The present disclosure relates to a sliding member, a gear box using the same, a wind powered generator, and a method for manufacturing a sliding member.
Conventionally, formation of a sliding member by arc welding is known (Japanese Patent Laid-Open No. 04-300073). In Japanese Patent Laid-Open No. 04-300073, a Cu—Sn—Pb alloy is laminated as a sliding layer on the surface of a back metal by arc welding. At this time, the sliding layer is formed using a powder containing Pb dispersed in advance in an alloy matrix. In Japanese Patent Laid-Open No. 04-300073, this reduces the evaporation of Pb caused by a high temperature during the welding and forms a structure in which Pb is uniformly dispersed in the sliding layer.
In recent years, for bearings in which a sliding member is used, there has been a demand for improvement in sliding characteristics in a high surface pressure environment due to a request of the additional reduction of a load on the environment and the like. Therefore, efforts are being made to improve the properties of the sliding layer by adding, for example, a low-melting point metal, a hard material or the like as an additive to the matrix. In this case, the sliding layer can be formed by, for example, performing welding using a powder or wire containing the additive added in advance to the matrix.
However, the low-melting point metal added to the matrix is likely to cause evaporation during welding and has a problem of causing a defect or segregation in the matrix of the sliding layer. In addition, the hard material added to the matrix is likely to cause aggregation during welding and has a problem in that uniform dispersion in the matrix is difficult. The uneven distribution of hard particles in the sliding layer has a problem of causing a decrease in the strength of the sliding layer and the deterioration of the sliding characteristics.
Therefore, an objective of the present disclosure is to provide a sliding member containing the particles of an additive uniformly dispersed in a sliding layer and having high sliding characteristics without impairing the strength, a gear box using the same, and a wind powered generator.
In addition, another objective of the present disclosure is to provide a method for manufacturing a sliding member in which the evaporation of an additive is reduced, the additive is uniformly dispersed and the sliding characteristics are further improved.
A sliding member according to one embodiment of the present disclosure is a sliding member including a base material; and a sliding layer that is laminated on the base material and has a matrix and particle phases uniformly and finely dispersed in the matrix.
That is, in the sliding member of one embodiment, the area rates Sv of the particle phases are all 0.2%≤Sv≤5% in a plurality of arbitrary observation regions extracted from an arbitrary observation cross section. As such, in the sliding member of one embodiment, the particle phases are uniformly present in the matrix of the sliding layer. In addition, a maximum particle diameter Da of the particle phases is refined to be 0 μm<Da≤30 μm. Therefore, the particles of the additive uniformly and finely disperse in the sliding layer, and it is possible to enhance the sliding characteristics without impairing the strength. In particular, the sliding member of one embodiment is capable of enhancing seizure resistance and wear resistance.
In a method for manufacturing the sliding member according to one embodiment of the present disclosure, the sliding layer is formed by arc welding of a wire to the base material. This method for manufacturing a sliding member includes a step of supplying the wire that is to turn into a matrix configuring the sliding layer; a step of melting the supplied wire by discharge with the base material to form a droplet; and a step of adding an additive that is to be added to the matrix to the formed droplet.
Therefore, the additive is mixed into the droplets of the molten wire. That is, in the present embodiment, the additive is added not to molten pools that are formed in the base material by an arc between the base material and the wire but to the droplets that are formed in the wire. Therefore, the additive uniformly and finely disperses in the droplets and uniformly and finely disperses in the sliding layer that is formed by the solidification of the droplets. This is because the droplets are rapidly cooled by the dropping of the droplets into the base material. That is, the additive added to the droplets is uniformly and finely mixed with droplets having a relatively small volume, then, drops into the base material to be cooled and solidifies while maintaining the uniformly and finely mixed state. In addition, the additive is added to the droplets, whereby the mixing between the base material and the additive is reduced compared with a case where the additive is added to molten pools. Furthermore, the additive is added to the droplets having a relatively small thermal capacity as in the present embodiment, whereby the additive is rapidly cooled in a state of being dispersed in the droplets, and a defect that is accompanied by the evaporation of the additive is also reduced. Therefore, it is possible to further improve the sliding performance.
In a method for manufacturing a sliding member according to another embodiment, the additive that is to be added to the matrix is added to the droplet as a particle, a powder containing the particle, a wire containing the particle or a bar containing the particle.
Hereinafter, an embodiment will be described based on drawings.
First, a welding device for manufacturing a sliding member will be described.
As shown in
When the front end of the wire 12 is made to come close to the base material 11 with the wire supply part 13, an arc is generated between the wire 12 and the base material 11. The wire 12 is instantly heated by the generated arc and melted. The molten wire 12 turns into a droplet 15 and drops toward the base material 11 side. When the droplet 15 of the molten wire 12 comes into contact with the base material 11, the base material 11 and the wire 12 are short-circuited, electrical conduction between the base material 11 and the wire 12 is paused, and the droplet 15 transfers to the base material 11. That is, the wire 12 is laminated on the base material 11 by the transfer of the droplet by arc welding. When the front end of the wire 12 is made to come apart from the base material 11 with the wire supply part 13, the base material 11 and the wire 12 are separated from each other, and an arc is generated between the base material 11 and the wire 12 again. When this process is repeated, a welding layer is formed on the base material 11 with a material that configures the wire 12.
The wire supply part 13 has a gas exhaust nozzle 16. The wire supply part 13 injects a shielding gas 17 from the gas exhaust nozzle 16. The shielding gas 17 contains an inert gas, for example, argon or helium, as a main component and oxygen or the like as an additive. The gas exhaust nozzle 16 injects the shielding gas 17 so as to surround the vicinity of a weld zone where the base material 11 and the wire 12 come into contact with each other. Therefore, the weld zone of the base material 11 and the wire 12 is shielded from outside air with the shielding gas 17. As the shielding gas 17, O2-containing Ar, 100% Ar, CO2, Ar+CO2, Ar+He or the like can be used.
The welding device 10 includes, in addition to the above-described parts, an additive supply part 20. The additive supply part 20 supply an additive 21 to the droplet 15 formed by the are between the base material 11 and the wire 12. In the present embodiment, the additive supply part 20 supplies the additive 21 not to a molten pool formed on the base material 11 side by the arc between the base material 11 and the wire 12 but to the droplet 15 formed on the wire 12 side. As shown in
As described above, in the case of the present embodiment, the welding device 10 includes the additive supply part 20. Therefore, the additive 21 is supplied to the droplet 15 that is formed of the wire 12 melted by the arc between the base material 11 and the wire 12.
Next, a method for manufacturing a sliding member using the above-described welding device and a sliding member that is obtained by the method will be described.
As shown in
As shown in
When the Vickers hardness of the high-hardness phase that configures the particle phases 35 is indicated by HV1 and the Vickers hardness of the matrix 34 is indicated by HV2, there is a relationship of 5≤HV1/HV2≤50 therebetween. That is, the Vickers hardness HV of the high-hardness phase that configures the particle phases 35 is 5 to 50 times that of the matrix 34. When the hardness of the high-hardness phase is set as described above with respect to the matrix 34, it is possible to reduce aggressiveness toward the mating material while improving the seizure resistance and the wear resistance.
In addition, the particle phases 35 may include low-hardness phases. The low-hardness phase is a phase of a particle having lower hardness than the matrix 34. The low-hardness phase is, for example, at least one element selected from Pb, Bi, Sn, Sb, In, Mg, Al, Zn and the like or a compound thereof. In this case, in a plurality of observation regions set in an arbitrary observation cross section, the area rate Sv of the particle phases 35 is 0.2%≤Sv≤5%. The particle phases 35 are uniformly dispersed in the matrix 34 of the sliding layer 32. In addition, the maximum particle diameter Da of the particle phases 35 is refined to be 0 μm<Da≤30 μm. Therefore, the particle phases 35 uniformly and finely disperse in the sliding layer 32, and it is possible to enhance the sliding characteristics without impairing the strength of the sliding layer 32. Particularly, as the sliding characteristics of the sliding layer 32, seizure resistance and wear resistance can be enhanced.
In addition, the low-hardness phases may be present together with the high-hardness phases in the particle phases 35. In this case, the high-hardness phases and the low-hardness phases may be uniformly and finely present in the matrix 34 of the sliding layer 32. Furthermore, the low-hardness phases may be configured to be not necessarily dispersed in the matrix 34 uniformly and finely while the high-hardness phases are configured to be uniformly and finely present in the matrix 34 of the sliding layer 32. In a case where the low-hardness phases are not uniformly and finely dispersed in the matrix 34 as described above, the amount of the low-hardness phase added in the sliding layer 32 is preferably 20 mass % or less. When the amount of the low-hardness phase added is set to 20 mass % or less as described above, the influence on the strength of the sliding layer 32 is reduced. Furthermore, the sliding layer 32 may contain a solid lubricant regardless of the hardness. The solid lubricant is, for example, at least one selected from graphite, MoS2 and the like. Hereinafter, the particle phases 35 are a collective term including the high-hardness phases and the low-hardness phases.
The wire 12 is supplied to the wire supply part 13 of the welding device 10 shown in
The particle phases 35 including at least any one of the low-hardness phases and the high-hardness phases are formed of the additive 21 that is supplied from the additive supply part 20. That is, the additive 21 is added to the droplet 15 of the molten wire 12, whereby a variety of materials that are to turn into the particle phases 35 are mixed into the droplet 15 of the molten wire 12. In addition, when the droplet 15 transfers to the base material 11 as shown in
The sliding layer 32 is not limited to the above-described example and may also be formed as shown in
These sliding layers 32 contain the particle phases 35 made of the additive 21 as a raw material in the matrix 34 as described above. In the case of the present embodiment, during the formation of the sliding layer 32, the additive 21 is added not to molten pools that are formed in the base material 11 by the arc between the base material 11 and the wire 12 but to the droplet 15 that is formed in the wire 12. Therefore, the additive 21 that is to turn into the particle phases 35 uniformly and finely disperses in the droplet 15 and also uniformly and finely disperses in the sliding layer 32 to be formed. This is because the droplet 15 is rapidly cooled by the dropping of the droplet 15 into the base material 11. That is, the additive 21 added to the droplet 15 is uniformly and finely mixed with the droplet 15 having a relatively small volume, then, drops into the base material 11 to be cooled and solidifies while maintaining the uniformly and finely mixed state.
In addition, the additive 21 is added to the droplet 15, whereby mixing with the base material 11 in the sliding layer 32 is reduced compared with a case where the additive 21 is added to molten pools. The molten pools are in a state where the wire 12 and the base material 11 are mixed together and melted. Therefore, for example, when the additive 21 is added to the molten pools, the additive 21 is mixed not only with the wire 12 that is to turn into the sliding layer 32 but also with the molten base material 11. In addition, for the base material 11, the wire 12 and the additive 21 that have been mixed together in the molten pools, the solidification rate becomes slow, and the additive 21 is likely to aggregate. Furthermore, for example, when the additive 21 is mixed with the wire 12 in advance, the temperature increases during the heating by the arc, and a defect is likely to be caused due to the evaporation of the additive 21 or the like.
In contrast, in the present embodiment, the additive 21 is added to the droplet 15 having a relatively small thermal capacity. Therefore, the particle phases 35 made of the additive 21 can be rapidly cooled in a state of being dispersed in the matrix 34 of the sliding layer 32. In addition, in the present embodiment, a defect that is accompanied by the evaporation of the additive 21 can be reduced.
The thickness T of the sliding layer 32 formed on the base material 11 by welding is set to be 0 mm<T≤0.5 mm by, for example, machining such as cutting or grinding. When the sliding layer 32 is formed by welding as described above, the sliding layer 32 is not required to have a tensile strength compared with a case where, for example, a bushing or the like is used. Therefore, it is possible to make the thickness T of the sliding layer 32 as thin as 0.5 mm or less.
The sliding member 30 having the sliding layer 32 laminated on the base material 11 is manufactured by the above-described procedure.
The sliding member 30 includes the base material 11 and the sliding layer 32 as shown in
One example of carrying out the sliding member 30 was verified. As the example of carrying out, a sliding layer 32 was formed by arc welding using a wire 12 of a Cu alloy on a steel sheet that was to be a base material 11 using the welding device 10 shown in
As described above, in the present embodiment, the additive 21 is added to the droplet 15 formed by the melting of the wire 12. Therefore, the particle phases 35 made of the additive 21 uniformly and finely disperse in the matrix 34 of the sliding layer 32 to be formed. Therefore, the sliding performance is further enhanced, and the sliding performance can be controlled as appropriate depending on the use by selecting the additive 21.
As shown in
As described above, when the sliding layer 32 is directly provided on the rotary shaft part 41 by welding, it is possible to cope with a high surface pressure with the sliding member 30 including the sliding layer 32 having a controlled sliding performance.
Next, the sliding layer 32 will be described in detail.
As described above, the sliding layer 32 has the matrix 34 and the particle phases 35. The area rate Sv of the particle phases 35 is 0.2%≤Sv≤5%. Specifically, in the sliding layer 32, an arbitrary observation cross section 50 is set as shown in
The area rate Sv of the particle phases 35 in this observation region 51 is 0.2%≤Sv≤5%. The area rate Sv is calculated from Sv=Sm/S×100 using the area S of the observation region 51 and the total Sm of the areas of the particle phases 35 that are included in this observation region 51. In the present embodiment, this area rate Sv is 0.2%≤Sv≤5% in any of the plurality of arbitrary observation regions 51 extracted from the observation cross section 50. That is, the area rate Sv of the particle phases 35 is 0.2%≤Sv≤5% in any of the observation regions 51. This indicates that the particle phases 35 have uniformly dispersed in the matrix 34 of the sliding layer 32. In addition, the maximum particle diameter Da of the particle phases 35 is 0 μm<Da≤30 μm. The maximum particle diameter Da may be observed in the observation cross section 50 or may be observed in the observation region 51. In any case, the maximum particle diameter Da of the particle phases 35 that are included in the sliding layer 32 is 0 μm<Da≤30 μm. As described above, it is indicated that the particle phases 35 that disperse in the matrix 34 of the sliding layer 32 are fine phases having a maximum particle diameter Da of 30 μm or less.
The volume proportion W of the particle phases 35 that are included in the sliding layer 32 is preferably 0.1 vol %≤W≤5.0 vol %. The volume proportion W is the total of the volumes of the particle phases 35 with respect to the volume of the sliding layer 32. This volume proportion W is more preferably 0.2 vol %≤W≤2.0 vol %. When the volume proportion W is 0.1 vol % or more, particularly, the high-hardness phases among the particle phases 35 further contribute to improvement in the seizure resistance. In addition, the upper limit of the volume proportion W is preferably set to 5.0 vol %. When the volume proportion W is set to 5.0 vol % or less, the aggressiveness toward the mating material is effectively suppressed.
The adhesive strength F between the base material 11 and the sliding layer 32 is preferably 250 N/mm2≤F. In a case where the adhesive strength F is secured as described above, the peeling of the sliding layer 32 from the base material 11 is reliably avoided even when the rotary shaft part 41 that is to turn into the base material 11 deflects. In addition, the depth Tt in the thickness direction up to which the base material 11 is affected by heat from the sliding layer 32 during the formation of the sliding layer 32 is preferably Tt≤500 μm. The range where the base material 11 is affected by heat induced from welding is reduced by appropriately securing the temperature of the base material 11 during the welding. Therefore, the influence on the strength of the base material 11 decreases. That is, in the case of the present embodiment, the time during which the base material 11 is heated is extremely short, and the influence of heat on the base material 11 becomes small. Therefore, it is possible to decrease the change in the structure of the base material 11 by heat and the accompanying influence on the strength of the base material 11.
The roughness Ra on the surface of the sliding layer 32 is preferably Ra≤0.6. Particularly, the roughness Ra on the surface of the sliding layer 32 is more preferably 0.3≤Ra≤0.6. When the roughness Ra on the surface of the sliding layer 32 is set as described above, it is possible to reduce machining man-hours and machining accuracy while reducing the friction coefficient of the sliding layer 32, and facility simplification accompanied by the reduction of machining accuracy can be achieved.
Hereinafter, specific Examples and Comparative Examples of the sliding member 30 will be described.
The Examples and the Comparative Examples were evaluated by an adhesion test and a sliding test. As a test piece, the sliding layer 32 was overlay-welded on the Fe-based base material 11 using the wire 12 and the additive 21. The sliding layer 32 was formed by MIG welding using a CMT method in which the wire 12 was repeatedly supplied forward and backward at a high rate to molten pools generated during the welding. After the welding, the test piece was made into a predetermined shape by machining such as cutting and grinding.
In the adhesion test, the adhesive strength was evaluated as the strength of the sliding member 30. The adhesive strength is the adhesive force between the base material 11 and the sliding layer 32. In the adhesion test, a test piece 60 in which the base material 11 and the sliding layer 32 were joined together across a predetermined joining area as shown in
In the sliding test, seizure resistance by a seizure test and wear resistance by a wear test were evaluated as the strength and sliding characteristics of the sliding member 30. In the seizure test, the maximum surface pressure at which the sliding member 30 did not seize was evaluated as the seizure resistance. In the wear test, the wear amount of the sliding member 30 was evaluated as the wear resistance. The seizure test and the wear test in the sliding test were performed by installing a test piece 70 formed in a toric shape as shown in
The evaluation results of the Examples and the Comparative Examples are shown in
In all of Sample 1 to Sample 9, which are Examples, the adhesive strength, the maximum surface pressure and the wear amount are evaluated as PASS as shown in
In Sample 12, Sample 15 and Sample 18, which are Comparative Examples, the area rates Sv of the particle phases 35 that are included in the sliding layer 32 are excessively small. Therefore, it is found that, in these Sample 12, Sample 15 and Sample 18, improvement in the seizure resistance and the wear resistance cannot be expected. In Sample 19 and Sample 20, which are Comparative Examples, the additive 21 is added to the molten pools that are generated in the base material 11. Therefore, in Sample 19 and Sample 20, segregation in which the particle phases 35 are locally generated is caused. It is found that, in Sample 19 and Sample 20, the variations of the seizure resistance and the wear resistance increase due to this segregation. In Sample 21 and Sample 22, which are Comparative Example, the additive 21 is not added, and the particle phases 35 are not included in the sliding layer 32. Therefore, it is found that, in Sample 21 and Sample 22, the seizure resistance and the wear resistance deteriorate.
The present invention described above is not limited to the above-described embodiment and can be applied to a variety of embodiments within the scope of the subject matter of the present invention.
For example, the sliding member 30 may include an overlay layer, not shown, in addition to the base material 11 and the sliding layer 32. In this case, the overlayer layer is formed on the surface of the sliding layer 32, that is, on the surface opposite to the base material 11 to overlap the sliding layer 32. For the overlay layer, for example, a soft metal such as Sn or Bi or an alloy thereof is preferably used. In addition, for example, a resin in which a solid lubricant is dispersed or the like may be used for the overlay layer. When the sliding member 30 includes the overlay layer, the outermost surface of this overlay layer becomes the sliding surface 33 that slides over the mating material. Furthermore, the sliding member 30 may include one or more interlayers, not shown, between the base material 11 and the sliding layer 32. In this case, for the interlayer, a material that increases the adhesive force between the base material 11 and the sliding layer 32, for example, Ni, an alloy thereof or the like, is preferably used.
Number | Date | Country | Kind |
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2022-056211 | Mar 2022 | JP | national |
The present application is a National Stage Entry into the United States Patent and Trademark Office from International Patent Application No. PCT/JP2023/012552, filed on Mar. 28, 2023, which is based on and claims priority to Japanese Patent Application No. 2022-056211, filed on Mar. 30, 2022, the entire contents of both of which are incorporated herein by reference.
Filing Document | Filing Date | Country | Kind |
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PCT/JP2023/012552 | 3/28/2023 | WO |