mode,





FIG. 4

is a graph showing how single longitudinal mode characteristics of a solid laser change in accordance with an effective reflectivity R


N


of an etalon and an inclination θ of an optical axis of an etalon,





FIG. 5

is a graph showing how an output of a solid laser changes in accordance with the effective reflectivity R


N


of the etalon and the inclination θ of an optical axis of the etalon,





FIG. 6

is a graph showing how beam quality obtained with a solid laser changes in accordance with the effective reflectivity R


N


of the etalon and the inclination θ of the optical axis of the etalon,





FIG. 7

is a graph showing a preferable range of the effective reflectivity R


N


of the etalon and the inclination θ of the optical axis of the etalon, and





FIG. 8

is a graph showing a more preferable range of the effective reflectivity R


N


of the etalon and the inclination θ of the optical axis of the etalon.











DESCRIPTION OF THE PREFERRED EMBODIMENTS




The present invention will hereinbelow be described in further detail with reference to the accompanying drawings.





FIG. 1

is a partially broken side view showing an embodiment of the single-longitudinal-mode solid laser in accordance with the present invention. By way of example, the single-longitudinal-mode solid laser is constituted as a semiconductor laser pumped solid laser. The single-longitudinal-mode solid laser is provided with a semiconductor laser


11


, which produces a laser beam


10


serving as a pumping beam, and a converging lens


12


, which converges the laser beam


10


having been produced as divergent light. The single-longitudinal-mode solid laser is also provided with a YVO


4


crystal


13


, which is a solid laser medium doped with neodymium (Nd). The YVO


4


crystal


13


doped with neodymium (Nd) will hereinafter be referred to as the Nd:YVO


4


crystal


13


. The single-longitudinal-mode solid laser is further provided with a resonator mirror


14


, which is located on the side downstream (i.e. the right side in

FIG. 1

) from the Nd:YVO


4


crystal


13


.




Further, an optical wavelength converting device


15


, a polarization control device


16


, and an etalon


17


are located between the Nd:YVO


4


crystal


13


and the resonator mirror


14


. The optical wavelength converting device


15


, the polarization control device


16


, and the etalon


17


are located in this order from the side of the Nd:YVO


4


crystal


13


.




In this embodiment, as will be described later, the Nd:YVO


4


crystal


13


and the resonator mirror


14


constitute the resonator of the solid laser. The optical wavelength converting device


15


, the polarization control device


16


, and the etalon


17


are thus located within the resonator. The Nd:YVO


4


crystal


13


, the resonator mirror


14


, the optical wavelength converting device


15


, the polarization control device


16


, and the etalon


17


are supported by a common resonator holder


18


, which may be made from copper, or the like. The resonator holder


18


is secured to a Peltier device


19


. The temperature within the resonator is kept at a predetermined value by the Peltier device


19


and a temperature adjusting circuit (not shown).




Furthermore, an automatic power control (APC) unit


20


is secured to the Peltier device


19


. The APC unit


20


is provided with a beam splitter


21


for splitting a second harmonic


31


having a wavelength of 532 nm, which is produced in the manner described later. The APC unit


20


is also provided with a photodetector


22


for detecting the split second harmonic


31


. The photodetector


22


may be constituted of a photodiode, or the like.




The Peltier device


19


is located on a metal plate


24


, which acts as a reinforcing plate for suppressing strain of the Peltier device


19


. The Peltier device


19


is secured via the metal plate


24


to a bottom wall of an enclosed type of package


25


. The package


25


is provided with a pumping beam entry window


26


and a second harmonic radiating window


27


, into which transparent members have respectively been fitted.




The optical wavelength converting device


15


is constituted of an MgO-doped LiNbO


3


crystal, which acts as a nonlinear optical material and in which a periodic domain inversion structure has been formed. The polarization control device


16


is constituted of a non-coated quartz glass plate located at a Brewster angle. The etalon


17


is constituted of a quartz glass plate provided with coating layers at the two end faces. Also, the resonator mirror (output mirror)


14


is constituted of a quartz glass plate, whose one end face is polished into a concave surface and whose two end faces are provided with coating layers.




The semiconductor laser


11


produces the laser beam


10


having a wavelength of 809 nm. The neodymium ions contained in the Nd:YVO


4


crystal


13


are excited by the laser beam


10


, and the Nd:YVO


4


crystal


13


thereby produces light having a wavelength of 1064 nm. Also, laser oscillation is caused to occur by the resonator, which is constituted by the Nd:YVO


4


crystal


13


and the resonator mirror


14


, as will be described later. In this manner, a solid laser beam


30


having a wavelength of 1064 nm is obtained. The solid laser beam


30


impinges upon the optical wavelength converting device


15


and is converted by the optical wavelength converting device


15


into its second harmonic


31


having a wavelength of 532 nm, which is one half of the wavelength of the solid laser beam


30


.




In this embodiment, the optical output of the second harmonic


31


, which has been split by the beam splitter


21


of the APC unit


20


, is detected by the photodetector


22


, and an output signal S is obtained from the photodetector


22


. The output signal S is fed from the photodetector


22


into a semiconductor laser driving circuit (not shown). The semiconductor laser driving circuit controls the driving current for the semiconductor laser


11


, such that the output signal S becomes equal to a predetermined value. In this manner, the output of the second harmonic


31


is kept at a predetermined level.





FIG. 2

is an enlarged view showing the part ranging from the Nd:YVO


4


crystal


13


to the resonator mirror


14


. The reflectivities or the transmittances of end faces


13




a


and


13




b


of the Nd:YVO


4


crystal


13


, end faces


15




a


and


15




b


of the optical wavelength converting device


15


, end faces


17




a


and


17




b


of the etalon


17


, and end faces


14




a


and


14




b


of the resonator mirror


14


with respect to the wavelengths of 809 nm, 1064 nm, and 532 nm described above are adjusted as listed in Table 1 shown below by the provision of appropriate coating layers. End faces


16




a


and


16




b


of the polarization control device


16


are not provided with coating layers. In Table 1 below, values in units of % represent the reflectivities. Also, AR represents the anti-reflection coating, HR represents the high-reflectivity coating, and “−” represents that no coating layer is provided.














TABLE 1













End face



















Wavelength




13a




13b




15a




15b




17a




17b




14a




14b









 809 nm




AR




AR




































1064 nm




HR




AR




AR




AR




60%




60%




HR











 532 nm









HR




AR




AR




AR




AR




AR




AR














With the configuration described above, the laser beam


30


having a wavelength of 1064 nm resonates between the end face


13




a


of the Nd:YVO


4


crystal


13


and the mirror surface


14




a


of the resonator mirror


14


. Also, the oscillation mode is brought to the single longitudinal mode by the effects of the etalon


17


described above in detail. Therefore, the second harmonic


31


is also brought to the single longitudinal mode. Approximately only the second harmonic


31


having thus been produced is radiated out from the light radiating end face


14




b


of the resonator mirror


14


.




In this embodiment, the Nd:YVO


4


crystal


13


, the optical wavelength converting device


15


, the polarization control device


16


, and the etalon


17


have the refractive indexes and the thicknesses listed in Table 2 below. Also, the resonator length, i.e. the distance between the end face


13




a


of the Nd:YVO


4


crystal


13


and the mirror surface


14




a


of the resonator mirror


14


, is equal to 9.23 mm.
















TABLE 2











Refractive index




Thickness






























Nd:YVO


4


crystal 13




2.168




1




mm







Optical wavelength




2.13




4




mm







converting device 15







Polarization control




1.45




0.4




mm







device 16







Etalon 17




1.45




0.223




mm















In cases where the refractive index of air within the resonator is taken as 1, in accordance with Formula (3) shown above, the resonator optical path length Lopt is equal to Lopt=15.2 mm. In such cases, from Formula (4) shown above, the resonator longitudinal mode interval Δλc becomes equal to Δλc=0.037 nm. Also, from Formula (2) shown above, the etalon longitudinal mode interval Δλe becomes equal to Δλe=1.75 nm.




In accordance with the values described above, from Formula (5) shown above, the effective reflectivity R


N


of the etalon


17


with respect to the wavelengths λ=λ


0


±Δλc deviating by the resonator longitudinal mode interval Δλc (=0.037 nm) from the resonance wavelength λ


0


(=1064 nm) of the etalon


17


becomes equal to R


N


=6.27%. Also, the etalon


17


is located such that the optical axis of the etalon


17


is inclined by an angle of θ=1.00 with respect to the optical axis of the resonator. As described above, in this embodiment, the relationships represented by the formulas 1.2%≦R


N


≦15% and 0.5°≦θ≦2.0° are satisfied. Further, the preferable relationships represented by the formulas 3.0%≦R


N


≦10% and 0.8°≦θ≦1.5° are also satisfied.




Experiments conducted with the single-longitudinal-mode solid laser having the constitution described above revealed that, in cases where the output of the semiconductor laser


11


was 2 W, the second harmonic


31


with an output of 500 mW was capable of being obtained from the reliable, single longitudinal mode oscillation. Also, it was found that the second harmonic


31


was in a TEM


00


mode and was an approximately ideal Gaussian beam.




In the embodiment described above, the Nd:YVO


4


crystal


13


is employed as the solid laser medium. The single-longitudinal-mode solid laser in accordance with the present invention is also applicable to various solid lasers, which produce a laser beam having a wavelength of the 1 μm band and which utilize one of various other solid laser media, such as Nd:YAG, Nd:YLF, Nd:GdVO


4


, Nd:YAlO, and Nd:glass. In such cases, the same effects as those described above are capable of being obtained.




Also, the single-longitudinal-mode solid laser in accordance with the present invention is also applicable to solid lasers, in which the produced laser beam is not subjected to conversion into its second harmonic, or the like, with the optical wavelength converting device.



Claims
  • 1. A single-longitudinal-mode solid laser capable of producing a laser beam having a wavelength of a band ranging from 1 μm to 1.1 μm, the solid laser comprising:i) a solid laser medium doped with neodymium, ii) a resonator, and iii) a Fabry-Pérot type of etalon, which is located within the resonator and brings an oscillation mode to a single longitudinal mode, wherein a thickness of the etalon, a reflectivity of the etalon, an inclination of the etalon, and a resonator longitudinal mode interval are adjusted so as to satisfy the relationships represented by the formulas: 1.2%≦RN≦15% and 0.5°≦θ≦2.0°in which RN represents an effective reflectivity of the etalon with respect to wavelengths λ=λ0±Δλc deviating by a resonator longitudinal mode interval Δλc from a resonance wavelength λ0 of the etalon, and θ represents an inclination of an optical axis of the etalon with respect to an optical axis of the resonator.
  • 2. A single-longitudinal-mode solid laser as defined in claim 1 wherein the thickness of the etalon, the reflectivity of the etalon, the inclination of the etalon, and the resonator longitudinal mode interval are adjusted so as to satisfy the relationships represented by the formulas:3.0%≦RN≦10% and 0.8°≦θ≦1.5°in which RN represents the effective reflectivity of the etalon, and θ represents the inclination of the optical axis of the etalon with respect to the optical axis of the resonator.
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5502738 Hyuga Mar 1996 A
5506860 Hyuga et al. Apr 1996 A
5657341 Hyuga Aug 1997 A
5703900 Nozaki et al. Dec 1997 A
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6049555 Ohtsuka et al. Apr 2000 A
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Number Date Country
5-218556 Aug 1993 JP
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8-186316 Jul 1996 JP