FIELD OF THE INVENTION
This invention relates to solar cells and more particularly the use of double groove diffraction grating to couple a first order component of normal incident light into and/or from the light-absorbing layer.
BACKGROUND OF THE INVENTION
In our co-pending application for U.S. patent Ser. No. 12/831,587, “Solar Cell Assembly with Diffraction Gratings”, filed Jul. 7, 2010, we disclosed the use of a diffraction grating in combination with dye sensitized and organic solar cells wherein the diffraction grating is structured to couple a first order diffraction component of normal incident light into an absorbing layer. In general, the combination enhances the efficiency of dye sensitized and/or organic absorbent-type solar cells.
The diffraction gratings as disclosed in our co-pending application are “single groove” diffraction gratings; i.e., gratings of the binary type having a single periodicity and an asymmetrical pattern of even groove width and spacing between the grooves of the diffraction grating.
SUMMARY OF THE PRESENT INVENTION
In accordance with our present invention, further enhancements in the operation of solar cells including solar cells of the dye sensitized and organic types, are realized through the use of double groove diffraction gratings; i.e., asymmetrical diffraction gratings with periodically arranged sets of adjacent grooves wherein each groove set comprises both a narrow groove and, adjacent thereto, a second groove of greater width. Both grooves are filled with TiO2 or an equivalent material in a transparent substrate layer such as glass. Through this arrangement, we are able to perform a number of performance enhancing functions including the selective coupling of only first order diffraction components into the absorbing layer in such a way as to cause multiple excursions of the coupled-in light, through the absorbing layer. In the various arrangements described herein, the solar cell may be transparent or reflective and the gratings may be applied on either the front or back side of the absorbing layer or both. Where total reflectivity is desired, a front side grating is used in combination with a back side metallic layer as hereinafter described in greater detail.
BRIEF SUMMARY OF THE DRAWINGS
The description herein makes reference to the accompanying drawings wherein like reference numerals refer to like parts throughout the several views and wherein:
FIG. 1 is a side sectional view of a dye sensitized solar cell having a double groove grating on the front or incident light side;
FIG. 2 is a sectional view of a second view of a dye sensitized solar cell having a different electrode arrangement;
FIG. 3 is a side sectional view of the construction of an organic solar cell with a double groove grating on the light incident side of the absorbing layer together with an anti-reflection coating on the glass layer;
FIGS. 4A-D show various arrangements of double groove diffraction gratings with solar cell absorbing layers to perform various desirable functions;
FIG. 5 shows diffraction angles of a TiO2 double groove grating at the interface of a glass and SnO2:F electrode from 450 nm to 800 nm as a function of wavelength; and
FIGS. 6A and 6B show the diffraction efficiencies for S-polarization and P-polarization, respectively.
DETAILED DESCRIPTION OF THE ILLUSTRATIVE EMBODIMENT
Referring to FIG. 1, there is shown a dye sensitized solar cell 10 having a double groove grating 24 on the light incident side. Solar cell 10 comprises a positive electrode 12 of SnO2:F and, spaced therefrom, a negative electrode 14 also constructed of SnO2:F. The two electrodes 12, 14 are joined and sealed together by impervious resin walls 16 to define an interior cavity within which is disposed a dye sensitized photoelectrode 18. In this case, the dye sensitized photoelectrode is primarily TiO2 but could also be ZnO. The balance of the cavity formed by the cell is filled with an electrolyte. Platinum particles 20 are bonded to the under surface of the positive electrode 12.
A glass layer 22 is formed on the light incident side of the negative electrode to receive incident light as indicated by the arrow through an anti-reflection grating 23 having a very high periodicity number; i.e., the grooves in the grating 23 are much smaller and closer together than any of the grooves in the grating 24.
The grating 24 is of the “double groove” type in that it comprises an asymmetric and periodic arrangement of groove sets wherein each set comprises regularly spaced narrow grooves 26 adjacent but spaced from wider grooves 28 having the dimensions set forth in our aforementioned co-pending application Ser. No. 12/831,587; i.e., the smaller groove width is 50 nm, the larger groove width is 170 nm, their center-to-center distance is 190 nm, the groove depth is 490 nm and the period is 540 nm. This gives rise to a diffraction angle larger than 30° when the operating wavelength is longer than 540 nm. The double groove grating 24 couples the first order component of normal incident light into the absorbing layer represented by the photoelectrode 18 with a diffraction angle greater than the critical angle of about 30° in the operating wavelength longer than 540 nm such that the first order component is reflected off of the SnO2:F glass interface and back into the cell for multiple transits of the photoelectrode.
In the arrangement shown in FIG. 1, the top glass layer 30 can be replaced with a polymer film or plate and the bottom glass layer 22 can be replaced by a transparent polymer plate. Typical thickness of the glass layers 22, 30 is from 0.5 mm to 5 mm. The material in the grating grooves 26, 28 is typically TiO2 but can be replaced with Ta2O5, ZrO2 or Nb2O5.
Referring to FIG. 2, there is shown a second dye sensitized solar cell 32 comprising a positive electrode 34 of SnO2:F and a negative or “counter” electrode 36 of In2O3:Sn+Pt in association with a side contact 38 for convenience in electrical serialization. The contact 38 is preferably SnO2:F. Sealing resin walls complete the electrolytic chamber along with a top glass layer 42 and bottom glass layer 44 which is formed with the double groove gating 48 on the light incident side of the positive electrode 34. Again, a high periodicity anti-reflection grating 46 is optionally employed.
The absorbing layer further comprises a TiO2+dye electrode 50 and a SiO2 separator 52 which is placed between the dye-sensitized photoelectrode 50 and the counter electrode 36. The double groove diffraction grating 48 follows the structural specification on the grating 24 in FIG. 1 and performs essentially the same function. The material of the counter electrode 36 can also be carbon in which case the platinum content is not needed.
FIG. 3 shows solar cell 54 with an organic absorbing layer 64. The solar cell 54 comprises an electrode 56 of aluminum bonded to the top or “opposite” side of the absorbing layer 64, an iridium tin oxide negative electrode 57 bonded to the light incident side of the absorbing layer 64 and a transparent glass layer 58 bonded to the incident side of the negative electrode 57 and carrying the double groove diffraction grating 60 as well as an anti-reflection grating 62 of high periodicity.
FIGS. 4A through 4D illustrate various arrangements in all of which the light-absorbing layer is represented by reference character 66. In FIG. 4A, there are asymmetric double groove diffraction gratings 68, 70 on both the light incident and opposite sides of the absorbing layer 66, it being understood that these double groove layers are embedded in a glass carrier and consist of one or the other of the materials described above. In FIG. 4A, only the first order component of normal incident light is coupled into the absorbing layer 66 at a diffraction angle greater than the critical angle. When it reaches the opposite side grating 70, it is reflected directly back through the absorbing layer 66 to the input grating 68 where it is again reflected at an angle back to the opposite side where it encounters the grating 70. Because of the order in which the narrow and wide grooves are arranged is the same on both sides, the second encounter with the opposite boundary causes the light component to exit the absorbing layer 66 creating transparency in the solar cell. In short, the absorbing layer 66 is illuminated from the bottom or input side as shown in FIG. 4A and the incident light is diffracted into oblique transmission within the absorbing layer where it is then diffracted into the normal reflection by the top grating and thereafter diffracting into the oblique reflection by the bottom grating 68 to cause the component to exit through the top grating 70 in the normal or “z” direction. The transparency of the solar cell is maintained with optical path enhancement.
In FIG. 4B, the double groove grating 68 is only located on the incident side while a metal layer 72 is deposited or otherwise bonded to the top or opposite side of the absorbing layer 66. The optical path is then doubled as shown by the arrows within the absorbing layer 66. Therefore, the absorbing layer with only one grating enjoys optical path enhancement due to reflection characteristics and a refraction angle which is larger than the critical angle.
In FIG. 4C, the diffraction grating is again on the input side and there is neither grating nor metallic layer on the opposite side of the absorbing layer 66. Accordingly, while there is optical enhancement, there is also transparency in that the normal or “z” direction component exits the absorbing layer 66 with a small lateral shift.
In FIG. 4D, the double groove layer 70 is deposited only on the opposite side of the absorbing layer 66. There is optical enhancement as shown.
FIG. 5 shows diffraction angles of the TiO2 double groove grating at the interface of the glass and SnO2:F electrode as a function of wavelength from 450 nm to 800 nm. The glass has a refractive index of 1.5 while the absorbing layer SnO2:F electrode and electrolyte have a refractive index of approximately 2. The TiO2 material in the grooves of the double groove grating has a refractive index of 2.38.
In FIGS. 6A and 6B, there are shown diffraction efficiencies for S-polarization and P-polarization respectively. S-polarized light is mainly coupled into the first order diffraction component over the entire wavelength range while P-polarized light has a major coupling of the positive first order diffraction component from 450 nm to 661 nm; it then switches to the 0th coupling from 661 nm to 800 nm.
It will be appreciated that the embodiments illustrated in the drawing and described above are exemplary and that implementation of the invention can be carried out in various other configurations.
Patent Application
20120174980
