Patent Application
20150082689
1. Field of Invention
The inventive subject matter relates to an insecticide sprayer capable of producing droplets less than 5 μm in size. The sprayer utilizes ultrasonic frequency to produce small droplet size.
2. Background Art
Insecticides are typically applied to flying insects by spraying the insecticide with random coating or application based on chance collision with the spray. Current methods of insecticide spraying entail application of a spray with random application of insecticide on the insect as the insect encounters the spray.
Because most spray contains droplets sizes that are relatively large, often as much as 100 μm, the sprayed material settles relatively quickly. This necessitates forming a spray starting fairly high, often using more chemical than is necessary. Production of smaller droplets is typically is accomplished by vaporizing the material by heating it. This approach, however, is problematic in insecticide application due to the often combustible or flammable nature of the chemicals in insecticide formulations.
The current invention relates to an insecticide sprayer and method of application of insecticides, capable of producing small size droplets.
Current insecticide spraying equipment are not generally capable of producing fine droplets in the range of 5 μm or less. Small droplets, defined as droplets 5 μm or less, are highly desirable in that small droplets would form a fog-like layer which would accumulate near the ground, where many insects reside. Currently there is only one type of sprayer that is capable of producing droplets less than five microns. This is called a thermo fogger, which uses the latent heat of combustion generated in a chamber that vaporizes the liquid. Unfortunately most of the formulations used in insecticidal spray formulation contain combustible materials. Therefore, use of this approach to produce small droplets may pose a serious safety hazard. This is especially true in areas where combustible materials are present, especially in enclosed or partially enclosed areas. However, use of a thermo fogger to atomize water only results in the formation of droplets in the 27-60 micron range.
It is an advantage to have small droplets for insecticidal spraying. As such there is a need for an apparatus for making less than 5 μm droplets without using heat and capable of forming less than 5 μm droplets cold spray. The problem is even worse for hand held/backpack portable sprayers where the smallest size attainable with water is 15 μm and the average is in the 50 to 100+μm. Interestingly, most hand-held sprayers using water produce 15 μm droplets or greater.
Table 1 shows how the droplet size relates, geometrically, to volume of liquid. The small droplets can have the effect of more effectively carrying and adhering to the target of interest. As shown in Table 1, 422 droplets with a diameter of 2 μm contains the same volume as one 15 μm droplet. Similarly, 3375 drops with a 1 μm diameter would contain the same volume as 1 droplet with a diameter of 15 μm. This attribute ensure more efficient use of material and cost savings.
Additionally, an important attribute of small droplets, especially droplets of less than 5 μm in diameter, is their ability to result in a stable, non-settling fog. A stable non-settling fog with the insecticide formulation would permit many more droplets to be available to contact target insects. Also, the non-settling nature of the fog would allow much greater time for the insects to fly in the presence of the insecticide. Collectively, the characteristics of small, 5 μm droplets increases the efficiency of exposure and delivery of insecticide to the target insects.
In addition to use of small, 5 μm droplets, application of charge to the droplets would be advantageous for further efficiency of application. Where application is intended for flying insects, the charge of the droplets should typically be negatively charged, since insects are believed to induce a positive charge on their bodies during flight. The negatively charged droplets would be attracted to the insect thus making the amount of charged droplets coming into contact with the insect is much greater.
In a preferred embodiment, the inventive device is capable of producing and expelling droplet sizes of liquids, defined as 5 μm or smaller. The device comprises a reservoir (1), connected, via a connection tube (3) capable of permitting fluid to pass to a transducer drum (5). The transducer drum contains one or more transducers (9) that are electrically connected to a suitable power source (17). The power source (17) is capable of generating electrical oscillations in the ultrasonic frequency range. Ultrasonic frequency range is defined as a frequency of oscillation above 19 kHz.
As an example, in one embodiment, the ultrasonic frequency is approximately 0.8 MHz to approximately 1.7 MHz. Power switching with the power switching transistor can be arranged as Colpitts oscillator. In a preferred embodiment, the frequency is 1.65 MHz.
Any type of transducer can be utilized, including magnetostrictive or piezo-electric transducers. In a preferred embodiment, piezo-electric transducers are utilized. In one embodiment, the frequency is adjustable to produce the desired droplet size.
The inventive device can be configured in a number of ways.
In a preferred embodiment, fluid in the reservoir (1) flows through the connection tube (3) to the transducer drum (5). In the transducer drum (5), fluid is subjected to sonication via one or more ultrasonic transducers (9), which vibrate at ultrasonic frequency. Any type of transducer can be utilized, including magnetostrictive or piezo-electric transducers.
Table 2 illustrates the results of a study using ultrasonic transducer to produce droplets of different fluid materials. In this study, various chemical formulations are emitted from a commercially available ultrasonic humidifier (Hunter® model 31004). The humidifier's transducer oscillates at an ultrasonic frequency of 1.65 MHz. The transducer is used here as a prototype that would be incorporated into the inventive device of
1Median of diameter
2Diameter of 10% of droplets
3Diameter of 90% of droplets
As illustrated in Table 2, the humidifier emits droplets within a range of 1.5 μm to 17.26 μm, depending on the source material. For example, the ultrasonic humidifier was able to produce droplets of 47.5% BVA 13 oil (BVA, Inc, Wixom, Mich.) with 47.5% ethyl acetate and 5% permethrin (3-Phenoxybenzyl (1RS)-cis,trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate) with an average diameter (i.e., DV0.5) of 4.72 μm, with 10% of the droplets as small as 2.2 μm. Similarly, 10% Aqua-Kontrol® Concentrate (Masterline®, Univar, Austin, Tex.) and 90% water yielded 10% of the droplets with a diameter of 1.5 μm with an average diameter of 6.78 μm.
In another study, droplets were created by a prototype mister, fabricated by Humidifirst™, Inc. (Boynton Beach, Fla.). The prototype mister comprised a solenoid valve control of water (i.e., fluid) flow into the humidifier; a float switch to control water level; and a float switch to provide for low water shutdown; a blower fan; and 4 piezoelecrtric crystals (i.e., transducers). Droplet size was monitored by a Phase Doppler Particle Analyzer (PDPA) (TSI, Inc, Shoreview, Minn.). The results of the study are illustrated in Table 3. As illustrate in Table 3, the median volume in this study was 7.13 μm to 7.35 μm, with approximately 10% of the droplets 3.75 μm to 3.82 μm.
1DV.1 = 10% of spray volume is contained in droplets of this volume or smaller; DV.5 = 50% of spray volume is contained in droplets of this volume or smaller; DV.9 = 90% of spray volume is contained in droplets of this volume or smaller.
Flying insects generate an electrical charge as they move through the air. As such, negatively charged particles would be attracted to those regions of the flying insect that have imparted a positive charge.
Procedures and devices have been described capable of generation of charged droplets. In general, this is conducted by exposing of droplets to a suitable electrical field (Ahn, et al., Biomicrofluidics 3, 044102 (2009); Pilat and Lukas, Air and Waste Manage. Assoc. 54: 3-7 (2004)). Exposing fluids to an electric field is also utilized in electrostatic spray devices and methods (Stark, et al., U.S. Patent Application 2010/0155496 (Jun. 24, 2010)); Imai, et al., U.S. Patent Application 2012/0153055 (Jun. 21, 2012)).
In one embodiment of the current device, illustrated in
The ensuing small (5 μm) droplets can then be imparted with a charge. Any number of methods for imparting charge on the droplets is contemplated. However, as an example, illustrated in
In another embodiment, charge droplets can be separated based on charge. Any number of separation methods are contemplated. However, as an example, also illustrated in
In applying insecticide sprays to flying insects, current methods typically entail spraying in the vicinity of the insects and the insects encountering the spray by random collisions with the droplets. Furthermore, since insecticide droplets are typically relatively large, often over 50 μm in diameter, the droplets tend to settle relatively quickly. The rapid settling of insecticide necessitates application of large amounts of material at a height to enable adequate collisions of the insects with the insecticide droplets. The result is that significant amounts of insecticide, which is wasted and not actually encountered by the insect, in order to afford efficacy of the spraying with adequate coverage of area.
In one embodiment, small, 5 μm diameter droplets, or less, are created with the device described in Example 1. Application of insecticide is then applied to the desired area creating a slow settling fog, since the small droplets will tend to settle to the ground slowly and linger longer in the air. The longer lingering increases the likelihood of collision with the droplets by flying insects. Use of the method would result in the need for less insecticide, with greater insecticide effectiveness.
In an additional embodiment, an electrical charge can be imparted on the small, i.e., 5 μm or less diameter, droplets, as in Example 2. The charged droplets would linger longer in the air, as a fog, than larger droplets increasing collision of droplets by flying insects. Additionally, the charged droplets will be attracted to the inherent electrical charge on the insects. Use of charged droplets would result in the need for even less insecticide material than if only small droplets were utilized.
Having described the invention, one of skill in the art will appreciate in the appended claims that many modifications and variations of the present invention are possible in light of the above teachings. It is therefore, to be understood that, within the scope of the appended claims, the invention may be practiced otherwise than as specifically described.
This application claims the benefit of provisional application, No. 61/708,184, filed Oct. 1, 2012.
