Smoking article with impaction filter segment

Information

  • Patent Grant
  • 8353298
  • Patent Number
    8,353,298
  • Date Filed
    Wednesday, July 11, 2007
    17 years ago
  • Date Issued
    Tuesday, January 15, 2013
    11 years ago
Abstract
A smoking article having a cylinder of smoking material and a filter system attached to the cylinder of smoking material. The filter system includes an upstream plug of filtering material, a downstream plug of filtering material, and a cavity between the upstream plug of filtering material and the downstream plug of filtering material. A flow restrictor is positioned within the cavity and has at least one orifice and a series of perforations provide ventilation to the smoking article.
Description
BACKGROUND

Cigarettes are typically categorized according to their delivery of tar (nicotine free, dry particulate matter) under standard test procedures such as the one established in 1967 by the Federal Trade Commission (FTC). The FTC method includes machine drawn puffs at 35 cm3 volume for 2-second duration each, at 60-second intervals. The International Organization for Standardization (ISO) has a similar smoking protocol.


In the 1990s, additional smoking protocols were proposed, including that of the Massachusetts Department of Public Health (MDPH), one of the so-called intense smoking regimes. The MDPH method includes machine drawn puffs at 45 cm3 volume for 2-second duration each, at 30-second intervals, with 50% of the cigarette filter ventilation holes blocked.


It has been found that commercial lit-end cigarettes tend to produce higher tar than FTC deliveries when puff draw volume, frequency of draw and/or puff duration are increased and/or ventilation holes are occluded in whole or in part. This tendency is reflected, for example, in differences in measurement of tar (FTC) and tar (MDPH) (i.e., Tar (mg/cigt)MDPH/Tar (mg/cigt)FTC), with tar (MDPH) being representative of a more intense drawing condition over that of the former.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a perspective view of a smoking article in the form of a cigarette.



FIG. 2 is a cross sectional view of the smoking article of FIG. 1.



FIG. 3 is a cross sectional view of the smoking article of FIG. 1 with the tipping paper partially unwrapped.



FIG. 4 is a view along the line 4-4 of FIG. 2.



FIG. 5 is a side view of the flow constrictor of the smoking article of FIG. 4.



FIG. 6 is a schematic view of another flow constrictor and plug.





DETAILED DESCRIPTION

With reference to FIGS. 1 and 2, a smoking article 10 in the form of a cigarette typically includes a tobacco rod 20 of smoking material 21, contained in a circumscribing outer wrapper 30. The outer wrapper 30 is typically a porous wrapping material or paper wrapper. The tobacco rod 20 has a lit end 12 and a tipped end 14 (FIG. 2). The smoking material 21 is preferably a shredded tobacco or blend of tobaccos (typically called “cut filler”). However, any suitable smoking material 21 can be used.


The smoking article 10 also includes a filter system 40 adjacent to the tipped end 14 of the tobacco rod 20 such that the filter system 40 and tobacco rod 20 are axially aligned in an end-to-end relationship, preferably abutting one another. The filter system 40 has a generally cylindrical shape, and the diameter thereof is essentially equal to the diameter of the tobacco rod 20. The ends (i.e., upstream end 16 (FIG. 2) and downstream end 18) of the filter system 40 are open to permit the passage of air and smoke therethrough. The filter system 40 includes a plurality of plugs 42, 46 (FIG. 2) of filtering material and a flow constrictor 44 (FIG. 2) circumscribed by a plug wrap 48. The plug wrap 48 is typically a paper, which optionally incorporates a carbonaceous material. The plug wrap 48 circumscribes the total length of the filter system 40.


The filter system 40 attaches to the tobacco rod 20 by a tipping material 50, which circumscribes both the entire length of the filter system 40 and an adjacent region of the tobacco rod 20. The tipping material 50 is typically a paper like product; however, any suitable material can be used. The inner surface of the tipping material 50 is fixedly secured to the outer surface of the plug wrap 48 and the outer surface of the wrapping material 30 of the tobacco rod 20, using a suitable adhesive. A ventilated or air diluted smoking article 10 can be provided with an air dilution means, such as a series of ventilation holes or perforations 60, each of which extends through the tipping material 50 and (optionally) the plug wrap 48. As shown in FIG. 1, ventilation of mainstream smoke can be achieved with a circumferential row (FIG. 1) or rows of ventilation holes or perforations 60 about a location along the filter system 40. In the preferred embodiment, a ratio of total particulate matter (“TPM”) and tar yield between MDPH and FTC/ISO methods is relatively constant for higher flavor delivery cigarettes, and low or ultra low flavor delivery cigarettes.


Upon lighting of the smoking article 10, the mainstream smoke is generated by and drawn from the tobacco rod 20 and through the filter system 40. Herein, the “upstream” and “downstream” relative positions between the filter system 40 and other features are described in relation to the direction of mainstream smoke as it is drawn from the tobacco rod 20 and through the filter system 40.



FIG. 2 shows a cross sectional view of FIG. 1 according to one embodiment of a smoking article 10 with the flow constrictor 44 having at least one constrictor member 70. As shown in FIG. 2, the filter system 40 is comprised of a first or upstream plug 42 of filtering material, a flow constrictor 44 and a second or downstream plug 46 of filtering material. The flow constrictor 44 comprises a constrictor member 70 having at least one orifice 72 (FIG. 4) and more preferably at least two orifices 72.


As shown in FIG. 2, the upstream plug 42 of filtering material and the downstream plug 46 of filtering material have a generally cylindrical shape, and an outer diameter 52 thereof that is essentially equal to the diameter of the tobacco rod 20. The filtering material is preferably cellulose acetate. However, it can be appreciated that the filtering material can be comprised of cellulose acetate with an activated carbon mixed throughout (often referred to as carbon-on-tow) or any other suitable filtering material and/or additives such as flavorants. The filter system 40 typically has an overall length 56 of about 15 to 40 mm for a smoking article 10 having an overall length 58 of about 80 to 160 mm. The filter system 40 also includes a plurality of ventilation holes or perforations 60 on the downstream side of the flow constrictor 44. In use, a cigarette or smoking article 10 incorporating the filter system 40 with the constrictor member 70 and the downstream ventilation holes, minimizes the ratio of total particulate matter (TPM) and tar yield by increasing the filtration efficiency with the increase of flow rate or puff volume. Specifically, the range of TPM or tar that the smoker is exposed to, by increasing puff volume, is reduced and the ratio of Tar (mg/cigt)MDPH/Tar (mg/cigt)FTC is made more uniform for full flavor delivery cigarettes and low or ultra low delivery cigarettes. In addition, it has been observed generally that the first puff of a cigarette may deliver more flavor (or may be perceived to deliver more flavor) than subsequent puffs in the same cigarette.



FIG. 3 shows a cross sectional view of the smoking article 10 with the flow constrictor member 70 and the upstream plug 42. The upstream plug 42 of the filter system 40 may comprise a cellulose acetate element mixed with an activated carbon material throughout in the form of a carbon-on-tow plug of filtering material. It can also be appreciated that the plugs 42, 46 of filtering material can contain activated carbon in a cavity provided within or adjacent to the upstream and downstream plugs 42, 46 of cellulose acetate material. Alternatively, the upstream and downstream plugs 42, 46 of filtering material can contain activated carbon or other gas-vapor phase sorbents.


In FIG. 3, arrows indicate the flow of mainstream smoke from the tobacco rod which has passed through the openings in the flow constrictor member 70. Some of the particulate matter in the mainstream smoke is deposited on an end surface of the downstream plug 46 of filter material. Additional arrows indicate the flow of ventilation air into the filter through the ventilation holes. As the mainstream smoke continues through the downstream plug 46 of filter material, the ventilation air enters the downstream plug 46 and the mainstream smoke tends to move toward the center of the downstream plug 46.



FIG. 4 shows the flow constrictor member 70 of the smoking article 10 of FIGS. 2 and 3 along the line 4-4. As shown in FIG. 4, the flow constrictor member 70 has a plurality of orifices 72. The constrictor member 70 preferably has a diameter 110 of about 7.0 to 8.0 mm and more preferably about 7.4 to 7.8 mm. The constrictor member 70 preferably has at least two orifices 72 having a diameter 112 of about 0.2 to about 0.8 mm and more preferably about 0.3 to 0.6, and most preferably about 0.4 mm each. The constrictor member 70 can be made of paper, plastic, or metal, and more preferably made of a paper product or other suitable material having biodegradability properties. The constrictor member preferably is made of foamed cellulose or foamed cellulose acetate or any other type of cellulosic material or cellulose acetate that can be formed into the desired shape of the constrictor member 70. The cellulosic material may be derived from tobacco, such as a cellulosic material derived from tobacco stems.



FIG. 5 shows a side view of the constrictor member 70 of the smoking article 10. As shown in FIG. 5, the constrictor member 70 preferably has an outer width 114 of about 2.0 to 6.0 mm and more preferably about 3.0 to 5.0 mm, and an inner width 115 of about 1.0 to 3.0 mm and more preferably about 1.5 to 2.25 mm. The spacing 116 (i.e., the difference between the outer width 114 and the inner width 115 divided by 2) is preferably about 1.5 to about 2.25 mm. The spacing 116 created by the difference in the outer width 114 and the inner width 115 forms an upstream cavity 118 and a downstream cavity 119. The upstream cavity 118 is positioned between the upstream plug 42 of filtering material and the flow constrictor 44, with the downstream cavity 119 positioned between the flow constrictor 44 and the downstream plug 46 of filtering material. The spacing especially between the flow constrictor and the downstream filter plug may be varied to vary the efficiency of the filter in removing particulate material. Similarly, the velocity of the mainstream smoke leaving the orifices and impacting the end face of the downstream filter plug affects the efficiency of the filter in removing the particulate material from the mainstream smoke. Generally, the higher the velocity, the more particulate material that is removed from the mainstream smoke at the end face of the downstream filter plug.


The annular portion of the flow constrictor is preferably spaced approximately 1-5 mm and more preferably 1-3 mm away from the end face of the downstream filter plug.



FIG. 6 schematically shows the flow of mainstream smoke toward the constrictor member 70 and through the orifices 72. Passage of the mainstream smoke through the orifices causes the velocity of the mainstream smoke to increase significantly as compared to the velocity of the mainstream smoke through the tobacco rod. Upon leaving the orifices 72 of the flow constrictor member 70, the larger particles of the mainstream smoke impacts an end face of the downstream plug 46 with the result that particulate matter is collected on the end face of the downstream plug 46 as indicated by the darks spots about the outer edge of the end face. These dark spots correspond directly to the location of the orifices 72 about the constrictor member 70.


The upstream plug 42 of filtering material and the downstream plug 46 of filtering material have a generally cylindrical shape, and an outer diameter that is essentially equal to the outer diameter of the tobacco rod 20. The filtering material is preferably a cellulose acetate material. However, the filtering material can be carbon-on-tow or any other suitable filtering material. The filter system 40 typically has an overall length of about 15 to 40 mm in length for a smoking article 10 having an overall length of about 80 to 160 mm. Each plug 42, 46 of filtering material can have the same length, or the upstream and downstream plugs 42, 46 can have different lengths. Also, the preferred length of the upstream and downstream plugs 42, 46 of filtering material can depend on the presence of additional materials within the filtering material such as activated carbons or other gas-vapor phase sorbent or additive materials.


As shown in FIG. 6, the flow constrictor 44 comprises the constrictor member 70 having a plurality of orifices 72 which are preferably equally spaced along the perimeter of the constrictor member. Preferably, the constrictor member is comprised of 2 orifices but may have, for example, 4 to 12 orifices 72 and, as illustrated, 8 orifices. However, it can be appreciated that any number of orifices 72 can be used. The number of orifices 72 as well as their size and position in the constrictor member depend on the desired resistance-to-draw (RTD) or pressure drop, and particulate efficiency for the filter 40. The orifices preferably have a diameter of 0.4 mm to 0.8 mm. In use, the filter of the cigarette preferably has a resistance to draw (RTD) of about 110 mm H2O.


In one embodiment, the filter plugs 42, 46 are preferably low particulate efficiency filter segments constructed from cellulose acetate tow of approximately 8.0 denier per filament and approximately 35,000 total denier. In one embodiment, the flow constrictor member comprises an annular partition that defines an orifice (or flow constrictor) of reduced diameter. Preferably, the flow constrictor also includes a tubular body portion upstream and downstream of the annular partition. The tubular body portions space the annular partition a predetermined distance apart from the adjacent filter segments, preferably approximately 1 to approximately 6 millimeter (mm), and more preferably approximately 1 to 3 mm. In addition, the upstream filter segment prevents the tobacco from the tobacco rod from blocking the orifices of the annular portion of the flow constrictor.


A ventilating zone is established preferably with a row of ventilation holes through the tipping paper 16. The ventilating zone is located downstream of the flow constrictor so that air drawn through the ventilation zone may mix with the mainstream smoke before arriving at the mouthpiece.


Preferably, the ventilation zone and the hole or holes in the flow constrictor achieve a ventilation level of the smoking article of at least 25% and more preferably about 50% to 90%.


The flow constrictor preferably has end to end symmetry which facilitates high speed filter rod making in that the component works the same whether or not the rod making machine orients one end of the flow constrictor first or the reverse. Preferably the flow constrictor is sized to contribute sufficient pressure drop such that the smoking article 10 presents a resistance to draw of at least 70 mm water or greater, preferably in the range of 90-120 mm water and most preferably 110 mm water. Preferably, the flow constrictor has a diameter of approximately 7.0 to 8.0 mm and more preferably approximately 7.4 to 7.8 mm wherein the flow constrictor preferably has one or optionally, at least one orifice of a diameter of about 0.5 mm to about 0.9 mm and more preferably about 0.5 to 0.7 mm. Since the pressure drop of the flow constrictor depends on the open area, multiple orifices can also be used. For example, in one preferred embodiment there are two orifices of 0.5 mm diameter each.


It will be understood that the foregoing description is of the preferred embodiments, and is, therefore, merely representative of the article and methods of manufacturing the same. It can be appreciated that variations and modifications of the different embodiments in light of the above teachings will be readily apparent to those skilled in the art. Accordingly, the exemplary embodiments, as well as alternative embodiments, may be made without departing from the spirit and scope of the articles and methods as set forth in the attached claims.

Claims
  • 1. A smoking article comprising: a tobacco rod adapted to produce mainstream smoke;a filter having an upstream end portion and a downstream end portion, said filter arranged to receive mainstream smoke at said upstream end portion, said filter comprising:an upstream filter plug segment at said upstream end portion;a downstream filter plug segment at said downstream end portion;a flow constricting segment consisting of a tubular portion, a single transverse plate, an upstream cavity and a downstream cavity, said upstream cavity and said downstream cavity having an equal volume and defined by said tubular portion and said single transverse plate, said flow constricting segment provided at a location adjacent said downstream filter plug segment, said flow constricting segment adapted to direct mainstream smoke at a relatively high velocity, compared to the velocity of the mainstream smoke through the tobacco rod, toward an adjacent region of said downstream filter plug segment, said flow constricting segment comprising at least one opening in the single transverse plate, said at least one opening spaced away from an end face of the downstream filter plug segment by at least about 1 mm; and,tipping paper attaching said filter with said tobacco rod and including an air-admissing ventilating zone superposed with the downstream filter plug segment.
  • 2. The smoking article of claim 1, wherein said air-admissing ventilating zone comprises a row of perforations extending through said tipping paper at said ventilating zone.
  • 3. The smoking article of claim 1, wherein said upstream filter plug segment and said downstream filter plug segment comprise material of low particulate efficiency.
  • 4. The smoking article of claim 2, wherein said single transverse plate comprises a plurality of openings disposed circumferentially about said single transverse plate, said single transverse plate being spaced away from the upstream filter plug segment and the downstream filter plug segment by said tubular portion, said single transverse plate being spaced away from the downstream filter plug approximately 1 to 5 mm.
  • 5. The smoking article of claim 2, wherein said ventilation zone is positioned to promote mixing of air drawn through said ventilation zone and mainstream smoke drawn from said tobacco rod.
  • 6. The smoking article of claim 1, wherein the flow constricting segment comprises a plurality of orifices, wherein each of the plurality of orifices has a diameter of about 0.2 mm to 0.6 mm.
  • 7. The smoking article of claim 1, wherein a predetermined resistance-to-draw for the smoking article is at least approximately 90 millimeters water.
  • 8. The smoking article of claim 1, wherein at least one of said upstream filter plug segment and said downstream filter plug segment comprises cellulose acetate tow of low denier.
  • 9. A filter for a smoking article comprising a tobacco rod adapted to produce mainstream smoke, said filter comprising an upstream end portion and a downstream end portion, said filter arranged to receive mainstream smoke at said upstream end portion, said filter further comprising: an upstream filter plug segment comprising said upstream end portion;a downstream filter plug segment comprising said downstream end portion;a flow constricting segment consisting of a tubular portion, a single transverse plate, an upstream cavity and a downstream cavity, said upstream cavity and said downstream cavity having an equal volume and defined by said tubular portion and said single transverse plate, said flow constricting segment provided at a location adjacent said downstream filter plug segment, said flow constricting segment adapted to direct mainstream smoke at a relatively high velocity, compared to the velocity of the mainstream smoke through the tobacco rod, toward an adjacent region of said downstream filter plug segment, said flow constricting segment comprising at least one opening in the single transverse plate, said at least one opening spaced away from an end face of the downstream filter plug segment by at least about 1 mm; andan air-admissing ventilating zone superposed with the downstream filter plug segment.
  • 10. The filter of claim 9, wherein said upstream filter plug segment and said downstream filter plug segment comprise material of low particulate efficiency.
  • 11. The filter of claim 10, wherein said single transverse plate comprises a plurality of openings disposed circumferentially about said single transverse plate.
  • 12. The filter of claim 11, wherein the flow constricting segment comprises a plurality of orifices, wherein each of the plurality of orifices has a diameter of about 0.2 mm to 0.6 mm.
  • 13. The filter of claim 12, wherein at least one of said upstream filter plug segment and said downstream filter plug segment comprises cellulose acetate tow of low denier.
  • 14. A filter for a smoking article comprising: an upstream filter plug segment at an upstream end portion of the filter;a downstream filter plug segment at a downstream end portion of the filter, said upstream filter plug segment and said downstream filter plug segment comprising material of low particulate efficiency comparable to that achieved by cellulose acetate of about 8.0 denier per filament and about 35,000 total denier;a flow constricting segment consisting of a tubular portion, a single transverse plate, an upstream cavity and a downstream cavity, said upstream cavity and said downstream cavity having an equal volume and defined by said tubular portion and said single transverse plate, said flow constricting segment provided at a location adjacent said downstream filter plug segment, said flow constricting segment comprising a plurality of openings in said single transverse plate, each of said openings having a diameter of about 0.2 mm to about 0.6 mm, said openings disposed circumferentially about said single transverse plate of said flow constricting segment, said flow constricting segment being spaced from an end face of the downstream filter plug segment by about 1 mm to about 3 mm such that said flow constricting segment operable to cause impaction of particulates during smoking on said end face; andan air-admissing ventilating zone superposed with the downstream filter plug segment.
  • 15. The smoking article of claim 1, wherein said flow restricting segment comprises a cellulosic foam material.
  • 16. The smoking article of claim 1, wherein the single transverse plate is planar.
CROSS REFERENCE TO RELATED APPLICATION

This application claims priority under 35 U.S.C. §119(e) to U.S. provisional Application No. 60/830,093, filed on Jul. 12, 2006, the entire content of which is incorporated herein by reference.

US Referenced Citations (168)
Number Name Date Kind
2511898 Brothers Jun 1950 A
2547119 Henderson Apr 1951 A
2592554 Frankenburg Apr 1952 A
2598680 Frankenburg Jun 1952 A
2764513 Brothers Sep 1956 A
2769734 Bandel Nov 1956 A
2954772 Lebert Oct 1960 A
2954778 Lebert Oct 1960 A
2954783 Lebert Oct 1960 A
2954786 Lebert Oct 1960 A
2592553 Frankenburg et al. Apr 1962 A
3098492 Wurzburg et al. Jul 1963 A
3234949 White et al. Feb 1966 A
3236244 Irby, Jr. et al. Feb 1966 A
3255760 Selke Jun 1966 A
3283762 Kissel Nov 1966 A
3292635 Kolodny Dec 1966 A
3318312 Curtis, Jr. May 1967 A
3323525 Miller Jun 1967 A
3356094 Ellis et al. Dec 1967 A
3389705 Levavi Jun 1968 A
3395713 Ent-Keller Aug 1968 A
3441028 Wall Apr 1969 A
3457927 Siragusa Jul 1969 A
3496945 Tomkin Feb 1970 A
3504677 Doppelt Apr 1970 A
3581748 Cameron Jun 1971 A
3599646 Berger et al. Aug 1971 A
3630210 Haslam Dec 1971 A
3637447 Berger et al. Jan 1972 A
3646941 Doppelt Mar 1972 A
3648712 Patterson Mar 1972 A
3685522 Kleinhans Aug 1972 A
3738375 Doumas Jun 1973 A
3756249 Selke et al. Sep 1973 A
3759270 Wright Sep 1973 A
3860011 Norman Jan 1975 A
3877470 Jewett et al. Apr 1975 A
3931824 Miano et al. Jan 1976 A
3968804 Kelly et al. Jul 1976 A
3986515 Egri Oct 1976 A
4016887 Uroshevich Apr 1977 A
4022222 Berger May 1977 A
4038994 Aikman Aug 1977 A
4091821 Scorzo May 1978 A
4119105 Owens, Jr. Oct 1978 A
4120310 Lee et al. Oct 1978 A
4135523 Luke et al. Jan 1979 A
4158364 Ligeti Jun 1979 A
4182349 Selke Jan 1980 A
4186756 Takemoto et al. Feb 1980 A
4197863 Clayton et al. Apr 1980 A
4256122 Johnson Mar 1981 A
4256126 Seligman et al. Mar 1981 A
4273141 Jan Van Tilburg Jun 1981 A
4292983 Mensik Oct 1981 A
4340072 Bolt et al. Jul 1982 A
4341228 Keritsis et al. Jul 1982 A
4343319 Cantrell Aug 1982 A
4357950 Berger Nov 1982 A
4380241 Horsewell Apr 1983 A
4386618 Cantrell Jun 1983 A
4421126 Gellatly Dec 1983 A
4460001 Browne et al. Jul 1984 A
4469112 Browne et al. Sep 1984 A
4506683 Cantrell et al. Mar 1985 A
4508525 Berger Apr 1985 A
4515170 Cantrell et al. May 1985 A
4542755 Selke et al. Sep 1985 A
4559955 Brockway et al. Dec 1985 A
4564030 Jessup et al. Jan 1986 A
4574820 Pinkerton et al. Mar 1986 A
4585015 Silberstein Apr 1986 A
4617946 Keith Oct 1986 A
4620553 Bale et al. Nov 1986 A
4622982 Gaisch et al. Nov 1986 A
4637409 Berger Jan 1987 A
4646762 Riehl et al. Mar 1987 A
4649944 Houck, Jr. et al. Mar 1987 A
4660579 Horsewell et al. Apr 1987 A
4677992 Bliznak Jul 1987 A
4687008 Houck, Jr. et al. Aug 1987 A
4700726 Townsend et al. Oct 1987 A
4702263 Strydom Oct 1987 A
4732168 Resce et al. Mar 1988 A
4754766 Luke et al. Jul 1988 A
4784632 Berger Nov 1988 A
4791943 Kupper et al. Dec 1988 A
4793365 Sensabaugh et al. Dec 1988 A
4867182 Roberts et al. Sep 1989 A
4896682 Liew Jan 1990 A
4924886 Litzinger May 1990 A
4942887 Abdelgawad et al. Jul 1990 A
4949736 Roberts et al. Aug 1990 A
4962774 Thomasson et al. Oct 1990 A
4972853 Brackmann et al. Nov 1990 A
4972854 Kiernan et al. Nov 1990 A
4984588 Stewart, Jr. Jan 1991 A
5046514 Bolt Sep 1991 A
5050621 Creighton et al. Sep 1991 A
5058608 Henning et al. Oct 1991 A
5060676 Hearn et al. Oct 1991 A
5074319 White et al. Dec 1991 A
5099864 Young et al. Mar 1992 A
5101839 Jakob et al. Apr 1992 A
5105836 Gentry et al. Apr 1992 A
5105838 White et al. Apr 1992 A
5129408 Jakob et al. Jul 1992 A
5152304 Bokelman et al. Oct 1992 A
5178166 Newsome et al. Jan 1993 A
5190061 Brackmann et al. Mar 1993 A
5203354 Hickle Apr 1993 A
5360023 Blakley et al. Nov 1994 A
5392792 Banerjee et al. Feb 1995 A
5392793 Molloy Feb 1995 A
5435326 Gentry et al. Jul 1995 A
5458107 Balogh et al. Oct 1995 A
5524647 Brackmann Jun 1996 A
5533530 Young et al. Jul 1996 A
5568819 Gentry et al. Oct 1996 A
5584306 Beauman et al. Dec 1996 A
5598868 Jakob et al. Feb 1997 A
5666976 Adams et al. Sep 1997 A
5690127 Chapman et al. Nov 1997 A
5709227 Arzonico et al. Jan 1998 A
5715844 Young et al. Feb 1998 A
5724998 Gellatly et al. Mar 1998 A
5727571 Meiring et al. Mar 1998 A
5743251 Howell et al. Apr 1998 A
5746230 Arterbery et al. May 1998 A
5817159 Cahill et al. Oct 1998 A
5839449 Banerjee et al. Nov 1998 A
5954061 Cardarelli Sep 1999 A
5979459 Schneider Nov 1999 A
6062228 Loercks et al. May 2000 A
6089238 Schneider et al. Jul 2000 A
6216706 Kumar et al. Apr 2001 B1
6257242 Stavridis Jul 2001 B1
6345625 Chew Feb 2002 B1
6502580 Luparini Jan 2003 B1
6718989 Clarke et al. Apr 2004 B1
6761174 Jupe et al. Jul 2004 B2
6779529 Figlar et al. Aug 2004 B2
6814786 Zhuang et al. Nov 2004 B1
6823873 Nichols et al. Nov 2004 B2
6883516 Hindle et al. Apr 2005 B2
6883523 Dante Apr 2005 B2
20020166561 Sinclair, Jr. Nov 2002 A1
20030200973 Xue et al. Oct 2003 A1
20030200976 Yoo Oct 2003 A1
20040025890 Yen Feb 2004 A1
20040159327 Dante Aug 2004 A1
20040261807 Dube et al. Dec 2004 A1
20050066981 Crooks et al. Mar 2005 A1
20060201524 Zhang et al. Sep 2006 A1
20070169785 Gedevanishvili et al. Jul 2007 A1
20070181140 Xue et al. Aug 2007 A1
20070186945 Olegario et al. Aug 2007 A1
20070235050 Li et al. Oct 2007 A1
20070261706 Banerjea et al. Nov 2007 A1
20080035162 Braunshteyn et al. Feb 2008 A1
20080047571 Braunshteyn et al. Feb 2008 A1
20080163877 Zhuang et al. Jul 2008 A1
20080216848 Li et al. Sep 2008 A1
20080216850 Li et al. Sep 2008 A1
20080216851 Olegario et al. Sep 2008 A1
20080216853 Li et al. Sep 2008 A1
20100288293 Slasli et al. Nov 2010 A1
Foreign Referenced Citations (36)
Number Date Country
679657 Oct 1966 BE
1000454 Dec 1988 BE
3439861 May 1985 DE
0 054 705 Jun 1982 EP
0077123 Apr 1983 EP
0101840 Mar 1984 EP
0212879 Mar 1987 EP
0 327 655 Aug 1989 EP
0364256 Apr 1990 EP
471581 Feb 1992 EP
0482872 Apr 1992 EP
0568107 Nov 1993 EP
0481596 Jan 1994 EP
2481581 Nov 1981 FR
2873899 Feb 2006 FR
1058342 Feb 1967 GB
1228747 Apr 1971 GB
1236344 Jun 1971 GB
1245518 Sep 1971 GB
1256154 Dec 1971 GB
1256154 Dec 1971 GB
1428018 Mar 1976 GB
2100573 Jan 1983 GB
2149287 Jun 1985 GB
2177890 Feb 1987 GB
19697 Nov 1983 NZ
216244 Sep 1989 NZ
WO 9009741 Sep 1990 WO
WO 9926495 Jun 1999 WO
WO 0000047 Jan 2000 WO
WO 0113745 Mar 2001 WO
WO 0203819 Jan 2002 WO
WO 2006070289 Jul 2006 WO
WO2006082529 Aug 2006 WO
WO2007093757 Aug 2007 WO
WO2007110650 Oct 2007 WO
Non-Patent Literature Citations (34)
Entry
International Preliminary Report on Patentability issued Jan. 13, 2009 for PCT/IB2007/002910.
International Search Report and Written Opinion dated Jan. 24, 2008 for PCT/IB2007/002910.
International Preliminary Report on Patentability issued Jan. 13, 2009 for PCT/IB2007/002869.
International Search Report and Written Opinion dated Jan. 25, 2008 for PCT/IB2007/002869.
International Search Report and Written Opinion mailed Jan. 27, 2009 for PCT/IB2008/001348.
International Preliminary Report on Patentability issued Sep. 15, 2009 for PCT/IB2008/001348.
New Zealand Examination Report cited in New Zealand Patent Application No. 573730, Jul. 8, 2010.
International Search Resort and Written Opinion dated Oct. 7, 2008 for PCT/1B2008/001382.
International Preliminary Report on Patentability issued Sep. 15, 2009 for PCT/IB2008/001382.
International Preliminary Report on Patentability issued Feb. 10, 2009 for PCT/IB2007/003165.
New Zealand Examination Report cited in New Zealand Patent Application No. 571453, Mar. 10, 2010.
International Search Report and Written Opinion dated Mar. 26, 2008 for PCT/IB2007/003165.
U.S. Appl. No. 12/576,922, filed Oct. 9, 2009.
U.S. Appl. No. 12/782,443, filed May 18, 2010.
International Search Report mailed Sep. 13, 2010 for International Application No. PCT/EP2010/003016.
Written Opinion dated Aug. 5, 2004 for International Application No. PCT/US04/04530.
International Search Report dated Aug. 5, 2004 for PCT/US04/04530.
International Search Report dated Oct. 19, 2007 for International Application No. PCT/IB2006/004202.
Written Opinion dated Oct. 19, 2007for International Application No. PCT/IB2006/004202.
Invitation to Pay Additional Fees and Annex to Form PCT/ISA/206 Communication Relating to the Results of the Partial International Search dated Oct. 16, 2007 for International Application No. PCT/IB2006/004209.
International Search Report and Written Opinion dated Mar. 17, 2008 for PCT/IB2006/004209.
International Preliminary Report on Patentability dated Jul. 10, 2008 for PCT/IB2006/004202.
International Preliminary Report on Patentability dated Jul. 10, 2008 for PCT/IB2006/004209.
International Search Report and Written Opinion dated Sep. 19, 2008 for PCT/IB2007/004503.
International Preliminary Report on Patentability mailed Jul. 9, 2009 for PCT/IB2007/004503.
International Preliminary Report on Patentability mailed Sep. 24, 2009 for International Application No. PCT/IB2008/001372.
International Search Report and Written Opinion dated Nov. 3, 2008 for PCT/IB2008/001372.
International Preliminary Report on Patentability for PCT/IB2007/004224 dated May 19, 2009.
International Preliminary Report on Patentability for PCT/GB2007/001144 dated Sep. 30, 2008.
International Search Report and Written Opinion for PCT/IB2007/004224 dated Jun. 13, 2008.
International Search Report and Written Opinion for PCT/GB2007/00114 dated Jul. 7, 2007.
International Preliminary Report on Patentability mailed Sep. 15, 2009 for PCT/IB2008/001383.
International Search Report and Written Opinion mailed Feb. 24, 2009 for PCT/IB2008/001383.
Partial International Search Report mailed Nov. 11, 2008 for PCT/IB2008/001383.
Related Publications (1)
Number Date Country
20080017204 A1 Jan 2008 US
Provisional Applications (1)
Number Date Country
60830093 Jul 2006 US