The present invention relates to a solar cell module and a method of manufacturing the same.
In recent years, spreading and expansion of a solar cell module has advanced in view of environmental protection. In general, a solar cell module is obtained by providing, in an order from a light receiving surface side, a translucent substrate, a solar cell element string (a solar cell string) having a periphery protected by a sheet-like filler formed by a transparent thermosetting resin or the like, and a back surface protecting member for protecting a back surface, and integrating them. In particular, a solar cell element containing silicon is often used because of high power generation efficiency. The solar cell string is formed by bonding an electrode provided on one of solar cell elements to an electrode of the other solar cell element which is adjacent to the one solar cell element with a conductor wire that is a wiring member through a solder, thereby connecting them electrically.
In some cases in which the solder is cooled after the bonding, however, a thermal stress is caused by a difference in a coefficient of thermal expansion between the solar cell element and the conductor wire so that a warpage occurs over the solar cell element. Particularly, in the case of a solar cell string in which main surfaces on the same side of the adjacent solar cell elements to each other, for example, non-light receiving surfaces that are back surfaces are bonded to each other through a conductor wire and the conductor wire is not disposed on the light receiving surface side, a warpage causing the light receiving surface side to be convexed as seen on a section taken in a longitudinal direction of the conductor wire is likely to occur in the solar cell element. In the case where the solar cell module is constituted by using the solar cell string including the solar cell element having such a warpage, a stress is applied to the bonding portion of the solar cell element and the conductor wire so that the bonding portion is cracked or broken. As a result, there is a possibility that an output of the solar cell module might be reduced.
Japanese Patent Application Laid-Open No. 2007-250623 proposes a method of locally decreasing a sectional area of a conductor wire, thereby relieving a thermal stress to reduce a warpage. In the case where the conductor wire is provided only on the main surface at the same side in the solar cell element, for example, the back surface, however, the warpage cannot be sufficiently reduced through this method.
The present invention has been made in view of the above problems, and an object thereof is to provide a solar cell module in which a stress of a solar cell string is relieved, and a method of manufacturing the same.
According to the present invention, a solar cell module includes a plurality of solar cell elements, each including a light receiving surface and a back surface positioned on a back side of the light receiving surface, and a plurality of conductor wires, each connecting one of the solar cell elements to any of the solar cell elements which is adjacent thereto and including connecting portions to be connected to one surface of one of the solar cell elements, wherein the plurality of solar cell elements have a convex shape toward the light receiving surface side in a perpendicular section to a longitudinal direction of the connecting portions.
According to the solar cell module of the present invention, a stress to be applied to a bonding portion of the solar cell element and the conductor wire is relieved, and it is possible to suitably decrease an occurrence of a crack or breakage in the bonding portion, and furthermore, a reduction in an output of the solar cell module.
Moreover, according to the present invention, a method of manufacturing a solar cell module includes a first step of electrically connecting, through a conductor wire, adjacent two solar cell elements among a plurality of solar cell elements each including a light receiving surface and a back surface positioned on a back side of said light receiving surface, and a second step of supporting said plurality of solar cell elements to be connected with a support member from a back surface side of the plurality of connected solar cell elements and continuously pressing in a longitudinal direction of the conductor wire by a pressing member from a light receiving surface side of the solar cell element.
According to the method of manufacturing a solar cell module in accordance with the present invention, the solar cell element planarized in the longitudinal direction of the conductor wire in the second step is used to constitute a solar cell string or a solar cell module. Therefore, a crack can be reduced suitably from occurring in the manufacturing process. Moreover, alignment precision in the solar cell string can be enhanced. In addition, in the solar cell module thus obtained, a stress to be applied to the bonding portion of the solar cell element and the conductor wire is relieved. Therefore, it is possible to suitably decrease an occurrence of a crack or breakage in the bonding portion, and furthermore, a reduction in an output.
A solar cell module and a method of manufacturing the same according to the present invention will be described below with reference to the accompanying drawings.
(Solar Cell Module)
As shown in
If the translucent substrate 1 is a member capable of causing light to be incident on the solar cell element 5, a material thereof is not particularly restricted. For example, a substrate having a high light transmittance and formed by a glass such as a white plate glass, a strengthened glass, a double strengthened glass or a heat reflecting glass, a polycarbonate resin or the like may be used as the translucent substrate 1. For example, it is preferable that a white plate strengthened glass having a thickness of approximately 3 mm to 5 mm or a synthetic resin substrate (formed by a polycarbonate resin or the like) having a thickness of approximately 5 mm be used as the translucent substrate 1.
The filler 2 serves to seal the solar cell element 5. For example, an organic compound containing, as a principal component, an ethylene vinyl acetate copolymer (EVA) or polyvinyl butyral (PVB) is used as the filler 2. More specifically, the organic compound is formed into a sheet having a thickness of approximately 0.4 to 1 mm by means of a T-die and an extruder, and the sheet is cut in an appropriate size, and a product thus obtained is used as the filler 2. The filler 2 may contain a crosslinking agent. The crosslinking agent serves to couple molecules such as the EVA. An organic peroxide for generating a radical through decomposition at a temperature of 70° C. to 180° C. can be used as the crosslinking agent, for example. Examples of the organic peroxide include 2,5-dimethyl-2,5-bis(t-butylperoxy)hexane, tert-hexylperoxypivalate, and the like. In the case where the EVA is used for the filler 2, it is preferable that the crosslinking agent be contained in a rate of approximately 1 part by mass with respect to 100 parts by mass of the EVA. In addition to the EVA and the PVB, it is possible to suitably utilize, as the filler 2, a thermosetting resin or a resin obtained by causing the thermoplastic resin to contain the crosslinking agent and to have a thermosetting characteristic. For example, an acryl resin, a silicone resin, an epoxy resin, EEA (an ethylene-ethyl acrylate copolymer) and the like can be utilized as the filler 2.
The back surface protecting member 4 serves to protect the filler 2 and the solar cell element 5. For the back surface protecting member 4, it is possible to use PVF (polyvinyl fluoride), PET (polyethylene terephthalate), PEN (polyethylene naphthalate), or a product obtained by laminating them.
As the solar cell element 5, for example, a back contact type such as a metal wrap through structure or an emitter wrap through structure is suitably used. In the present embodiment, as an example, description will be given to the case where the solar cell element 5 having the metal wrap through structure is used. In the solar cell element 5, moreover, the light receiving surface is indicated as 5b and the back surface is indicated as 5a.
The solar cell element 5 has a structure in which a PN junction of a P layer containing a P-type impurity such as boron in a large quantity and an N layer containing an N-type impurity such as phosphorus in a large quantity is provided in a single crystal silicon substrate or a polycrystalline silicon substrate, and an electrode formed of silver or aluminum (a collecting electrode 51, an output electrode 53, or the like) is disposed on a light receiving surface and/or a back surface of the silicon substrate.
For example, as the single crystal silicon substrate or the polycrystalline silicon substrate, there is used a rectangular shape substrate which is cut out through slicing processing from an ingot, having a thickness of approximately 0.1 mm to 0.3 mm and a size of approximately 150 mm to 160 mm square. Such a silicon substrate can be formed by using a silicon material having a purity of 6 N to 11 N, for example. Moreover, the electrode is formed by using a conductive paste such as a silver paste or an Al paste through a screen printing method or the like.
In the case of the solar cell element 5 shown in
In the case where a bus bar electrode is not provided on the light receiving surface as in the solar cell element 5 shown in
The conductor wire 6 is a member formed by cutting, in an appropriate length, a product obtained by solder coating in a thickness of approximately 20 μm to 70 μm by means of plating or dipping over a surface of a metallic conductor having a low resistance such as copper or aluminum. Since the conductor wire 6 is formed of metal, it has ductility. For the metallic conductor, it is also possible to use a clad copper foil having a structure of copper/invar/copper. In this case, a coefficient of thermal expansion of the conductor wire 6 approximates to that of silicon, whereby the warpage of the solar cell element 5 can be reduced.
The conductor wire 6 is connected to one of the surfaces of the solar cell element and is led out to cross one of the sides which corresponds to an end of the surface. The conductor wire 6 connects output electrodes having different polarities in two adjacent solar cell elements 5 which are adjacent to each other in the solar cell string 3. In other words, the conductor wire 6 is disposed to connect an output electrode 53a of one solar cell element to an output electrode 53b of the other solar cell element. Moreover, as shown in
The conductor wire 6 may have a uniform and long shape with no concavo-convex portion, or, as shown in
The longitudinal direction of the connecting portion is a direction in which a distance from an end to another end of the connecting surface is the greatest. In other words, in the present specification, the longitudinal direction of the connecting portion represents a crossing direction from an end of the conductor wire in the connecting portion toward a crossing portion where the conductor wire crosses one of the sides of the solar cell element.
Furthermore, it is preferable that each of the solar cell elements 5 in the solar cell string 3 have a convex shape toward the light receiving surface 5b side in the perpendicular section to the longitudinal direction of the connecting portion and that a maximum distance (hereinafter referred to as a first maximum distance) in a thickness direction from the back surface 5a toward the light receiving surface 5b in the perpendicular section to the longitudinal direction of the connecting portion is greater than a maximum distance (hereinafter referred to as a second maximum distance) in the thickness direction in the section along the longitudinal direction of the connecting portion. The maximum distance in the thickness direction indicates a perpendicular distance from a lowermost end to an uppermost end as seen in cross-section for each section of the solar cell element 5.
With such a structure, height positions of the connecting portions of the two adjacent solar cell elements are almost equal to each other so that a separation of the connecting portion can be reduced from being caused by a difference in the height position.
More specifically, a maximum distance d1 in a thickness direction is shown in the perpendicular section to the array direction of the solar cell element 5 schematically illustrated in
Further, it is preferable that the distance d2 be equal to or smaller than 20 times as much as the thickness of the solar cell element.
Consequently, it is possible to reduce a generation of a stress to be applied to the solar cell element in the solar cell module.
Further, it is preferable that the distance d1 be 21 to 40 times as much as the thickness of the solar cell element.
Consequently, it is possible to reduce the generation of the stress to be applied to the solar cell element in the solar cell module.
Further, it is preferable that a rate d1/d2 of the distance d1 to the distance d2 be 1.5 to 20.
Consequently, it is possible to stabilize a balance of a warpage in X and Y directions while maintaining a relationship of d1>d2.
In the case where the solar cell module X (which is referred to as a solar cell module Xb) constituted by using the solar cell string 3 having the shape shown in
Moreover, for comparison,
By comparing the solar cell string 3a used in the solar cell module Xc with the solar cell string 3 used in the solar cell modules Xa and Xb illustrated in
It is more preferable that the solar cell element 5 of the solar cell string 3 constituting the solar cell module X have a convex shape toward the light receiving surface 5b side in the perpendicular section to the longitudinal direction of the conductor wire 6 in a low temperature environment, as described above, but have a convex shape toward the back surface 5a side in a perpendicular section to the array direction in a high temperature environment. In the present embodiment, it is assumed that a low temperature indicates a relatively low temperature range including at least −10° C., a high temperature indicates a relatively high temperature range including at least 80° C., and an ordinary temperature indicates a temperature range between both of them. This can be implemented by causing the solar cell element 5 to include the output electrode 53 formed of Al, for example. In this case, the solar cell string 3 maintains the shape shown in
Note that the invention is not restricted to the embodiment described above, but the case of a protrusion toward a back side is included if an internal stress applied by an electrode or a conductor wire at the back side is higher than that at the light receiving surface side, and a pressing direction in the following manufacturing method is also changed correspondingly as necessary.
(Method of Manufacturing Solar Cell Module)
A method of manufacturing the solar cell modules X (Xa, Xb) according to the present embodiment will be described with reference to
First of all, as a first step, the solar cell element 5 and the conductor wire 6 are bonded to each other as shown in
The output electrode 53a or the output electrode 53b and the conductor wire 6 are bonded to each other through a solder. In other words, a heated and molten solder is provided between the output electrode 53a or the output electrode 53b and the conductor wire 6, and this solder is then cooled so that the output electrode 53a or the output electrode 53b and the conductor wire 6 are bonded to each other.
After the bonding, as shown in
Therefore, in the present embodiment, in order to eliminate or reduce the warpage occurring in the array direction in the solar cell element 5 constituting the solar cell string 3 prior to the formation of the solar cell module X, the light receiving surface 5b side of the solar cell string 3 is continuously pressed by means of a rotating member from one end side toward the other end side in the longitudinal direction of the conductor wire 6 to carry out processing for applying a bending stress as a second step.
As shown in
The base 71 can mount the solar cell string 3 thereon in the longitudinal direction of the conductor wire 6. The solar cell string 3 is mounted in such a manner that the light receiving surface 5b is turned upward.
The first elastic member 72 is a member which is provided to mainly abut on the conductor wire 6 in a state where the solar cell string 3 is mounted in the manner described above. As shown in
The pressing roller 73 is a substantially cylindrical member and has a central shaft 73a supported by a bearing portion 75a provided on the moving means 75. The pressing roller 73 is rotated around the central shaft 73a when a rotating force along an outer periphery thereof is applied. In other words, the pressing roller 73 is a rotor. The pressing roller 73 can be moved in a vertical direction (a z-axis direction) and a horizontal direction (an x-axis direction) along the base 71 by means of the moving means 75.
The second elastic member 74 is a member which is provided around the pressing roller 73 to abut on the solar cell string 3 in an upper position of the conductor wire 6 when the pressing roller 73 presses the solar cell string 3. As shown in
For the first elastic member 72 and the second elastic member 74, it is suitable to use a member having a rubber hardness of approximately 5 to 25. In this case, a bending stress is distributed and applied to the solar cell string 3. Furthermore, it is possible to use a material having an excellent abrasion resistance further suitably. As a specific material, for example, a foam product such as silicone rubber, fluororubber, or urethane rubber is suitable.
The rubber hardness can be measured in accordance with JIS-K6523.
In the second step using the processing apparatus 70 having such a structure, first of all, the solar cell string 3 is mounted on the base 71 in such a manner that the light receiving surface 5b is turned upward and the conductor wire 6 abuts on the first elastic member 72 as shown in
In the state in which the pressing roller 73 carries out the pressing, the solar cell element 5 and the conductor wire 6 which constitute the solar cell string 3 are deformed so at to be is convexed toward the back surface 5a side as shown in
More specifically, as shown in
Moreover, in the second step, the pressing force from the pressing roller 73 is applied as a distributed load Fl to only the bonding portion of the conductor wire 6 and the solar cell element 5 and the vicinity thereof as shown in
Meanwhile,
On the other hand, in the present embodiment, a load is rarely applied to portions other than the bonding portion of the solar cell element 5 and the conductor wire 6 upon the pressing by the pressing roller 73, and the first elastic member 72 is deformed to cover the conductor wire 6 as shown in
The solar cell string 3 is not directly pressed between the base 71 and the pressing roller 73 but is pressed through the first elastic member 72 and the second elastic member 74. It is advantageous in that the stress concentration on a part of the solar cell element 5 is reduced to distribute the stress.
More specifically, by pressing the solar cell string 3 through the first elastic member 72 and the second elastic member 74 as shown in
Moreover, as shown in
As a result of the processing by using the processing apparatus 70, the solar cell string 3 has the shape shown in
Further, in the solar cell module, it is preferable that at least one of the at least one first conductor wire and the at least one second conductor wire have a connecting portion to be connected to the back surface of the solar cell element and a non-connecting portion which is not connected thereto, and an angle between the connecting portion and the non-connecting portion should be greater than 90 degrees.
Consequently, the conductor wire 6 is likely to be deformed along the concavo-convex portions.
In addition, it is preferable that the solar cell module have the plurality of conductor wires formed by a clad copper foil.
Consequently, it is also possible to cause a coefficient of thermal expansion of a core member in the conductor wire 6 to approximate to that of ceramic. Thus, it is possible to reduce a warpage.
Moreover, in the solar cell module, it is preferable that the solar cell element have a rectangular shape and the plurality of conductor wires be parallel with one of the sides of the solar cell element.
Consequently, it is possible to wholly cause a warpage in a certain direction.
Further, in the solar cell module, it is preferable that the at least one first conductor wire and the at least one second conductor wire be positioned alternately.
Consequently, it is possible to wholly cause a warpage in a certain direction.
In addition, the solar cell module can also be applied to the case in which, among the plurality of solar cell elements, two adjacent solar cell elements are connected electrically at the light receiving surface of one solar cell element and at the other back surface of the other solar cell element through each of the plurality of conductor wires.
Then, the solar cell string 3 is subjected to the step of laminating the translucent substrate 1, the light receiving surface side filler 2a, the non-light receiving surface side filler 2b, and the back surface protecting member 4 and heating, and pressurizing the laminated body thus obtained, thereby melting the filler 2. Thus, the solar cell module X which is wholly integrated as shown in
On the other hand, if the solar cell string 3a is laminated as is on the filler 2 and the other members, four corner portions of the solar cell element 5 may be caught on the filler 2 and a load is likely to be generated in the corner portions. As a result, the occurrence of the crack in the solar cell element 3 or the bend of the conductor wire 6 is likely to be caused upon the heating and pressurization of the filler 2, which is not preferable.
Moreover, even if the conductor wire 6 is extended to planarize the solar cell string 3a in the array direction of the solar cell element 5 upon the heating and pressurization for the integration, the solar cell string 3 is hardly extended evenly and flatly and the crack is likely to occur in the solar cell element 5, which is not preferable. This is because the solar cell elements 5 are connected to each other through the conductor wire 6, while the solar cell element 5 is curved in the longitudinal direction of the conductor wire 6.
As compared with this, referring to the manufacturing method according to the present embodiment, the solar cell string 3 planarized in the longitudinal direction of the conductor wire 6 in advance through the second step is used to constitute the solar cell module X. Preferably, the solar cell module X is constituted by using the solar cell string 3 including the solar cell element 5 having a convex shape toward the light receiving surface 5b side and having the first maximum distance d1 which is greater than the second maximum distance d2. Thus, it is possible to suitably reduce the occurrence of the crack or the like in such a manufacturing process.
<Method of Verifying Shape of Solar Cell Element in Solar Cell Module>
It is possible to verify, by disassembling an actual product, that each of the solar cell elements 5 in the solar cell string 3 has a protruded shape toward the light receiving surface 5b side in the longitudinal direction of the conductor wire 6 in the solar cell module X according to the embodiment of the present invention. For example, it is possible to carry out the verification by dissolving the filler 2 of the solar cell module X to take out the solar cell string 3 by the following method.
First of all, the back surface protecting member 4 is cut in. The cut-in processing may be carried out by a manual work using a cutter, a disc type cutter, a laser cutter, or the like, but more preferably carried out by using an automatic machine of a disc type cutter, a disc type grindstone, or a laser cutter. Accordingly, it is possible to quicken a penetration of an organic solvent, thereby shortening a time required for collecting the solar cell string 3.
Then, a vessel having such a size that the whole solar cell module X can be put in at least a horizontal condition is filled with the organic solvent for decomposing the filler 2, and furthermore, the solar cell module X is immersed in the vessel. For the organic solvent, it is possible to use d-limonene, xylene, toluene, or the like. The organic solvent may be maintained at an ordinary temperature, however, by raising the temperature to 80° C. to 100° C., it is possible to quicken the dissolution of the filler 2, thereby shortening a time required for the decomposition. By immersing the solar cell module X for approximately 24 hours if the organic solvent is maintained at the ordinary temperature, and immersing for approximately one to two hours if the organic solvent is heated to 80° C. to 100° C., the filler 2 is dissolved, and thus, the solar cell string 3 can be taken out.
The shape of the solar cell string 3 thus taken out can be measured by an apparatus for measuring a shape of a three-dimensional curved surface by means of a laser, for example. In addition, it is also possible to measure the shape by putting the solar cell string 3 on a platen, and measuring a lift from the platen by means of a caliper and carrying out plotting. By these techniques, the shape of the solar cell string 3 is specified and the solar cell element 5 is confirmed to have the wavy shape shown in the embodiment described above.
Alternatively, it is also possible to specify the warpage shapes of the solar cell element 5 and the solar cell string 3 by focusing observed light in a plurality of places of the light receiving surface 5b in the solar cell element 5 from an outside of the solar cell module X, measuring a focal depth in the respective places, and plotting a spatial change thereof by means of an optical observing device such as an optical microscope.
Number | Date | Country | Kind |
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2009-018414 | Jan 2009 | JP | national |
2009-198435 | Aug 2009 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2010/051293 | 1/29/2010 | WO | 00 | 8/16/2011 |